Sequestration has been suggested as a solution for resolving the problem of increasing greenhouse gas emissions. CO2 is the major greenhouse gas which results from using fossil fuels for domestic and industrial purposes. Different geological targets have been suggested as reservoirs for CO2 sequestration with saline aquifers being the focus of this research. Monitoring and verification of injected CO2 into the ground is an essential part of CO2 sequestration because there is a strong requirement to understand and correctly manage the CO2 flow and movement within the reservoir over time. This includes a need to understand mobile CO2 in its all phases (gas, liquid, supercritical and dissolved in formation water). It is now well recognised that monitoring injected liquids in the sub-surface can be done remotely using surface seismic monitoring techniques. Seismic waves are sensitive to the contrast in the physical properties of formation water and CO2. As a gas, the migration path of CO2 has been shown to be easily imaged but such images provide only a qualitative rather than a quantitative solution, which is inadequate to remotely verify storage volumetrics. The complexity of saline aquifer reservoirs containing the different phases of CO2 (a function of reservoir pressure, temperature, and chemical composition and the state of phase of injected CO2) requires a good knowledge base of how the seismic response changes to such changes in CO2 phase and reservoir heterogeneities for verification purposes. / In this research, transmission ultrasonic seismic experiments were performed under controlled pressure, temperature and CO2 dissolution conditions in water. Different forms of simulated rock matrix were used to understand how seismic attributes changed with changing sequestration conditions. Data analysis showed that the commonly used approach of seismic velocity analysis is not particularly sensitive to dissolved CO2 whereas seismic amplitude was very sensitive to dissolved CO2 content and is the seismic attribute of choice for the future quantification of CO2. The density increase in formation water brine as a result of CO2 mixture was found to be directly related to transmission amplitude and provides the potential for prediction and thus, remote quantification. Also, there was confirmation during the transmission experiments that seismic amplitude changes markedly when CO2 changes phase from its dissolved form into a gas, as a result of significant attenuation by CO2 bubbles. Analysis showed that the dominant and centre frequency of the spectra also responded to CO2 phase when it changed from dissolved to its free gas form. However, these attributes appear to be of use in a qualitative manner rather than quantitative. The CO2 pre-bubble phase was studied in an attempt to obtain a basic knowledge of the effect on seismic amplitude variation for quantifying dissolved gas amounts with some success. This knowledge has an application in Gas-to-Oil-Ratio mapping in depleting oil fields and can assist the future management of production from fields which are at the stage of near-bubble point due to pressure depletion. / The results of this research have an application in time-lapse seismic monitoring and operational management of greenhouse gas sequestration operations. In particular, the VSP and cross-well seismic methods are immediate beneficiaries of this research, with further work required for application to 3-D reflectivity methods in time-lapse surface seismic monitoring.

he feasibility of sequestering supercritical CO2 in depleted gas reservoirs. The experimental runs involved the following steps. First, the 1 ft long by 1 in. diameter carbonate core is inserted into a viton Hassler sleeve and placed inside an aluminum coreholder that is then evacuated. Second, with or without connate water, the carbonate core is saturated with methane. Third, supercritical CO2 is injected into the core with 300 psi overburden pressure. From the volume and composition of the produced gas measured by a wet test meter and a gas chromatograph, the recovery of methane at CO2 breakthrough is determined. The core is scanned three times during an experimental run to determine core porosity and fluid saturation profile: at start of the run, at CO2 breakthrough, and at the end of the run. Runs were made with various temperatures, 20°C (68°F) to 80°C (176°F), while the cell pressure is varied, from 500 psig (3.55 MPa) to 3000 psig (20.79 MPa) for each temperature. An analytical study of the experimental results has been also conducted to determine the dispersion coefficient of CO2 using the convection-dispersion equation. The dispersion coefficient of CO2 in methane is found to be relatively low, 0.01-0.3 cm2/min.. Based on experimental and analytical results, a 3D simulation model of one eighth of a 5-spot pattern was constructed to evaluate injection of supercritical CO2 under typical field conditions. The depleted gas reservoir is repressurized by CO2 injection from 500 psi to its initial pressure 3,045 psi. Simulation results for 400 bbl/d CO2 injection may be summarized as follows. First, a large amount of CO2 is sequestered: (i) about 1.2 million tons in 29 years (0 % initial water saturation) to 0.78 million tons in 19 years (35 % initial water saturation) for 40-acre pattern, (ii) about 4.8 million tons in 112 years (0 % initial water saturation) to 3.1 million tons in 73 years (35 % initial water saturation) for 80-acre pattern. Second, a significant amount of natural gas is also produced: (i) about 1.2 BSCF or 74 % remaining GIP (0 % initial water saturation) to 0.78 BSCF or 66 % remaining GIP (35 % initial water saturation) for 40-acre pattern, (ii) about 4.5 BSCF or 64 % remaining GIP (0 % initial water saturation) to 2.97 BSCF or 62 % remaining GIP (35 % initial water saturation) for 80-acre pattern. This produced gas revenue could help defray the cost of CO2 sequestration. In short, CO2 sequestration in depleted gas reservoirs appears to be a win-win technology.

To safely store carbon dioxide in enhanced oil recovery/ CO2 sequestration projects it is important to ensure the integrity of the caprock during and after production and injection. A change in fluid pressure and temperature within a porous reservoir will generally induce stress changes within the reservoir and the rocks that surround it. Amongst the potential hazards resulting from these induced stress changes is the reactivation of existing faults or fractures and inducing new fractures, which may breach the hydraulic integrity of the caprock that bounds the reservoir.<p> The theories of inclusions and inhomogeneities have been used in this research to derive semi-analytical and closed-form solutions for induced stress change during pore pressure change within a reservoir and in the surrounding rock, under plane strain and axisymmetric conditions. Methods have been developed to assess fault reactivation and induced fracturing during injection or production within a reservoir. The failure stress change concept for a Coulomb failure criterion has been used to study the likelihood of fault reactivation and induced fracturing within the reservoir. Formulations have been adopted to calculate the critical pressure change for fault reactivation and induced fracturing within the reservoir and in the surrounding rock during injection and production. Sensitivity analysis has been performed to study the effects of different parameters such as initial in-situ stress, reservoir geometry, reservoir depth, reservoir tilt or dip , material property contrast between the reservoir and surrounding rock, fault geometry, fault strength, and intact rock strength. General patterns of induced stress change, in-situ stress evolution, fault reactivation, and induced fracturing have been identified.<p> The developed methodologies have been applied to six different case studies: fault reactivation analysis in the entire field for a synthetic case study; induced fracturing analysis in the entire field in a synthetic case study; fault reactivation and induced stress change analysis within the Ekofisk oil reservoir in North Sea; fault reactivation analysis in the Lacq gas reservoir in France; the Weyburn-Midale EOR/CO2 Storage project in southeast Saskatchewan; and acid gas injection in Zama oil field, Alberta. The results of these case studies show good consistency with field observation, and physical and numerical models.<p> The generality, simplicity, and straightforwardness of the developed methodologies, along with their flexibility to model different plausible scenarios and their ease of implementation for systematic sensitivity analyses makes them suitable for decision-making and uncertainty management, specifically in early stages of reservoir development or site assessment for geological sequestration of carbon dioxide.

To safely store carbon dioxide in enhanced oil recovery/ CO2 sequestration projects it is important to ensure the integrity of the caprock during and after production and injection. A change in fluid pressure and temperature within a porous reservoir will generally induce stress changes within the reservoir and the rocks that surround it. Amongst the potential hazards resulting from these induced stress changes is the reactivation of existing faults or fractures and inducing new fractures, which may breach the hydraulic integrity of the caprock that bounds the reservoir.<p> The theories of inclusions and inhomogeneities have been used in this research to derive semi-analytical and closed-form solutions for induced stress change during pore pressure change within a reservoir and in the surrounding rock, under plane strain and axisymmetric conditions. Methods have been developed to assess fault reactivation and induced fracturing during injection or production within a reservoir. The failure stress change concept for a Coulomb failure criterion has been used to study the likelihood of fault reactivation and induced fracturing within the reservoir. Formulations have been adopted to calculate the critical pressure change for fault reactivation and induced fracturing within the reservoir and in the surrounding rock during injection and production. Sensitivity analysis has been performed to study the effects of different parameters such as initial in-situ stress, reservoir geometry, reservoir depth, reservoir tilt or dip , material property contrast between the reservoir and surrounding rock, fault geometry, fault strength, and intact rock strength. General patterns of induced stress change, in-situ stress evolution, fault reactivation, and induced fracturing have been identified.<p> The developed methodologies have been applied to six different case studies: fault reactivation analysis in the entire field for a synthetic case study; induced fracturing analysis in the entire field in a synthetic case study; fault reactivation and induced stress change analysis within the Ekofisk oil reservoir in North Sea; fault reactivation analysis in the Lacq gas reservoir in France; the Weyburn-Midale EOR/CO2 Storage project in southeast Saskatchewan; and acid gas injection in Zama oil field, Alberta. The results of these case studies show good consistency with field observation, and physical and numerical models.<p> The generality, simplicity, and straightforwardness of the developed methodologies, along with their flexibility to model different plausible scenarios and their ease of implementation for systematic sensitivity analyses makes them suitable for decision-making and uncertainty management, specifically in early stages of reservoir development or site assessment for geological sequestration of carbon dioxide.

During the operation of a geological carbon storage project, verifying that the CO₂ plume remains within the permitted zone is of particular interest both to regulators and to operators. However, the cost of many monitoring technologies, such as time-lapse seismic, limits their application. For adequate predictions of plume migration, proper representation of heterogeneous permeability fields is imperative. Previous work has shown that injection data (pressures, rates) from wells might provide a means of characterizing complex permeability fields in saline aquifers. Thus, given that injection data are readily available and inexpensive, they might provide an inexpensive alternative for monitoring; combined with a flow model like the one developed in this work, these data could even be used for predicting plume migration. These predictions of plume migration pathways can then be compared to field observations like time-lapse seismic or satellite measurements of surface-deformation, to ensure the containment of the injected CO₂ within the storage area. In this work, two novel methods for creating heterogeneous permeability fields constrained by injection data are demonstrated. The first method is an implementation of a probabilistic history matching algorithm to create models of the aquifer for predicting the movement of the CO₂ plume. The geologic property of interest, for example hydraulic conductivity, is updated conditioned to geological information and injection pressures. The resultant aquifer model which is geologically consistent can be used to reliably predict the movement of the CO₂ plume in the subsurface. The second method is a model selection algorithm that refines an initial suite of subsurface models representing the prior uncertainty to create a posterior set of subsurface models that reflect injection performance consistent with that observed. Such posterior models can be used to represent uncertainty in the future migration of the CO₂ plume. The applicability of both methods is demonstrated using a field data set from central Algeria. / text

he feasibility of sequestering supercritical CO2 in depleted gas reservoirs. The experimental runs involved the following steps. First, the 1 ft long by 1 in. diameter carbonate core is inserted into a viton Hassler sleeve and placed inside an aluminum coreholder that is then evacuated. Second, with or without connate water, the carbonate core is saturated with methane. Third, supercritical CO2 is injected into the core with 300 psi overburden pressure. From the volume and composition of the produced gas measured by a wet test meter and a gas chromatograph, the recovery of methane at CO2 breakthrough is determined. The core is scanned three times during an experimental run to determine core porosity and fluid saturation profile: at start of the run, at CO2 breakthrough, and at the end of the run. Runs were made with various temperatures, 20°C (68°F) to 80°C (176°F), while the cell pressure is varied, from 500 psig (3.55 MPa) to 3000 psig (20.79 MPa) for each temperature. An analytical study of the experimental results has been also conducted to determine the dispersion coefficient of CO2 using the convection-dispersion equation. The dispersion coefficient of CO2 in methane is found to be relatively low, 0.01-0.3 cm2/min.. Based on experimental and analytical results, a 3D simulation model of one eighth of a 5-spot pattern was constructed to evaluate injection of supercritical CO2 under typical field conditions. The depleted gas reservoir is repressurized by CO2 injection from 500 psi to its initial pressure 3,045 psi. Simulation results for 400 bbl/d CO2 injection may be summarized as follows. First, a large amount of CO2 is sequestered: (i) about 1.2 million tons in 29 years (0 % initial water saturation) to 0.78 million tons in 19 years (35 % initial water saturation) for 40-acre pattern, (ii) about 4.8 million tons in 112 years (0 % initial water saturation) to 3.1 million tons in 73 years (35 % initial water saturation) for 80-acre pattern. Second, a significant amount of natural gas is also produced: (i) about 1.2 BSCF or 74 % remaining GIP (0 % initial water saturation) to 0.78 BSCF or 66 % remaining GIP (35 % initial water saturation) for 40-acre pattern, (ii) about 4.5 BSCF or 64 % remaining GIP (0 % initial water saturation) to 2.97 BSCF or 62 % remaining GIP (35 % initial water saturation) for 80-acre pattern. This produced gas revenue could help defray the cost of CO2 sequestration. In short, CO2 sequestration in depleted gas reservoirs appears to be a win-win technology.

Research on green roofs has focused on grasses, sedums, and forbs. The aims of this thesis were to determine the potential of rooftop gardens (RTGs) in an urban setting to reduce local levels of CO2, remediate storm water runoff, and provide boutique vegetables for a restaurant. The garden roof footprint was 238 ft2, with 14% covered by vegetated boxes. The soil mixture used had 96% absorbency with 54.12 gallons of the 55 gallons of precipitation that fell within the rain catcher boxes absorbed. Total biomass production was 37.98 Kg of wet biomass and 5.04 Kg of dry biomass. The amount of CO2 removed equals 0.22 Kg ft-2. RTGs have a limited capacity to help sequester CO2, but retain precipitation in amounts similar to green roofs. The restaurant was provided with 4.7 Kg (wet weight) of produce (several varieties of tomatoes, peppers, and eggplant). These results support the utility of RTGs. / Bayer School of Natural and Environmental Sciences / Environmental Science and Management (ESM) / MS / Thesis

Permanently sequestering carbon dioxide (CO2) in gas-bearing shale formations is beneficial in that it can mitigate greenhouse gas emissions as well as enhance gas recovery in production wells. This is possible due to the sorption properties of the organic material within shales and their greater affinity for CO2 over methane. The phenomenon of preferentially adsorbing CO2 while desorbing methane has been proven in coalbed reservoirs successfully, and is feasible for shale formations. The objective of this thesis is to explore the potential for enhanced gas recovery from gas-bearing shale formations by injecting CO2 into a targeted shale formation. With the advancement of technologies in horizontal drilling combined with hydraulic fracturing, shale gas has become a significant source of energy throughout the United States. With over 6,000 trillion cubic feet (Tcf) of theoretical gas-in-place, Appalachia has proven a major basin for gas production from organic shales. With its extensive shale reserves and lack of conventional reservoirs typically used for CO2 storage, Appalachia's unconventional reservoirs are favorable candidates for CO2 storage with enhanced gas recovery. Enhancing gas recovery not only increases reserves, but extends the life of mature wells and fields throughout the basin. As part of this research, 510 tons of CO2 were successfully injected into a horizontal production well completed in the Chattanooga shale formation, a late Devonian shale, in Morgan County, Tennessee. An extensive monitoring program was implemented during the pre-injection baseline, injection, soaking, and flowback phases of the test. Multiple fluorinated tracers were used to monitor for potential CO2 breakthrough at offset production wells and to help account for the CO2 once the well was flowed back. Results from this test, once the well was put back into normal production state, confirm the injectivity and storage potential of CO2 in shale formations, as well as an increase in gas production rate and quality of gas produced. / Master of Science

Carbon capture and sequestration (CCS) is an engineering-based approach for mitigating excess anthropogenic CO2 emissions. Deep brine aquifers and basalt reservoirs have shown outstanding performance in CO2 storage based on their global widespread distribution and large storage capacity. Capillary trapping and mineral trapping are the two dominant mechanisms controlling the distribution, migration, and transportation of CO2 in deep brine aquifers and basalt reservoirs. Understanding the behavior of CO2 in a storage reservoir under realistic conditions is important for risk management and storage efficiency improvement. As a result, numerical simulations have been implemented to understand the relationship between fluid properties and multi-phase fluid dynamics. However, the physics-based simulations that focus on the uncertainties of fluid flow dynamics are complicated and computationally expensive. Machine learning method provides immense potential for improving computational efficiency for subsurface simulations, particularly in the context of parametric sensitivity. This work focuses on parametric uncertainty associated with multi-phase fluid dynamics that govern geologic CO2 storage. The effects of this uncertainty are interrogated through ensemble simulation methods that implement both physics-based and machine learning modeling strategies. This dissertation is a culmination of three projects: (1) a parametric analysis of capillary pressure variability effects on CO2 migration, (2) a reactive transport simulation in a basalt fracture system investigating the effects of carbon mineralization on CO2 migration, and (3) a parametric analysis based on machine learning methods of simultaneous effects of capillary pressure and relative permeability on CO2 migration. / Doctor of Philosophy / Carbon capture and sequestration (CCS) has been proposed as a technological approach to mitigate the deleterious effects of anthropogenic CO2 emissions. During CCS, CO2 is captured from power plants and then pumped in deep geologic reservoirs to isolate it from the atmosphere. Deep sedimentary formations and fractured basalt reservoirs are two options for CO2 storage. In sedimentary systems, CO2 is immobilized largely by physical processes, such as capillary and solubility trapping, while in basalt reservoirs, CO2 is transformed into carbonate minerals, thus rendering it fully immobilized. This research focuses on how a large range of capillary pressure variabilities and how CO2-basalt reactions affect CO2 migration. Specifically, the work presented utilizes numerical simulation and machine learning methods to study the relationship between capillary trapping and buoyancy in a sandstone formation, as well as the combined effects of capillary pressure and relative permeability on CO2 migration. In addition, the work also identifies a new reinforcing feedback between mineralization and relative permeability during reactive CO2 flow in a basalt fracture network. In aggregate, the whole of this work presents a new, multi-dimensional perspective on the multi-phase fluid dynamics that govern CCS efficacy in a range of geologic formations.

Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce the amount of CO2 emitted into the atmosphere. However, a better understanding of the chemical and physical interactions between CO2, water, and formation rock is necessary before sequestration. These interactions can be evaluated by the change in mineral content in the water before and after injection, or from the change in well injectivity during CO2 injection. It may affect the permeability positively due to rock dissolution, or negatively due to precipitation. Several physical and chemical processes cover the CO2 injection operations; multiphase flow in porous media is represented by the flow of the brine and CO2, solute transportation is represented by CO2 dissolution in the brine forming weak carbonic acid, dissolution-deposition kinetics can be seen in the rock dissolution by the carbonic acid and the deposition of the reaction products, hydrodynamic instabilities due to displacement of less viscous brine with more viscous CO2 (viscous fingering), capillary effects and upward movement of CO2 due to gravity effect. The objective of the proposed work is to correlate the formation damage to the other variables, i.e. pressure, temperature, formation rock type, rock porosity, water composition, sulfates concentration in the water, CO2 volume injected, water volume injected, CO2 to water volumetric ratio, CO2 injection rate, and water injection rate. In order to achieve the proposed objective, lab experiments will be conducted on different rock types (carbonates, limestone and dolomite, and sandstone) under pressure and temperature that simulate the field conditions. CO2 will be used at the supercritical phase and different CO2-water-rock chemical interactions will be addressed. Quantitative analysis of the experimental results using a geochemical simulator (CMG-GEM) will also be performed. The results showed that for carbonate cores, maintaining the CO2/brine volumetric ratio above 1.0 reduced bicarbonate formation in the formation brine and helped in minimizing precipitation of calcium carbonate. Additionally, increasing cycle volume in WAG injection reduced the damage introduced to the core. Sulfate precipitation during CO2 sequestration was primarily controlled by temperature. For formation brine with high total dissolved solids (TDS), calcium sulfate precipitation occurs, even at a low sulfate concentration. For dolomite rock, temperature, injection flow rate, and injection scheme don't have a clear impact on the core permeability, the main factor that affects the change in core permeability is the initial core permeability. Sandstone cores showed significant damage; between 35% and 55% loss in core permeability was observed after CO2 injection. For shorter WAG injection the damage was higher; decreasing the brine volume injected per cycle, decreased the damage. At higher temperatures, 200 and 250 degrees F, more damage was noted than at 70 degrees F.