This study set out to investigate the shear stress behaviour at the bed under combined wave and current action. The intention of the study was to make experimental measurements to determine how wave and current shear stresses combine, so that theoretical models describing the combined flow condition could be proposed. Two types of experiment were conducted, and theoretical models for the combined flow were assessed. One set of experiments attempted to use a shear plate to make direct measurements of the combined flow shear stress, and of the shear stresses for the component waves and steady currents. This approach failed because the large correction terms introduced by the non-uniform wave pressure field could not be accurately estimated. The second set of experiments used a laser doppler anemometer to make detailed velocity profile measurements over flat sediment beds. The onset of sediment motion was used as a criterion to carefully control the experiments. It is assumed that the threshold of sediment motion represents a specific shear stress intensity at the bed for sediments of narrow size ranges. As the shear stresses can be determined from the velocity fields under waves and currents, their additive nature under combined flow conditions could be investigated. For each sediment size range, it is shown that the same maximum velocity very near the bed can be used to specify the threshold of sediment motion condition for all flow types, be they under waves, currents, or combined waves and currents. It is also shown that the near-bed velocity under a laboratory wave can be predicted accurately from second order wave theory and that the velocity under a current can be predicted from combining Manning's relation with the universal log velocity law. It is further shown that the near-bed velocity under a combined wave and current can be described by the vectorial addition of the maximum component wave velocity and the average component current velocity. The shear stress for the onset of motion is calculated for the steady current using Manning's relation, for the wave by combining the oscillatory shear stress formula with Kamphuis's rough turbulent friction factor relation, and for the combined wave and current by the simple vectorial addition of the component shear stresses, and is shown to be comparable with Shields's threshold criterion for nearly all conditions tested. / Applied Science, Faculty of / Civil Engineering, Department of / Graduate

This thesis describes firstly, a study involving the thermal rearrangement of substituted 6-e̲x̲o̲-(1-alkenyl) bicyclo-[3.1.0]hexenes, and secondly, the application of this type of transformation to a total synthesis of (±)-sinularene (1̲2̲5̲). The 6-e̲x̲o̲-(1-alkenyl)bicyclo[3.1.0]hexenes (1̲8̲7̲, 1̲8̲9̲, 1̲9̲2̲, 1̲9̲4̲, 2̲4̲0̲, 2̲7̲4̲ and 340) were prepared and thermolyzed in sealed tubes to afford the corresponding bicyclo[3.2.1]octa-2,6-dienes (1̲8̲8̲, 1̲9̲0̲, 1̲9̲3̲, 1̲9̲5̲, 2̲4̲1̲, 2̲7̲6̲ and 3̲4̲1̲) in generally excellent yields. With the exception of 1̲9̲0̲, the thermolysis products were subjected to acid-catalyzed hydrolysis to give the respective bicyclo[3.2.1]octenones. From this study, it is clear that a) the Cope rearrangement of substrates, such as 2̲7̲4̲ and 3̲4̲0̲, containing even sterically bulky substituents on the 6-alkenyl side chain presents a viable means of generating functionalized bicyclo [ 3.2.1] octa-2 , 6-dienes, b) this methodology provides for the placement of synthetically useful functionalities on any of the carbon bridges of the bicyclo-[3.2.1]octane skeleton, and c) the transformations 2̲4̲0̲→2̲4̲1̲ and 2̲7̲4̲→2̲7̲6̲ provide strong evidence for the stereospecificity of the rearrangement process. In the total synthesis of (±)-sinularene (1̲2̲5̲), the key step involved the thermal rearrangement of 3̲2̲2̲ to afford the bicyclo[3.2.1]octadiene 3̲2̲1̲. The compound 3̲2̲2̲̲ was readily prepared as follows. 1-Lithio-3-methyl-1-butyne was treated with methacrolein to furnish the allylic alcohol 3̲3̲1̲, which was transformed into the ester 3̲3̲2̲ v̲i̲a̲ an orthoester Claisen rearrangement (hot triethyl .orthoacetate, propionic acid). Hydrolysis of the ester 3̲3̲2̲, followed by reaction of the resultant acid with oxalyl chloride in refluxing hexane gave the corresponding acid chloride 3̲3̲4̲. Treatment of 3̲3̲4̲ with a cold, ethereal solution of diazomethane afforded the diazo ketone 3̲3̲5̲, which in the presence of copper (II) acetoacetonate in refluxing benzene, underwent an intramolecular carbenoid cyclization to furnish the bicyclic ketone 3̲3̲6̲. Semihydrogenation of 3̲3̲6̲ using Lindlar’s catalyst gave stereoselectively the c̲i̲s̲-alkenyl ketone 3̲3̲7̲. The enone 3̲3̲8̲ was obtained by oxidizing the trimethylsilyl enol ether of 3̲3̲7̲ using palladium (II) acetate in acetonitrile. When the enone 3̲3̲8̲ was treated with lithium divinylcuprate, the two epimeric products 3̲3̲9̲ and 3̲4̲6̲ were obtained in a ratio of 9:1, respectively, and were sus-sequently separated by column chromatography. Trapping the lithium enolate of 3̲3̲9̲ with t̲-butyldimethylsilyl chloride led to the required enol ether 3̲3̲2̲. Thermolysis (220°C, sealed tube) of 3̲3̲2̲ in benzene produced exclusively in 86% yield the desired bicyclic triene 3̲2̲1̲. Subjection of 3̲2̲1̲ to hydroboration using disiamylborane gave, after oxidative workup, the alcohol 3̲4̲7̲, which on treatment with p̲-toluenesulfonyl chloride in the presence of 4-dimethylaminopyridine, afforded the ketone 3̲4̲9̲. Successive hydrogenation of 3̲4̲9̲ and Wittig olefination of the resultant ketone 2̲8̲0̲ completed the total synthesis of (±)-sinularene (1̲2̲5̲). [formula omitted] / Science, Faculty of / Chemistry, Department of / Graduate

Two problems in oceanic/atmospheric modelling are examined in this thesis. In the first problem the release of fresh water from a midlatitude estuary to the continental shelf is modelled numerically as a Rossby adjustment problem using a primitive equation model. As the initial salinity front is relaxed, a first baroclinic mode Kelvin wave propagates into the estuary, while along the continental shelf, the disturbance travels in the direction of coastally trapped waves but with a relatively slow propagation speed. When a submarine canyon extends offshore from the estuary, the joint effect of baroclinicity and bottom relief provides forcing for barotropic flow. The disturbance now propagates along the shelf at the first coastally trapped wave mode phase speed, and the shelf circulation is significantly more energetic and barotropic than in the case without the canyon. For both the experiments with and without a canyon an anticyclonic circulation is formed off the mouth of the estuary, generated by the surface outflow and deeper inflow over changing bottom topography. As the deeper inflow encounters shallower depth, the column of fluid is vertically compressed, thereby spinning up anticyclonically due to the conservation of potential vorticity. This feature is in qualitative agreement with the Tully eddy observed off Juan de Fuca Strait. A study of the reverse estuary (where the estuarine water is denser than the oceanic water) shows that this configuration has more potential energy available for conversion to kinetic energy than the normal estuary. Bass Strait may be considered as a possible reverse estuary source for the generation of coastally trapped waves. Model solutions are compared with field observations in the Bass Strait region and with the results of the Australian Coastal Experiment. The effects of a wider shelf and a wider estuary are examined by two more experiments. For the wider shelf, the resulting baroclinic flow is similar to that of the other runs, although the barotropic flow is weaker. The wide estuary model proves to be the most dynamic of all, with the intensified anticyclonic circulation now extending well into the estuary. In the second problem the effect of the horizontal structure of midlatitude oceanic heating on the stationary atmospheric response is examined by means of a continuously stratified model and a simple two level model, both in the quasigeostrophic β-plane approximation. Solutions are obtained for three non-periodic zonal heating structures (line source, segmented cosine, and segmented sine). Little difference is observed between the solutions for these two different models (continuously stratified and two level). There are two cases which emerge in obtaining analytic solutions. In case 1, for large meridional wavenumbers, there exists a large local response and a constant downstream response. In case 2, for small meridional wavenumbers, the far field response is now sinusoidal. A critical wavenumber separating these two cases is obtained. The effect of oceanic heating on the atmosphere over the Kuroshio region is examined in an attempt to explain the large correlations observed between winter Kuroshio oceanic heat flux anomalies, and the winter atmospheric surface pressure and 500 & 700 mb geopotential heights, both upstream and downstream of the heating region. In both models, the response is consistent with the observed correlations. When western North Pacific heating and eastern North Pacific cooling are introduced into the models, a large low pressure response is observed over the central North Pacific. This feature is in excellent agreement with the observed correlations. A time dependent, periodic, two level model (with and without surface friction) is also introduced in order to study the transient atmospheric response to oceanic heating. The height at which the thermodynamic equation is applied is found to be crucial in determining the response of this model. When the heating is entered into the model near to the surface, unstable modes are prevalent sooner than they would be when the heat forcing is applied at a higher level. As in the steady state models, two cases dependent on the meridional wavenumber ɭ emerge in the analysis. For small scale meridional heating structures (large ɭ), the response consists of an upper level high and a lower level low which propagate eastward with time. For large scale meridional heating structures (small ɭ) the response essentially consists of a wavenumber 3-4 perturbation superimposed on the solution for large ɭ. / Science, Faculty of / Mathematics, Department of / Graduate

Turbidity currents, both continuous flow and surge-type, have been detected with acoustic sounders operating at 42.5, 107 and 200, kHz. The turbidity currents are associated with the discharge of mine tailing into Rupert Inlet. A linear relation is obtained between the backscattered acoustic signal at 200 kHz and the one-half power of suspended particulate concentration from 10 to 1000 mg 1⁻¹. This relation is consistent with Rayleigh scattering theory in form and (relative to a standard target) amplitude, and is used to generate a cross-sectional profile of sediment concentration in the discharge plume. Estimates of surge speeds from the acoustic records based on a universal shape for density current heads range from 30 to 120 cm s⁻¹. The excess density of one surge was estimated from the reverberation amplitude to be 0.12 g cm⁻³. The additional attenuation of sound waves by suspended particles is important in turbidity currents and may be used to estimate suspended particulate concentration. Thermal processes contribute very little to the additional attenuation by particles with the grain densities of common minerals. A leveed submarine channel extended from the point of the tailing discharge (outfall) over the surface of the tailing deposit as early as 1974. The upper reach of this system was buried in 1978, and by late 1979 a new channel had developed. In 1976-77, the original channel consisted of: (1) a left-hooking upper reach with an average slope of 2.2°, (2) a middle reach (1° slope) with pronounced meanders (700-1100 m wavelengths) "increasing in curvature with distance downstream and (3) a straight lower reach (0.5° slope). The cross-sectional area of the channel decreased with distance downstream, excepting an increase in the first 100-200 m, until the channel disappeared about 5.5 km from the outfall. Acoustic records of the discharge plume in bends indicate overspill from the outer bank and an upward tilt of the upper interface away from the centre of bend curvature. The interfacial slope is steeper than indicated by the cross-channel difference in levee heights. These records together with observed tidal currents suggest that the left hook in the upper reach is caused by a mechanism similar to that which has been suggested for deep-sea channels. Turbidites in gravity cores from the levees are present as layers of vertically-graded, Cu-rich and Fe-poor sand and silt, some of which have load-casted flame-structures or load-pockets at their basai contacts. These layers comprise more of the sediment column with distance down-channel, suggesting that levee-building by overbank spillage from continuous flow becomes less important, and that most of the material transported through the lower reach is carried by turbidity surges. Surge recurrence intervals of 2-5 d are obtained from the number turbidites per core and the local deposition rate. The latter ranged from 0.3-4 m yr⁻¹, as given by changes in water depth, in tailing thickness from seismic reflection surveys, and in diatom frustule abundance in the cores. A model of continuous turbidity flow in submarine channels including entrainment is applied to the Rupert Inlet channel. Results are consistent with a sediment budget based on changes in the tailing deposit volume, and with turbidity surge recurrence intervals. / Science, Faculty of / Earth, Ocean and Atmospheric Sciences, Department of / Graduate

Le contrôle non destructif (CND) de pièces pour des applications dans l'industrie a mené au besoin de modèles rapides et précises. Tels modèles servent au développement des méthodes d'inspection, à l'optimisation des capteurs utilisés aux essais, à l'évaluation des courbes de Probabilité de Detection (POD) ainsi qu'à la caractérisation de défauts. Cette thèse se focalise au CND par Courants de Foucault (CF) de pièces cylindriques avec des discontinuités selon z et contenant un défaut fin. Un modèle pour l'inspection de telles pièces a été développé afin de traiter des applications comme l'inspection des pièces alésées trouvées en aéronautique et des tubes des générateurs de vapeur utilisés dans l'industrie nucléaire. Ce modèle est basé sur une formulation d'équation intégrale. Plus précisément, la variation de l'impédance du capteur, dit signal CF, est calculée à partir d'une équation intégrale sur la surface du défaut. La formulation suivie est basée sur la méthode d'intégration surfacique (SIM). Cette formulation nécessite, d'un côté, le calcul du champ électrique en absence du défaut et, de l'autre côté, l'expression d'une fonction de Green qui correspond à la géométrie de la pièce sans défaut. Les deux problèmes électromagnétiques sont résolus en utilisant la méthode Truncation Region Eigenfunction Expansion (TREE). La méthode TREE est un outil performant pour la résolution des problèmes électromagnétiques qui prend en compte la décroissance rapide de l'intensité du champ afin de tronquer le domaine d'intérêt à une distance, où le champ est négligeable.Le modèle est validé en comparant le signal CF calculé avec des résultats obtenues par une approche combinant la méthode d'intégration volumique (VIM) et SIM, dite l'approche VIM-SIM (implémentée dans la plateforme CIVA) ainsi qu'avec le modèle d'éléments finis (FEM). Nous avons traité trois configurations différentes : un demi-espace conducteur alésé avec un défaut fin, une plaque conductrice avec un alésage et un défaut, et un tube semi-infini avec un défaut fin à la proximité de son bord. La comparaison des résultats montre un très bon accord entre les trois modèles. Le temps de calcul avec le modèle SIM est considérablement inférieur aux temps de calcul des autres modèles. En outre, le modèle SIM donne la possibilité d'effectuer le balayage du capteur dans le tube ou l'alésage dans le cas des pièces alésées. / Nondestructive Testing (NDT) of parts for industrial applications such as in nuclear and aeronautical industry has led to the need for fast and precise models. Such models are useful for the development of the inspection methods, the optimisation of probes, the evaluation of the Probability of Detection (POD) curves or for the flaw characterisation.This PhD thesis focuses on the eddy-current NDT of layered cylindrical pieces with discontinuities in the z direction and containing a narrow crack. A model for the inspection of such pieces is developed in order to be applied on the inspection of fastener holes met in aeronautics and of steam generator tubes in nuclear sector.The model is based on an integral equation formalism. More precisely, for the calculation of the impedance change one needs to solve an integral equation over the surface of the narrow crack, which is represented by a surface electric dipole distribution. This is the method known as surface integration method (SIM). This formulation requires, on the one hand, the calculation of the electric field in the absence of the flaw, the so-called primary field, and, on the other hand, the Green's function expression corresponding to the geometry of the flawless piece. Both electromagnetic problems are solved by means of the Truncation Region Eigenfunction Expansion (TREE) method. The TREE method is a powerful tool for the solution of electromagnetic problems which uses the rapid decrease of the field in order to truncate the region of interest at a distance where the field is negligible.The model is validated by comparing the results of the coil impedance variation with those obtained by an approach that combines the volume integral method (VIM) with SIM, known as VIM-SIM method, implemented in the commercial software CIVA and the finite element method (FEM) implementation in COMSOL software. Three different configurations have treated. The more general geometry of a conducting half-space with a borehole, a conducting plate with a borehole and a crack and a conducting semi-infinite tube with a crack near the edge. The results of the three models show good agreement between them. The computational time of the SIM model is significantly lower compared to previous models. Furthermore, another advantage of the SIM model is that it provides the possibility of a scan inside the borehole.

TSDC (thermally stimulated depolarization current) is one of the most important and popular technique for investigating electret materials. TSDC technique can indicate the magnitude of polarization and depolarization, relaxation time, charge-storage, glass transition, and activation energy. To fully investigate polarization and relaxation for pure epoxy and filled epoxy materials, a TSDC system was built and verified by the research. The article describes the building processes and verification of the TSDC system. TSDC, TSPC, and TWC tests data for epoxy and filled epoxy samples are presented in the article. To compare TSDC technique with other related techniques, DEA (dielectric analysis), DMA (dynamic mechanical analysis), and DSC (differential scanning calorimetry) tests are introduced.

Patch-clamp recordings in whole-cell configuration were made from ventrolateral medulla neurons of brainstem slices from 8-12-day-old rats. 5- Hydroxytryptamine (3-30 μM) concentration-dependently suppressed excitatory and inhibitory postsynaptic currents evoked by focal stimulation. An augmentation of inhibitory synaptic currents by 5-hydroxytryptamine was noted in a small number of neurons. 5-Hydroxytryptamine depressed synaptic currents with or without causing a significant change in holding currents and membrane conductances; the inward or outward currents induced by exogenously applied glutamate or GABA/glycine were also not significantly changed by 5- hydroxytryptamine. In paired-pulse paradigms designed to evaluate a presynaptic site of action, 5-hydroxytryptamine suppressed synaptic currents but enhanced the paired-pulse facilitation. 5-Hydroxytryptamine reduced the frequency of miniature excitatory postsynaptic currents without significantly affecting the amplitude. 5-Carboxamidotryptamine, 8-hydroxy-2(di-n- propylamino)tetralin, sumatriptan and N-(3-trifluoromethylphenyl)piperazine which exhibit 5-hydroxytryptamine1 receptor agonist activity, depressed synaptic currents with different potencies, with 5-carboxamidotryptamine being the most potent. The non-selective 5-hydroxytryptamine1 receptor antagonist pindolol attenuated the presynaptic effect of 5-hydroxytryptamine, whereas the 5-hydroxytryptamine(1A) antagonist pindobind-5- hydroxytryptamine(1A) and 5-hydroxytryptamine2 receptor antagonist ketanserin were ineffective. Our results indicate that 5-hydroxytryptamine suppressed synaptic transmission in ventrolateral medulla neurons by activating presynaptic 5-hydroxytryptamine1 receptors, probably the 5- hydroxytryptamine(1B)/5-hydroxytryptamine(1D) subtype. In addition, 5- hydroxytryptamine augmented inhibitory synaptic currents in a small number of neurons the site and mechanism of this potentiating action are not known.

Numerous studies have identified the west coast of Canada as an attractive place for the development of wave energy projects. To evaluate the viability of these projects, an accurate description of the wave resource is crucial. Most of the previous efforts to characterize the wave climate in B.C. at shallower waters, where wave energy converters (WECs) are most likely to be deployed, lack the necessary nearshore spatial resolution, and were driven by overly simplistic wave boundary conditions. In addition, none of the previous studies have included the effect of tidal currents, which have been proven to be significant in wave resource characterizations in other locations. This work increased the fidelity of the wave resource characterization and developed an understanding of the impact of tidal currents on the wave conditions in this region by generating two most accurate, long-term (14 years, 2004 to 2017), high resolution (in space and time) datasets of the wave resource for the west coast of Canada. The two datasets were generated using nearly identical SWAN wave models, which their only difference was that one of them (V5), did not incorporate the effect of currents, while the other (V6) included tidal currents as forcing. Thus, the pure influence of the tidal currents on the wave characteristics was able to be identified when comparing the two wave model results. This study developed simple, robust, and objective metrics to support the calibration process and to evaluate the performance of the models. Utilizing these metrics, the V5 and V6 models presented substantial improvements in reproducing the wave conditions of about 18% and 20%, respectively and in relation to the previous most complete and accurate wave model of the region (V4). Their better performance was largely achieved by a significant increment in their ability to reproduce the significant wave height (H_m0) and energy period (T_e). The inclusion of tidal currents in the wave model increased the accuracy of the wave resource characterization, mainly by improving the model’s ability in simulating T_e by 5.1%. The most sensitive wave parameter to the tidal currents was the peakedness of the wave spectrum (Q_p), which was consistently and significantly reduced by values even larger than 2.5. In some regions, directions characterized by the mean wave direction (D_m) and the directional spreading (D_spr) were also noticeably very sensitive to the currents, which even deflected D_m to its opposite direction and drove changes in D_spr that reached values of up to 40°. However, these significant transformations were less frequent and reduced in magnitude at exposed (to swell-waves) sites, where strong currents have affected waves in a reduced part of their trajectory. Typically, tidal currents had the effect of reducing the wave power density (P), but in a relatively small amount, however, during rare events, tidal currents were able to induce changes in this parameter ranging -140 kW/m to 75 kW/m. At these extreme events, it was observed that the peak of the wave spectra became flatter, with some of its wave height variance redistributed to near increasing and decreasing frequencies and directions, regardless to the magnitude and direction of the local tidal currents. Impacts of the tidal currents on P were largely attributed to the induced changes in H_m0 and T_e. Although D_spr and Q_p were greatly transformed by the action the tidal currents, they account very little in explaining the variations in P. These four wave parameters together, and how they are transformed under the presence of currents, can explain a large part of the changes in P, however, other transformations of the wave spectrum due to the currents, not investigated in this study, must account for a considerable part of the changes in P. / Graduate

Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Meteorology, 1980. / Microfiche copy available in Archives and Science. / Bibliography: leaves 85-88. / by Donald Albert Campbell. / M.S.

Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Civil Engineering, 1981. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND ENGINEERING. / Bibliography: leaves 91-92. / by François-Marc Turpin. / M.S.