Submitted by Maike Costa (maiksebas@gmail.com) on 2016-05-20T15:06:45Z No. of bitstreams: 1 arquivo total.pdf: 3354479 bytes, checksum: 996d07df4c09abbfebfb68b78cde4ed6 (MD5) / Made available in DSpace on 2016-05-20T15:06:45Z (GMT). No. of bitstreams: 1 arquivo total.pdf: 3354479 bytes, checksum: 996d07df4c09abbfebfb68b78cde4ed6 (MD5) Previous issue date: 2015-02-27 / Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPES / The compressed natural gas (CNG) is a fossil derivative mostly comprised of light hydrocarbons (methane, ethane, and propane), which has great energy importance for modern society. Considering the growing demand for CNG, it is also necessary to an effective control of the composition of the majority gases, which are mainly responsible for the energy efficiency of this fuel. The composition of these gases in CNG follows a certain pattern of conformity (control group) established by the ANP (National Agency of Petroleum, Natural Gas and Biofuels), to ensure the energy efficiency of CNG sold in Brazil. This work proposes the development of a methodology for automatic preparation of gas mixtures of methane standards, ethane and propane, in order to chromatographic determination of these gases levels in CNG, employing elaborate calibration models and validated by analysis of variance (ANOVA) and test recovery. The automatic system is of the dynamic type and is fully controlled by a program in order to prepare, as programmed by the user, binary mixtures of nitrogen / methane / nitrogen and nitrogen ethane / propane at levels (at fraction mol / mol) ranging in order to obtain good calibration models that consider the concentrations of these gases in the CNG. The evaluation methodology using ANOVA was quite satisfactory, the models built for the three gases methane, ethane and propane showed a high correlation (R2> 0.99) and significant in the regression, and showed no lack of fit and systematic variation at the residual plot. The performance parameters obtained from built models had lower detection and quantification limits 10-2 to 10-1, the analytical frequency was 4 samples per hour. A recovery study , involving three gas mixtures of certified composition and Natural Gas sample Vehicle (NGV) was also performed and the percentage values mean were 99.7 ± 3.1; 100.7 ± 4.4 and 98.0 ± 5.8 for methane, ethane and propane, respectively. The conclusion is based on the recovery values, as well as ANOVA, the proposed method was validated, with satisfactory precision and accuracy. / O gás natural veicular (GNV) é um derivado fóssil composto majoritariamente por hidrocarbonetos leves (metano, etano e propano), que tem grande importância energética para a sociedade moderna. Considerando a crescente demanda de GNV, se faz necessário, também, um efetivo controle da composição destes gases majoritários, que são os principais responsáveis pela eficiência energética deste combustível. A composição destes gases em GNV segue um determinado padrão de conformidade (faixa de controle) estabelecido pela ANP (Agência Nacional do Petróleo, Gás Natural e Biocombustíveis), de modo a garantir a eficiência energética do GNV comercializado no Brasil. Este trabalho propõe o desenvolvimento de uma metodologia para preparação automática de misturas gasosas padrões de metano, etano e propano, visando à determinação cromatográfica dos teores destes gases em GNV, empregando modelos de calibração elaborados e validados por análise de variância (ANOVA) e teste de recuperação. O sistema automático é do tipo dinâmico e é totalmente controlado por um programa de modo a preparar, conforme programado pelo usuário, misturas binárias de nitrogênio/metano, de nitrogênio/etano e de nitrogênio/propano, com teores (em fração mol/mol) que variam de modo a se obter bons modelos de calibração que contemplem as concentrações desses gases no GNV. A avaliação da metodologia por meio da ANOVA foi bastante satisfatória, os modelos construídos para os três gases metano, etano e propano apresentaram uma alta correlação (R2 > 0,99) e significância na regressão, e não demonstraram falta de ajuste e variação sistemática no gráfico dos resíduos. Os parâmetros de desempenho obtidos a partir dos modelos construídos tiveram limites de detecção menores que 10-2 e de quantificação menores que 10-1, a frequência de amostragem foi 4 amostras por hora. Um estudo de recuperação, envolvendo três misturas gasosas de composição certificada e uma amostra de Gás Natural Veicular (GNV), foi também realizado e os valores médios percentuais obtidos foram de 99,7 ± 3,1; 100,7 ± 4,4 e 98,0 ± 5,8 para o metano, etano e propano, respectivamente. Conclui-se com base nos valores de recuperação, bem como na ANOVA, que o método proposto foi devidamente validado, apresentando uma satisfatória precisão e exatidão.

Sweden has recently increased its efforts to reach net-zero greenhouse gas emission by 2045.The purpose of this study is to assess the feasibility for Bollnäs municipality to meet itsenvironmental goals through the conversion of its current fleet to a Natural Gas Vehicle basedfleet. A CO2 emission-based comparison has been used to estimate from an environmentalstandpoint the viability of biogas as the main fuel for the Bollnäs municipality fleet. Theresults have shown how a compressed natural gas (CNG) based fleet would lower by morethan five times the estimated CO2 emission of the current fleet. The viability of a biogas fleethas been proven and further results have shown how if the CNG fuel was produced from100% renewable resources the environmental impact would be even lower. The results havealso shown how Electric Vehicles (EV) and Hydrogenated Vegetable Oil (HVO) from 100%renewable resources could be viable environmental alternatives but it requires furtherinvestigation from an infrastructure and economic standpoint. / <p>2021-06-04</p>

Submitted by PPG Engenharia e Tecnologia de Materiais (engenharia.pg.materiais@pucrs.br) on 2018-02-19T14:21:21Z No. of bitstreams: 1 Tese RONALDO SILVESTRE DA COSTA Final Entrega PGETEMA.pdf: 3370134 bytes, checksum: 383fa921245f353cae4a408bd4641901 (MD5) / Approved for entry into archive by Caroline Xavier (caroline.xavier@pucrs.br) on 2018-02-23T17:34:28Z (GMT) No. of bitstreams: 1 Tese RONALDO SILVESTRE DA COSTA Final Entrega PGETEMA.pdf: 3370134 bytes, checksum: 383fa921245f353cae4a408bd4641901 (MD5) / Made available in DSpace on 2018-02-23T17:39:49Z (GMT). No. of bitstreams: 1 Tese RONALDO SILVESTRE DA COSTA Final Entrega PGETEMA.pdf: 3370134 bytes, checksum: 383fa921245f353cae4a408bd4641901 (MD5) Previous issue date: 2016-11-30 / Funda??o de Amparo ? Pesquisa do Estado do Rio Grande do Sul (FAPERGS) / The transport sector represents a significant responsibility in the pollution emissions. Also, the consumption of fossil fuels is related with the rising of global average temperature due to the greenhouse gas emissions. Biofuels and natural gas are investigated as alternative fuels to mitigate the environmental impacts. However, due to the several source emissions within a product life-cycle, the environmental performance of an environmental friendly product must be verified. This work aims to quantify greenhouse gas emissions during household waste collection by heavy vehicles (trucks) fueled with different fuels. It was proposed the development and implementation of a methodology to compare both pollutant gas emissions and noise for the use of CNG (compressed natural gas) and diesel-B5, aiming to mitigate environmental impacts in captive fleet that travels daily in the Porto Alegre city, Rio Grande do Sul state, Brazil. The trucks were monitored using a portable gas analyzer equipment (O2, CO, CO2, NO, NO2, NOx, SO2, HC), and the fuel consumptions and autonomy were obtained from the company that provides the service. With the data collected on established routes, it was applied the Life Cycle Assessment (LCA) methodology to carry out the study comparing the environmental performance of the use of CNG and Diesel-B5. The results showed that higher global warming impact (according IPCC method) was observed to CNG, independently of the time horizon considered (20 100 or 500 years). When comparing the contribution of the process stages (from production to use of fuels), CNG presented higher impacts in the collection and venting steps, while diesel -- B5 presented in the collection step. / O setor de transportes apresenta significativos problemas ambientais relacionados ?s emiss?es de poluentes, agravados em regi?es urbanas. A queima e a explora??o de combust?veis f?sseis s?o constantemente relacionadas ao aumento da temperatura m?dia global. O uso de combust?veis, como os de origem vegetal e g?s natural, tem sido uma alternativa frequente na mitiga??o de gases de efeito estufa. No entanto, devido ?s v?rias fontes de poluentes presentes no ciclo de vida do produto, o desempenho ambiental de produtos considerados amig?veis ao meio ambiente deve ser verificado. Este trabalho teve como objetivo quantificar as emiss?es de gases de efeito estufa emitidos durante a coleta de res?duos domiciliares por ve?culos pesados (caminh?es) abastecidos com diferentes combust?veis: g?s natural e diesel-B5. Prop?e-se o desenvolvimento e a implementa??o de uma metodologia para a compara??o das emiss?es de poluentes para o uso de GNV (g?s natural veicular) e Diesel-B5, objetivando a mitiga??o de impactos ambientais em frota cativa que trafega diariamente na cidade de Porto Alegre ? RS. Os caminh?es foram monitorados com um equipamento analisador port?til de gases (O2, CO, CO2, NO, NO2, NOx, SO2, HC), e os consumos e a autonomia dos combust?veis foram obtidos junto ? empresa prestadora do servi?o. Com os dados levantados nas rotas estabelecidas, foi aplicada a metodologia de Avalia??o do Ciclo de Vida (ACV) para realizar o estudo de compara??o do desempenho ambiental entre o uso de GNV e Diesel-B5, considerando todas as etapas desde a produ??o at? o consumo final dos combust?veis. Os resultados mostraram que o maior potencial para aquecimento global (segundo o m?todo IPCC) ocorre para o GNV, considerando per?odos de 20 anos, 100 anos e 500 anos. Quando comparadas as contribui??es das diferentes etapas do processo, desde a produ??o at? o uso do combust?vel, observou-se que o GNV apresenta os maiores impactos nas etapas de transporte e coleta de res?duos, enquanto o Diesel-B5 apresenta impacto significativo apenas na etapa de coleta de res?duos.

In-cylinder fuel-air mixing in a compressed natural gas (CNG)-fuelled, single-cylinder, spark-ignited engine is analysed using a transient three-dimensional computational fluid dynamic model built and run using STAR-CD, a commercial CFD software. This work is motivated by the need for strategies to achieve improved performance in engines utilizing gaseous fuels such as CNG. The transient in-cylinder fuel-air mixing is evaluated for a port gas injection fuelling system and compared with that of conventional gas carburetor system. In this work pure methane is used as gaseous fuel for all the computational studies. It is observed that compared to the premixed gas carburetor system, a substantial level of in-cylinder stratification can be achieved with the port gas injection system. The difference of more than 20% in mass fraction between the rich and lean zones in the combustion chamber is observed for the port gas injection system compared to less than 1% for the conventional premixed system. The phenomenon of stratification observed is very close to the “barrel stratification” mode. A detailed parametric study is undertaken to understand the effect of various injection parameters such as injection location, injection orientation, start of injection, duration of injection and rate of injection. Furthermore, the optimum injection timing is evaluated for various load-speed conditions of the engine. It is also observed that the level of stratification is highest at 50% engine load with a reduced level at 100% load. For low engine loads, the level of stratification is observed to be very low. To analyse the effect of stratification on engine performance, the in-cylinder combustion is modeled using the extended coherent flame model(ECFM). For simulating the ignition process, the arc and kernel tracking ignition model(AKTIM) is used. The combustion model is first validated with measured in-cylinder pressure data and other derived quantities such as heat release rate and mass burn fraction. It is observed that there is a good agreement between measured and simulated values. Subsequently, this model is use to simulate both premixed and stratified cases. It is observed that there is a marginal improvement in terms of overall engine efficiency when the stoichiometric premixed case is compared with the lean stratified condition. However, a major improvement in performance is observed when the lean stratified case is compared with lean premixed condition. The stratified case shows a faster heat release rate which could potentially translate to lower cycle-to-cycle variations in actual engine operation. Also, the stratified cases show as much as 20% lower in-cylinder NOx emissions when compared with the conventional premixed case at the same engine load and speed, underscoring the potential of in-cylinder stratification to achieve improved performance and lower NOx emissions.

[ES] El aumento global de las emisiones de gases de efecto invernadero desde el inicio de la Revolución Industrial se ha convertido en un grave peligro para la vida humana. Además de la generación de energía y la industria, el transporte, con el aumento del número total de vehículos en las últimas décadas, es uno de los principales responsables de este incremento exponencial de los gases causantes del calentamiento global. De hecho, ciudades como Barcelona o Madrid, entre muchas otras, están imponiendo restricciones al tráfico para mitigar esta situación. Sin embargo, la humanidad aún está a tiempo de invertir esta tendencia negativa y solucionar el problema medioambiental para las generaciones futuras. El objetivo principal de la presente Tesis se centra en el estudio, implementación y análisis del concepto de encendido por precámara pasiva para su aplicación en la próxima generación de vehículos automóviles. Más específicamente, esta investigación aborda los fenómenos físicos que intervienen en el proceso de combustión cuando se utiliza el sistema de encendido por precámara en un motor de encendido provocado. A continuación, se aplican algunas estrategias para mejorar el rendimiento térmico que se obtiene operando con este concepto. Finalmente, a partir del conocimiento generado, se presentan unas directrices básicas para el prediseño de este tipo de precámaras. La primera aproximación al concepto consiste en su implementación directa en el motor, obteniendo resultados experimentales en tres condiciones de funcionamiento diferentes en términos de carga y régimen de giro del motor. Además, también se evalúan diferentes geometrías de precámara. Aunque su implementación directa es relativamente sencilla mediante la sustitución de la bujía, la comprensión de ciertos fenómenos relevantes relacionados con la combustión, como el intercambio de gases o la penetración de los chorros, es extremadamente difícil sin el apoyo de herramientas computacionales. Esta es la principal razón que justifica el uso de herramientas numéricas 1D en la presente Tesis, ya que con un modelado adecuado basado en datos experimentales, se puede obtener información relevante en aquellas situaciones en las que no es factible generarla experimentalmente. Estas herramientas 1D tienen las ventajas de su bajo coste computacional y su capacidad de proporcionar resultados en poco tiempo. En cuanto al rendimiento térmico, se adoptan dos estrategias diferentes, como el aumento de lambda o el aumento de la tasa de recirculación de los gases de escape, para incrementar aún más las ventajas del sistema de encendido por precámara pasiva. Sin embargo, se alcanzan los límites físicos de aplicación de ambas estrategias y se proponen una serie de posibilidades para ampliar estos límites y aumentar el rendimiento térmico. Finalmente, a partir de los resultados experimentales y numéricos, se sugieren algunas pautas para diseñar una precámara que aproveche las ventajas observadas, aumentando el rendimiento térmico en comparación con los conceptos de encendido por bujía convencional y por precámara pasiva actuales. / [CA] L'augment global de les emissions de gasos d'efecte d'hivernacle des de l'inici de la Revolució Industrial s'ha convertit en un greu perill per a la vida humana. A més de la generació d'energia i la indústria, el transport, amb l'augment del nombre total de vehicles en les últimes dècades, és un dels principals responsables d'aquest increment exponencial dels gasos causants de l'escalfament global. De fet, ciutats com Barcelona o Madrid, entre moltes altres, estan imposant restriccions al trànsit per a mitigar aquesta situació. No obstant això, la humanitat encara és a temps d'invertir aquesta tendència negativa i solucionar el problema mediambiental per a les generacions futures. L'objectiu principal de la present Tesi se centra en l'estudi, implementació i anàlisi del concepte d'encesa per precàmera passiva per a la seua aplicació en la pròxima generació de vehicles automòbils. Més específicament, aquesta investigació aborda els fenòmens físics que intervenen en el procés de combustió quan s'utilitza el sistema d'encesa per precàmera en un motor d'encesa provocada. A continuació, s'apliquen algunes estratègies per a millorar el rendiment tèrmic que s'obté operant amb aquest concepte. Finalment, a partir del coneixement generat, es presenten unes directrius bàsiques per al predisseny d'aquesta mena de precàmeres. La primera aproximació al concepte consisteix en la seua implementació directa en el motor, obtenint resultats experimentals en tres condicions de funcionament diferents en termes de càrrega i règim de gir del motor. A més, també s'avaluen diferents geometries de precàmera. Encara que la seua implementació directa és relativament senzilla mitjançant la substitució de la bugia, la comprensió d'uns certs fenòmens rellevants relacionats amb la combustió, com l'intercanvi de gasos o la penetració dels dolls, és extremadament difícil sense el suport d'eines computacionals. Aquesta és la principal raó que justifica l'ús d'eines numèriques 1D en la present Tesi, ja que amb un modelatge adequat basat en dades experimentals es pot obtindre informació rellevant en aquelles situacions en les quals no és factible generar-la experimentalment. Aquestes eines 1D tenen com a principal avantatge el seu baix cost computacional i la seua capacitat de proporcionar resultats en poc temps. Quant al rendiment tèrmic, s'adopten dues estratègies diferents, com l'augment de lambda o l'augment de la taxa de recirculació dels gasos d'escapament, per a incrementar encara més els avantatges del sistema d'encesa per precàmera passiva. No obstant això, s'aconsegueixen els límits físics d'aplicació de totes dues estratègies i es proposen una sèrie de possibilitats per a ampliar aquests límits i augmentar el rendiment tèrmic. Finalment, a partir dels resultats experimentals i numèrics, se suggereixen algunes pautes per a dissenyar una precàmera que aprofite els avantatges observats, augmentant el rendiment tèrmic en comparació amb els conceptes d'encesa per bugia convencional i per precàmera passiva actuals. / [EN] The global greenhouse gas emissions increase since the start of the Industrial Revolution has become a serious hazard to human life. In addition to power generation and industry, transportation, with the rise in the total vehicle number in the last decades, is one of the main contributors to this exponential increase of global warming-causing gases. In fact, cities such as Barcelona or Madrid, among many others, are imposing traffic restrictions to mitigate this situation. However, mankind is still on time to reverse this negative tendency and fix the environmental issue for the upcoming generations. The main goal of the present Thesis focuses on the study, implementation and analysis of the passive pre-chamber ignition concept in a near-future light-duty passenger car application. To be more specific, the investigation addresses the physical phenomena involving the combustion process when pre-chamber ignition system is used in a spark-ignition engine. Then, some strategies to improve thermal efficiency while employing this concept are applied. Finally, with all the knowledge gathered, basic guidelines for a pre-chamber pre-design are presented. The first approach to the concept consists of its direct implementation in the engine, obtaining experimental results in three different operating conditions in terms of engine load and speed. Furthermore, different prechamber geometries are also evaluated. Although its direct implementation is relatively straightforward by exchanging the spark plug, understanding some of the relevant phenomena related to the combustion process, such as gas exchange or jet-tip penetration, is extremely difficult without the support of computational tools. This is the main reason supporting the use of 1D numerical tools in the present Thesis, since with proper modeling based on experimental data, further knowledge can be obtained in those situations where experimental evaluations are not feasible. These 1D tools have the benefits of their low computational cost and their ability to provide reasonably good results in a short period of time. In terms of thermal efficiency, two different strategies, such as the increase of lambda or the increase of the exhaust gas re-circulation rate, are adopted to extend further the benefits of the passive pre-chamber ignition system. However, the physical application limits of both strategies are reached, and a series of possibilities are proposed to expand these limits and increase thermal efficiency. Finally, with all the experimental and numerical results, some guidelines are suggested to design a pre-chamber that takes advantage of the benefits, increasing thermal efficiency compared with the conventional spark ignition and the current passive pre-chamber concepts. / The respondent wishes to acknowledge the financial support received through contract FPI-S2-19-21993 of the Programa de Apoyo para la Investigación y Desarrollo (PAID) of Universitat Politècnica de València. Parts of the work presented in this thesis have been supported by different collaborations with the research partner Sandia National Laboratories LLC, 7011 East Ave, Livermore, California, US. / Martínez Hernándiz, PJ. (2023). Implementation and Analysis of the Pre-Chamber Ignition Concept in a SI Engine for Passenger Car Applications [Tesis doctoral]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/202063