This study, conducted on August 12th and 13th, 2008 at Fort Riley, Kansas on a clay loam soil, evaluated the terrain impacts of four commonly used tracked and wheeled military vehicles: the M1A1 Abrams Main Battle Tank, M998 High Mobility Multipurpose Wheeled Vehicle, M985 Heavy Expanded Mobility Tactical Truck, and M113 Armored Personnel Carrier. Disturbed width and impact severity were assessed along 14 spirals subjected to a maximum of eight consecutive passes for a total of 696 impact points. Data indicate that multiple passes produce increased vegetative impacts, with multipass coefficients ranging from 0.98 to 4.44 (compared to the commonly accepted value of 2.00) depending on vehicle type and turn severity. The widely-used MPC of 2.00 fits the M985 HEMTT and M113 at sharp turns, with an MPC of 1.00 fitting the straight and intermediate turning conditions of these vehicles, as well as all turning conditions for the M998 HMMWV. For the M1A1, a MPC of 2.00 is suitable for straight paths, a MPC of 3.00 is suitable for intermediate turns, while sharp turns can be represented by a MPC of 4.00. The data suggests that MPCs should be adjusted depending on the vehicle type and according to the turning radius of the vehicle, as tracked vehicles were found to have a higher multipass coefficient than wheeled vehicles, with multipass coefficients increasing with vehicle weight and the sharpness of turns.

Water quality regulators, such as the Tennessee Department of Environment and Conservation, are challenged by data scarcity when identifying surface water quality impairment causes and pollutant sources. Surface water quality model users also seek to identify pollutant sources and design and place best management practices to efficiently improve water quality, but have insufficient data for model calibration. This research documents the design and evaluation of a novel, intensive water quality data collection system consisting of a automatic sampler, bi-weekly grab sampling, and a long term deployment sonde. System design characteristics that were emphasized included a focus on gathering data for common impairment causes (pathogens, siltation, nutrients, and dissolved oxygen-DO) and water quality criteria not currently being evaluated (pH and temperature rate of change and diurnal DO fluctuations). In addition, the system was designed to gather data for watershed model calibration in rural, un-gauged watersheds because agriculture is listed as the predominant source of water quality impairment in Tennessee. Thus, the system was unmanned to reduce labor input, self-powered because of limited access to the electrical grid, provided sample preservation (refrigeration at low pH), and included stage measurement. Two identical prototype systems were installed in adjacent ecoregion 67g watersheds in Greene County, Tennessee: Lick Creek, impaired for pathogens, nutrients, and low DO, and Little Chucky Creek, which is unimpaired and a former ecoregion reference stream. The two primary objectives of this research were to evaluate the system power demand and determine whether a large water quality dataset improved impairment cause and source identification. A 270 watt solar panel power supply ultimately failed at Lick Creek during the summer when the refrigerated sampler cooling demand peaked, but was sufficient at Little Chucky Creek. System power supply design equations are provided, but with optimization the power supply used would likely be sufficient. The data collected did significantly improve insight into impairment cause identification. For example, total phosphorus rather than total nitrogen concentrations and low DO appeared to be a potential cause of impairment at Lick Creek. The system design was reliable and could be used to calibrate watershed models to improve source assessment.

With the increasing demand for biodiesel, the accumulation of byproduct, crude glycerol has become a problem which needs to be solved. Lactic acid is one of the value-added chemical which can be produced from glycerol that has wide uses in food and chemical industry. Although glycerol can be converted to lactic acid with an alkali as the catalyst at high glycerol conversion (100 mol%) and lactic acid yield (around 90 mol%), the high alkalinity would cause severe corrosiveness to a stainless steel reactor. In this study two tasks were performed to convert glycerol to lactic acid with satisfactory conversion and selectivity, and to reduce the corrosiveness of reaction medium. First, CaO was used as solid base catalyst. The highest lactic acid yield achieved was 40.8 mol% with a 97.8 mol% glycerol conversion, when operating at 290°C after 150 min reaction with molar ratio of CaO: glycerol=0.3. Also CaO has advantages such as high lactic acid productivity (3.35 g/(min·L)) and reusability. Meanwhile, CaO can be used as the catalyst for both biodiesel production and the following crude glycerol conversion to lactic acid. Second, for glycerol conversion with NaOH as catalyst, a fed-batch reactor was applied to continuously supply NaOH during reaction process, compensating the OH- neutralized by newly formed lactic acid. The optimal lactic acid yield of 80.5 mol%, with 92.8% glycerol conversion was obtained at 300 °C for 220min, with 1.1 M glycerol initial concentration. A first-order kinetic model for glycerol concentration versus time was developed and verified experimentally under conditions with different initial glycerol concentration and reaction temperature. Although crude glycerol samples contained large amount of impurities, both methods, conversion with solid base catalyst and with fed-batch reactor, were applied successfully to three crude glycerol samples provided by biodiesel manufacturers, and the lactic acid yield reached 52.3 mol% and 72.7 mol% respectively. Finally, the corrosion issue of different methods was compared based on the Fe3+ concentration (analyzed with atomic-absorption spectroscopy) in the products. Both methods of glycerol conversions, with solid base catalyst and fed-batch reactor, can reduce the corrosiveness of glycerol conversion with an alkali as the catalyst.

Eradicating poverty, malnutrition, and the burden of disease have been included as three of the major issues facing the world. The United Nation member countries, having set forth the Millennium Development Goals, have committed themselves to solving these problems. Two major factors which affect solutions to these problems are increasing water stress and implementing improved sanitation. Integration of tilapia aquaculture and reuse of wastewater has been suggested as a solution which addresses both of these factors. The objective of this study is to examine the feasibility, and explore the benefits and drawbacks, to implementing small community wastewater fed (WWF) aquaculture systems in the developing world. The water quality characteristics of treated effluent from nine wastewater treatment (WWT) plants were compiled from other studies. The concentration of total nitrogen in the effluent and the flow rate were of most importance, as they were used to calculate the nitrogen loading at each WWT plant. The nitrogen loading was then used to estimate the total pond size which could be supported by each WWT plant, the expected yearly yield for tilapia, and the percentage of the population who would benefit from provision of protein associated with the integration a fish farming system with the WWT plant. Results show that WWF, semi-intensive tilapia culture can provide 10 grams per day of dietary protein for 11% - 52% of the population of the communities in this study when integrated with a community managed wastewater treatment system. To assess potential risks to human health, associated with WWF aquaculture, the level of fecal coliform (FC) contamination was compared to the standard set by the World Health Organization; less than 105 FC per 100 mL for reuse in fish ponds. The level of FC contamination in the WWT plant effluents ranged from 653 to 1.78 × 105 FC per 100 mL, exceeding this standard. Given the context, the level of fecal coliforms should not rule out integrated reuse and aquaculture as an option. The nutrients found in wastewater are valuable resources in tilapia culture; therefore, allowing their persistence through treatment for reuse, while optimizing wastewater treatment technologies for pathogen removal is an appropriate solution for small communities in developing countries for reducing poverty, malnutrition, and disease burden of waterborne illnesses.

Mature karst topography is well recognized within the hydrology and geology communities to include subterranean fluid pathways that act as turbulent conduits conveying fluid from surface stream sinks called swallets to sources called springs. However, we find that little knowledge has been reported with regards to the transport and fate of terrestrially-derived sediment organic carbon (SOC) within karst watersheds. This study investigated the hypothesis that karst pathways could act as biologically active conveyors of SOC that temporarily store sediment, turnover carbon at higher rates than otherwise considered, and recharge depleted SOC back to the surface stream within the fluvial system. Mixed research methods were applied within a mature karst network. Methods included high resolution measurements of water and sediment characteristics of surface streams, carbon and stable carbon isotope measurements of transported sediment, and numerical modeling of water and sediment pathways. The mixing of sediment during net zero deposition and erosion was investigated in this study using a parameter calibrated to SOC data. Results of this study showed that heterotrophic bacteria in the subsurface conduit oxidized 0.05 tCkm-2y-1 resulting from the temporary storage of terrestrial carbon in the karst conduit. The subsurface conduit transports 0.15 tCkm-2y-1 out of the fluviokarst watershed.

Hydraulic geometry relationships and regional curves are used in natural channel design to assist engineers, biologists, and fluvial geomorphologists in the efforts undertaken to ameliorate previous activities that have diminished, impaired or destroyed the structure and function of stream systems. Bankfull channel characteristics were assessed for 14 United States Geological Survey (USGS) gaged sites in the Inner Bluegrass and 15 USGS gaged sites in the Outer Bluegrass Regions of Kentucky. Hydraulic geometry relationships and regional curves were developed for the aforementioned regions. Analysis of the regression relationships showed that bankfull discharge is a good explanatory variable for bankfull parameters such as area, width and depth. The hydraulic geometry relationships developed produced high R2 values up to 0.95. The relationships were also compared to other studies and show strong relationships to both theoretical and empirical data. Regional curves, relating drainage area to bankfull parameters, were developed and show that drainage area is a good explanatory variable for bankfull parameters. R2 values for the regional curves were as high as 0.98.

Conventional stripping of burley tobacco is labor intensive and typically requires 50 to 75 worker hours per acre (wkr•hr/ac). The goal of the project was to reduce labor by optimizing leaf removal by string trimmer heads using combinations of strings lengths and motor speeds. In tests conducted on a single grade, all leaves outside the grade were removed by hand. Plants were run through the machine for sting lengths of 5, 7 and 9 inches and associated motor speeds which were monitored and recorded. Stripping efficiencies were calculated for each plant and collectively for each set of four plants. The machine was then tested for three grade stripping efficiency. Particle size analysis tests were run to determine potential losses due to leaf shredding. Efficiencies for single grade testing ranged from 93 to 96% for optimal string length and speed combinations. Stripping three grades by machine resulted in an average of 97% efficiency. Potential losses due to shredding accounted for 5.6% of the total weight mechanically removed. It is believed that this stripping concept, implemented on a full scale four grade basis, could result in savings of at least 18 wkr •hr/ac [45 wkr•hr/ha].

Curd syneresis, a critical step in cheesemaking, directly influences the quality of cheese. The syneresis process is empirically controlled in cheese manufacturing plants. A sensor technology for this step would improve process control and enhance cheese quality. A light backscatter sensor with a Large Field of View (LFV) was tested using a central composite design over a broad range of cheese process conditions including milk pH, calcium chloride addition level, milk fat to protein ratio, temperature, and a cutting time factor (β). The research objectives were to determine if the LFV sensor could monitor coagulation and syneresis steps and provide information for predicting pressed curd moisture. Another objective was to optimize cheese yield and quality. The LFV sensor was found to monitor coagulation and syneresis and provide light backscatter information for predicting curd moisture content. A model for relating final curd moisture content with light backscatter response was developed and tested. Models for predicting whey fat losses, pressed curd moisture, and cheese yield were successfully developed (R2>0.75) using the test factors as independent variables. This was the first attempt to develop a technology for controlling pressed curd moisture using a sensor to monitor the syneresis step.

Small lowland agricultural systems promote conditions where benthic biological communities can thrive. These biogeochemical processes have significant impacts on terrestrial ecosystem processes including POC flux and fate, nutrient balances, water quality budges, and aquatic biological functioning. Limited information is available on coupled biological and hydrologic processes in fluvial systems. This study investigates the mixture of biological and hydrologic processes in the benthic layer in order to understand POC cycling in the South Elkhorn system. Further, comprehensive modeling of POC flux in lowland systems has not been performed previously and the behavior of potentially controlling variables, such as hydrologic forcing and seasonal temperature regimes, is not well understood. Conceptual hydraulic and sediment transport models were simulated for the South Elkhorn. Based on data and model results it was concluded that during a hydrologic event, upland and bank sources produce high variability of POC sources. Likewise, over time, the density of hydrologic events influenced accrual of benthic algal biomass in the POC pool. Environmental variables such as temperature and light availability drove seasonal variations of POC in the streambed. Based on model estimates, around 0.29 metric tCkm-2yr-1 of POC is flushed from the system annually with 13 % coming from autochthonous algae.

Many aspects associated with conversion of lignocellulose to biofuels and other valuable products have been investigated to develop the most effective processes for biorefineries. The goal of this research was to improve the efficiency and effectiveness of the lignocellulose conversion process by achieving a more basic understanding of pretreatment and enzymatic hydrolysis at high solids, including kinetic modeling and separation and recovery of glucose. Effects of NaOH pretreatment conditions on saccharide yields from enzymatic hydrolysis were characterized in low- and high-solids systems. Factors associated with pretreatment and hydrolysis were investigated, including duration of pretreatment at different temperatures and NaOH loadings, as well as different solids and enzyme loadings. Under relatively mild pretreatment conditions, corn stover composition was essentially equivalent for all time and temperature combinations; however, components were likely affected by pretreatment, as differences in subsequent cellulose conversions were observed. Flushing the hydrolyzate and reusing the substrate was also studied as a method for inhibitor mitigation while increasing overall glucose yields. Flushing the PCS throughout the hydrolysis reaction eliminated the need to wash the pretreated biomass prior to enzymatic hydrolysis when supplementing with low doses of enzyme, thus reducing the amount of process water required. The robustness of an established kinetic model was examined for heterogeneous hydrolysis reactions in high-solids systems. Michaelis-Menten kinetics is the traditional approach to modeling enzymatic hydrolysis; however, high-solids reactions violate the main underlying assumption of the equation: that the reaction is homogeneous in nature. The ability to accurately predict product yields from enzymatic hydrolysis in high-solids systems will aid in optimizing the conversion process. Molecularly-imprinted materials were studied for use in both bulk adsorption and in column chromatography separations. Glucose-imprinted materials selectively adsorbed glucose compared xylose by nearly 4:1. Non-imprinted materials were neither selective in the type of sugar adsorbed, nor were they capable of adsorbing sugar at as high a capacity as the glucose-imprinted materials. Liquid chromatography with imprinted materials was not a suitable means for separating glucose from solution under the conditions investigated; however, many factors impact the effectiveness of such a separation process and warrant further investigation.