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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
41

Metal coordination directed folding of intramolecularly hydrogen-bonded dendrons

Preston, Sarah Suzanne 05 January 2006 (has links)
No description available.
42

Optimum design for sustainable green bonded concrete overlays : failure due to sheer and delamination

Olubanwo, A. January 2013 (has links)
Adequate interfacial bond performance of Bonded Concrete Overlay (BCO) systems requires novel integration of material mixture design, compatibility model development, and interfacial bond design. This entails the use of the right materials, on the right substrate, in the right way, in order to secure the best possible composite behaviour. The overall composite performance of BCOs depends largely on achieving the right proportion of blend for the overlay material. The use of mixture experiments provides a flexible, easy, and quick way of optimizing multi-component materials of this nature. This study describes the use of optimization techniques within the concept of material mixture experiments for proportioning and designing the material constituents of a Bonded Roller Compacted Fibre Reinforced Polymer Modified Concrete (BRCFRPMC). By constraining the range of variability of the constituents, a feasible design space was created with 13 experimental points treated based on the required structural and elastic properties of the overlay. The optimum consistency-time for full consolidation and composite behaviour with the substrate ordinary Portland cement concrete (OPCC) was established between 34.05 and 34.87 seconds, while the resulting apparent maximum density achieves between 97.11% - 98.03% of the theoretical air-free density. In addition, compressive strength response at early and matured ages of 3 and 28 days were satisfied at 100% desirability. The elastic modulus response at age 3 showed 0% desirability, but attains about 99.96% of the target response by 28 days. The verification experiments conducted on each response property shows that positive correlations exist between the measured responses and the predicted values from the optimization analysis. Also, the bond capability of the optimum designed overlay material was evaluated using both tensile and shear bond strengths parameters. The overall assessment results showed that the overlay material exhibits good bonding with the substrate OPCC and would be able to withstand substantial stresses where sufficient surface texture is provided for aggregates interlocking. Other material properties included in the evaluation process of the overlay material included its tensile strength, coefficient of thermal expansion, and drying shrinkage. Stresses in the overlay, substrate, and at the interface were assessed analytically under various differential movement related conditions. Though the interface and the overlay material exhibited sufficient strength against thermal and shrinkage cracking, the theoretical shrinkage cracking in the overlay was predicted at 6.92MPa when fully restrained axially. Further, for effective fracture process description of the interface, experimentally determined parameters in shear and tension were coupled in Mixed-Mode Finite Element Analysis using differential edge deformation model between the overlay and the underlay. The results indicated that delamination in partial fracture process varied from that of complete fracture process, influenced distinctly and largely by the magnitude of the applied load. Other influencing factors in the analyses included the elastic mismatched properties, initial edge defect size, and the plane of loading. Lastly, analytical solution to the FEA problem was implemented using the proposed Modified Eigenvalue Buckling Analysis (MEBA). The result indicated that the proposed analytical method simulates and compares well with the FEA result. The proposed method also provided a good technique for predicting the Mixed-Mode Buckling failure Mode-Shape of the overlay.
43

Calcium-Aluminate as Biomaterial : Synthesis, Design and Evaluation

Lööf, Jesper January 2008 (has links)
<p>In this thesis different aspects of calcium-aluminate (CA) as biomaterial are presented. Calcium aluminate is a chemically bonded ceramic with inherent properties making it suitable for use as biomaterial in some applications. In this thesis the emphasis is put on the basic chemical, physical and mechanical properties that may be achieved using the CA system as well as synthesis of the CA raw material. The basis for using CA in any application is the synthesis of the raw material. Different synthesis routes for producing CA are presented with focus on high temperature routes and the micro-structural and phase development during synthesis. As a base for further understanding of the CA properties a thorough outline of the reaction chemistry for CA is presented also including a description of how the reactions may be controlled and how formulations can be designed. The surface reactions of CA when subjected to simulated body fluid showed that CA is <i>in vitro</i> bioactive. An <i>in vivo</i> study in teeth also indicates that CA produces apatite at the tooth material interface. Dental materials are subjected to a harsh environment in the mouth with high mechanical forces, erosion and thermal changes. Also the demands on precise handling characteristics are high. For these reasons the <i>in vitro</i> evaluation of physical and mechanical properties are important. In this work several mechanical and physical properties of Ca-based formulations for dental applications has been tested using different methods. Some attention is also put on the specific characteristics of CA and the difficulties that arise when new material classes needs to be tested according to consensus standard methods. Finally studies on a CA-based formulation intended for Vertebroplasty is presented. The studies include basic mechanical properties as well as testing the material in an <i>in vitro</i> model utilising synthetic cancellous bone.</p>
44

Computational Models of Adhesively Bonded Joints

Schmidt, Peter January 2007 (has links)
Simulations using the Finite Element Method (FEM) play an increasingly important role in the design process of joints and fasteners in the aerospace industry. In order to utilize the potential of such adhesive bonding, there is an increasing need for effective and accurate computational methods. The geometry and the nature of an adhesive joint are, however, not so simple to describe effectively using standard FEM-codes. To overcome this difficulty, special FEM-elements can be developed that provide a material surface treatment of the adhesive and the joined parts. In order to create a model that reflects the above features, one may introduce proper scalings on the geometry and on the material properties in terms of a perturbation parameter. Within the framework of three-dimensional elasticity, together with an asymptotic expansion method, a material surface model is obtained through a systematic procedure. In such a derivation, no a priori assumptions for the displacements or stress fields are needed. The final result is a variational equation posed over a single reference surface which forms the basis of a structural element for the compound joint. Through the usage of continuum damage mechanics and the framework of a generalized standard material, the linear elastic model is extended to include an elastic-plastic material model with damage for the adhesive. The model is FE-discretized and an important implication is that the (quasi-static) propagation of the local failure zone in the adhesive layer can be simulated. The failure load is obtained as a computational result and consequently no postulated failure criterion is needed. The derived FE-method opens up the possibility to efficiently model and analyze the mechanical behavior of large bonded structures. / At the time the thesis was defended paper I. was in fact two manuscripts, which later were combined to give the published article.
45

Modelling of FRP-concrete interfacial bond behaviour

An, Feng-Chen January 2015 (has links)
Externally bonding of fibre-reinforced polymer (FRP) strips or sheets has become a popular strengthening method for reinforced concrete structures over the last two decades. For most such strengthened concrete beams and slabs, the failure is at or near the FRP-concrete interface due to FRP debonding. The objective of this thesis is to develop a deeper understanding of the debonding behaviour of the FRP-concrete interface through mesoscale finite element simulation. Central to the investigation is the use of the concrete damaged plasticity (CDP) model for modelling the concrete. The FRP is treated as an elastic material. The numerical simulation is focused on the single shear test of FRP-concrete bonded joints. This problem is known to be highly nonlinear and has many difficulties in achieving a converged solution using the standard static loading procedures. A dynamic loading procedure is applied in this research and various parameters such as time step, loading rate etc. are investigated. In particular, the effect of the damping ratio is investigated in depth and an appropriate selection is recommended for solving such problems. It has been identified that the concrete damage model can have a significant effect on the numerical predictions in the present problem. Various concrete empirical damage models are assessed using cyclic test data and simulation of the single shear test of the FRP-concrete bonded joint and it is proposed that the Birtel and Mark’s (2006) model is the most appropriate one for use in the present problem. Subsequently, the effects of other aspects of the concrete behaviour on the FRP-concrete bond behaviour are investigated. These include the tensile fracture energy, compression strain energy and different concrete compression stress-strain models. These leads to the conclusion that the CEBFIP1990 model is the most appropriate one for the problem. An important issue for recognition is that the actual behaviour of the FRP-concrete bonded joints is three dimensional (3D), but most numerical simulations have treated the problem as two dimensional (2D) which has a number of imitations. True 3D simulation is however very expensive computationally and impractical. This study proposes a simple procedure for modelling the joint in 2D with the 3D behaviour properly considered. Numerical results show that the proposed method can successfully overcome the limitations of the traditional 2D simulation method. The above established FE model is then applied to simulate a large number of test specimens. The bond stress-slip relationship is extracted from the mesoscale FE simulation results. An alternative model is proposed based on these results which is shown to be advantageous compared with existing models. This new model provides the basis for further investigation of debonding failures in FRP strengthened concrete structures in the future.
46

From Bonded Laborers to Educated Citizens? Immigration, Labor Markets, and Human Capital in São Paulo, Brazil (1820-2010)

Witzel de Souza, Bruno Gabriel 15 February 2019 (has links)
No description available.
47

Transforming composite design by use of structural health monitoring

Liddel, Paul Daniel January 2016 (has links)
Commercial composite aerospace structure is required to be designed and managed under the damage tolerant principle. Airworthiness is maintained through a process of regulated inspections and if required maintenance. Currently inspections use visual and assisted visual (non-destructive inspection - NDI) techniques. Damage tolerant operation is therefore reliant on inspectability. Unlike metal structure composite and adhesively bonded structure may show few if any recognisable indicators prior to rapid failure, either visually or using NDI. Although stringent manufacturing processes are demanded to best ensure components are fit for service strategies such as reducing stresses by oversizing components or in the case of bonded features additional mechanical fasteners may be included to allow operation with this potential structural uncertainty. Structural Heath Monitoring (SHM) uses data from in-situ sensors to assess the condition of the structure. If via SHM any uncertainty associated with difficult to inspect components could be eliminated less reliance would be required of additional structure or features allowing lighter and more efficient structure to be viable with no impact on current airworthiness demands. Despite much previous research no SHM system is in use with in-service composite or bonded aerospace components. When operating a structure under Damage-tolerance operational requirements damage must be positively identified to allow repairs to be made whist ensuring appropriate airworthiness demands are maintained. Such demands must also be met by structure inspected using SHM. Unlike previous studies this research combines the process of structural design and in-situ monitoring to address the issues identified. Termed SHM enabled design this approach allows the implementation of monitoring technology and the potential for benefits including the reduced reliance on inefficient additional structure to be viably included in actual structure ... [cont.].
48

Estudo de obtenção de revestimento de elementos combustíveis para reatores FBNR

Bastos, Marcelo Bratenahl January 2008 (has links)
Este trabalho teve por objetivo obter revestimento de carbeto de silício para esferas combustíveis utilizadas em reatores nucleares do tipo FBNR, através da sinterização de SiC por reação com silício metálico (RBSiC). As matérias-primas foram moídas em moinho de bolas por 24 horas e as temperaturas utilizadas na sinterização foram de 1500° e 2000°C, durante tempos que variaram de 30 a 240 minutos. As amostras foram caracterizadas quanto a fases cristalinas, densidade, microestrutura e resistência mecânica. As peças sinterizadas a 2000°C apresentaram valores de resistência mecânica na faixa de 95 MPa, e densidade de cerca de 90% foram alcançadas, superiores aos valores encontrados para 1500°C.Foram obtidos revestimentos com as técnicas de gel casting e spin coating. A resistência mecânica desses revestimentos foi de, aproximadamente, 50% das amostras sinterizadas a 2000°C. / The aim of this work was to get covering of silicon carbide for use in nuclear fuel reactors of type FBNR, through the sintering of SiC by reaction bonded silicon carbide (RBSiC). The samples were homogenized in a ball mill and the sintering temperatures were 1500°C and 2200°C, during times that varied of 30 until 240 minutes. The product was characterized by crystalline phases, density, microstructure and mechanical resistance. The samples sintering at 2000°C had presented values of mechanical resistance around of 95 MPa, and density around 90%, better that samples sintering at 1500°C. Gel casting and Spin coating techniques had success in coverings process. The mechanical resistance of this coverings were around 50% of the samples sintering at 2000°C.
49

Resistência da linha de cola em superfícies lixadas da madeira de eucalipto /

Alves, Paulo Roberto Gomes. January 2012 (has links)
Orientador: Marcos Tadeu Tibúrcio Gonçalves / Coorientador: Manoel Cléber de Sampaio Alves / Banca: Marcos Valério Ribeiro / Banca: Ivaldo de Domenico Valarelli / Resumo: Este trabalho apresenta estudos de usinabilidade de peças de madeira de eucalipto, tendo por objetivo principal efetuar análises da resistência de juntas coladas em relação à qualidade das superfícies usinadas, a fim de se verificar a influência da rugosidade superficial sobre a adesão das superfícies coladas com adesivo à base de acetato de polivinila (PVA). Amostras da espécie de madeira Eucalyptus saligna foram preparadas para testes de resistência na lâmina de cola em ensaios de ruptura por cisalhamento e por tração normal segundo a norma NBR 7190. As superfícies de colagem foram preparadas por operação de fresamento empregando-se velocidade nominal de avanço de 11,0 m/min e posteriormente por operação de lixamento empregando-se cinco diferentes granulometrias de lixas, de granas: 80, 100, 120, 150 e 220. Depois de lixadas, as superfícies foram submetidas à medição da rugosidade com rugosímetro equipado com uma ponta apalpadora de diamante, de forma cone-esférica, com raio de ponta de 2µm, em conjunto com o programa de análise de superfícies. Dos resultados obtidos podem-se destacar os melhores desempenhos de resistência a ruptura; ao cisalhamento para superfícies lixadas por lixa de grana 220; à tração normal para superfícies lixadas por lixa de grana 120 / Abstract: This paper shows studies on machinability of eucalyptus wood battens; main goal is make analysis of resistance bonded joints in relation the quality of machined surface to determine the influence of surface roughness on the adhesion of the bonded surfaces adhesive-based polyvinyl acetate (PVA). Samples Eucalyptus saligna wood species were prepared for resistance testing in trials blade glue shear rupture and tensile normal according to NBR 7190. The bonding surfaces were prepared by milling operation employing feed speed of 11.0 m/min and then by the grinding operation using five different grain sizes of sandpaper (grands: 80, 100, 120, 150 and 220). After sanding, the surfaces were subjected to measurements of roughness with roughness equipped with a diamond probe tip of cone-spherical shape, with nose radius of 2µm, together with surface analysis program. Among the results we can point out the best performances of rupture strength, shear strength for sanded surfaces by sanding the bundles 220, the normal traction surfaces sanded by sanding to 120 cash / Mestre
50

Caractérisation et modélisation des joints de colles sous sollicitations bi-axiales statiques / Characterization and modeling of adhesive bonded joints under quasi-static loadings

Destouesse Villa, Jaime 16 November 2018 (has links)
Le collage structural se présente comme une alternative intéressante aux méthodes classiques d'assemblages par ajout d’éléments mécaniques pour alléger les structures aéronautiques. Cependant, l'utilisation de cette méthode soulève de nombreuses questions en termes de conception, caractérisation ou modélisation. Ce travail, à fort caractère expérimental, visent deux grands objectifs : (i) sélectionner les moyens d'instrumentation les plus adaptés pour la caractérisation du comportement jusqu'à rupture des assemblages collés et (ii) prédire le comportement des assemblages collés à partir d'une caractérisation et d'une modélisation complète sous chargements quasi-statiques bi-axiaux, en utilisant un type d’essai simple et industrialisable. Dans un premier temps, pour atteindre ces objectifs, un nouvel essai appelé Scarf modifié a été proposé, afin de caractériser le comportement mécanique du joint de colle, en minimisant les effets de bord par la présence de becs. La deuxième partie de la thèse porte sur le développement d'une stratégie de caractérisation simplifiée du comportement de joint de colle, sous certaines hypothèses (états de contraintes/déformations, continuité du champ de contraintes). Cette stratégie a permis d'obtenir le comportement intrinsèque de l’adhésif sous la forme de courbes contraintes/déformations. La dernière partie abordée dans ces travaux, s'intéresse quant à elle à l'identification et la sélection des moyens de métrologie les plus appropriés, pour accompagner la caractérisation expérimentale. / Today, structural bonding presents an interesting alternative to conventional methods of assembly, in order to reduce the weight within aeronautical structures. However, the use of this method raises many questions in terms of design, characterization or modeling. This work presents a robust experimental work, aiming two main objectives: (i) select the most suitable instrumentation for the characterization of the behavior of bonded joints up to failure and (ii) predict the behavior of bonded joints from complete characterization and modeling under quasi-static bi-axial loading, using a simple test, directly integrated to industry. In a first stage, to achieve this goal, modified Scarf test has been proposed to characterize the mechanical behavior of adhesive joints. This type of specimen allows applying multiaxial loadings without having high-stress concentrations near the edges. The second part of the thesis deals with the development of a strategy for simplifying the characterization of a bonded joint using some hypotheses (stress/strain states). This strategy allows obtaining the intrinsic behavior of the adhesive in the form of the stress/strain curves. The last part of this work deals with the identification and selection of the most appropriate instrumentation systems in the experimental characterization.

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