Thesis (Ph. D.)--University of Texas at Austin, 2005. / Vita. Includes bibliographical references.

Thesis (Ph. D.)--State University of New York at Binghamton, Chemistry Department, 2005. / Includes bibliographical references.

Thesis (Ph. D.)--University of Texas at Austin, 2008. / Vita. Includes bibliographical references.

Yang, Li. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references (leaves 67-72). / Abstract also in Chinese. / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Background and Motivation --- p.1 / Chapter 1.2 --- Objectives --- p.2 / Chapter 1.3 --- Contributions --- p.2 / Chapter 1.4 --- Organization of the Dissertation --- p.3 / Chapter 2 --- Carbon Nanotubes as Sensing Elements --- p.4 / Chapter 2.1 --- Introduction --- p.4 / Chapter 2.2 --- Introduction to Carbon Nanotubes --- p.4 / Chapter 2.3 --- Chemical Sensor Applications --- p.6 / Chapter 2.3.1 --- Semiconducting Sensors --- p.7 / Chapter 2.3.2 --- Dielectric Sensors --- p.8 / Chapter 2.3.3 --- Adsorption Based Sensors --- p.9 / Chapter 2.4 --- Dielectrophoresis of CNTs --- p.9 / Chapter 2.4.1 --- Theory and Methodology --- p.10 / Chapter 2.4.2 --- Basic CNTs Sensor Fabrication Process Using DEP Force --- p.13 / Chapter 2.4.3 --- Electronic-Grade Carbon Nanotubes --- p.13 / Chapter 2.4.4 --- Simulation --- p.14 / Chapter 2.5 --- Photodesorption Phenomenon --- p.16 / Chapter 2.5.1 --- Chemical Desorption Process Induced by UV Illumination --- p.16 / Chapter 2.6 --- Summary --- p.19 / Chapter 3 --- Design of NaOCl Sensors Based on EG-CNTs in Microfluidic System --- p.20 / Chapter 3.1 --- Introduction --- p.20 / Chapter 3.2 --- Chemical --- p.20 / Chapter 3.2.1 --- Introduction to Chemical Properties and Reactions --- p.21 / Chapter 3.2.2 --- Reagents --- p.23 / Chapter 3.3 --- Methods for Chemical Detection --- p.23 / Chapter 3.3.1 --- Hypochlorite Detection --- p.23 / Chapter 3.3.2 --- Chlorine Gas Detection --- p.24 / Chapter 3.4 --- Design and Fabrication --- p.26 / Chapter 3.4.1 --- Sodium Hypochlorite Sensor Using Microfluidic System --- p.26 / Chapter 3.4.2 --- Modified Design For Indirect Detection to Chlorine Gas --- p.29 / Chapter 3.5 --- Equipments --- p.30 / Chapter 3.5.1 --- Source Meter --- p.30 / Chapter 3.5.2 --- Pneumatic Pump --- p.31 / Chapter 3.5.3 --- UV Illumination Devices --- p.31 / Chapter 3.5.4 --- Experimental Setup --- p.32 / Chapter 3.6 --- Summary --- p.34 / Chapter 4 --- Results --- p.35 / Chapter 4.1 --- Introduction --- p.35 / Chapter 4.2 --- Processes of the Experiments --- p.35 / Chapter 4.2.1 --- Response to Static Solution --- p.35 / Chapter 4.2.2 --- Response to Fluid Flow --- p.36 / Chapter 4.2.3 --- Response to Gas --- p.36 / Chapter 4.3 --- Noise and Accuracy --- p.37 / Chapter 4.4 --- I-V Characteristics --- p.38 / Chapter 4.4.1 --- EG-CNTs Sensor --- p.38 / Chapter 4.4.2 --- Variation Under UV Illumination --- p.39 / Chapter 4.5 --- Responses to Sodium Hypochlorite Solution --- p.41 / Chapter 4.5.1 --- Typical Responses --- p.41 / Chapter 4.5.2 --- Selectivity --- p.44 / Chapter 4.5.3 --- Sensitivity --- p.45 / Chapter 4.5.4 --- Effect of Injection Flow Rate on Sensor Performance --- p.50 / Chapter 4.5.5 --- Effect of Volume on Sensor Performance --- p.51 / Chapter 4.5.6 --- Continuous Detection --- p.54 / Chapter 4.5.7 --- Operating Power Limit --- p.57 / Chapter 4.6 --- Response to Chlorine Gas by Modified Design --- p.59 / Chapter 4.7 --- Desorption Induced by UV Illumination --- p.60 / Chapter 4.8 --- Summary --- p.63 / Chapter 5 --- Conclusion --- p.64 / Chapter 5.1 --- Future Work --- p.65 / Chapter 5.1.1 --- Selectivity --- p.65 / Chapter 5.1.2 --- Gaseous Chlorine Detection --- p.66 / Chapter 5.1.3 --- UV-LED Induced Desorption --- p.66 / Chapter 5.2 --- Concluding Remarks --- p.66 / Bibliography --- p.67

A sensing method that can monitor metallic structures continuously would eventually produce safer metallic structures as well as a more efficient and economic way to monitor corrosion. A secondary focus of this research is the implementation of a fiber optic sensor to measure refractive indices of unknown solutions. The surface plasmon sensor, interrogated with white light resulted in attenuations of light at different wavelengths when solutions of different refractive indices were introduced. This sensor has been shown to respond to the three configurations of polished single mode and multimode, as well as the unpolished multimode sensors. The sensitivity calculated was comparable with the sensitivity of the Kretschmann arrangement The transmissive aluminum-clad fiber sensor was shown to be effective in providing a response to the process of corrosion. Varying lengths of aluminum-clad fiber was spliced to acrylate multimode fiber and different wavelengths of sources were used to test the sensor in a bath of NaOH. The results were similar and reproducible. A tapered sensor configuration was attempted and proved to be very useful. / Master of Science

This dissertation describes the design, development and results of a simple, inexpensive, rugged, pyroelectric heat-of-reaction detector that can be made in many configurations. The measured heat of reaction results from the reaction of a substrate on an enzyme. The enzyme is immobilized in a flow channel with a pyroelectric polymer film, poly(vinylidene fluoride) or PVDF. The sample is introduced into the flow channel using flow injection analysis technology. The heat from the reaction causes the pyroelectric material to produce an electrical potential proportional to the change in temperature which, in turn, is proportional to the substrate concentration. This potential is amplified and recorded. A differential instrument amplifier produces a difference signal from a sample and reference PVDF film. This removes noise caused by stray electromagnetic radiation and piezoelectric pressure responses. A conventional Flow Injection Analysis unit was employed. The FIA flow rate was four ml/min and the time from injection to peak maximum was less than three seconds, with a return to baseline of less than thirty seconds. This gives a quick analysis time and a reasonable number of analyses per unit time. Data interpretation is straight forward, peak height is proportional to the concentration. A 70 μl sample gives a good response. Larger samples do not improve the signal. The system showed minimum detectable number of moles that is comparable to other methods, 7 x 10⁻⁸ moles. The detector showed good response for more than two orders of magnitude. The results show excellent correlation to the modeled system of heat trans+er through the PVDF sensor. / Ph. D.

Hydrogen terminated silicon surfaces have been utilized to develop sensors for semiconductor and environmental applications. The interaction of these surfaces with different environments has also been studied in detail. The sensor assembly relevant to the semiconductor industry utilizes a silicon-based sensor to detect trace levels of metallic contaminants in hydrofluoric acid. The sensor performance with respect to two non-contaminating reference electrode systems was evaluated. In the first case, conductive diamond was used as a reference electrode. In the second case, a dual silicon electrode system was used with one of the silicon-based electrodes protected with an anion permeable membrane behaving as the quasi reference electrode. Though both systems could function well as a suitable reference system, the dual silicon electrode design showed greater compatibility for the on-line detection of metallic impurities in HF etching baths. The silicon-based sensor assembly was able to detect parts- per-trillion to parts-per-billion levels of metal ion impurities in HF. The sensor assembly developed for the environmental application makes use of a novel method for the detection of Ni2+using attenuated total reflection (ATR) technique. The nickel infrared sensor was prepared on a silicon ATR crystal uniformly coated by a 1.5 micron Nafion film embedded with dimethylglyoxime (DMG) probe molecules. The detection of Ni2+ was based on the appearance of a unique infrared absorption peak at 1572 cm-1 that corresponds to the C=N stretching mode in the nickel dimethylglyoximate, Ni(DMG)2, complex. The suitable operational pH range for the nickel infrared sensor is between 6-8. The detection limit of the nickel infrared sensor is 1 ppm in the sample solution of pH=8. ATR - FTIR spectroscopy was used to study the changes that the hydride mode underwent when subjected to different environments. The presence of trace amounts of Cu2+ in HF solutions was found to roughen the silicon surface as observed ATR-IR spectroscopy. The initial stages of oxidation in UPW and Cu2+ / UPW was studied. Trace amounts of Cu2+ were found to drastically increase the rate of oxidation, while the rate of oxidation was found to be retarded on removing dissolved oxygen that was present in UPW.

Chow Ka-man. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2001. / Includes bibliographical references (leaves 52-55). / Abstracts in English and Chinese. / Chapter 1 --- Introduction / Chapter 1.1 --- Chemical sensors --- p.1 / Chapter 1.2 --- Quartz crystal microbalance --- p.4 / Chapter 1.3 --- Concept of affinity mass sensor --- p.8 / Chapter 1.4 --- Film immobilization technologies --- p.9 / Chapter 1.5 --- Research outlines --- p.13 / Chapter 2 --- Experimental / Chapter 2.1 --- Sensor fabrication --- p.14 / Chapter 2.2 --- Flow-through cell --- p.16 / Chapter 2.3 --- Analysis procedures --- p.19 / Chapter 2.4 --- Response curve --- p.19 / Chapter 2.5 --- Experimental setup --- p.21 / Chapter 3 --- Detection of ascorbic acid by affinity mass sensor based on 3-aminophenylboronic acid / Chapter 3.1 --- Conventional analytical methods --- p.23 / Chapter 3.2 --- Research method - affinity mass sensor based on APBA --- p.24 / Chapter 3.3 --- To locate the binding site in ascorbic acid --- p.25 / Chapter 3.3.1 --- Steric energy calculated by molecular modeling --- p.26 / Chapter 3.4 --- Optimization of experimental variables --- p.29 / Chapter 3.4.1 --- Effect of pH --- p.29 / Chapter 3.4.2 --- Effect of sample volume --- p.30 / Chapter 3.4.3 --- Effect of flow velocity --- p.30 / Chapter 3.5 --- Calibration and Reproducibility --- p.32 / Chapter 3.6 --- Kinetic analysis --- p.33 / Chapter 3.7 --- Stability of sensor --- p.37 / Chapter 3.8 --- Interference studies --- p.37 / Chapter 3.9 --- Determination of ascorbic acid in real samples --- p.39 / Chapter 3.9.1 --- Results and Discussion --- p.39 / Chapter 3.10 --- Comparison with conventional ascorbic acid sensors --- p.42 / Chapter 3.11 --- Summary --- p.42 / Chapter 4 --- Boronic acid derivatives for the detection of sugars / Chapter 4.1 --- Scope of this work --- p.43 / Chapter 4.2 --- Results and Discussion --- p.44 / Chapter 4.3 --- Summary --- p.49 / Conclusion --- p.50 / References --- p.52 / List for tables --- p.56 / List for figures --- p.57 / Appendix I --- p.59 / Appendix II --- p.61

Ouyang, Mengxing. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2009. / Includes bibliographical references (leaves 83-88). / Abstracts in English and Chinese. / Chapter 1. --- Introduction --- p.1 / Chapter 1.1 --- Background and Motivation --- p.1 / Chapter 1.2 --- Objectives --- p.2 / Chapter 1.3 --- Contributions --- p.3 / Chapter 1.4 --- Organization of the Dissertation --- p.3 / Chapter 2. --- CNTs and Their Application as Sensors --- p.5 / Chapter 2.1 --- Introduction to CNTs --- p.5 / Chapter 2.2 --- CNTs Based Sensors --- p.8 / Chapter 3. --- F-CNTs Based Ethanol Sensors --- p.10 / Chapter 3.1 --- Introduction --- p.10 / Chapter 3.1.1 --- Carbon Nanotube Alcohol Sensors --- p.11 / Chapter 3.1.2 --- CNTs Sensor Configuration --- p.12 / Chapter 3.1.3 --- Activation of CNTs Sensor --- p.13 / Chapter 3.1.4 --- Functionalization of CNTs --- p.14 / Chapter 3.2 --- Fabrication of F-CNTs Based Ethanol Sensors --- p.16 / Chapter 3.2.1. --- Fabrication of f-CNTs --- p.16 / Chapter 3.2.2. --- Fabrication of Sensing Elements by DEP Manipulation --- p.17 / Chapter 3.2.3. --- Experimental Setup --- p.19 / Chapter 3.2.4. --- Mechanism of Ethanol Sensor --- p.20 / Chapter 3.3 --- Characterization of F-CNTs Based Ethanol Sensors --- p.21 / Chapter 3.3.1. --- I-V Characteristics --- p.21 / Chapter 3.3.2. --- Thermal Sensitivity --- p.22 / Chapter 3.3.3. --- Stability --- p.23 / Chapter 3.3.4. --- FFT and Spectral Analysis --- p.23 / Chapter 3.4 --- Performance of F-CNTs Based Ethanol Sensors --- p.26 / Chapter 3.4.1. --- Typical Response --- p.26 / Chapter 3.4.2. --- Selectivity --- p.27 / Chapter 3.4.3. --- Towards Low Concentration --- p.28 / Chapter 3.4.4. --- Towards Realistic application --- p.29 / Chapter 3.5 --- Constant Power Configuration --- p.32 / Chapter 3.5.1. --- Constant Power Circuit for Ethanol Detection --- p.32 / Chapter 3.5.2. --- Sensor Response versus Power --- p.35 / Chapter 3.5.3. --- Responsivity --- p.37 / Chapter 3.5.4. --- Noise --- p.38 / Chapter 3.5.5. --- Sensitivity --- p.39 / Chapter 3.5.6. --- Dynamic Response --- p.41 / Chapter 3.6 --- Comparison between F-MWNTs and MWNTs --- p.43 / Chapter 3.6.1. --- I-V Characteristics --- p.43 / Chapter 3.6.2. --- Cycling Response --- p.44 / Chapter 3.6.3. --- Dynamic Response --- p.46 / Chapter 3.6.4. --- Sensor Performance under Different Power --- p.48 / Chapter 3.7 --- Summary --- p.53 / Chapter 4. --- EG-CNTs Based Flow Sensors --- p.55 / Chapter 4.1 --- Introduction to CNTs Flow Sensors --- p.55 / Chapter 4.2 --- EG-CNTs and Their Applications --- p.56 / Chapter 4.2.1 --- Intro to EG-CNTs Sensor --- p.56 / Chapter 4.2.2 --- Fabrication of EG-CNTs Sensor --- p.57 / Chapter 4.2.3 --- Experimental Characterization --- p.59 / Chapter 4.2.3.1. --- I-V Characteristics --- p.59 / Chapter 4.2.3.2. --- Thermal Sensitivity --- p.61 / Chapter 4.2.3.3. --- Humidity responsivity --- p.63 / Chapter 4.2.3.4. --- Stability --- p.65 / Chapter 4.2.3.5. --- Hysteresis --- p.66 / Chapter 4.2.4 --- Summary --- p.68 / Chapter 4.3 --- Fabrication of EG-CNTs Flow Sensor --- p.70 / Chapter 4.3.1. --- Fabrication Procedure --- p.70 / Chapter 4.3.2 --- Experimental Setup --- p.73 / Chapter 4.4 --- Characterization of EG-CNTs Flow Sensor --- p.74 / Chapter 4.4.1. --- Typical Response --- p.74 / Chapter 4.4.2. --- Power Consumption --- p.75 / Chapter 4.4.3. --- Repeatability --- p.77 / Chapter 4.4.4. --- Flow Sensitivity --- p.78 / Chapter 4.5 --- Summary --- p.79 / Chapter 5. --- Conclusion --- p.80 / Chapter 6. --- Bibliography --- p.83

Triethanolamine (TEA) is a semiconducting polymer which exhibits a resistance change when exposed to various gases. The polymer also exhibits a number of reactions with nitrogen dioxide, with the reaction products being heavily dependent on the presence or absence of water vapor. Previous studies have attempted the incorporation of a TEA-carbon nanoparticle composite as the active sensing layer in a chemresistive sensor for detection of NO₂. The incorporation of carbon nanoparticles in the polymer nanocomposite was thought to amplify the sensor's response. There are a number of chemical reactions that can occur between TEA and NO₂, with the reaction products being heavily dependent on the presence and amount of water vapor in the environment. Because of this influence, it becomes necessary to know to what degree the presence of water vapor interferes with the sensing response. In this work we show that the sensor exhibits a reversible resistance change as background humidity changes. This sensitivity to humidity changes is so large that it renders undetectable any resistance change that could be caused by the reaction of TEA with NO₂. Furthermore, we show that the presence of low levels of NO₂ do not interfere with adsorption of water vapor. The detection mechanism is based on measuring resistance changes in the TEA film due to the adsorption/desorption of water vapor. The sensing response can be described by Langmuir adsorption by using a site-based model for the polymer film resistance. Breakdown of the polymer film over time due to continuous adsorption of water vapor, as well as photodegradation of the polymer film, will be discussed. SEM images will also be presented showing growth of crystallites on the electrode walls, as well as experimental results demonstrating degradation of the sensing film during sensor operation.