Grouting techniques have been in used for many years, but several new grout materials have surfaced in recent decades that have re-defined the boundaries of the limitations of grouting programs. Typically these applications are used for seepage control in earthen impoundments, but strength of these earthen impoundments should be considered where there is potential for movement in the grouted soil mass. This study investigated initial conditions that could affect grout application effectiveness. The initial conditions in question were soil grain size and in situ moisture content. Two grouts were used, ultrafine and acrylate, and variations in pure grout properties were studied. An apparatus was developed so that a uniform grout could penetrate the pore spaces of a soil specimen. The rate of penetration of the grout into the soil was studied. The unconfined compressive strength of the resulting grouted soil was then analyzed. In testing neat ultrafine grout, it was shown that increased water-to-cement ratios had negative effects on the stability of the grout. Increasing the water-to-cement ratio from 0.5 to 2.5 resulted in a decrease in strength by a factor of 100. An inhibitor chemical was used to increase the time for reaction in the acrylate grout. During the chemical reaction, the curing temperature and gel times were monitored. A grout mix was selected for the acrylate grout that achieved appropriate gel times. In general, this study found that the grout penetrations rates into the soil increased as the initial moisture was increased from dry conditions to a gravimetric moisture content of nine percent. In each study, increased initial moisture decreased the grouted soil strength, with decreases in strength exceeding 50 percent. Empirical relationships were realized when compared to the initial matric suction of the soil. This suggests initial matric suction may be a useful initial condition for estimating increases in soil strength upon implementation of a grouting program for both the acrylate and ultrafine grouts.

Stricter greenhouse gas emission limits and renewable energy requirements are expected to further increase the worldwide practices of firing biomass and co-firing biomass with coal, which are both considered more sustainable energy sources than coal-only combustion. Reuse options for the by-products of these processes -biomass ash and co-fired fly ash -remain limited. Therefore, this research examines their use as supplementary cementitious materials (SCMs) in concrete and as precursors for alkali-activated geopolymers. Toward their potential use as an SCM, after characterizing these ashes assessing their compliance with ASTM C618 requirements, their impact on early-age hydration kinetics, rheology, setting time and permeability was assessed. Furthermore, the pozzolanic reactivity and the microstructural and hydrated phase development of the cement-ash samples were analyzed. The results show that a wood biomass ash sample was not satisfactory for use as an SCM. On the other hand, the findings demonstrate that co-fired fly ashes can significantly improve the strength and durability properties of concrete compared to ordinary portland cement, in part due to their pozzolanicity. Thus, it is recommended that the ASTM C618 standard be modified to permit co-fired fly ash sources that meet existing requirements and any additional requirements deemed necessary to ensure their satisfactory performance when used in concrete. Toward their potential use in geopolymers, this study characterized the early-age reaction kinetics and rheological behavior of these materials, showing that their exothermic reactivity, plastic viscosity and yield stress are significantly influenced by the activator solution chemistry and other characteristics of the ash. Two co-fired fly ashes were successfully polymerized, with compressive strengths generally highest for ashes activated with solutions with a molar ratio of SiO₂/(Na₂O + K₂O) = 1. The results show that geopolymerization is a viable beneficial reuse for these emerging by-products. Further characterization of these materials by scanning transmission X-ray microscopy analysis revealed the heterogeneity of the aluminosilicate phase composition of the co-fired fly ash geopolymer gel at the nano- to micro-scale.

<p>Extending the functional lifetime of acrylic poly(methyl methacrylate) (PMMA) bone cement may reduce the number of revision total joint replacement (TJR) surgeries performed each year. We developed a system utilizing an encapsulated water-reactive, FDA-approved tissue adhesive, 2-octyl cyanoacrylate (OCA), as a healing agent to repair microcracks within a bone cement matrix. The proposed research tested the following hypotheses: (1) reactive OCA can be successfully encapsulated and the resulting capsules thoroughly characterized; (2) the static mechanical properties of the PMMA composite can be improved or maintained through inclusion of an optimal wt% of OCA-containing capsules; (3) PMMA containing encapsulated OCA has a prolonged lifetime when compared with a capsule-free PMMA control as measured by the number of cycles to failure; and (4) the addition of capsules to the PMMA does not significantly alter the biocompatibility of the material. Based on the experiments reported herein, the primary conclusions of this dissertation are as follows: (1) functional OCA can be encapsulated within polyurethane spheres and successfully incorporated into PMMA bone cement; (2) lower wt% of capsules maintained the tensile, compressive, fracture toughness, and bending properties of the PMMA; (3) inclusion of 5 wt% of OCA-containing capsules in the matrix increased the number of cycles to failure when compared to unfilled specimens and those filled with OCA-free capsules; and (4) MG63 human osteosarcoma cell proliferation and viability were unchanged following exposure to OCA-containing PMMA when compared with a capsule-free control.</p> / Dissertation

Rising South African electricity prices and reduced sales following the 2008 economic recession have led cement manufacturers to seek ways to reduce production costs. Prior research has shown that reduced electricity costs are possible by shifting load from expensive Eskom peak pricing periods to lower cost times. Due to the complex considerations and variables in cement production, this is not typically implemented. Several simulation and optimisation models are available in literature to schedule plant operation in an electricity cost effective manner. However, these models have not been implemented in practice. The simulation models are reviewed and evaluated for the task of scheduling cement production on South African factories. A model is identified to be implemented, and the requirements for implementing this model on a cement factory are investigated. A computerised management system is designed to automatically incorporate the required information and data to implement the optimisation model on a practical level. An interface is also designed to allow factory personnel access to the optimised production plan. The system is implemented and evaluated through system level testing. Four case studies are presented within which the system is implemented on South African cement factories. The performance of the system is evaluated over a nine month period, within which a total cost saving of R8.6-million is reported. / Thesis (MIng (Computer and Electronic Engineering))--North-West University, Potchefstroom Campus, 2013.

Cement production is an energy intensive process. In South Africa the cost of energy increased since 2006, while cement sales have dropped dramatically. It has become important to focus on methods to optimise energy consumption to achieve cost savings in the cement industry. Various methods of reducing production cost by improving energy efficiency are available, but require extended installation periods and high initial capital expenditure. Other methods such as operational optimisation can reduce production cost, but offer limited savings. The aim of this study is to integrate the optimisation of multiple component operations to improve savings and reduce interruption during implementation. Although integrated optimisation models have been developed, no literature could be found on the application of these models in the cement industry. This thesis reports on the development and implementation of an energy management system at four South African cement plants. The total electricity costs were reduced without installing costly infrastructure upgrades. The results summarise the success of the improved production planning. A conclusion regarding the feasibility of this implementation is compiled by comparing the savings achieved by the implementation of the energy management system to other energy saving methods. Recommendations are also made for further study and the implementation of the energy management system in similar industries. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

South African cement manufacturers are under financial pressure. Sales have declined due to the 2008 recession and electricity costs have tripled from 2005 to 2012. Electricity cost savings are therefore more important than ever. Unfortunately retrofitting highly energyefficient equipment is not ideal. These installations are costly and take a long time to implement. Alternative strategies that can produce quick results in reducing electricity costs are needed. One such alternative is a programme called Demand Market Participation (DMP). The DMP programme was implemented by Eskom, South Africa’s national electricity utility, to reduce electricity demand during supply shortages. This programme offers potential cost savings for clients with excess production capacity. Clients such as cement plants can switch off non-essential production equipment in Eskom’s peak demand periods for a financial incentive. To maximise the benefits for both the clients and Eskom, accurate electricity forecasting is needed, as are systems enabling a quick response to load reduction requests. In this study DMP opportunities on typical cement plants were identified. A DMP strategy to assist cement plants was developed to achieve maximum cost savings without influencing production, quality and safety. An existing energy management system (EnMS) was adapted to incorporate the new DMP participation strategy. The new EnMS and DMP strategy were implemented at a South African cement plant, resulting in savings of R220 000 per month. This translates into an annual cost-saving potential of R2-million for the plant, and an R13- million cost-saving potential for the total South African cement industry. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2014

Rising South African electricity prices and reduced sales following the 2008 economic recession have led cement manufacturers to seek ways to reduce production costs. Prior research has shown that reduced electricity costs are possible by shifting load from expensive Eskom peak pricing periods to lower cost times. Due to the complex considerations and variables in cement production, this is not typically implemented. Several simulation and optimisation models are available in literature to schedule plant operation in an electricity cost effective manner. However, these models have not been implemented in practice. The simulation models are reviewed and evaluated for the task of scheduling cement production on South African factories. A model is identified to be implemented, and the requirements for implementing this model on a cement factory are investigated. A computerised management system is designed to automatically incorporate the required information and data to implement the optimisation model on a practical level. An interface is also designed to allow factory personnel access to the optimised production plan. The system is implemented and evaluated through system level testing. Four case studies are presented within which the system is implemented on South African cement factories. The performance of the system is evaluated over a nine month period, within which a total cost saving of R8.6-million is reported. / Thesis (MIng (Computer and Electronic Engineering))--North-West University, Potchefstroom Campus, 2013.

Cement production is an energy intensive process. In South Africa the cost of energy increased since 2006, while cement sales have dropped dramatically. It has become important to focus on methods to optimise energy consumption to achieve cost savings in the cement industry. Various methods of reducing production cost by improving energy efficiency are available, but require extended installation periods and high initial capital expenditure. Other methods such as operational optimisation can reduce production cost, but offer limited savings. The aim of this study is to integrate the optimisation of multiple component operations to improve savings and reduce interruption during implementation. Although integrated optimisation models have been developed, no literature could be found on the application of these models in the cement industry. This thesis reports on the development and implementation of an energy management system at four South African cement plants. The total electricity costs were reduced without installing costly infrastructure upgrades. The results summarise the success of the improved production planning. A conclusion regarding the feasibility of this implementation is compiled by comparing the savings achieved by the implementation of the energy management system to other energy saving methods. Recommendations are also made for further study and the implementation of the energy management system in similar industries. / Thesis (MIng (Mechanical Engineering))--North-West University, Potchefstroom Campus, 2013.

Deterioration of reinforced concrete structures due to reinforcement corrosion is a serious problem that faces concrete infrastructure worldwide. Effect of the rebar corrosion in the shear span on the structural behaviour is not fully addressed in the published literature. This study examined the effects of corrosion of the longitudinal reinforcement in the shear span on the structural behaviour of RC beams and the effectiveness of three rehabilitation schemes on the structural performance of such beams. The experimental program consisted of testing fifteen medium-scale reinforced concrete beams (150mm wide x 350mm deep x 2400mm long) under static load. Test variables included: span to depth ratio, the degree of corrosion and the anchorage end condition and repair schemes. Two span to depth (a/d) ratios were considered: a/d=3.4 with one-point loading and a/d=2.4 with two-point loading. Two anchorage end-conditions were used: bonded or un-bonded reinforcement in the an-chorage zone. Four degrees of corrosion were chosen to simulate minor (2.5% to 5% mass loss), medium (7.5% mass loss), and severe (15% mass loss) degrees of corrosion. Corrosion was induced in the longitudinal reinforcement in the shear-span using accelerated corrosion techniques based on Faradays’ law. Three different repair scenarios were applied. The first scenario included removing the deteriorated concrete, cleaning the corroded steel and patching with a new self-compacting concrete. The second scenario included U-wrapping the beams cross-section using Glass fiber reinforced cement-based composite (GFRCM), and Carbon fiber reinforced cement-based composite (CFRCM) without removing the deteriorated concrete. The third scenario included patch repair and confinement by wrapping with GFRCM or CFRCM. Following corrosion and repair, all specimens were loaded statically to failure. Test results showed no major effect of shear-span corrosion on the flexural behaviour for the beams with end anchorage whereas a noticeable effect on the flexural behaviour was observed for beams with no end anchorage regions. The corrosion degree and the shear span to depth ratio affected the mode of failure for the specimens with no end anchorages. The type of repair significantly affected the overall behaviour of the corroded specimens. An analytical model was proposed and used to predict the load-deflection response of the tested specimens. The program calculated the mid-span deflection for a given load as an integration of the deflection of a series of elements, with the deflection being based on the elongation of the steel reinforcement in each element. A modified bond stress-slip model was incorporated into the calculations to account for the change in bond strength caused by the corrosion and/or confinement that are provided by repairs. The predicted results were in reasonable agreement with the experimental results.