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No / In order to investigate the eccentric compression behaviors of steel-FRP composite bar (SFCB) reinforced concrete (RC) columns subjected to chloride corrosion, the mechanical experiments of chloride corroded SFCBs and SFCBs RC eccentric compression columns were conducted. The effect of reinforcement type and ratio, eccentricity, slenderness, stress level and corrosion duration on bearing capacity, deformation, crack and failure pattern were investigated. The results showed that the strength retention ratio of reinforcement decreases with the increase of corrosion duration, the ultimate strengths of steel rebar, SFCB and FRP rebar decreased by 12.2%, 9.9% and 3.6%, respectively, when compared with those of uncorroded counterparts. With the increase of steel content of reinforcement, the load bearing capacity of eccentric compression RC column increases while the deformation decreases gradually. The load bearing capacity of corroded steel, SFCB and FRP RC columns maximally decreased by 16.6%, 12.4% and 7.2%, respectively, when compared with those of uncorroded counterparts. Based on the simplified materials constitutive relations and reasonable basic assumptions, formulae for discriminate failure mode, moment magnification factor and bearing capacity were developed. The predicted failure pattern, moment magnification factor and bearing capacity are in good agreement with the test results, confirming the validity of the proposed formulae, the results can be used as a reference for engineering application. / High-End Foreign Experts Project of Ministry of Science and Technology, China (G2022014054L), the Natural Science Foundation of Jiangsu Province, China (BK20201436), the Science and Technology Project of Jiangsu Construction System (2018ZD047, 2021ZD06), the Science and Technology Project of Gansu Construction System (JK2021-19), the Opening Foundation of Jiangsu Province Engineering Research Center of PrefabricatedBuilding and Intelligent Construction (2021), the Science and Technology Cooperation Fund Project of Yangzhou City and Yangzhou University (YZ2022194, YZU212105), the Science and Technology Project of Yangzhou Construction System (2022ZD03, 202204), the Nantong Jianghai (226) talents project, the Blue Project Youth Academic Leader of Colleges and Universities in Jiangsu Province (2020).

Yes / This paper presents test results of eccentrically loaded concrete columns reinforced with steel-fibre-reinforced polymer (FRP) composite bars (SFCBs) subjected to chloride corrosion. The first stage of the experimental work explored the tensile and compressive tests of various reinforcements (SFCBs with different cross section, steel and FRP bars) used in the large reinforced concrete (RC) columns after chloride corrosion with or without sustained stresses. The results showed that the tensile and compressive stress-strain relationships of SFCBs are characterised by stable secondary (post-yield) stiffness. The second stage of the testing investigated the structural performance of RC columns with various amounts and types of reinforcements, slenderness ratio, applied load eccentricity and chloride corrosion rate. The results showed that the effect of reinforcements on eccentric compression behaviour is significant. The deformation and crack width of SFCB RC columns, respectively, decreased by 12.2%~52.6% and 8.5%~71.0%, while the load capacity improved by 0.9%~18.8%, when compared with the corresponding FRP RC columns having the same eccentricity and reinforcement ratio. The use of SFCBs as the reinforcement of RC columns, especially with high reinforcement ratio or SFCBs having high area ratio of inner steel to SFCB, is beneficial to reduce the deflection and crack width as well as improve the bearing capacity utilization coefficients under serviceability limit state.

We focused on a non-cooling room temperature microbolometer infrared imaging array device which includes a sensing layer of p-type a-Si:H component layers doped with boron. Boron incorporation and bonding configuration were investigated for a-Si:H films grown by plasma enhanced chemical deposition (PECVD) at varying substrate temperatures, hydrogen dilution of the silane precursor, and dopant to silane ratio using multiple internal reflection infrared spectroscopy (MIR-IR). This study was then confirmed from collaborators via Raman spectroscopy. MIR-IR analyses reveal an interesting counter-balance relationship between boron-doping and hydrogen-dilution growth parameters in PECVD-grown a-Si:H. Specifically, an increase in the hydrogen dilution ratio (H2/SiH4) or substrate temperature was found to increase organization of the silicon lattice in the amorphous films. It resulted in the decrease of the most stable SiH bonding configuration and thus decrease the organization of the film. The new chemical bonding information of a-Si:H thin film was correlated with the various boron doping mechanisms proposed by theoretical calculations. The study revealed the corrosion morphology progression on aluminum alloy (Al, 0.5% Cu) under acidic chloride solution. This is due to defects and a higher copper content at the grain boundary. Direct galvanic current measurement, linear sweep voltammetry (LSV), and Tafel plots are used to measure corrosion current and potential. Hydrogen gas evolution was also observed (for the first time) in Cu/Al bimetallic interface in areas of active corrosion. Mechanistic insight that leads to effective prevention of aluminum bond pad corrosion is explored and discussed. (Chapter 4) Aluminum bond pad corrosion activity and mechanistic insight at a Cu/Al bimetallic interface typically used in microelectronic packages for automotive applications were investigated by means of optical and scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and electrochemistry. Screening of corrosion variables (temperature, moisture, chloride ion concentration, pH) have been investigated to find their effect on corrosion rate and to better understand the Al/Cu bimetallic corrosion mechanism. The study revealed the corrosion morphology progression on aluminum alloy (Al, 0.5% Cu) under acidic chloride solution. The corrosion starts as surface roughening which evolves into a dendrite structure and later continues to grow into a mud-crack type corrosion. SEM showed the early stage of corrosion with dendritic formation usually occurs at the grain boundary. This is due to defects and a higher copper content at the grain boundary. The impact of copper bimetallic contact on aluminum corrosion was explored by sputtering copper microdots on aluminum substrate. Copper micropattern screening revealed that the corrosion is activated on the Al/Cu interface area and driven by the large potential difference; it was also seen to proceed at much higher rates than those observed with bare aluminum. Direct galvanic current measurement, linear sweep voltammetry (LSV), and Tafel plots are used to measure corrosion current and potential. Hydrogen gas evolution was also observed (for the first time) in Cu/Al bimetallic interface in areas of active corrosion. Mechanistic insight that leads to effective prevention of aluminum bond pad corrosion is explored and discussed. Micropattern corrosion screening identified hydrogen evolution and bimetallic interface as the root cause of Al pad corrosion that leads to Cu ball lift-off, a fatal defect, in Cu wire bonded device. Complete corrosion inhibition can be achieved by strategically disabling the mutually coupled cathodic and anodic reaction cycles.