<div> <p>Fiber reinforced polymer composites are widely used in manufacturing advanced light weight structures for the aerospace, automotive, and energy sectors owing to their superior stiffness and strength. With the increasing use of composites, there is an increasing need to monitor the health of these structures during their lifetime. Currently, health monitoring in filament wound composites is facilitated by embedding piezoelectrics and optical fibers in the composite during the manufacturing process. However, the incorporation of these sensing elements introduces sites of stress concentration which could lead to progressive damage accumulation. In addition to introducing weak spots in the structure, they also make the manufacturing procedure difficult. </p> <p> </p> <p>Alternatively, nanofiller modification of the matrix imparts conductivity which can be leveraged for real time health monitoring with fewer changes to the manufacturing method. Well dispersed nanofillers act as an integrated sensing network. Damage or strain severs the well-connected nanofiller network thereby causing a local change in conductivity. The self-sensing capabilities of these modified composites can be combined with low cost, minimally invasive imaging modalities such as electrical impedance tomography (EIT) for damage detection. To date, however, EIT has exclusively been used for damage detection in planar coupons. These simple plate-like structures are not representative of real-world complex geometries. This thesis advances the state of the art in conductivity-based structural health monitoring (SHM) and nondestructive evaluation (NDE) by addressing this limitation of EIT. The current study will look into damage detection of a non-planar multiply connected domain – a filament-wound glass fiber/epoxy tube modified by carbon black (CB) filler. The results show that EIT is able to detect through holes as small as 7.94 mm in a tube with length-to-diameter ratio of 132.4 mm-to-66.2 mm (aspect ratio of 2:1). Further, the sensitivity of EIT to damage improved with decreasing tube aspect ratio. EIT was also successful in detecting sub-surface damage induced by low velocity impacts. These results indicate that EIT has much greater potential for composite SHM and NDE than prevailing work limited to planar geometries suggest.</p> </div> <br>

Leaf springs are a part of the suspension system attached between the axle and the chassis of the vehicle to support weight and provide shock absorbing capacity of the vehicle. For more than half a century the leaf springs are being made of steel which increases the weight of the vehicle and is prone to rusting and failure. The current study explores the feasibility of composite leaf spring to reduce weight by designing, manufacturing and testing the leaf spring for the required load cases. An off the shelf leaf spring of Ford F-150 is chosen for making of composite hybrid spring prototype. The composite hybrid prototype was made by replacing all the leaves with glass fiber unidirectional laminate except the first leaf. Fatigue tests are then done on steel and composite hybrid leaf spring to observe the failure locations and mechanism if any. High frequency fatigue tests were then done on composite beams with varying aspect ratio in a displacement-controlled mode to observe fatigue location and mechanism of just glass fiber composite laminate. It was observed that specimens with low aspect ratio failed from crack propagation initiated from stress concentrations at the loading tip in 3-point cyclic flexure test and shear forces played a dominant role in propagation of crack. Specimens with high aspect ratio under the same loading did not fail in cyclic loading and preserved the same stiffness as before the cyclic loading. The preliminary fatigue results for high aspect ratio composite beams predict a promising future for multi-leaf composite springs.

<div> <p><a>Polymer nanocomposites are envisioned for use in many advanced applications, such as structural industries, aerospace, automotive technology and electronic materials, due to the improved properties like mechanical strengthening, thermal and chemical stability, easy bulk processing, and/or light-weight instigated by the filler-matrix combination compared to the neat matrix. In recent years, due to increasing environmental concerns, many industries are inclining towards developing sustainable and renewable polymer nanocomposites. Cellulose nanomaterials (CNs), including cellulose nanocrystals (CNCs) and cellulose nanofibrils (CNFs), have gained popularity due to their excellent mechanical properties and eco-friendliness (extracted from trees, algae, plants etc.). However, to develop CN-reinforced nanocomposites with industrial applications it is necessary to understand impact of hygroscopic swelling (which has very limited </a>quantitative study at present), aspect ratio, orientation, and content of CNs on the overall performance of nanocomposites; and overcome the low dispersibility of CNs and improve their compatibility with hydrophobic matrix. In this work, we attempt to understand the influence of single nanocrystals in the hygroscopic and optical response exhibited by nanostructured films; effect of CNCs on the properties of PVA/CNC fibers by experimental evidence with mathematical modeling predictions; and hydrophobized CNFs using a facile, aqueous surface modification to improve interfacial compatibility with epoxy. </p><p><br></p> <p>To evaluate the effect of CNC alignment in the bulk response to hygroscopic expansion, self-organized and shear-oriented CNC films were prepared under two different mechanisms. The coefficient of hygroscopic swelling (CHS) of these films was determined by using a new contact-free method of Contrast Enhanced Microscopy Digital Image Correlation (CEMDIC) that enabled the characterization of dimensional changes induced by hygroscopic swelling of the films. This method can be readily used for other soft materials to accurately measure hygroscopic strain in a non-destructive way. By calculating the CHS values of CNC films, it was determined that hygroscopic swelling is highly dependent on the alignment of nanocrystals within the films, with aligned CNC films showing dramatically reduced hygroscopic expansion than randomly oriented films. Finite element analysis was used to simulate moisture sorption and kinetics profile which further predicted moisture diffusion as the predominant mechanism for swelling of CNC films. </p> <p><br></p><p>To study the effects of different types and aspect ratios of CNCs on mechanical, thermal and morphological properties of polyvinyl alcohol (PVA) composite <a>fibers, CNCs extracted from wood pulp and cotton were reinforced into PVA to produce fibers by dry-jet-wet spinning. The fibers were collected as-spun and with first stage drawing up to draw ratio 2. </a>The elastic modulus and tensile strength of the fibers improved with increasing CNC content (5 – 15 wt. %) at the expense of their strain-to-failure. The mechanical properties of fibers with cotton CNC were higher than the fibers with wood CNC when the same amount of CNCs were added due to their higher aspect ratio. The degree of orientation along the spun fiber axis was quantified by 2D X-ray diffraction. As expected, the CNC orientation correlates to the mechanical properties of the composite fibers. Micromechanical models were used to predict the fiber performance and compare with experimental results. Finally, surface and cross-sectional morphologies of fibers were analyzed by scanning electron microscopy and optical microscopy.</p><p><br></p> <p>To improve the dispersibility and compatibility of CNFs with epoxy, CNFs were modified by using a two-step water-based method where tannic acid (TA) acts as a primer with CNF suspension and reacts with hexadecylamine (HDA), forming the modified product as CNF-TA-HDA. The modified (-m) and unmodified (-um) CNFs were filled into hydrophobic epoxy resin with a co-solvent (acetone), which was subsequently removed to form a solvent-free two component epoxy system, followed by addition of hardener to cure the resin. Better dispersion and stronger adhesion between fillers and epoxy were obtained for m-CNF than the um-CNF, resulting in better mechanical properties of nanocomposites at the same loading. Thermal stability and the degradation temperature of m-CNF/epoxy improved when compared to neat epoxy. </p> </div> <br>

<p>The thesis covers the following topics:</p> <p>1. aggregation and size effect on metal-polymer nanocomposite thermal interface materials</p> <p>2. diffusion limited cluster aggregation lattice simulation on thermal conductivty</p> <p>3. thermal interfacial resistance reduction between metal and dielectric materials by inserting an intermediate metal layer</p> <p>4. absence of coupled thermal interfaces in al2o3/ni/al2o3 sandwich structure</p> <p>5. ultra-efficient low-cost radiative cooling paints</p>

<p>Inaccurate cost estimates contribute to lost implementation opportunity of novel manufacturing technologies or lost revenue due to under-bidding or loss of an over-bid contract. High-volume, long-term orders, such as those the automotive industry begets, are desired as they lock in revenue streams for months into years. However, high-rate composite materials and their manufacturing processes are novel among the industry and traditional costing methods have not advanced at a proportional rate. This research effort developed a method to reduce the complex composite manufacturing systems to fungible, upgradable, and linkable individual processes that derive their manufacturing parameters from the performance part design process. Employing technical cost modeling, this method accurately quantifies the value of pursuing composite manufacturing by integrating impregnation, solidification, heat transfer, kinetics, and additional technical data from computer-aided part design simulation tools to deliver an accurate cost estimate. </p> <p>Cost modeling provides a quantitative result that weighs heavily in the decision making process for adoption of a new manufacturing method. In this dissertation, three case studies were investigated for three different management decision cases: part production management, in-house manufacturing management, and global manufacturing management. </p> <p>Part production management is the decision making process for selecting a certain manufacturing method. A case study with a Tier 1 Part Producer was conducted to provide a comparison of two emerging novel preforming systems versus their in-use, metals based high-rate manufacturing line in manufacturing a structural automotive part. Determining material usage was the primary cost driver focus. Equipment Supplier A’s process operated by seaming single layers of thermoplastic tape into rolls and then stacking prior to consolidation and resulted in a scrap rate of 23-28% with a cost of $32.87-36.01 per kilogram saved depending on the input tape width. Equipment Supplier B’s layup process, essentially a multi-head automatic tape layup machine, resulted in scrap rate of 20-27% with a cost of $34.48-36.67 per kilogram saved depending on the input tape width. This exceeded the Tier 1 Part Producer’s requirement of $6.6-11 per kilogram saved and led to them to abandon this application as a feasible project and instead look for a different part with a higher return regarding cost for weight saved.</p> <p>In-house manufacturing management is the decision making process governing manufacturing operating procedures. A case study for the Manufacturing Design Laboratory’s (MDLab) hybrid molding line was undertaken to determine the manufacturing cost for a composite test coupon. Processing parameters were obtained from three sources: performance design computer aided engineering (CAE), common industry transfer estimation times, and a calculated preform layup time. Compared to a similarly shaped test coupon made of aluminum, highly-automated manufacturing realizes weight savings of 46.25% and cost savings of 16.5%. Low-automation manufacturing captures the same weight savings, but has a cost for weight saved penalty, cost increase, of $9.89 per kilogram, showing how influential the labor contribution is to manufacturing cost. </p> <p>Global manufacturing management is the decision making process governing manufacturing location. Various manufacturing cost drivers are location dependent, thus a dataset was developed to alter these parameters for the U.S. states. Global comparisons are accomplished through indexing of global cost of living allowances and labor rates. Within the U.S., high-automation manufacturing costs in the West Coast/Pacific are 20.1% greater compared to the Midwest and similarly, low-automation costs are 21.2% greater. Globally, high-automation manufacturing costs in North America are 52.1% greater compared to Asia while low-automation costs are 116.5% greater. These variations highlight why we see geographically clustered manufacturing centers within the states and major manufacturing relocations due to cost sensitive and labor sensitive production. </p>

<div>Despite the advances of analytical and numerical methods for composite materials, it is still challenging to predict the onset and evolution of their different failure mechanisms. Because most failure mechanisms are irreversible processes in thermodynamics, it is beneficial to model them within a unified thermodynamic framework. Noting the advantages of so-called generalized standard models (GSMs) in this regard, the objective of this work is to formulate constitutive models for several main failure mechanisms: brittle fracture, interlaminar delamination, and fatigue behavior for both continuum damage and delamination, in a generalized standard manner.</div><div><br></div><div>For brittle fracture, the numerical difficulties caused by damage and strain localization in traditional finite element analysis will be addressed and overcome. A nonlocal damage model utilizing an integral-type regularization technique will be derived based on a recently developed ``local'' continuum damage model. The objective is to make this model not only rigorously handle brittle fracture, but also incorporate common damage behavior such as damage anisotropy, distinct tensile and compressive damage behavior, and damage deactivation. A fully explicit integration scheme for the present model will be developed and implemented.</div><div><br></div><div>For fatigue continuum damage, a viscodamage model, which can handle frequently observed brittle damage phenomena, is developed to produce stress-dependent fatigue damage evolution. The governing equation for damage evolution is derived using an incremental method. A class of closed-form incremental constitutive relations is derived. </div><div><br></div><div>For interlaminar delamination, a cohesive zone model (CZM) will be proposed. Focus is placed on making the associated cohesive elements capable of displaying experimental critical energy release rate--mode mixture ratio relationships. To achieve this goal, each cohesive element is idealized as a deformable string exhibiting path dependent damage behavior. A damage model having a path dependence function will be developed, which will be constructed such that each cohesive element can exhibit designated, possibly sophisticated mixed-mode behavior. The rate form of the cohesive law will be subsequently derived.</div><div><br></div><div>Finally, a CZM for interlaminar fatigue, capable of handling brittle damage behavior, is developed to produce realistic interlaminar crack propagation under high-cycle fatigue. An implicit integration scheme, which can handle complex separation paths and mixed-mode delamination, is developed. Many numerical examples will be utilized to clearly demonstrate the capabilities of the proposed nonlocal damage model, continuum fatigue damage model, and CZMs for quasi-static and fatigue delamination.</div>

<p>Microparticles have been investigated not only as feedstock spherical or amorphous bulk materials used for shape molding, but also as agents that can perform work in the micron scale. The fabrication of microparticles with active properties of self-propulsion, self-assembly, and mobility with enhanced mechanical, thermal, and chemical properties is of particular interest for emerging technologies such as drug delivery, micro-robotics, micro energy generation/harvesting, and MEMS. Conventional fabrication methods can produce several complex particle shapes in one fabrication session or hundreds of spheroid shaped particles per second. Innovative techniques, as flow lithography, have demonstrated control over particle form and composition for continuous fabrication cycles. In recent years predefined shape polymer microparticles have been fabricated as well as ceramic microparticles through suspension processing with these set of techniques. Even though ceramic materials have been fabricated, there is still a strong need to increment the palette of available materials to be processed via flow lithography. We have pioneered the production of shaped ceramic microparticles by Stop-Flow Lithography (SFL) using preceramic polymers, providing control of particle size and shape in the range of 1 – 1000 μm. The principal arranged technique (SFL) combines aspects of PDMS-based microfluidics and photolithography for the continuous cyclable fabrication of microparticles with predefined shapes. The PDMS microchannel devices used were fabricated with vinyl film molds in a laminar hood avoiding the need for a cleanroom, procedure that reduced fabrication costs. After a fabrication session, the preceramic polymer microparticles were collected, washed, and dried before entering an inert atmosphere furnace for pyrolysis. Additionally, by treating the material initially as liquid polymer, special properties can be added by converting it into an emulsion or a suspension. Microparticles were functionalized by introducing porosity and magnetic nanoparticles in the preceramic polymer matrix. The porous characteristic of a particle leads to an increase in surface area, allowing the particle to be infiltrated with a catalyzer or act as a chemical/physical carrier, and the magnetic behavior of the particles allows a controllable trajectory with defined external magnetic fields. These two properties can be used to fabricate bifunctional microparticles to serve as drug carriers through human arteries and veins for drug delivery purposes. We successfully fabricated solid and functional ceramic microparticles in the 10 – 50 μm range with predefined shapes as hexagons, gears, triangles, and ovals. This system is an economical route to fabricate functional defined shape particles that can serve as microrobots to perform tasks in liquid media.</p>

<p>Naturally-occurring biological materials with stiff mineralized reinforcement embedded in a ductile matrix are commonly known to achieve excellent balance between stiffness, strength and ductility. Interestingly, nature offers a broad diversity of architectural motifs, exemplify the multitude of ways in which exceptional mechanical properties can be achieved. Such diversity is the source of bio-inspiration and its translation to synthetic material systems. In particular, the helicoid and the “brick and mortar” architectured materials are two key architectural motifs we are going to study and to synthesize new bio-inspired materials. </p> <p>Due to geometry mismatch(misorientation) and incompatibilities of mechanical properties between fiber and matrix materials, it is acknowledged that misoriented stiff fibers would rotate in compliant matrix beneath uniaxial deformation. However, the role of fiber reorientation inside the flexible matrix of helicoid composites on their mechanical behaviors have not yet been extensively investigated. In the present project, fiber reorientation values of single misoriented laminae, mono-balanced laminates and helicoid architectures under uniaxial tensile are calculated and compared. In the present work, we introduce a Discontinuous Fiber Helicoid (DFH) composite inspired by both the helicoid microstructure in the cuticle of mantis shrimp and the nacreous architecture of the red abalone shell. We employ 3D printed specimens, analytical models and finite element models to analyze and quantify in-plane fiber reorientation in helicoid architectures with different geometrical features. We also introduce additional architectures, i.e., single unidirectional lamina and mono-balanced architectures, for comparison purposes. Compared with associated mono-balanced architectures, helicoid architectures exhibit less fiber reorientation values and lower values of strain stiffening. The explanation for this difference is addressed in terms of the measured in-plane deformation, due to uniaxial tensile of the laminae, correlated to lamina misorientation with respect to the loading direction and lay-up sequence.</p> <p>In addition to fiber, rod-like, reinforced laminate, platelet reinforced composite materials, “brick and mortar” architectures, are going to be discussed as well, since it can provide in-plane isotropic behavior on elastic modulus that helicoid architecture can offer as well, but with different geometries of reinforcement. Previous “brick and mortar” models available in the literature have provided insightful information on how these structures promote certain mechanisms that lead to significant improvement in toughness without sacrificing strength. In this work, we present a detailed comparative analysis that looks at the three-dimensional geometries of the platelet-like and rod-like structures. However, most of these previous analyses have been focused on two-dimensional representations. We 3D print and test rod-like and tablet-like architectures and analyze the results employing a computational and analytical micromechanical model under a dimensional analysis framework. In particular, we focus on the stiffness, strength and toughness of the resulting structures. It is revealed that besides volume fraction and aspect ratio of reinforcement, the effective shear and tension area in the matrix governs the mechanical behavior as well. In turns, this leads to the conclusion that rod-like microstructures exhibit better performance than tablet-like microstructures when the architecture is subjected to uniaxial load. However, rod-like microstructures tend to be much weaker and brittle in the transverse direction. On the other hand, tablet-like architectures tend to be a much better choice for situations where biaxial load is expected.</p> <p>Through varying the geometry of reinforcement and changing the orientation of reinforcement, different architectural motifs can promote in-plane mechanical properties, such as strain stiffening under uniaxial tensile, strength and toughness under biaxial tensile loading. On the other hand, the various out-of-plane orientation of the reinforcement leads to functionally graded effective indentation stiffness. The external layer of nacre shell is composed of calcite prisms with graded orientation from surface to interior. This orientation gradient leads to functionally graded Young’s modulus, which is confirmed to have higher fracture resistance than homogenous materials under mode I fracture loading act.</p> <p>Similar as graded prism orientation in calcite layer of nacre, the helicoid architecture found in nature exhibits gradients on geometrical parameters as well. The pitch distance of helicoid architecture is found to be functionally graded through the thickness of biological materials, including the dactyl club of mantis shrimp and the fish scale of coelacanth. This can be partially explained by the long-term evolution and selection of living organisms to create high performance biological materials from limited physical, chemical and geometrical elements. This naturally “design” procedure can provide us a spectrum of design motifs on architectural materials. </p> <p>In the present work, linear gradient on pitch distance of helicoid architectures, denoted by functionally graded helicoid (FGH), is chose to be the initial pathway to understand the functionality of graded pitch distance, associated with changing pitch angle. Three-point bending on short beam and low-velocity impact tests are employed in FEA to analyze the mechanical properties of composite materials simultaneously. Both static(three-point bending) and dynamic(low-velocity impact) tests reveal that FGH with pitch angle increasing from surface to interior can provide multiple superior properties at the same time, such as peak load and toughness, while the helicoid architectures with constant pitch angle can only provide one competitive property at one time. Specifically, helicoid architectures with smaller pitch angle, such as 15-degree, show higher values on toughness, but less competitive peak load under static three-point bending loading condition, while helicoid architectures with middle pitch angle, larger than or equal to 22.5-degree and smaller than 45-degree, exhibit less value of toughness, but higher peak load. The explanation on this trend and the benefits of FGH is addressed by analyzing the transverse shear stresses distribution through the thickness in FEA, combined with analytical prediction. In low-velocity impact tests, the projected delamination area of helicoid architectures is observed to increase when the pitch angle is decreasing. Besides, laminates with specific pitch angles, such as 45-degree, classical quasi-isotropic laminate, 60-degree, specific angle ply, and 90-degree, cross-ply, are designed to compare with helicoid architectures and FGH.</p>

<p> Optical metamaterials have triggered extensive studies driven by their fascinating electromagnetic properties that are not observed in natural materials. Aside from the extraordinary progress, challenges remain in scalable processing and material performance which limit the adoption of metamaterial towards practical applications. The goal of this dissertation is to design and fabricate nanocomposite thin films by combining nitrides with a tunable secondary phase to realize controllable multi-functionalities towards potential device applications. Transition metal nitrides are selected for this study due to the inherit material durability and low-loss plasmonic properties that offer stable two-phase hybridization for potential high temperature optical applications. Using a pulsed laser deposition technique, the nitride-metal nanocomposites are self-assembled into various geometries including pillar-in-matrix, embedded nanoinclusions or complex multilayers, that possess large surface coverage, high epitaxial quality, and sharp phase boundary. The nanostructures can be further engineered upon precise control of growth parameters. </p><p> This dissertation is composed of a general review of related background and experimental approaches, followed by four chapters of detailed research chapters. The first two research chapters involve hybrid metal (Au, Ag) - titanium nitride (TiN) nanocomposite thin films where the metal phase is self-assembled into sub-20 nm nanopillars and further tailored in terms of packing density and tilting angles. The tuning of plasmonic resonance and dielectric constant have been achieved by changing the concentration of Au nanopillars, or the tuning of optical anisotropy and angular selectivity by changing the tilting angle of Ag nanopillars. Towards applications, the protruded Au nanopillars are demonstrated to be highly functional for chemical bonding detection or surface enhanced sensing, whereas the embedded Ag nanopillars exhibit enhanced thermal and mechanical stabilities that are promising for high temperature plasmonic applications. In the last two chapters, dissimilar materials candidates beyond plasmonics have been incorporated to extend the electromagnetic properties, include coupling metal nanoinclusions into a wide bandgap semiconducting aluminum nitride matrix, as well as inserting a dielectric spacer between the hybrid plasmonic claddings for geometrical tuning and electric field enhancement. As a summary, these studies present approaches in addressing material and fabrication challenges in the field of plasmonic metamaterials from fundamental materials perspective. As demonstrated in the following chapters, these hybrid plasmonic nanocomposites provide multiple advantages towards tunable optical or biomedical sensing, high temperature plasmonics, controllable metadevices or nanophotonic chips.</p><div><br></div>

<p>Nonlinear transmission lines (NLTLs) provide a solid state alternative to conventional vacuum based high power microwave (HPM) sources. The three most common NLTL implementations are the lumped element, split ring resonator (SRR), and the nonlinear bulk material based NLTLs. The nonlinear bulk material implementation provides the highest power output of the three configurations, though they are limited to pulse voltages less than 50 kV; higher voltages are possible when an additional insulator is used, typically SF₆ or dielectric oil, between the nonlinear material and the outer conductor. The additional insulator poses a risk of leaking if structural integrity of the outer conductor is compromised. The desire to provide a fieldable NLTL based HPM system makes the possibility of a leak problematic. The work reported here develops a composite based NLTL system that can withstand voltages higher than 50 kV and not pose a risk of catastrophic failure due to a leak while also decreasing the size and weight of the device and increasing the output power.</p> <p>Composites with barium strontium titanate (BST) or nickel zinc ferrite (NZF) spherical inclusions mixed in a silicone matrix were manufactured at volume fractions ranging from 5% to 25%. The dielectric and magnetic parameters were measured from 1-4 GHz using a coaxial airline. The relative permittivity increased from 2.74±0.01 for the polydimethylsiloxane (PDMS) host material to 7.45±0.33 after combining PDMS with a 25% volume fraction of BST inclusions. The relative permittivity of BST and NZF composites was relatively constant across all measured frequencies. The relative permeability of the composites increased from 1.001±0.001 for PDMS to 1.43±0.04 for a 25% NZF composite at 1 GHz. The relative permeability of the 25% NZF composite decreased from 1.43±0.05 at 1 GHz to 1.17±0.01 at 4 GHz. The NZF samples also exhibited low dielectric and magnetic loss tangents from 0.005±0.01 to 0.091±0.015 and 0.037±0.001 to 0.20±0.038, respectively, for all volume fractions, although the dielectric loss tangent did increase with volume fraction. For BST composites, all volume fraction changes of at least 5% yielded statistically significant changes in permittivity; no changes in BST volume fraction yielded statistically significant changes in permeability. For NZF composites, the change in permittivity was statistically significant when the volume fraction varied by more than 5% and the change in permeability was statistically significant for variations in volume fraction greater than 10%. The DC electrical breakdown strength of NZF composites decreased exponentially with increasing volume fraction of NZF, while BST composites exhibited no statistically significant variation with volume fraction. </p> <p>For composites containing both BST and NZF, increasing the volume fraction of either inclusion increased the permittivity with a stronger dependence on BST volume fraction. Increasing NZF volume fraction increased the magnetic permeability, while changing BST volume fraction had no effect on the composite permeability. The DC dielectric breakdown voltage decreased exponentially with increased NZF volume fraction. Adding as little as 5% BST to an NZF composite more than doubled the breakdown threshold compared to a composite containing NZF alone. For example, adding 10% BST to a 15% NZF composite increased the breakdown strength by over 800%. The combination of tunability of permittivity and permeability by managing BST and NZF volume fractions with the increased dielectric breakdown strength by introducing BST make this a promising approach for designing high power nonlinear transmission lines with input pulses of hundreds of kilovolts.</p> <p>Coaxial nonlinear transmission lines are produced using composites with NZF inclusions and BST inclusions and driven by a Blumlein pulse generator with a 10 ns pulse duration and 1.5 ns risetime. Applying a 30 kV pulse using the Blumlein pulse generator resulted in frequencies ranging from 1.1 to 1.3 GHz with an output power over 20 kW from the nonlinear transmission line. The output frequencies increased with increasing volume fraction of BST, but the high power oscillations characteristic of an NLTL did not occur. Simulations using LT Spice demonstrated that an NLTL driven with a Blumlein modulator did not induce high power oscillations while driving the same NLTL with a pulse forming network did. </p> <p>Finally, a composite-based NLTL could be driven directly by a high voltage power supply without a power modulator to produce oscillations both during and after the formed pulse upon reaching a critical threshold. The output frequency of the NLTLs is 1 GHz after the pulse and ranged from 950 MHz to 2.2 GHz during the pulse. These results demonstrate that the NLTL may be used as both a pulse forming line and high power microwave source, providing a novel way to reduce device size and weight, while the use of composites could provide additional flexibility in pulse output tuning. </p>