Submitted by Automa??o e Estat?stica (sst@bczm.ufrn.br) on 2016-02-29T21:36:02Z No. of bitstreams: 1 RaimundoJorgeSantosParanhos_TESE.pdf: 4812222 bytes, checksum: a3fafdef35f0753c7d1a15d6d7faed55 (MD5) / Approved for entry into archive by Arlan Eloi Leite Silva (eloihistoriador@yahoo.com.br) on 2016-03-01T00:42:05Z (GMT) No. of bitstreams: 1 RaimundoJorgeSantosParanhos_TESE.pdf: 4812222 bytes, checksum: a3fafdef35f0753c7d1a15d6d7faed55 (MD5) / Made available in DSpace on 2016-03-01T00:42:05Z (GMT). No. of bitstreams: 1 RaimundoJorgeSantosParanhos_TESE.pdf: 4812222 bytes, checksum: a3fafdef35f0753c7d1a15d6d7faed55 (MD5) Previous issue date: 2015-02-23 / O presente estudo tem como objetivo avaliar a potencialidade da utiliza??o das cinzas do baga?o da cana-de-a??car (CBC) como fundente, em substitui??o ao filito e/ou ao feldspato na massa padr?o para produ??o industrial de porcelanato esmaltado, verificando a possibilidade de as CBC contribu?rem para a redu??o do coeficiente de expans?o t?rmica global da massa cer?mica. Para isso, como um resultado da pesquisa, foram caracterizadas as mat?rias-primas componentes da massa padr?o (argila, filito, caulim, feldspato, quartzo e talco) e o res?duo das CBC, por meio de ensaios por FRX, DRX, AG, ATD e ATG. Foram confeccionados corpos de prova (CDP) nas dimens?es de 100 mm x 50 mm x 8 mm em matriz uniaxial, sob press?o de compacta??o de 33 MPa, reunidos em lotes de 3 unidades, posteriormente sinterizados nas temperaturas de 1150 ?C ? 1210 ?C variando a escala de avalia??o em 10 ?C, rampa de aquecimento e resfriamento de 50 ?C/min e 25 ?C/min, com tempo de patamares de 1 min, 3 min, 5 min, 8 min, 10 min, 15 min, 30 min e 60 min., analisando os resultados das propriedades f?sicas de absor??o de ?gua (AA), retra??o linear de queima (RLq), an?lise dilatom?trica (ADT), tens?o de resist?ncia ? flex?o (TRF) e MEV dos corpos sinterizados, a fim de verificar a adequa??o dos CDP ?s normas ISO 13006, ISO 10545, NBR 13816; NBR 13817 e NBR 13818. O estudo mostrou que as formula??es que mais atendem aos requisitos das normas s?o: a G4 ? na qual se aplicou 10% de CBC em substitui??o ao filito, temperatura de sinteriza??o de 1210 ?C e tempo de patamar de 10 min., e F3 ? com aplica??o de 7,5% de CBC em substitui??o ao feldspato, nas temperaturas de sinteriza??o de 1190 ?C, 1200 ?C e 1210 ?C e tempo de patamar de 10 min. Essas formula??es apresentaram melhor desempenho quanto ? forma??o de cristais de mulita, com redu??o consider?vel de trincas e poros, atendendo aos pr?- requisitos das normas para porcelanato esmaltado. A an?lise dos resultados comprova que a utiliza??o da CBC como fundente na prepara??o de massa para porcelanato atende aos par?metros normalizados para fabrica??o desse produto, e, com isso, pode-se reduzir o impacto ambiental e o custo de produ??o. Portanto, ? recomendada a utiliza??o desse res?duo na ind?stria ceramista, por conta de sua viabilidade industrial, comercial e colaborativa para a sustentabilidade. / The present study aims to evaluate the potential use of bagasse ash from sugar cane (CBC) as a flux, replacing phyllite and/or feldspar in standard industrial mass production of enameled porcelain, verifying the possibility of the CBC contribute to the overall reduction of the coefficient of thermal expansion of the ceramic mass. To this end, as a result of the research, we characterized the raw material components of the standard mass (clay, phyllite, kaolin, feldspar, quartz and talc) and the residue of BCC, by testing by XRF, XRD, AG, DTA and ATG. Specimens (CDP) were manufactured in the dimensions of 100 mm x 50 mm x 8 mm in uniaxial matrix under compaction pressure of 33 MPa, assembled in batches of 3 units subsequently sintered at temperatures of 1150?C to 1210?C by varying the Rating Scale at 10?C, heating and cooling ramp of 50?C/min and 25?C/min, with levels of 1 min, 3 min, 5 min, 8 min, 10 min, 15 min, 30 min and 60 min. analyzing the results of the physical properties of water absorption (WA), linear firing shrinkage (LFS), dilatometric analysis (DTA), flexural strain (SFT) and SEM of the sintered bodies in order to verify the adequacy of CDP to ISO 13006, ISO 10545, NBR 13816 standards; NBR 13817 and NBR 13818. The study showed that the formulations that best suit the requirements of the standards are:. G4 - which was applied in 10% of replacing the CBC phyllite, sintering temperature 1210 ? C for 10 min and porch, and F3 - with application of 7.5% of CBC to replace the feldspar in the sintering temperatures of 1190?C, 1200?C and 1210?C for 10 min and porch. These formulations showed better performance regarding the formation of primary and secondary mullite, with considerable reduction of cracks and pores, meeting the prerequisites of standards for glazed porcelain. The results shows that the use of the CBC as a flux in the preparation of porcelain mass meets standard parameters for the manufacture of the product, and thereby can reduce environmental impact and the cost of production. Therefore, it is recommended to use this residue in the ceramics industry, due to its industrial, commercial and collaborative viability for sustainability.