Thesis submitted for the degree MAGISTER SCIENTIAE to the Faculty of Science, Department of Geology, University of the Witwatersrand, Johannesburg / The Koperberg Suite intrusion at Jubilee, Namaqualand varies in composition from anorthosite, through mica diorite to pyroxene leucodiorite and pyroxene diorite. Detailed mapping and petrological studies of these rocks indicate that they were sequentially emplaced into the Concordia Granite country rocks, and that each of the rock types represent discrete magmatic events. The sequence of intrusion is from more acidic to more basic. Whole-rock geochemical analyses indicate that these rocks represent cumulates involving variable proportions of plagioclase, orthopyroxene, mica, quartz, oxides and immiscible sulphides. These cumulate phases intruded into the Concordia Granite at the time of peak of metamorphism and deformation in the Okiep Copper District, i.e, about 1030Ma ago, At the time of intrusion, the country rocks were under going partial melting under high grade (granulite facies) metamorphic conditions. and granitic anatects were present in the crust. Hybridisation of basic magma and granitic melts occurred within the shear zones along which the basic magmas ascended. The En content of orthopyroxene in the Koperberg Suite exceeds the An content of plagioclase. This is atypical of basic intrusions and is a consequence of this mixing. Mixing calculations based on the initial 87Sr/86Srratio (Ru) of the Jubilee samples at 1030Ma, imply high levels of assimilation (as much as 80% assimilation in the case of anorthositic rocks) between a granitic component, similar in composition to the Nababeep Gneiss and a mantle-derived basic magma. Sulphide mineralisation was initiated by the assimilation process, which caused the separation of immiscible sulphides from the hybridised magma. Subsequent oxidation of the original sulphide assemblage produced bornite, chalcopyrite and Ti-poor magnetite. / Andrew Chakane 2019

Heavy metal pollution in water and soil is a serious concern to human health and the associated environment. Some heavy metals have bio-importance but the bio-toxic effects of many of them in human health are of great concern. Hence, there was a need for proper understanding of the concentration levels of these heavy metals in ground water and soil around the community residing in the vicinity of the defunct mine. Mining has become prominent in this area because of the existence of copper lodes, veins and veinlets. It was therefore necessary to assess these selected metals associated with copper mining as their concentration has a tendency to affect the environment and human health. The objective of this study was to establish the levels of lead (Pb)-zinc (Zn)-copper (Cu)-arsenic (As)-nickel (Ni) metals in ground water and soil associated with an old copper mine in the vicinity of the township and to compare them with the South African and international standards in order to safeguard the health of the community using such water for drinking purpose. Clean sampling plastic bottles were used to collect water from five water boreholes being used at present. Water samples were filtered using membrane filtration set LCW (0.45 μm). The samples were digested sequentially with different procedures for the total metal concentration. Concentrations of four metals commonly associated with Cu mining were examined at five different water boreholes which are used for drinking and industrial purposes. Flame Atomic Absorption Spectrophotometer (Perkin Elmar S/n 000003F6067A, Singapore) was used to analyze metals in water samples at Eskom Ga-Nala Laboratory: pH, electrical conductivity and turbidity were analyzed using an auto titrator meter (AT- 500,Japan), conductivity meter (Cole-parmer® YO-19601-00) and turbidity meter (AL 250TIR, Agua lytic, German) respectively. Soil samples were collected from the selected areas where human health is of a serious concern, and a hand held auger drill was used to recover samples, while shovels were used to prepare the sampling area. The samples were sieved up to 63.0 μm particle size and digested with aqua-regia. Flame Atomic Absorption Spectrophotometer (Model: AA400; Year: 2008; Manufacturer: Perkin Elmer; Germany; Serial no: 201S6101210) was used at the University of Venda Laboratory to analyze soil from the study area for possible heavy metal contamination due to the defunct Cu mine in the area. v The results showed variation of the investigated parameters in water samples as follows: pH, 6.0 to 7.51; EC, 70.0 to 96.40 μS/cm and turbidity, 1.05 to 4.56 NTU. The mean concentration of the metals increased in the followed order: Pb<Cu<As<Ni. Ni is the most abundant in the ground water determined with value of (6.49 μg/g). The observations have confirmed that most ground water contains an appreciable quantity of Ni. The mean value of As in water is (4.20 to 4.84 μg/g), Pb and Cu have (2.13 to 2.58 μg/g) and (1.52 to 2.52 μg/g) respectively. For soil samples, the mean concentration of the metals increased in the following order: Pb<Cu<Zn<As<Ni. Pb ranged from (0.023 to 0.036 μg/g) followed by Cu (0.28 to 0.45 μg/g) then Zn (0.026 to 0.053 μg/g), the mean range of As in soil ranged from (0.054 to 0.086 μg/g). However, some studies show much higher contamination of As from the natural sources and Ni with (0.057 to 0.144 μg/g) lastly. Accumulation of heavy metals in soil is of concern due to their toxic effects on human and animals. The quality of ground water from the five boreholes studied was satisfactory with turbidity (T), electrical conductivity (EC) and heavy metals (HM’s) below the WHO limit. The water therefore may, according to the WHO Standards be safely used as a drinking water. The concern lies on pH which was slightly (0.5) below the standard. There is a serious need to monitor the ground water which is now used for drinking purposes. This study revealed that heavy metal pollution in soil from the abandoned Cu mine in Musina is a threat to the health of the community. Although pollution was between medium and low in the contamination index, it is therefore important for the Musina Municipality or mine owner of Musina (TVL) Development Co Ltd copper mine to advocate possible remedial actions which will safeguard the environment and human health. The tailing at Musina’s old Cu mine have high pH and they lack normal soil stabilization processes, as a result the tailing does not develop a good plant cover. Pollution of the ground water resources is also evident in the study area where there is seepage or ingress of polluted water to the underground aquifers. Small-scale mining in Musina is causing further degradation to the environment but it supports the South African Waste Hierarchy by promoting the reuse and recycling of the tailing and mine dumps for the production of bricks. Mine workers are exposed to the above mentioned toxic heavy metals daily. Medicine will not help stop the poisoning. The only way to stop the metal poisoning is to stop being exposed to the heavy metals. / Environmental Sciences / M. Sc. (Environmental Management)

Heavy metal pollution in water and soil is a serious concern to human health and the associated environment. Some heavy metals have bio-importance but the bio-toxic effects of many of them in human health are of great concern. Hence, there was a need for proper understanding of the concentration levels of these heavy metals in ground water and soil around the community residing in the vicinity of the defunct mine. Mining has become prominent in this area because of the existence of copper lodes, veins and veinlets. It was therefore necessary to assess these selected metals associated with copper mining as their concentration has a tendency to affect the environment and human health. The objective of this study was to establish the levels of lead (Pb)-zinc (Zn)-copper (Cu)-arsenic (As)-nickel (Ni) metals in ground water and soil associated with an old copper mine in the vicinity of the township and to compare them with the South African and international standards in order to safeguard the health of the community using such water for drinking purpose. Clean sampling plastic bottles were used to collect water from five water boreholes being used at present. Water samples were filtered using membrane filtration set LCW (0.45 μm). The samples were digested sequentially with different procedures for the total metal concentration. Concentrations of four metals commonly associated with Cu mining were examined at five different water boreholes which are used for drinking and industrial purposes. Flame Atomic Absorption Spectrophotometer (Perkin Elmar S/n 000003F6067A, Singapore) was used to analyze metals in water samples at Eskom Ga-Nala Laboratory: pH, electrical conductivity and turbidity were analyzed using an auto titrator meter (AT- 500,Japan), conductivity meter (Cole-parmer® YO-19601-00) and turbidity meter (AL 250TIR, Agua lytic, German) respectively. Soil samples were collected from the selected areas where human health is of a serious concern, and a hand held auger drill was used to recover samples, while shovels were used to prepare the sampling area. The samples were sieved up to 63.0 μm particle size and digested with aqua-regia. Flame Atomic Absorption Spectrophotometer (Model: AA400; Year: 2008; Manufacturer: Perkin Elmer; Germany; Serial no: 201S6101210) was used at the University of Venda Laboratory to analyze soil from the study area for possible heavy metal contamination due to the defunct Cu mine in the area. v The results showed variation of the investigated parameters in water samples as follows: pH, 6.0 to 7.51; EC, 70.0 to 96.40 μS/cm and turbidity, 1.05 to 4.56 NTU. The mean concentration of the metals increased in the followed order: Pb<Cu<As<Ni. Ni is the most abundant in the ground water determined with value of (6.49 μg/g). The observations have confirmed that most ground water contains an appreciable quantity of Ni. The mean value of As in water is (4.20 to 4.84 μg/g), Pb and Cu have (2.13 to 2.58 μg/g) and (1.52 to 2.52 μg/g) respectively. For soil samples, the mean concentration of the metals increased in the following order: Pb<Cu<Zn<As<Ni. Pb ranged from (0.023 to 0.036 μg/g) followed by Cu (0.28 to 0.45 μg/g) then Zn (0.026 to 0.053 μg/g), the mean range of As in soil ranged from (0.054 to 0.086 μg/g). However, some studies show much higher contamination of As from the natural sources and Ni with (0.057 to 0.144 μg/g) lastly. Accumulation of heavy metals in soil is of concern due to their toxic effects on human and animals. The quality of ground water from the five boreholes studied was satisfactory with turbidity (T), electrical conductivity (EC) and heavy metals (HM’s) below the WHO limit. The water therefore may, according to the WHO Standards be safely used as a drinking water. The concern lies on pH which was slightly (0.5) below the standard. There is a serious need to monitor the ground water which is now used for drinking purposes. This study revealed that heavy metal pollution in soil from the abandoned Cu mine in Musina is a threat to the health of the community. Although pollution was between medium and low in the contamination index, it is therefore important for the Musina Municipality or mine owner of Musina (TVL) Development Co Ltd copper mine to advocate possible remedial actions which will safeguard the environment and human health. The tailing at Musina’s old Cu mine have high pH and they lack normal soil stabilization processes, as a result the tailing does not develop a good plant cover. Pollution of the ground water resources is also evident in the study area where there is seepage or ingress of polluted water to the underground aquifers. Small-scale mining in Musina is causing further degradation to the environment but it supports the South African Waste Hierarchy by promoting the reuse and recycling of the tailing and mine dumps for the production of bricks. Mine workers are exposed to the above mentioned toxic heavy metals daily. Medicine will not help stop the poisoning. The only way to stop the metal poisoning is to stop being exposed to the heavy metals. / Environmental Sciences / M. Sc. (Environmental Management)

MENVSC / Department of Ecology and Resource Management / Historically, mining activities have generated vast quantities of abandoned tailings dumps in several regions of South Africa and throughout the world. The management and disposal of huge volumes of tailings dumps has constituted a major challenge to the environment. The current study aims to establish the physicochemical properties and mineralogical characterization of the old copper tailings dump in Musina, to reveal the mobility patterns and attenuation dynamics of potentially toxic or heavy metal species as a function of depth, with a view of assessing their potential environmental impact with respect to surface and ground water systems. This information is crucial in the beneficial utilization of copper tailings in the development of sustainable construction materials as part of reuse approach management system. About twelve tailings samples were collected into polyethylene plastic bags from three established tailings profiles drilled by a hand auger. The collected tailings samples were characterized using standard analytical procedures i.e., X-ray fluorescence (XRF), X-ray diffraction (XRD) and scanning electron microscopy/energy dispersive spectroscopy (SEM-EDS). The transfer of potentially toxic or heavy metal species from tailings to water was evaluated using the standardized batch leaching test (EN 12457) and speciation-equilibrium calculations on the aqueous extracts performed by MINTEQA2. The leachate concentration of cations in the collected tailings samples was determined by inductively coupled mass spectrometry (ICP-MS) and the leachate concentration of anions was determined by ion chromatography (IC). A modified sequential extraction scheme was applied on the selected tailings samples of the drilled tailings profiles to further understand the mode of occurrence, the geochemical partitioning and distribution, real mobility, and environmental bioavailability of potentially toxic or heavy metal species in the tailings and tailings-soil interface. The extracted fractions or phases from sequential scheme were as follows: (F1) water-soluble fraction, (F2) exchangeable fraction, (F3) carbonate fraction, (F4) iron and manganese hydroxide associated fraction, (F5) organic matter and secondary sulphide associated fraction, (F6) primary sulphide bound fraction, and (F7) residual or silicate fraction. The results obtained from the seven steps sequential extraction scheme were validated by the determination vi of percentage recoveries from pseudo-total digestion or total metal content of the original sample. The distribution of major elements and potentially toxic or heavy metal species in different leachate fractions obtained after each step of sequential extraction of the selected tailings samples was determined by inductively coupled plasma mass spectrometry (ICP-MS). The appraised data was used to reveal the impact of atmospheric oxygen and infiltrating rain-water on the chemistry of copper tailings dump by depth profiles. Macroscopic properties revealed that the abandoned Musina copper tailings are fine to medium coarse grained, and range in color from light/dark gray at the upper or shallow depth of the tailings, to dark reddish-brown at the deeper zone where the tailings are mixed with the underlying soil or soil-interface. The drilled respective tailings profiles were uniform and slightly varied in both mineralogical and bulk chemical compositions with tailings depth. Mineralogical analysis showed the following order of mineralogical composition within the respective tailings profiles: quartz> epidote> chlorite> muscovite> calcite> hematite. Chalcopyrite was the only sulphide mineral observed by optical microscopy, although not identified or quantified by XRD and SEM-EDS analysis. The observed discrete chalcopyrite grains were attributed to the primary mined ore (i.e., chalcopyrite, chalcocite and bornite) during past copper mining activities in Musina. The tailings profiles were characterized by a medium alkaline pH (7.97-8.37) that corresponds very well with the tailings leachates or pore-water pH (8.36-8.46). This pH was constant and slightly varied with tailings depth in the respective tailings profiles. The high abundance of alumino-silicate minerals and traces of carbonates as calcite coupled with low sulphide mineral content, suggested a high neutralization capacity of the tailings which was in common agreement with an alkaline nature of the copper tailings dump. The chemical composition of major elements within the respective tailings profiles followed the order: Si>Al>Fe>Ca>Mg>K>Na, and corresponds very well with the mineralogical composition of the tailings, whereby alumino-silicates were the most abundant minerals in the tailings samples. Nevertheless, the solid-phase concentration of metals decreases with increasing tailings depth as Cu>Sr>Zr>Ni>Zn and was incongruent with the mineralogical composition within the respective tailings profiles. The main secondary minerals were calcite and hematite, and their proportion increased with increasing tailings vii depth. In addition, hematite formed coatings on the rims and corners of chlorite as observed from optical microscopy, and retained relatively high amounts of potentially toxic or heavy metals (up to 862 ppm of Cu, up to 36 ppm of Ni, and up to 25 ppm of Zn) at the upper and shallow depth of the respective tailings profiles, where bulk density was high and low porosity. Based on batch leaching tests, the amounts of potentially toxic or heavy metal species released into solution were low (0.27-0.34 μg/L Pb, 0.54-0.72 μg/L Ni, 0.88-1.80 μg/L Zn, and 20.21-47.9 μg/L Cu) and decreases with increasing tailings depth, indicating that, presently, the tailings have a minor impact on heavy metals load transported to the receiving surface and groundwater systems. The low concentration of potentially toxic or heavy metal species in solution is primarily due to their retention by secondary Fe oxide phases (i.e., hematite) and the prevailing medium alkaline pH condition of the tailings leachate or pore-water. The observations are consistent with MINTEQA2 speciation calculations, which predicted the precipitation of secondary phase cuprite (Cu2O) as the main solubility-controlling mineral phase for Cu, Zn, and Ni. Primary factors influencing aqueous chemistry at the site are neutralization and dissolution reactions as a function of pH, precipitation, and sorption into hydrous oxides (hematite and cuprite). Based on sequential extraction results, the leachable concentration of potentially toxic or heavy metal species in the water-soluble, exchangeable and carbonate fractions of the respective tailings profiles was relatively low, except for Cu and Mn. For instance, the leachable concentration of Cu and Mn reached 10.84 mg/kg and 321.7 mg/kg at the tailings-soil interface (3 m) in tailings profile C, respectively. The low concentration of potentially toxic or heavy metal species (Cr, Co, Ni, Zn, Cd, and Pb) in these fractions could be due to the low solubility of minerals bearing these trace elements caused by variations in pore-water pH in the respective tailings profiles. The high concentration of Cu and Mn in these fractions suggests their high mobility and therefore most available for uptake in the environment. Except for Cu>Mn>Cr, the contents of potentially toxic or heavy metal species in the Fe and Mn oxides and organic matter or sulphides bound fractions was low, due to the low viii quantity of these fractions in the tailings, despite their high affinity and sorption capacity for potentially toxic or heavy metal species. Likewise, the residual fraction of the respective tailings profiles contained the highest proportion of potentially toxic or heavy metal species. Although the highest potentially toxic or heavy metal species content was in fractions with limited mobility, care must be taken since any geochemical change or shift in the tailings pH or acidic conditions may cause them to be displaced to more mobile fractions, thereby increasing their mobility and environmental bioavailability. Therefore, physicochemical properties of the tailings including pH and mineralogical composition of the tailings samples were the main substrate controlling the geochemical partitioning and distribution, potential mobility, and environmental bioavailability of potentially toxic or heavy metal species by tailings depth. The knowledge of mobility and eco-toxicological significance of tailings is needed when considering tailings dump disposal or reuse in the environment. The addition of copper tailings at 3 and 28 days successfully improved the compressive strength of cement mortar mixtures incorporating tailings at C5 (5%) and C10 (10%) respectively, although with small margin relative to the control mixture (C0). The maximum strength was 31.15 Mpa attained after 28 curing days, and slightly varied when compared with other compressive strength on copper blended cement mortars mixtures in other countries, used for the development of sustainable construction materials. The chemical composition, physical properties and improved compressive strength on cement mortars mixtures incorporating copper tailings, implies that copper tailings are suitable for the development of sustainable construction materials, thereby ensuring job creation, availability of land for development usage, and the reduction of environmental pollution induced by the abandoned copper tailings dumps.

PhDENV (Geology) / Department of Mining and Environmental Geology / The study focused on the geology, structural setting and mineralisation of copper-sulphide deposits in the Musina area, located in the Central Zone of the Limpopo Mobile Belt of South Africa. The Messina copper deposits are located in the eastern part of Limpopo Province near the border with Zimbambwe. The deposits stretch from northeastern to southwestern direction for about 15 km. Previous copper mining in the area took place at Artonvilla, Messina, Harper, Campbell and Lilly copper deposits. The current study, however, focused on two main deposits, Campbell and Artonvilla. The origin, nature and mode of formation of the Cu-sulphide deposits in the Musina area have not been established with certainty. Two principal hypotheses on the origin of the Messina copper sulphide deposits have been proposed, viz; a magmatic-hydrothermal model, and meteoric waters model. Consequently, the mode of formation and mineralisation style of the Messina Cu-sulphide deposits remain contentious. Therefore, the main objective of the study was to investigate the nature and mode of formation of Cu-sulphide deposits in the Musina area. Different research methods have been applied in the current study so as to unpack the contradictory positions on the genesis of the Messina copper deposits. This included fieldwork, remote sensing data acquisition, laboratory work, and data analysis and interpretation. Fieldwork involved soil geochemical survey as well as rock and ore sampling within the study area. A total of 295 soil samples, 33 rock specimens and 21 ore samples were collected for laboratory investigation. Laboratory work consisted of a range of methods that included; geochemical analysis, petrographic and cathodoluminescence microscopy, ore mineralogy and ore microscopy, fluid inclusion geothermometry and isotope geochemistry. The work was done in different laboratories including: Mining and Environmental Geology Laboratory, Unviersity of Venda; Department of Geology Laboratory, University of Johannesburg; MINTEK Laboratory in Johannesburg; Société Générale de Surveillance Laboratory in Johannesburg, South Africa; Department of Applied Geology, Geoscience Institute, Göttingen University, Germany and Department of Geology, University of Georgia, Athens, United States of America. Remote sensing data was acquired from Southern Mapping Company, Johannesburg, South Africa. Interpretation of Remote sensing data was done at the University of Applied Sciences, Oswestfalen-Lippe, Germany. Data analysis and interpretation of laboratory results involved the use of: Desktop ArcGIS 10.4.1 for geochemical data interpretation; ENVI 5.1 and ArcGIS 10.4.1 Softwares for remote sensing data; and Triplot version 4.1.2 software for ternary plot for compositional variation of rocks. Soil geochemical survey revealed geochemical anomalies for Pb, Zn, Cu, As and Ni over the known copper deposits in the area as well as over six other areas that have not been associated with any sulphide mineralisation. Such new anomalous areas have been identified as target areas for future exploration of sulphide ore mineralisation. Petrographic studies of the rocks confirmed the host rocks to be amphibolite-quartz granulite, biotite-garnet-quartz granulite, amphibolite, quartzite, hornblende gneiss, quartzo-feldspathic gneiss, potassium-feldspathic gneiss and cal-silicate gneiss. These rocks were subjected to hydrothermal alteration during ore mineralisation within the area. It was further noted that epidote alteration was quite intensive in ore samples, while in unmineralised rock samples it was less intensive. Remote sensing data interpretation revealed spatial distribution and intensity of epidote alteration within the study area and in places coincided either with the known copper deposits or structural features, thus led to the identification of target areas for future mineral exploration in the Musina area. The current study established that the process of ore mineralisation in the Messina copper deposits took place in two distinct phases: first the formation of garnet, graphite, magnetite and hematite during regional metamorphism of the Limpopo Mobile Belt; and secondly, sulphide ore mineralisation resulting in the formation of copper ore comprising, veined, disseminated and brecciated ores. Sulphide ore mineralisation consisted mainly of pyrite, chalcopyrite, sphalerite, bornite, chalcocite and minor pyrrhotite and galena as well as traces of pentlandite, tennantite, mollybdenite, cobaltite and tetrahedrite. This confirms that the Messina copper deposits had complex sulphide ore mineralisation that is typical of hydrothermal mode of ore mineralisation from a magmatic source. The study further establishes the paragenitic sequence of ore mineralisation, comprising four stages: Stage I (Garnet- graphite – Fe oxides); stage II (Quartz- pyrite); stage III (Pyrite- sphalerite - chalcopyrite); and stage IV (Carbonates). Stage III represented the main stage of sulphide ore mineralisation in the area, while Stage IV comprising calcite, dolomite and ankarite marked the final stage of hydrothermal ore mineralisation. Paragenetic sequence identified three generations of quartz; first generation being associated with garnet, graphite, magnetite and hematite, second generation with pyrite and third generation with pyrite, sphalerite and chalcopyrite. Previous studies, however, indicated that there was only one generation of quartz that formed at the temperature between 210o to 150°C, but the current study established that the entrapment temperature of first generation quartz ranges from 315o to 200°C; second generation quartz from 235o to 135°C and third generation quartz from 240o to 115°C. At the same time, sulphur isotope investigation of chalcopyrite-pyrite pair from Campbell deposit registered a temperature of 359°C. The study therefore concluded that the temperature of ore formation within the Messina copper deposits ranged between 359°C and 115°C. The presence of halite and calcite as daughter minerals within the fluid inclusions was noted and this apparently is indicative of high salinity of fluid inclusions, which is considered as a product of direct exolution of crystalizing magma. Raman spectroscopy revealed the composition of gases in the fluid inclusions to be CH4 and N2 with 80% and 20% composition respectively, however, some inclusions were gas-poor. The presence of gases in the fluid inclusions is an indication that there was boiling at the time of entrapment. A narrow range of 34S values of -0.5 to 0.5‰ obtained in this study further confirms the magmatic source of Sulphur as Sulphur from the host rock was found to have high 𝛿34S value of 8.2‰. A genetic model for copper ore mineralisation within Musina area is proposed. The deposits are of polymetallic vein type that are genetically associated with porphyry copper deposits. According to this model, copper ore bodies were formed from hydrothermal fluids originating from magma and were epigenetic in nature. Geological structures in the area acted as conduits for hydrothermal fluids that resulted in the alteration of the host rocks and mineralisation of copper sulphide ore. Thus, the Messina coper deposits are of magmatic hydrothermal origin although the apparent location of a batholith is still unknown and the study recommends further viii research work on the location of the batholith that is presumed to have been the magmatic source. The study further recommend dating of later rocks as well as orebody s it is essential for understanding the process of ore formation in this area. For further exploration, areas that have undergone “moderate” to “high” degree of epidote alteration and lie in close proximity to geological structures such as faults and thrust folds that could have acted as conduits for hydrothermal fluids and resulted in sulphide ore mineralisation and registered high geochemical anomalies for Pb, Zn, As and Ni should be targeted. In support of further mineral exploration within the study area, the study recommend a detailed geostatistical application for the purpose of delineating homogeneous areas based on the combination of lineaments, interpolated soil geochemical maps and thematic maps. / NRF

MENVSC / Department of Ecology and Resource Management / Mine tailings (MT) have been a global problem due to the environmental impacts the waste generates such as air, soil and water pollution. The detrimental impacts include a global problem such as acid mine drainage (AMD) which has been difficult to cleanup. Several studies have been conducted to find alternative measures in reducing or mitigating impacts such as AMD and air pollution. Several studies have revealed how alumino-silicate mineral waste can be used as raw material to produce construction materials. This study aimed at evaluating the potential of synthesizing a geopolymer material from Musina copper mine tailings. Tailings were characterized for their physicochemical and mineralogical compositions using standard laboratory techniques in order to evaluate suitability in geopolymerization. First section of the results presented physicochemical and mineralogical characterization of the Musina copper tailings together with the bioavailability of the chemical species. It was observed that the tailings are mainly composed of SiO2 and Al2O3 as the major oxides indicating that they are aluminosilicate material. Mineralogical analysis revealed dominance of quartz, epidote and chlorite as the major minerals. The bioavailability assessment showed that largely Cu and Ca are bioavailable and highly soluble in an aqueous solution while Al, Mg, Ni, Co, Cr and Fe have a high proportion in non-labile phase. Second section presented the preliminary results wherein the potential application of Musina copper tailings in geopolymerization was evaluated. The results showed that Musina copper tailings can be used to synthesize a geopolymer material. However, it was recommended that several parameters influencing geopolymerization need to be evaluated. The third section presented the evaluation of optimum parameters that influence the geopolymerization process, which include type of alkali activators, alkali activator concentration, curing temperature, liquid-solid (L/S) ratio and curing regime. It was observed that a mixture of NaOH:Na2SiO3.5H20 at a ratio of 70:30 yields a better geopolymer material. The concentration of 10 M NaOH:Na2SiO3.5H20 at a ratio of 70:30 was observed to be the best that yielded the UCS that is acceptable according to SANS1215 standards. When evaluating curing regime, it was found that the material cured using greenhouse has lower UCS as compared to the material cured using oven. The v effect of temperature showed that the UCS decreases with increasing curing temperature. An admixture of river sand and cement was introduced which resulted in a high UCS of 21.16 MPa when using an admixture of cement. The mineralogical composition of the geopolymer bricks showed formation of secondary minerals such as phlogopite, fluorapatite, diopside and actinolite. Batch leaching conducted on the geopolymer bricks detected high leaching of Na from the bricks. Based on the findings of the study of the raw MT potential to produce geopolymer bricks, it was concluded that the material can be used to produce bricks that are within the SANS 1215 requirements. The study further recommended that the study a focus on using cylindrical moulds, other alkali activators and a mechanical mixer. It was also recommended that the greenhouse be restructured to contain heat within the greenhouse during the evening so as to allow constant temperature within / NRF