Volcanic ash, or tephra, blankets the local and regional landscape following a volcanic eruption. If this ash layer is preserved and identified, it can act as a time synchronous marker bed (isochron) for correlation between marine, terrestrial, glacial and lacustrine deposits. This can be a powerful tool when attempting to determine the true age of a marine sample (e.g. clam or mollusk), affected by the marine reservoir effect (MRE). The MRE causes dated radiocarbon to appear the age that carbon was last in equilibrium with the atmosphere rather than the time that a dated material was deposited. The offset (in years) caused by the MRE is referred to as ΔR. Presented in this study is new data on the lowermost part of SWERUS-L2-2-PC1 (2PC), a marine sedimentary core retrieved from the Chukchi shelf north of Siberia. By using quantification of rhyolitic tephra to locate tephra-rich layers for further study, results show a thick layer that is interpreted to have originated from the caldera-forming eruption of Aniakchak (Aniakchak II). The geochemical identification of the tephra was done using electron probe micro-analysis. A grain size analysis was also conducted to learn more about the sedimentology of 2PC and the possible proxies that can be used when trying to determine where to place the isochron. The isochron was finally placed with the help of relevant literature and the results from this study. That position shifted the previous age model of 2PC at a position to yield a ΔR of 482 years for the Chukchi Sea during this time period.

Loss of sea ice due to global warming may affect the phenology and distribution of polar bear (Ursus maritimus) denning by altering access to denning habitats. We examined trends in the selection of maternal denning substrate (land versus sea-ice denning) in the southern Beaufort Sea (SB), addressing the potential influence of summer land-use and fall sea-ice conditions on substrate selection. We developed an algorithm based on statistical process control methods to remotely identify denning bears and estimate denning phenology from temperature sensor data collected on collars deployed 1985–2013 in the SB and Chukchi Sea (CS). We evaluated cub survival relative to den entrance, emergence, and duration, and examined differences in the phenology of land and sea-ice dens. Land denning in the SB was more common during years when ice retreated farther from the coast and off of the continental shelf in September. All SB bears that occupied land prior to denning subsequently denned on land; however, only 29% of denning bears that summered on sea ice denned on land. Den entrance and duration in the SB and CS were similar, although CS bears emerged later. Land dens were occupied longer than those on ice. Bears later observed with cubs remained in dens 23 days longer and emerged from denning 17 days later on average than bears that denned but were subsequently observed without cubs, suggesting that den exit dates are related to cub survival. The increase in land-based denning in the SB when sea ice retreated farther from shore, along with the positive correlation between fall land-use and land denning, suggest that further sea-ice declines may result in continued increases of onshore denning. Growing numbers of denning females along the coast may increase the potential for human-bear interactions.

Environmental data hold important information regarding humanity’s past, present, and future, and are managed in various ways. The database structure most commonly used in contemporary applications is the relational database. Its usage in the scientific world for managing environmental data is not as popular as in businesses enterprises. Attention is caught by the diverse nature and rapidly growing volume of environmental data that has been increasing substantially in recent. Environmental data for the Chukchi Sea, with its embedded potential oil resources, have become important for characterizing the physical, chemical, and biological environment. Substantive data have been collected recently by researchers from the Chukchi Sea Offshore Monitoring in the Drilling Area: Chemical and Benthos (COMIDA CAB) project. A modified Observations Data Model was employed for storing, retrieving, visualizing and sharing data. Throughout the project-based study, the processes of environmental data heterogeneity reconciliation and relational database model modification and implementation were carried out. Data were transformed into shareable information, which improves data interoperability between different software applications (e.g. ArcGIS and SQL server). The results confirm the feasibility and extendibility of employing relational databases for environmental data management. / text

The Chukchi and Beaufort Sea shelves host diverse and productive seafloor ecosystems important for carbon and nitrogen cycling for the Arctic Ocean. The benthic food web transfers energy from primary producers to high trophic level organisms (e.g., birds, fish, and mammals), which are important for cultural practices and subsistence hunting by Native Alaskans. This work focuses on the trophic ecology of arctic food webs through use of several different approaches. First, variation in the natural abundance of stable carbon and nitrogen isotopes facilitated the identification of trophic pathways and, subsequently, allowed the comparison of trophic guilds and food webs from the Chukchi and Beaufort Seas. Compared to water column and sedimentary organic matter end-members, second trophic level grazers and suspension feeders were conspicuously ¹³C-enriched throughout the Chukchi Sea, which supports the hypothesis that microbial degradation of organic matter occurred prior to metazoan assimilation. Second, food web recovery from disturbances caused by exploratory oil drilling at the seafloor that had occurred approximately 20 years prior were assessed in both the Chukchi and Beaufort Seas. Based on isotopic trophic niche overlap between organisms common to drilled and reference sites in the Chukchi and Beaufort Seas, the oil drilling sites had similar food web structure, indicating recovery from the activity associated with the drilling process. Third, photosynthetic pigment biomarkers were used to better understand the diagenetic process, specifically focusing on how both microbial and metazoan grazing pathways degrade organic matter in relation to seasonal sea ice retreat in the Chukchi Sea. The benthic macrofaunal and microbial food web caused rapid degradation of organic matter upon the initial pulse of microalgal food sources to the seafloor. These diagenetic pathways are linked to the ¹³C-enrichment of residual organic matter, which corresponds to the stable isotope values measured in the benthic macrofauna. Lastly, high-precision liquid chromatography and spectrophotometry were compared for estimating sedimentary pigments in the marine environment. Substantial differences in pheopigment (chlorophyll degradation products) concentrations were observed between the two techniques, suggesting the need for revisions to the monochromatic spectrophotometric equation that relates absorbance to pigment concentrations. One pheopigment, pheophorbide, was found to interfere with the accuracy of the spectrophotometric equation and caused the overestimation of pheopigments. / text

This thesis develops and demonstrates an approach for estimating the three-dimensional (3D) location of a vocalizing underwater marine mammal using acoustic arrival time measurements at three spatially separated receivers while providing rigorous location uncertainties. To properly account for uncertainty in the measurements of receiver parameters (e.g., 3D receiver locations and synchronization times) and environmental parameters (water depth and sound speed correction), these quantities are treated as unknowns constrained with prior estimates and prior uncertainties. While previous localization algorithms have solved for an unknown scaling factor on the prior uncertainties as part of the inversion, in this work unknown scaling factors on both the prior and arrival time uncertainties are estimated. Maximum a posteriori estimates for sound source locations and times, receiver parameters, and environmental parameters are calculated simultaneously. Posterior uncertainties for all unknowns are calculated and incorporate both arrival time and prior uncertainties. Simulation results demonstrated that, for the case considered here, linearization errors are generally small and that the lack of an accurate sound speed profile does not necessarily cause large uncertainties or biases in the estimated positions. The primary motivation for this work was to develop an algorithm for locating underwater Pacific walruses in the coastal waters around Alaska. In 2009, an array of approximately 40 underwater acoustic receivers was deployed in the northeastern Chukchi Sea (northwest of Alaska) from August to October to record the vocalizations of marine mammals including Pacific walruses and bowhead whales. Three of these receivers were placed in a triangular arrangement approximately 400 m apart near the Hanna Shoal (northwest of Wainwright, Alaska). A sequence of walrus knock vocalizations from this data set was processed using the localization algorithm developed in this thesis, yielding a track whose estimated swim speed is consistent with current knowledge of normal walrus swim speed. An examination of absolute and relative walrus location uncertainties demonstrated the usefulness of considering relative uncertainties for applications where the precise location of the mammal is not important (e.g., estimating swim speed). / Graduate

Sea level regression during the Last Glacial Maximum exposed the Bering Land Bridge, and cut off the connection between the North Pacific and Arctic Ocean, ending the exchange of North Pacific Water through the Bering Strait. Exchange of North Pacific Water comprises a major portion of fresh water input to the Arctic Ocean, and is of vital importance to North Atlantic Deep Water formation, a vital component of Atlantic Meridional Overturning Circulation. Bering Strait throughflow thus plays an integral role in global climate stability. A suite of four cores was selected, three in the Bering Sea and one in the Chukchi Sea, to bracket the Bering Strait in order to elucidate changes in sediment delivery, productivity and regional oceanography as the Bering Land Bridge flooded and modern ocean circulation was established during the last deglaciation. The arrival of nutrient rich North Pacific Water in the Chukchi Sea is recorded around 8 ka by organic carbon isotope depletion and an increase in total organic carbon and organic nitrogen, reflecting an increasingly marine isotopic signal and increased productivity. In the Bering Sea, the early deglaciation is marked by depleted organic carbon isotopes that indicate increasing terrestrial input, and increased total organic carbon. Principal component analysis of sedimentologic, geochemical and isotopic data clearly captures discrete sediment populations that correspond to key climatic intervals, representing changes in sediment delivery, productivity and circulation during the last deglaciation. In the Bering Sea we observe that deglaciation began in earnest around 18–17 ka, but lack of confidence in our age control does not allow for a precise date. Our results suggest that modern circulation through the Bering Strait, and thus for the Bering and Chukchi Seas, was established ~8 ka. Prior to 8 ka there is an interval of sediment that appears record a possible reversal of flow through the Bering Strait corresponding to the 8.2 ka event.

Tephrochronology is a powerful tool to correlate and improve the chronology of sedimentaryarchives in the Arctic Ocean. The Aniakchak Caldera Forming Eruption (CFE) in Alaska at3.6 cal kyr BP ejected ash that were found in a widespread layer in Alaska, and as cryptotephrain the Chukchi Sea, Newfoundland, and Greenland. This study presents data from the coreSWERUS-L2-4-PC1 (4PC) taken at a water depth of 120 m in the Chukchi Sea. The sharp peakin tephra shards concentration permitted to clearly place the isochron. Unfortunately, the microprobeanalyses were unsuccessful, however measurements of trace elements were performedwith Laser Ablated-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS). The geochemicalsignature of the Aniakchak 3.6 eruption was ensured with significant trace elementratios. The isochron of the eruption combined with the radiocarbon dates from 4PC permittedto calculate the local marine radiocarbon reservoir age offset DR=36446 years. This value isrelatively low compared to recent estimates in the Chukchi Sea, especially to the neighbouringcore SWERUS-L2-2-PC1 were DR=47760. The DR value of this study is explained by theinfluence of the "young" Atlantic water mixing with the "old" Pacific water at the depth wherethe core was taken.

Hydrologic Information Systems (HIS) have emerged as a means to organize, share, and synthesize water data. This work extends current HIS capabilities by providing additional capacity and flexibility for marine physical and chemical observations data and for freshwater and marine biological observations data. These goals are accomplished in two broad and disparate case studies – an HIS implementation for the oceanographic domain as applied to the offshore environment of the Chukchi Sea, a region of the Alaskan Arctic, and a separate HIS implementation for the aquatic biology and environmental flows domains as applied to Texas rivers. These case studies led to the development of a new four-dimensional data cube to accommodate biological observations data with axes of space, time, species, and trait, a new data model for biological observations, an expanded ontology and data dictionary for biological taxa and traits, and an expanded chain-of-custody approach for improved data source tracking. A large number of small studies across a wide range of disciplines comprise the “Long Tail” of science. This work builds upon the successes of the Consortium of Universities for the Advancement of Hydrologic Science, Inc. (CUAHSI) by applying HIS technologies to two new Long Tail disciplines: aquatic biology and oceanography. In this regard this research improves our understanding of how to deal with collections of biological data stored alongside sensor-based physical data. Based on the results of these case studies, a common framework for water information management for terrestrial and marine systems has emerged which consists of Hydrologic Information Systems for observations data, Geographic Information Systems for geographic data, and Digital Libraries for documents and other digital assets. It is envisioned that the next generation of HIS will be comprised of these three components and will thus actually be a Water Information System of Systems. / text

No description available.

The sediment Core SWERUS-L2-2-PC1 (2PC) retrieved from the Chukchi Sea, Arctic Ocean sits in an oceanographically dynamic location at the Arctic-Pacific Ocean gateway. The 8.3 m-long core was retrieved in Herald Canyon at the marginal ice zone at 57 m depth. Core 2PC is well-positioned to record variability in inflow of Bering Sea Water (BSW) and Pacific Water (PW) in Herald Canyon. With the 2PC high sedimentation rate (200 cm/kyr), two independent age models (radiocarbon and palaeomagnetism) based on tephra age markers, and a richness in well-preserved siliceous sediment, validate 2PC as an outstanding sequence for applying diatom assemblage analysis as a proxy for ocean-climate change back to 4250 years BP, including the past few hundred years where global warming and sea ice decline is recorded by instrumental records. These characteristics make Core-2PC a useful record for investigating the role of PW on sea ice variability in the Chukchi Sea, both in the past and predicting the future. To investigate the impact of PW on ocean and sea ice conditions in the Chukchi Sea, diatom assemblage analysis was performed on 49 samples through the Late Holocene. The over-arching goal was to test the hypothesis, suggested by existing research on 2PC using benthic foraminifera Mg/Ca palaeothermometry, that the strength of PW inflow into the Chukchi Sea via Herald Canyon has varied on a time scales of ~500-1000 years in the past 4000 years. PW is slightly warmer than resident Arctic surface waters and is known to be an important control on Arctic sea-ice. The diatom assemblage approach assumes that there are recognizable differences between end-member diatom assemblages that are characteristic of PW versus Arctic Ocean type environments associated with extensive sea-ice conditions. The mapping of species in the Herald Canyon was used to test the idea of variability of sea-ice extent and the role of the Pacific Ocean forcings into the western Chukchi Sea. The results reveal diverse diatom assemblages throughout the past 4000 years in Herald Canyon, showing this core to be very useful for diatom palaeoclimate reconstructions. A total of 126 species with abundance >1% are recognized. Several generalist species typically dominate assemblages especially Chaetoceros, ice-algae, marine-neritic and near ice or cold-water planktic centric diatoms. Distinct changes in stratigraphy are illustrated by changes in identified diatom assemblage zones. The 2PC diatom assemblages were contrasted with records from Chukchi-, Laptev-, East Siberian- and Bering Sea and North Pacific Ocean. At 2PC, sympagic (sea-ice related), planktic and neritic species abundance varies on time scales of ~500-1000 years. Importantly, there is a clear similarity between the timing of diatom assemblage changes and the 2PC benthic foraminifera Mg/Ca bottom water temperature (BWT) reconstruction. In particular, abundance changes in the warm water species Thalassionema nitzschioides, Shionodiscus oestrupii and Thalassionema simonsenii, tychoplanktic Paralia sulcata, Ice algae- and sympagic assemblages and cold-water indicators correspond best to BWT fluctuations shown by the Mg/Ca reconstruction. These oscillations are suggestive of changes in warmer PW inflow. Other aspects of the diatom data appear to correlate with colder and warmer climate events and suggest that changes in PW inflow amplified the effects of these events in the Chukchi Sea region through the Late Holocene in the Northern Hemisphere. It can thus, be concluded that diatoms from 2PC, support the palaeoceanographic reconstruction suggested by the benthic foraminifera Mg/Ca palaeothermometry and that variations in PW inflow through Herald Canyon is an important driver of sea ice variability on thousand-year time scales.