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Fixed Bed Countercurrent Low Temperature Gasification of Dairy Biomass and Coal-Dairy Biomass Blends Using Air-Steam as OxidizerGordillo Ariza, Gerardo 2009 August 1900 (has links)
Concentrated animal feeding operations such as cattle feedlots and dairies
produce a large amount of manure, cattle biomass (CB), which may lead to land, water,
and air pollution if waste handling systems and storage and treatment structures are not
properly managed. However, the concentrated production of low quality CB at these
feeding operations serves as a good feedstock for in situ gasification for syngas (CO and
H2) production and subsequent use in power generation. A small scale (10 kW)
countercurrent fixed bed gasifier was rebuilt to perform gasification studies under quasisteady
state conditions using dairy biomass (DB) as feedstock and various air-steam
mixtures as oxidizing sources. A DB-ash (from DB) blend and a DB-Wyoming coal
blend were also studied for comparison purposes. In addition, chlorinated char was also
produced via pure pyrolysis of DB using N2 and N2-steam gas mixtures.
The chlorinated char is useful for enhanced capture of Hg in ESP of coal fired
boilers. Two main parameters were investigated in the gasification studies with air-steam
mixtures. One was the equivalence ratio ER (the ratio of stochiometric air to actual air) and the second was the steam to fuel ratio (S:F). Prior to the experimental studies, atom
conservation with i) limited product species and ii) equilibrium modeling studies with a
large number of product species were performed on the gasification of DB to determine
suitable range of operating conditions (ER and S:F ratio). Results on bed temperature
profile, gas composition (CO, CO2, H2, CH4, C2H6, and N2), gross heating value (HHV),
and energy conversion efficiency (ECE) are presented.
Both modeling and experimental results show that gasification under increased
ER and S:F ratios tend to produce rich mixtures in H2 and CO2 but poor in CO.
Increased ER produces gases with higher HHV but decreases the ECE due to higher tar
and char production. Gasification of DB under the operating conditions 1.59<ER less than6.36
and 0.35<s:f>less than0.8 yielded gas mixtures with compositions as given below: CO (4.77 -
11.73 %), H2 (13.48 - 25.45%), CO2 (11-25.2%), CH4 (0.43-1.73 %), and C2H6 (0.2-
0.69%). In general, the bed temperature profiles had peaks that ranged between 519 and
1032 degrees C for DB gasification.
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A Mechanistic Model for Flooding in Vertical TubesHogan, Kevin J. 2009 August 1900 (has links)
In a counter-current two-phase flow system, flooding can be defined as the onset
of flow reversal of the liquid component which results in an upward co-current flow.
Flooding in the surge line of pressurized water reactors poses a significant technical
challenge in the analysis of several postulated nuclear reactor accident scenarios.
Despite the importance of flooding in these analyses, previous work does not
identify a universally accepted rigorous physics-based model of flooding, even for
the simple case of flooding in adiabatic, vertical tubes. This can be attributed to
a lack of conclusive understanding of the physics of two-phase counter-current flow,
specifically the mechanism of flooding, and the large amount of uncertainty among
data from various flooding experiments. This deficiency in phenomenological and
experimental knowledge has led to the use of many empirical and semi-empirical
correlations for specific system conditions and geometries. The goal of this work
is the development of a model for flooding in vertical, adiabatic tubes from first
principles.
To address a source of uncertainty in the analysis of flooding, a model for the
prediction of average film thickness in annular co- and counter-current flows has been
developed by considering the conservation of momentum of the liquid and gas flows.
This model is shown to be a quantitative improvement over the most commonly used
models, those of Nusselt and Belkin, Macleod, Monrad, and Rothfus. The new model
better considers the effects of interfacial shear and tube curvature by using closure
relations known to represent forces appropriately in co- and counter-current flow. Previous work based on semi-empirical flooding models has been analyzed to
develop a new theory on the hydrodynamic mechanism which causes flooding. It is
postulated that the growth of an interfacial wave due to interfacial instability results
in a flow reversal to ensure that momentum is conserved in the counter-current flow
system by causing a partial or complete co-current flow.
A model for the stability of interfacial waves in a counter-current flow system
is proposed and has been developed herein. This model accurately represents the
geometric and flow conditions in vertical adiabatic tubes and has been shown to have
limits that are consistent with the physical basis of the system. The theory of waves
of finite amplitude was employed to provide closure to an unknown parameter in
the new model, the wave number of the wave that generates the interfacial instabil-
ity. While this model underpredicts the flooding superficial gas velocity, the result
is a conservative estimate of what conditions will generate flooding for a system.
In the context of the analysis of a nuclear reactor, specifically a pressurized water
reactor, conservatism means that the gas flow rate predicted to cause flooding for
a fixed liquid flow rate will be less than the flow rate found experimentally, mean-
ing that liquid delivery to the core would be safely underestimated. Future work
includes the improvement of the closure relation for the limiting wave number that
will cause unstable interfacial waves, as well as an assessment of the applicability of
the stability-based model to flooding in the presence of phase change and flooding
in complex geometries.
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Simulation and Analysis of a Tissue Equivalent Proportional Counter Using the Monte Carlo Transport Code FLUKANorthum, Jeremy Dell 2010 May 1900 (has links)
The purpose of this study was to determine how well the Monte Carlo transport
code FLUKA can simulate a tissue-equivalent proportional counter (TEPC) and produce
the expected delta ray events when exposed to high energy heavy ions (HZE) like in the
galactic cosmic ray (GCR) environment. Accurate transport codes are desirable because
of the high cost of beam time, the inability to measure the mixed field GCR on the
ground and the flexibility they offer in the engineering and design process.
A spherical TEPC simulating a 1 um site size was constructed in FLUKA and its
response was compared to experimental data for an 56Fe beam at 360 MeV/nucleon. The
response of several narrow beams at different impact parameters were used to explain
the features of the response of the same detector exposed to a uniform field of radiation.
Additionally, an investigation was made into the effect of the wall thickness on the
response of the TEPC and the range of delta rays in the tissue-equivalent (TE) wall
material. A full impact parameter test (from IP = 0 to IP = detector radius) was
performed to show that FLUKA produces the expected wall effect. That is, energy deposition in the gas volume can occur even when the primary beam does not pass
through the gas volume.
A final comparison to experimental data was made for the simulated TEPC
exposed to various broad beams in the energy range of 200 - 1000 MeV/nucleon.
FLUKA overestimated energy deposition in the gas volume in all cases. The FLUKA
results differed from the experimental data by an average of 25.2 % for yF and 12.4 %
for yD. It is suggested that this difference can be reduced by adjusting the FLUKA
default ionization potential and density correction factors.
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The mispricing of reverse convertible the case of ABN Amro's Rex in the U.S. O.T.C. market /Obadia, Emmanuel. January 2009 (has links) (PDF)
Thesis (M.B.A.)--University of North Carolina Wilmington, 2009. / Title from PDF title page (February 17, 2010) Includes bibliographical references (p. 21)
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Neural networks for financial markets analyses and options valuation /Wu, Ing-Chyuan, January 2002 (has links)
Thesis (Ph. D.)--University of Missouri-Columbia, 2002. / Typescript. Vita. Includes bibliographical references (leaves 167-172). Also available on the Internet.
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Neural networks for financial markets analyses and options valuationWu, Ing-Chyuan, January 2002 (has links)
Thesis (Ph. D.)--University of Missouri-Columbia, 2002. / Typescript. Vita. Includes bibliographical references (leaves 167-172). Also available on the Internet.
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Working through a monumental break up : ideological transitions, ironic monumental disruptions, and public deliberationVartabedian, Sarah Ellen 25 February 2013 (has links)
At present the literature of counter-monument studies does not account for the complex interactions of irony and nostalgia in memorial spaces. The three case studies examined in this project show that nostalgia can produce critically engaging spaces of deliberation depending on how ironic commemoration intervenes in comic or tragic frames. In order to show that more rhetorical focus is possible, I have challenged the conceptualization of counter-monument studies through what I have termed the “ironic monumental disruption.” Monument studies must address how the idea of the counter-monument, in which the "counter" supposedly resides in the artifact itself, valorizes monolithic critiques and fails to recognize that contexts, interactions, and artifacts all shape the symbolism of the commemorative site. Alternatively, ironic monumental disruptions offer critical and deliberative opportunities in their interactions with visitors and provide more conceptual insight into transitional commemorative practices. The monuments reviewed in this project initially appeared to provide additional reinforcement for escapist, capitalist narratives, but my examination of them has revealed that allowing for (ironic) commemorative contradictions provides discursive openings for publics unknowingly silenced by a lack of public deliberation. Commemorative irony produces valuable insights into the current historical moment and the representational issues created by ideological transitions. The citizens of Bosnia, Bulgaria, and Hungary express varying levels of nostalgia about their communist past, which is why the commemorative sites within these countries create a valuable spectrum of ironic and nostalgic entanglements. Commemorative irony produces valuable insights into the current historical moment and the representational issues created by ideological transitions. / text
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High New York: The Birth of a Psychedelic Subculture in the American City2015 October 1900 (has links)
The consumption of LSD and similar psychedelic drugs in New York City led to a great deal of cultural innovations that formed a unique psychedelic subculture from the early 1960s onwards. Historians and other commentators have offered conflicting views on this phenomenon by using either an epidemiological approach or by giving drug users more agency. The present study sides with the latter category to offer a new social history of LSD, but problematizes this topic in a sophisticated way by understanding psychedelic drug use as a social fact that in turn produces meaning for its consumers. It analyses the multiple cultural features of psychedelia through the lenses of politics, science, religion, and art, but also looks at the utopian and radical off-shoots of that subculture. To balance this thematic approach, it historicises the subculture by analysing its early days and discussing its origins, and then by pointing to the factors that led to its metamorphosis towards the end of the 1960s. In order to give LSD consumers a clearer voice, this dissertation is based on memoirs, correspondence and interviews that are used to balance press coverage gleaned from archival collections. With this wide array of primary sources supplemented by up-to-date secondary literature, it argues that the use of LSD and psychedelics led to a rich subculture that can be explained by the inherent complexity of the psychedelic experience. In turn, the plurality of opinions regarding the meaning and purposes of the experience led to tensions and polarisations within the large subculture, as well as with other drug subcultures and outsiders leery of illicit drug use. In doing so, this dissertation contributes to the social history of illicit substance consumption and adds to the fields of urban history and the history of subcultures, and makes a case for understanding LSD and psychedelics as a unique category of forbidden drugs that differ vastly in their cultural meaning from other drugs.
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Υλοποίηση κρυπτο-επεξεργαστικής πλατφόρμας για πιστοποίηση μηνυμάτων στο πρότυπο Galois/Counter Mode (GCM)Σακελλαρίου, Παναγιώτης 19 October 2009 (has links)
Η παρούσα διπλωματική προτείνει μια hardware υλοποίηση του μηχανισμού πιστοποίησης μηνυμάτων βασισμένη στο πρότυπο Galois/Counter Mode (GCM) . O αλγόριθμος κρυπτογράφησης Galois/Counter Mode (GCM) εκδόθηκε από τον οργανισμό National Institute of Standards and Technology (NIST) τον Νοέμβριο του 2007. Σε συνεργασία με τον μηχανισμός κρυπτογράφησης μηνυμάτων, υλοποιείται το πρότυπο GCM για online λειτουργία.
Στο Κεφάλαιο 1, αρχικά γίνεται μια σύντομη ιστορική αναδρομή στον τομέα της κρυπτογραφίας. Στην συνέχεια παρουσιάζονται οι λόγοι που οδήγησαν στην δημιουργία αυτού του αλγορίθμου. Ακολουθεί μια σύντομη εισαγωγή στον GCM και στους τρόπους με τους οποίος αυτός δουλεύει. Στο τέλος του κεφαλαίου αναφέρονται οι πρακτικές εφαρμογές που έχει η χρήση του GCM.
Στο Κεφάλαιο 2, αρχικά αναφέρονται οι συμβολισμοί που χρησιμοποιούνται στην διπλωματική καθώς και οι βασικές έννοιες που χρησιμοποιούνται. Στην συνέχεια, αναλύεται το μαθηματικό υπόβαθρο που είναι απαραίτητο για την κατανόηση των εσωτερικών μηχανισμών του GCM. Η ανάλυση που γίνεται σε αυτή την ενότητα αποτελεί και την βασική αρχή στην οποία στηρίχτηκε η δημιουργία του αλγορίθμου. Ακολουθεί η ανάλυση των μαθηματικών συνιστωσών του GCM. Η ενότητα αυτή κατατάσσεται τόσο σε μαθηματική ανάλυση όσο και σε hardware προσέγγιση των επιμέρους συνιστωσών . Ιδιαίτερο ενδιαφέρον παρουσιάζει η τελευταία υποενότητα του κεφαλαίου που παρουσιάζει τον τρόπο με τον οποίο από τον σειριακό πολλαπλασιαστή στο GF(2128) οδηγούμαστε στον παράλληλο πολλαπλασιαστή.
Στο Κεφάλαιο 3, αρχικά παρουσιάζεται ο Advanced Encryption Standard (AES) και πιο συγκεκριμένα η forward function αυτού με υποστηριζόμενο κλειδί 128 bit. Στην συνέχεια του κεφαλαίου, παρουσιάζονται τα πλεονεκτήματα για την υλοποίηση με χρήση FPGAs, επίσης γίνεται μια σύντομη περιγραφή των βασικών διαφορών που παρουσιάζονται στις δύο οικογένειες FPGAs που χρησιμοποιήθηκαν.
Στο Κεφάλαιο 4 , πραγματοποιείται η ανάλυση του αλγορίθμου GCM βασισμένη στο recommendation του NIST. Παρουσιάζονται όλοι οι επιμέρους αλγόριθμοι που χρησιμοποιούνται καθώς και ο τρόπος με τον οποίον αυτοί αλληλεπιδρούν και συνεργάζονται για την δημιουργία του GCM αλγορίθμου. Στο τέλος του κεφαλαίου, αναφέρονται οι απαιτήσεις για key και IV που πρέπει να ικανοποιούνται για να θεωρείται ο αλγόριθμος κρυπτογραφικά ισχυρός.
Στο Κεφάλαιο 5, αρχικά γίνεται μια top down ανάλυση του GCM. Η ανάλυση αυτή χρησιμοποιείται στην δεύτερη ενότητα όπου προτείνεται και αναλύεται η αρχιτεκτονική που χρησιμοποιήθηκε για την hardware υλοποίηση. Στην συνέχεια, αναλύονται τα βασικά δομικά στοιχεία του GCM. Στην τελευταία ενότητα αναφέρεται η δομή που χρησιμοποιήθηκε με σκοπό την υλοποίηση για high speed απαιτήσεις.
Στο Κεφάλαιο 6, αρχικά γίνεται εισαγωγή στον μηχανισμό πιστοποίησης μηνυμάτων έτσι όπως αυτό υλοποιήθηκε. Στην συνέχεια , παραθέτονται τα αποτέλεσμα που προέκυψαν από την εξομοίωση του VHDL κώδικα. Ακολουθούν τα αποτελέσματα της σύνθεσης και σύγκριση μεταξύ διαφορετικών τρόπων υλοποίησης. Στο τέλος του κεφαλαίου γίνεται σύγκριση μεταξύ των δύο τεχνολογιών που χρησιμοποιήθηκαν για την σύνθεση.
Στο κεφάλαιο 7, αρχικά γίνεται εισαγωγή στον τρόπο με τον οποίο ο μηχανισμός πιστοποίησης και κρυπτογράφησης μηνυμάτων συνεργάζονται. Στην δεύτερη ενότητα παραθέτεται ο τρόπος λειτουργίας του GCM μηχανισμού που υλοποιήθηκε. Ακολουθούν τα αποτελέσματα της εξομοίωσης. Στην τελευταία ενότητα παραθέτονται τα αποτέλεσμα σύνθεσης σε δύο διαφορετικές τεχνολογίες.
Στο Παράρτημα Α παρουσιάζεται ο τρόπος χρήσης του Xilinx ISE που χρησιμοποιήθηκε για την σύνθεση του VHDL κώδικα για την τεχνολογία Virtex 5.
Τέλος στο Παράρτημα Β παρουσιάζονται κάποια βασικά κομμάτια του κώδικα C. / The Galois/Counter Mode of Operation (GCM), recently standardized by NIST, simultaneously authenticates and encrypts data at speeds not previously possible for both software and hardware implementations. In GCM, data integrity is achieved by chaining Galois field multiplication operations while a symmetric key block cipher such as the Advanced Encryption Standard (AES), is used to meet goals of confidentiality.
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Canadian Maritime Security in an Era of Climate Change: The Away GameGillis, J. Matthew 19 August 2010 (has links)
Beyond possible sovereignty disputes resulting from melting Arctic ice, very little is said or written about the maritime security implications of climate change. What does climate change mean for Canadian maritime security, and how can Canada adequately prepare to ensure continued safe and secure use of the world’s oceans in an era of climate change?
Climate change is relevant to maritime security through two chief dimensions. First, navies will more frequently be tasked to deliver humanitarian assistance and disaster relief in the wake of more intense natural disasters. Second, increasing disorder on land will ‘slop over’ into the world’s oceans, threatening the safety of maritime commerce.
Canada has stakes in both of these dimensions, and so there is great impetus for preparedness. The recommended model for preparedness sees Canada’s navy adopting a more varied fleet structure, one better suited for constabulary and diplomatic functions as opposed to traditional military functions.
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