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<p>Chemical weathering of highly reactive mafic and ultramafic igneous rocks may be a key sink in the global carbon cycle. Understanding how uplift of these rocks during arc-arc and arc-continent collisions through earth history has affected the evolution of global climate, including the onset of icehouse periods, requires improved constraints on the relative sensitivity of their weathering rates to physical erosion vs. climate. If weathering rates depend chiefly on erosion, then tectonic uplift of mafic and ultramafic rocks may have a strongly destabilizing effect on global climate. Conversely, if weathering rates are limited primarily by temperature or runoff, then a negative feedback mechanism between weathering and climate may attenuate the effects of rock uplift. This work characterizes the relationship between chemical weathering rates, physical erosion rates, and climate in tropical, montane watersheds in Puerto Rico that are underlain by volcanic arc rocks and associated ophiolitic serpentinite. Key to this analysis are new constraints on long-term erosion rates on these rocks from cosmogenic Cl-36 produced <em>in situ</em> in magnetite. These cosmogenic erosion rates are paired with classical measurements of stream solute fluxes and sediment geochemistry across runoff gradients to quantify the limits to volcanic arc rock and serpentinite weathering rates. </p> <p><br></p> <p>This work is divided into three chapters. Chapter 2 constrains the altitude scaling behavior of Cl-36 production in magnetite. This allows erosion rates to be determined more accurately in watersheds near sea level in Puerto Rico. Chapter 3 demonstrates that volcanic arc rock weathering rates in the humid tropics are more strongly limited by physical erosion than by climatic factors. However, a positive correlation between erosion and runoff observed in this landscape may enhance the coupling between climate and weathering rates. Chapter 4 finds that, in contrast to volcanic arc rocks, serpentinite weathering is strongly limited by runoff and weakly limited by erosion. These results are presented as empirical power-law relationships that can be readily applied in global carbon cycle modeling.  </p>

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The evolution of mountain landscapes is controlled by complex interactions between large-scale tectonic, surficial and climate conditions. Dominant processes are attributed to creating characteristic features of the landscape, but topographic features are the cumulative result of coupled surficial processes, each locally effective in a different climate or elevation regime. The focus of erosion by glacial, fluvial, or mass wasting processes is highly sensitive to small changes in boundary conditions, therefore spatial and temporal variability can be high when observed over short time scales. This work evaluated methods for dissecting the history of complex alpine landscapes to understand the role of individual processes influenced by changing climate and underlying bedrock. It also investigated how individual and combined mechanisms of surficial processes influenced the evolution of topography in the Teton Range in Wyoming. Detrital apatite (U-Th)/He thermochronology and cosmogenic radionuclide erosion rates were applied to determine spatial and temporal variability of erosion in the central catchments of the range. Spatial variability existed between the glacial and fluvial systems, indicating that sediment erosion and deposition by these processes was controlled by short-term variability in climate conditions. Effective glacial incision also controlled other processes, specifically enhancing rock fall activity and inhibiting fluvial incision. Short-term erosion rates were highly variable and were controlled by stochastic processes, particularly hillslope failures in response to slope oversteepening due to glacial incision and orientation and spacing of bedrock fractures. Erosion rates averaged over 10 ky time scales were comparable to long-term exhumation rates measured in the Teton Range. The similarity of spatial erosion patterns to predicted uniform erosion and the balance between intermediate and long-term erosion rates suggests the landscape of the Teton Range is approaching steady-state, but frequent stochastic processes, short-term erosional variability and coupled processes maintain rugged topographic relief. / Ph. D.

Many passive margins experience pulsed exhumation events late in their history as a result of plate boundary distal geodynamic mechanisms or climatic events. The onset of late Cenozoic glaciation, often associated with enhanced rates of erosion, is one such possible cause of passive margin rejuvenation. However, along passive margins the effectiveness of Plio-Pleistocene glaciers at eroding the landscape may be limited by low tectonic rock uplift rates or as a result of erosionally inefficient cold based continental ice-sheets. In this dissertation the evolution of post-orogenic topography and the effect of glaciations on denuding landscapes along the North Atlantic Passive Margin, in the White Mountains of New Hampshire and the western Scottish Highlands, was investigated. Background exhumation rates averaged over 106-7 yr timescale were determined using apatite (U-Th)/He thermochronology. To resolve whether or not a change in exhumation rate occurred coincident with glaciation these background exhumation rates were compared to magnitudes of erosion averaged over the glacially relevant 103-4 yr timescale using the in situ terrestrial cosmogenic nuclide 10Be. In chapter two, 106-7 yr timescale exhumation and burial histories across the western Scottish Highlands were determined. The results show that post-orogenic burial and exhumation is mostly a result of plate margin distal tectonic and magmatic factors that are variable across short distances (i.e., <100 km). In chapter three, patterns and magnitudes of erosion during glaciation and following deglaciation in the Scottish Highlands were investigated. The results indicate that polythermal glacial erosion denuded low elevation portions of the Scottish Highlands and preserved summits. This produced relief but did not significantly lower the maximum elevation of the landscape. Following deglaciation Scotland's sediment budget remains dominated by glaciogenic sediment. In the fourth chapter, magnitudes of background exhumation in the Presidential and Carter Ranges of the White Mountains, New Hampshire were compared to magnitudes of glacial erosion. The results indicate that most relief was produced prior to glaciation and that background exhumation rates in the Cenozoic are low (<0.01 mm yr-1). In the late-Cenozoic, cold- based glaciation prevented an acceleration of erosion in the White Mountains. The post- glacial sediment budget is made up of dominantly glaciogenic sediment. Overall, the main findings of this dissertation are; (1) post-orogenic burial, exhumation, and relief production are mainly the result of spatially heterogeneous plate margin distal vertical crustal motions; across passive margins covered by large continental ice sheets; (2) cold-based ice limits the magnitudes of late Cenozoic glacial erosion sediment budgets continue to be dominated by glaciogenic sediment, >10 ka after and (3) post-glacial deglaciation. / Ph. D.

The New River crosses the core of the ancient, tectonically quiescent Appalachian orogen as it follows its course through North Carolina, Virginia, and West Virginia. It is ideally situated to record the changes in geomorphic process rates that occur in the Appalachians as a response to late Cenozoic climate variations. Active erosion features on resistant bedrock that floors the river at prominent knickpoints demonstrate that the river is currently incising toward base level. However, large packages of alluvial fill and fluvial terraces cut into this fill record an incision history for the river that includes several periods of stalled downcutting and aggradation. Cosmogenic 10-Be exposure dating, aided by mapping and sedimentological examination of terrace deposits, is used to constrain the timing of events in this history. Fill-cut and strath terraces at elevations 10, 20, and 50 m above the modern river yield cosmogenic exposure ages of approximately 130, 610, and 955 ka, respectively, but uncertainties on these ages are not well-constrained. This translates to a long-term average incision rate of 43 m/my, which is comparable to rates measured elsewhere in the Appalachians. During specific intervals over the last 1 Ma, however, the New River's incision rate reached 97 m/my. Fluctuations between aggradation and rapid incision appear to be related to late Cenozoic climate variations, though uncertainties in modeled ages preclude direct correlation of these fluctuations to specific climate change events. Erosion rates on higher alluvial deposits adjacent to the river are estimated from 10-Be concentrations; these rates are very low, about 2 m/my or less. This demonstrates a disequilibrium in the modern landscape, with river incision greatly outpacing erosion from nearby landforms. / Master of Science

This thesis presents stratigraphic, sedimentological and geochronological results from valley fill and glacial moraines of the Hope-Waiau Valleys in North Canterbury, New Zealand. The findings demonstrate that a substantial portion of the modern valley fill comprises in-situ sedimentary sequences that were deposited during the penultimate glaciation (OIS 6), the last interglacial (OIS 5) and during the mid-late last glacial cycle (OIS 3/2). The sediments survived at low elevations in the valley floor despite overriding by later glacial advances. Sedimentologically, the fill indicates deposition in an ice marginal zone and consists of paraglacial/distal-proglacial aggradation gravels and ice-proximal/marginal-subglacial sediments. Deposition during glacial advance phases was characterized by the sedimentation of outwash gravels and small push moraines while glacial retreat phases are dominated by glaciolacustrine deposits which are frequently interbedded with debris flow diamictons. The overall depositional arrangement indicates that glacial retreat from the lower valley portion occurred via large scale ice stagnation. Results from infra-red stimulated luminescence (IRSL) dating gives evidence for five large aggradation and degradation phases in the Hope-Waiau Valleys over the last 200 ka. Combined with surface exposure dating (SED) of moraines the geochronological results indicate that glacial advances during OIS 6 were substantially larger in both ice extent and ice volume than during OIS 4-2. The last glacial maximum (LGM) ice advance occurred prior to 20.5 ka and glacial retreat from extended ice positions began by ~18 ka BP. A late glacial re-advance (Lewis Pass advance) occurred at ~13 ka BP and is probably associated with a regional cooling event correlated to the Antarctic Cold Reversal (ACR). The findings from the Hope-Waiau Valleys were integrated into a model for glaciations in the Southern Alps which uses data from a snow mass balance model to analyse the sensitivity of glacial accumulation to temperature forcing. Model results indicate that in the central hyperhumid sector of the Southern Alps ice would expand rapidly with minor cooling (2-4℃) suggesting that full glaciation could be generated with little thermal forcing. Some Quaternary glacial advances in the Southern Alps may have been triggered by regional climate phenomena (e.g. changes in ENSO mode) rather than requiring a thermal trigger from the Northern Hemisphere.

This thesis develops a better knowledge of the extent and timing of glaciations in southern Argentina throughout the Quaternary. It provides a detailed understanding of successive major glacial outlet lobes in the Lago Pueyrredón valley. The glacial and glaciofluvial deposits in the valley, as elsewhere in the region, are extremely well-preserved and reflect punctuated glacial advances between ~ 1.1 Ma and ~ 17 ka. Several intermediate glaciations are undated, constrained by the limited time frame of radiocarbon age dating, the limited potential volcanic sites for K-Ar or 40Ar/39Ar age dating, and erosion and exhumation problems associated with cosmogenic-nuclide surface exposure ages on moraines. This thesis provides a new chronology for the mid-Quaternary glaciations based on methodological advances in cosmogenic-nuclide surface exposure age dating. This is done by deriving ages from glacial outwash terrace sediment and demonstrating their reliability. The work shows that for younger (i.e., last glacial) moraines, well-constrained ages can be derived from the common-practice of dating large boulders on the moraine surface. However, on older moraines, the ages so-derived become considerably scattered. This is interpreted to be caused primarily by boulder exhumation as a consequence of moraine erosion, resulting in shorter residence of some boulders at the surface relative to the moraine formation date. By contrast, glacial outwash surfaces in this area, if carefully chosen, can be shown to have undergone little aggradation or erosion, and thus have had long and consistent surface exposure since formation. Provided these surfaces can be stratigraphically linked with the glacial limits, they can provide good surface exposure ages. This has been convincingly confirmed in one location by a sequence of ages obtained from a 10Be concentration depth-profile which demonstrate the surface stability and lack of inherited nuclides. Using these methods, cosmogenic 10Be and 26Al surface exposure ages indicate successive major advances occurred at ~ 1.2 Ma, ~ 600 ka, ~ 260 ka and ~27 – 17.5 ka. These are correlated with global marine and ice core records.