Vibration problems are still the major constraint in modern machining processes that seek higher material removal rate, shorter process time, longer tool life and better product quality. Depending on the process, the weaker structure element can be the tool/tool holder, workpiece/fixture or both. When the tool/tool holder is the main source of vibration, the stability limit is determined in most cases by the ratio of length-to-diameter. Regenerative chatter is the most significant dynamic phenomenon generated through the interaction between machine tool and machining process. As a rule of thumb, the ratio between the tool’s overhang length and the tool’s diameter shouldn’t exceed 4 to maintain a stable machining process while using a conventional machining tool. While a longer tool overhang is needed for specific machining operations, vibration damping solutions are required to ensure a stable machining process. Vibration damping solutions include both active and passive damping solutions. In the passive damping solutions, damping medium such as viscoelastic material is used to transform the vibration strain energy into heat and thereby reduce vibration amplitude. For a typical cantilever tool, the highest oscillation displacement is near the anti-node regions of a vibration mode and the highest oscillation strain energy is concentrated at the node of a vibration mode. Viscoelastic materials have been successfully applied in these regions to exhibit their damping property. The node region of the 1st bending mode is at the joint interfaces where the cantilever tools are clamped. In this thesis, the general method that can be used to measure and characterize the joint interface stiffness and damping properties is developed and improved, joint interfaces’ importance at optimizing the dynamic stiffness of the joint interface is studied, and a novel advancing material that is designed to possess both high young’s modulus and high damping property is introduced. In the joint interface characterization model, a method that can measure the joint interface’s stiffness and damping over the full frequency range with only the assembled structure is presented. With the influence of a joint interface’s normal pressure on its stiffness and damping, an optimized joint interface normal pressure is selected for delivering a stable machining process against chatter with a boring bar setting at 6.5 times overhang length to diameter ratio in an internal turning process. The novel advancing material utilizes the carbon nano particles mixed in a metal matrix, and it can deliver both high damping property and high elastic stiffness to the mechanical structure. / <p>QC 20130521</p> / PoPJIM, HydroMod, XPRES, NanoComfort

Philosophiae Doctor - PhD (Chemistry) / Lithium ion capacitors are new and promising class of energy storage devices formed from a combination of lithium-ion battery electrode materials with those of supercapacitors. They exhibit better electrochemical properties in terms of energy and power densities than the above mentioned storage systems. In this work, lithium manganese oxide spinel (LiMn2O4; LMO) and lithium manganese phosphate (LiMnPO4; LMP) as well as their respective nickel-doped graphenised derivatives (G-LMNO and G-LMNP) were synthesized and each cathode material used to fabricate lithium ion capacitors in an electrochemical assembly that utilised activated carbon (AC) as the negative electrode and lithium sulphate electrolyte in a two-electrode system. The synthetic protocol for the preparation of the materials followed a simple solvothermal route with subsequent calcination at 500 - 800 ?C. The morphological, structural and electrochemical properties of the as prepared materials were thoroughly investigated through various characterisation techniques involving High resolution scanning electron microscopy (HRSEM), High resolution transmission electron microscopy (HRTEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction (XRD), Small-angle X-ray scattering (SAXS), Electrochemical impedance spectroscopy (EIS), Cyclic voltammetry (CV) and Galvanostatic charge/discharge.