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Thesis (Ph. D.)--University of Chicago, Dept. of Astronomy and Astrophysics, March 2000. / Includes bibliographical references. Also available on the Internet.

An integral field unit fiber array spectrograph was used to observe the emission spectra of radical species (C2, C3, CH, CN, and NH2) in multiple comets. The resultant azimuthal and radial division maps produced from the reduced data provide a unique method of analyzing features with these radicals in the comae, as well as how they behave over time. A Monte Carlo model was developed in order to simulate the behavior of particles from the outer nucleus and coma of each comet depending on various parameters including rotational period, outflow velocity, and active area location. The results from the model were used to constrain the physical parameters of three comets: 10P/Tempel 2, C/2009 P1 (Garradd), and 168P/Hergenrother.

Context. Studying the coma environment of comet 67P/Churyumov-Gerasimenko (67P) is one of the primary scientific goals of the VIRTIS experiment on the ESA Rosetta mission. Aims. The distribution and variability of water vapour and carbon dioxide in the comet's coma are needed to estimate their production rate, abundances in the nucleus, and the spatial distribution of the active regions. Methods. Infrared emission lines from vibrational bands of water and carbon dioxide at 2.67 and 4.27 mu m, respectively, were observed by the VIRTIS-M imaging channel and mapped from close to the nucleus up to similar to 10 km altitude with a resolution of similar to 40 m/px. A dataset consisting of 74 observations in the 1 5 mu m spectral range acquired from 8 to 14 April 2015 when 67P was at a heliocentric distance of 1.9 AU is analysed in this work. A statistical correlation between the gas distribution and the surface's active regions was performed. Results. The maximum H2O emission is observed within 3 km from the nucleus and is mainly concentrated above two active regions, Aten-Babi and Seth-Hapi, while the CO2 distribution appears more uniform with significant emissions coming from both the "head" and southern latitude regions. In the equatorial region, the column densities of both species decrease with altitude, although CO2 decreases more rapidly than H2O. The calculated CO2/H2O column density ratios above Aten-Babi and Seth-Hapi are 2.4 +/- 0.6% and 3.0 +/- 0.7%, respectively. A value equal to 3.9 +/- 1.0% is observed at equatorial latitudes in the region encompassing Imothep. Conclusions. VIRTIS-M has mapped the distribution of water vapour and carbon dioxide around the nucleus of 67P with unprecedented spatial resolution. The different water and carbon dioxide outgassing above the surface, seen in the VIRTIS-M data, might be indicative of a different thermal history of the northern and southern hemispheres of 67P.

Infrared photometry has been used to determine the physical characteristics of cometary solids. Observations were made of the reflected and thermal parts of the spectra of seven comets. Two of these comets, Bowell and West, were nonperiodic; the other five, Chernyhk, Encke, Kearns-Kwee, Stephan-Oterma, and Tuttle, were periodic. Observations in the 3 μm region of the spectrum of Comet Bowell provide the first direct evidence for the presence of H₂O ice in a comet. This detection represents one of the strongest possible confirmations of Whipple's (1950) icy conglomerate model of cometary nuclei. The observations of the periodic comets have yielded the following picture of the dust in this type of objects: grains with a size distribution ranging from about 0.3 μm to 10 μm, and peaking around a few microns. These grains were made up of at least two components, a silicate material and an absorbing material. These characteristics are remarkably similar to those of the dust in nonperiodic comets. This indicates that the type of dust a comet ejects does not change with age, and supports the absence of large scale differentiation in cometary nuclei. Comet West is the first case of a splitting comet in which the fragments were observed to have differences in their dusty component. These observations suggest that the nucleus of this comet did not have an "onion skin" or layered structure but rather had pockets containing dust grains with different size distributions. Based on the results presented, the relation between cometary and interstellar dust, and the origin of comets are discussed.

This study addressed the problem of water vapor production and distribution in comet P/Halley, based upon interpretation of observational data obtained during the recent 1985-86 apparition. The data was acquired using the Lunar and Planetary Laboratory charge-coupled device (CCD) on the 154-cm Catalina telescope of the University of Arizona Observatories. Our data acquisition system was employed in two modes. The long-slit (∼200") spectroscopy mode covered the wavelength range 5200-10400 Å at a spectral resolution ∼14 Å. The narrow band filter imaging mode allowed two-dimensional mapping of selected cometary emission features, as well as the continuum, with a field of view of roughly 10 arc-min. Both neutral and ionized (H₂O⁺) water species were studied, with emphasis on the ion distribution. This involved comparing long-slit spatial profiles obtained ∼UT 1986 March 05.5, as well as cuts across filter images (∼ March 06.5) centered on the H₂O⁺ 0,8,0-band emission, with the Vega-1 spacecraft in situ ion density measurements (∼ March 06.3). Our March 05 spectroscopic data revealed a central dip, of order 30% relative to the profile peak, in H₂O⁺ column density in the inner coma (inside ∼ 2 x 10⁴ km from the nucleus), which filled in farther tailward. Similarly the BD - 3 plasma detector aboard Vega-1 measured a decrease in local ion density, of roughly 60% at the closest approach distance (∼ 9000 km sunward of the nucleus), relative to the inbound maximum density at R ≃ 12000 km from the nucleus. These results suggest a bimodal flow of ions out of the coma and/or an extended region over which the H₂0 molecules were being ionized. Our imaging data showed that, while the falloff in ion density was relatively rapid sunward of the nucleus, it was much more gradual in the anti-solar direction. This is due to the solar wind sweeping ions from the head of the comet into the plasma tail, whose width was of order 10⁵ km in the inner coma, diverging slowly and breaking up into a ray pattern farther tailward. The distribution of neutral water was mapped out using the [O I] λ6300 emission as diagnostic probe. In contrast to the ions, the H₂0 molecules were mainly confined to the inner few x 10⁴ km of the coma, and exhibited a much more symmetrical distribution. Integration of the [O I] slit profiles, assuming azimuthal symmetry, allowed calculation of the H₂0 production rate, which ranged from ∼ 10²⁸ molecules s⁻¹, when Halley was at a distance r≳ 2 AU from the sun, to a value of ∼ 1.5 x 10³⁰ molecules s⁻¹ for 1986 March 05 (r ≃ 0.78 AU). Using the latter production rate, and assuming a 100/1 production ratio of H₂0/ H₂O⁺, a spatially-averaged, tailward flow speed of ions out of the inner coma, < v⁺ > ≃ 16 km s⁻¹, was derived by integrating our March 05 H₂O⁺ profile, for which the slit was oriented across the coma, just tailward of the nucleus.

Observations provided from RPC-ICA in combination with the data from RPC-MAG and ROSINA-COPS show that many aspects of the time variability of the detected ions is correlated with the magnetic field or -- to a smaller extent -- with neutral atmosphere density. We also show that not all changes in the cometary ion data reflect the nature of the plasma dynamics, but are a consequence of the instrumental limitations. The main outcome of the article in Appendix 1 is that the cometary ions can be divided into two populations with distinct characteristics. One population we termed the convecting population, is accelerated to higher energies through the interaction with the solar wind. The other population we termed the expanding population is moving radially away from the nucleus in the terminator plane. Both populations exhibit a significant anti-sunward component.In addition we present in this thesis a case with observations day-side of the terminator plane. There we show how the expanding population has a sunward component, consistent with initial radial expansion of the ions from the nucleus which gradually turn into an anti-sunward flow which is then observed in the terminator plane.

We analyse the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA) - the Double Focusing Mass Spectrometer data between 2014 August and 2016 February to examine the effect of seasonal variations on the four major species within the coma of 67P/Churyumov-Gerasimenko (H2O, CO2, CO, and O-2), resulting from the tilt in the orientation of the comet's spin axis. Using a numerical data inversion, we derive the non-uniform activity distribution at the surface of the nucleus for these species, suggesting that the activity distribution at the surface of the nucleus has not significantly been changed and that the differences observed in the coma are solely due to the variations in illumination conditions. A three-dimensional Direct Simulation Monte Carlo model is applied where the boundary conditions are computed with a coupling of the surface activity distributions and the local illumination. The model is able to reproduce the evolution of the densities observed by ROSINA including the changes happening at equinox. While O-2 stays correlated with H2O as it was before equinox, CO2 and CO, which had a poor correlation with respect to H2O pre-equinox, also became well correlated with H2O post-equinox. The integration of the densities from the model along the line of sight results in column densities directly comparable to the VIRTIS-H observations. Also, the evolution of the volatiles' production rates is derived from the coma model showing a steepening in the production rate curves after equinox. The model/data comparison suggests that the seasonal effects result in the Northern hemisphere of 67P's nucleus being more processed with a layered structure while the Southern hemisphere constantly exposes new material.

Sublimation experiments have been carried out to determine the effect of the mineral dust content of porous ices on the isotopic composition of the sublimate gas over medium (days to weeks) timescales. Whenever mineral dust of any kind was present, the D/H ratio of the sublimated gas was seen to decrease with time from the bulk ratio. Fractionations of up to 2.5 were observed for dust mixing ratios of 9 wt% and higher of JSC MARS-1 regolith simulant 1-10 mum crushed and sieved fraction. These favored the presence of the light isotope, H2O, in the gas phase. The more dust was added to the mixture, the more pronounced was this effect. Theoretical modeling of gas migration within the porous samples and adsorption on the excavated dust grains was undertaken to explain the results. Adsorption onto the dust grains is able to explain the low D/H ratios in the sublimate gas if adsorption favors retention of HDO over H2O. This leads to significant isotopic enrichment of HDO on the dust over time and depletion in the amount of HDO escaping the system as sublimate gas. This effect is significant for planetary bodies on which water moves mainly through the gas phase and a significant surface reservoir of dust may be found, such as on Comets and Mars. For each of these, inferences about the bulk water D/H ratio as inferred from gas phase measurements needs to be reassessed in light of the volatile cycling history of each body.PACS CODES:98.80.Ft Isotopes, abundances and evolution (astronomy)], 64.70.Hz Sublimation], 68.43.-h Adsorption at solid surfaces]

The discovery of Ni-, Cu-, and Zn-bearing Fe-sulfides from comet 81P/Wild 2 represents the strongest evidence, in the Stardust collection, of grains that formed in an aqueous environment. Crystalline sulfide assemblages from Wild 2 and the hydrothermally altered CI chondrite Orgueil were investigated. Structural and compositional characterizations of the sulfide grains from both collections reveal similarities. The Stardust samples include a cubanite (CuFe₂S₃) grain, a pyrrhotite [(Fe,Ni)₁₋ₓS]/pentlandite [(Fe,Ni)₉S₈] assemblage, and a pyrrhotite/sphalerite [(Fe,Zn)S] assemblage. Similarly, the CI-chondrite sulfides include individual cubanite and pyrrhotite grains, cubanite/pyrrhotite assemblages, pyrrhotite/pentlandite assemblages, as well as possible sphalerite inclusions within pyrrhotite grains. The cubanite is the low temperature orthorhombic form, which constrains temperature to a maximum of 210°C. The Stardust and Orgueil pyrrhotites are the 4C monoclinic polytype, which is not stable above ~250°C. The combinations of cubanite and pyrrhotite, as well as pyrrhotite and pentlandite, signify even lower temperatures. The crystal structures, compositions, and petrographic relationships of these sulfides constrain formation and alteration conditions. Taken together, these constraints attest to low-temperature hydrothermal processing. The hydrothermal conditions under which cubanite forms were investigated through thermodynamic modeling and experimental synthesis. A thermodynamic model for cubanite was developed to constrain its formation environment. Cubanite was synthesized under hydrothermal conditions consistent with those predicted for the CI-chondrite parent body. The similarity between Stardust and CI-chondrite sulfides suggest similar fluid conditions may have existed on the comet at some point in its history. The presence of cubanite in the Stardust collection has implications for large scale issues such as: heat sources in the comet-forming region; aqueous activity on cometary bodies; and the extent and mechanisms of radial mixing of material in the early nebula. The Wild 2 sulfides are most likely the products of low-temperature aqueous alteration and provide evidence of radial mixing of material from the inner solar system to the comet-forming region and possible secondary aqueous processing on the cometary body.