During operation of the solid polymer fuel cell (SPFC). its performance is limited by the concentrations of hydrogen and oxygen at the reaction interfaces and in most SPFC designs, the hydration state of the membrane. Since in general, the concentrations of water and the gaseous species vary along the flow channel, the performance is also likely to change along the flow channel. In order to study this phenomenon, a measurement system was developed to map the current distribution across the electrode surface. The current distribution has been measured by dividing one of the current collectors into a number of electrically isolated segments. The current flowing through each of the segments was measured while maintaining a constant potential across the surface of the gas diffusion layer. Two separate segmented current collectors were developed. The first was used to measure the current distribution for an 80 cm2 single cell, and the second was used to investigate the local current densities around a single flow channel. The effects of the feed gas humidities on the spatial current density in the 80 cm2 fuel cell were investigated for two different membrane-electrode configurations. With Nafion 117 as electrolyte and at a cell temperature of 80°C. the membrane was found to dehydrate in the initial portion of the gas flow channel when the relative humidity of both the hydrogen and oxygen feed gases was less than 50%. With a Gore-Select membrane electrode assembly (hydrogen and air. temperature- 60°C). the membrane was sufficiently hydrated at all feed gas humidification conditions. The performance of the cell was found to deteriorate at higher feed gas humidities as a result of the lower partial pressures of the reactant gases. Measurements of the effects of gas pressures, stoichiometries and humidities on the length-wise and width-wise perfonnance around a single flow channel (Gore-Select membrane electrode assembly) are discussed in relation to a gas flow model.

Two direct consolidation methods usually used for advanced ceramics have been combined in this project in order to develop a novel fabrication route for traditional ceramics. Specifically the method used is based on the Additive Manufacturing extrusion process using direct writing of high solid loading ceramic pastes and then freeze-casting to solidify the deposited material. This novel fabrication method, for which a patent has been granted, has been christened “Direct Writing Freeze-Casting” (DWFC). Although the DWFC process is the subject of investigation by other researchers for a range of different applications, including the production of medical implants with alumina, the research presented in this thesis focuses on its use in the manufacture of white wares, giftware, and applied arts and crafts in general. This new system will provide designers, potters, artists, craft makers and manufacturers with a flexible and automated way of manufacturing porcelain objects. One of the major challenges to be overcome to exploit the DWFC process is the development of suitable slurry material formulations. Initial trials demonstrated that it is not possible to use conventional clay based porcelain materials with a platelet shaped microstructure which inhibits freeze casting. In this thesis the development and characterisation of non plastic porcelain slurry, based on substitution of kaolin (clay) with a calcined clay material (molochite), which can be processed using this new method is presented. The new non plastic porcelain formulation, which has a high solid load of 75.47% wt., has been subjected to detailed analysis to assess its suitability at each stage of the process; extrusion, freeze-casting (solidification) and firing.

International Telemetering Conference Proceedings / October 26-29, 1992 / Town and Country Hotel and Convention Center, San Diego, California / The Space Ground Link Subsystem (SGLS) provides full duplex communications for commanding, tracking, telemetry and ranging between spacecraft and ground stations. The up-link command signal is an S-Band carrier phase modulated with the frequency shift keyed (FSK) command data. The command data format is a ternary (S, 1, 0) signal. Command data rates of 1, 2, and 10 Kbps are used. The method presented uses direct digital synthesis (DDS) to generate the SGLS command data and clock signals. The ternary command data and clock signals are input to the encoder, and an FSK subcarrier with an amplitude modulated clock is digitally generated. The command data rate determines the frequencies of the S, 1, 0 tones. DDS ensures that phase continuity will be maintained, and frequency stability will be determined by the microprocessor crystal accuracy. Frequency resolution can be maintained to within a few Hz from DC to over 2 MHZ. This allows for the generation of the 1 and 2 Kbps command data formats as well as the newer 10 Kbps format. Additional formats could be accommodated through software modifications. The use of digital technology provides for encoder self-testing and more comprehensive error reporting.

Master of Science / Department of Diagnostic Medicine/Pathobiology / Sanjeev K. Narayanan / The use of antimicrobials in animal feed has come under increasing scrutiny from the public and regulatory agencies. Direct-fed microbials (DFM) are considered valuable alternatives to antimicrobials in food animal nutrition. DFM are products containing live (viable microorganisms). Studies in Europe have reported antimicrobial resistance (AMR) in organisms used in DFM. This is of serious concern because of the potential for transferring resistance to pathogenic bacteria in the gut. The aim of the present study is to characterize phenotypic and genotypic AMR profiles for 20 different antimicrobials in bacterial strains isolated from 10 commercially available DFM used in. Two antimicrobial susceptibility testing methods, disc diffusion and broth micro-dilution based assay were performed. Enterococcus faecium isolates showed resistance towards metronidazole (n=9/9) with a MIC of > 32 µg/mL, erythromycin (n=5/9) with a MIC of ≥ 8 µg/mL, ciprofloxacin (n=2/9) with a MIC ≥ 4 μg/mL, ceftriaxone (n=6/9) with a MIC ≥ 0.25 μg/mL, rifampin (n=8/9) with a MIC of > 4 µg/mL, trimethoprim/sulfamethoxazole (n=4/9) with a MIC ≥ 1 μg/mL and clindamycin (n=5/9) with a MIC of > 0.5 µg/mL. A Propionibacterium freudenreichii isolate showed resistance towards kanamycin with a MIC of > 64 µg/mL. The same strain also had a MIC of 16 µg/mL for levofloxacin. Two Lactobacillus acidophilus were resistant to vancomycin (n=2/6) with a MIC ≥ 32 μg/mL. All the Lactobacillus species including L. acidophilus (n=6), L. casei (n=4) and L. plantarum (n=2) were resistant to metronidazole, MIC > 32 µg/mL. Two strains of Bacillus subtilis showed resistance to clindamycin, with an MIC of 4 µg/mL and erythromycin with an MIC of > 8 µg/mL, and one strain had no zone of inhibition for metronidazole (MIC > 32 µg/mL). Microarray analysis revealed resistance genes in E. faecium strains of 3 different DFM, including aminoglycoside resistance genes, ant(4’)-Ia, erythromycin resistance genes, ere(A2) and ermB, tetracycline resistance genes, tet39, tet31, tetK and tetC, and beta-lactam resistance gene, pbp5. Conjugation with filter mating showed erythromycin resistance gene transfer, msrC gene, from donor strains to a recipient strain (E. faecium 45-24). These studies show that AMR is prevalent among bacterial strains used as DFM in the cattle industry in the U.S., justifying further characterization, detection and observation of transferable antibiotic resistance between the same genus.

Since only little is known in the field of Solid Oxide Fuel Cell (SOFC) operation about internal reforming of methane at present, the aim of this thesis study is to conduct a detailed investigation delivering the basis for further experimental and theoretical work. Also information is required if the concept of internal reforming has technical development potential. The thesis is arranged into two major parts being a thermodynamic investigation and an application of a suitable kinetic model. Pure methane tends to decompose at the high operation temperatures of the SOFC (about 950°C) thus forming solid carbon. Therefore it is necessary to include a fuel preparation process delivering H2 and CO that can be utilized by the SOFC. The fuel processing can either be carried out by steam reforming or partial oxidation. It is shown by a thermodynamic investigation that fuel processing by partial oxidation yields a fuel gas of inferior quality than fuel processing by steam reforming. The kinetic part contains the application of a model describing the chemical and electrochemical conversion occuring in the SOFC as detailed as possible at present. This model is used to investigate the thermal behaviour of an SOFC process referring to technical operation parameters. It is shown that internal reforming has technical development potential although a lot of care must be paid to the heat management. Particular operation conditions might exist where the highly endothermic steam reforming process could cause a breakdown of the complete fuel cell process due to its enormous local cooling effect.

This thesis describes four novel superconducting machine concepts, in the pursuit of finding a suitable design for large offshore wind turbines. The designs should be reliable, modular and light-weight. The main novelty of the topologies reside in using a single loop shaped stationary superconducting field winding, which eliminates the rotating transfer couplers and electric brushes or brushless exciters. Furthermore, the electromagnetic forces in the superconducting wire are also eliminated, which simplifies the design and manufacturing of the cryostat and the support structure. Among the four topologies presented, the claw pole type machine is the most promising one. The rotor of the machine composes of claw-poles made from laminated electrical sheets, the superconducting field winding and the armature winding are stationary. The machine is analysed using 3D FEA simulations and a small linear machine prototype is manufactured to verify the simulations. For large scale applications, a double-sided claw pole machine is proposed, which has balanced magnetic attraction forces in the rotor. The machine has a modular cryostat structure, which increases the availability of the machine. Thus, even if a fault occurs in the cryocoolers or in the armature coils, the rest of the machine can operate at partial load until the maintenance is performed. Moreover, it is much easier to replace the faulty parts, as full disassemble of the machine is not required, and a small on-site crane can be used. As a result, it offers operational advantages over the existing superconducting topologies. A 10 MW, 10 rpm generator design is presented, which has a diameter of 6.6 m and an axial length of 1.4 m. The total active mass of the generator is 58 tonnes, and the structural mass is 126 tonnes, which gives a total mass of 184 tonnes. There are four independent cryostats and two independent armature windings in the machine to improve modularity. The biggest advantage of the design is the significantly less superconducting wire usage compared to any other designs; 10 MW machine just needs 15 km of MgB2 wire at 30 K. Thus, it is believed that the proposed topology is a very cost effective and suitable candidate for a successful entry to the wind turbine market.

Floating wind turbines (FWTs) are considered a new lease of opportunity for sustaining growth from offshore wind energy. In recent years, several new concepts have emerged, with only a few making it to demonstration or pre-commercialisation stages. Amongst these, the spar-buoy based FWT has been extensively researched concept with efforts to optimise the dynamic response and reduce the costs at acceptable levels of performance. Yet, there exist notable lapses in understanding of these systems due to lack of established design standards, operational experience, inaccurate modelling and inconsistent reporting that hamper the design process. Previous studies on spar-buoy FWTs have shown inconsistencies in reporting hydrodynamic response and adopted simplified mooring line models that have failed to capture the coupled hydrodynamic behaviour accurately. At the same time, published information on drive-trains for FWTs is scarce and limited to geared systems that suffer from reliability issues. This research was aimed at filling the knowledge gaps with regard to hydrodynamic modelling and drive-train research for the spar-buoy FWT. The research proceeds in three parts, beginning with numerical modelling and experimental testing of a stepped spar-buoy FWT. A 1:100 scale model was constructed and tested in the University of Edinburgh’s curved wave tank for various regular and irregular sea states. The motion responses were recorded at its centre of mass and nacelle locations. The same motions were also simulated numerically using finite element method based software, OrcaFlex for identical wave conditions. The hydrodynamic responses were evaluated as Response Amplitude Operator (RAO) and compared with numerical simulations. The results showed very good agreement and the numerical model was found to better capture the non-linearities from mooring lines. A new design parameter, Nacelle Magnification Factor, was introduced to quantify coupled behaviour of the system. This could potentially encourage a new design approach to optimising floating wind turbine systems for a given hub height. The second part of the research was initiated by identification of special design considerations for drive-trains to be successfully integrated into FWTs. A comparative assessment of current state of the art showed good potential for directdrive permanent magnet synchronous generators (PMSG). A radial flux topology of the direct-drive PMSG was further examined to verify its suitability to FWT. The generator design was qualified based on its structural integrity and ability to ensure minimal overall impact. The results showed that limiting the generator weight without compromising air-gap tolerances or tower-foundation upgrades was the biggest challenge. Further research was required to verify the dynamic response and component loading to be at an acceptable level. The concluding part of research investigated the dynamic behaviour of the directdrive generator and the various processes that controlled its performance in a FWT. For this purpose, a fully coupled aero-hydro-servo-elastic model of direct-drive FWT was developed. This exercise yet again highlighted the weight challenge imposed by the direct-drive system entailing extra investment on structure. The drive-train dynamics were analysed using a linear combination of multi-body simulation tools namely HAWC2 and SIMPACK. Shaft misalignment, its effect on unbalanced magnetic pull and the main bearing loads were examined. The responses were found to be within acceptable limits and the FWT system does not appreciably alter the dynamics of a direct-drive generator. Any extra investment on the structure is expected to be outweighed by the superior performance and reliability with the direct-drive generator. In summary, this research proposes new solutions to increase the general understanding of hydrodynamics of FWTs and encourages the implementation of direct-drive generators for FWTs. It is believed that the solutions proposed through this research can potentially help address the design challenges of FWTs.

International Telemetering Conference Proceedings / October 17-20, 1988 / Riviera Hotel, Las Vegas, Nevada / This paper describes the design, test and the analysis of the test results of a new type S-band FM telemetry transmitter. Compared with the modulator adopting conventional fundamental crystal direct modulation, the transmitter which adopts UHF fundamental crystal direct modulation has a comparatively better modulation characteristics and a higher center frequency stability. The test results show that the deviation sensitivity of the transmitter is up to 400KHz/Vrms, frequency response is DC~200 KHz, total harmonic distortion is 3% and the center frequency stability is ten to the minus fifth power within the range of - 30~+70°c. Because of the high operating frequency of the modulator, the complicacy of the frequency multiplier has been requced, design of circuitry simplified and harmonic and spurious outputs has been improved to a great extent.

The aim of this study is to explain the effect of arousal on consumer’s attitude towards a direct service in terms of evaluation extremity. An important element within consumer behavior is the attitude that consumers have towards products and services. After the conceptual framework was developed through an extensive literature review on arousal, attitude and services, a hypothesis was formulated stating that: Arousal has an effect on consumer's attitude towards a direct service in terms of their evaluation extremity.  An experiment was carried out within various lectures of a university in Sweden, whereas the sampling used was a convenience sample of university students. The total amount of respondents who participated in the experiment were 154, whereof 102 were valid respondents. The experimenttriggerused to influence their level of arousal was caffeinated coffee, while the control trigger was decaffeinated coffee. The Fishbein model was used to measure attitude translated into a questionnaire which was administered at the experiment, while the three adjective scale was utilized to measure the level of arousal for control. The collected data was imported into the statistics program SPSS for analysis and discussion. Quality criteria and ethics standards were adhered to  during the entire research process. At the conclusion of the research, the hypothesis was accepted. However, it should be taken into consideration that the caffeine did not have the desired effect on the level of arousal, and the study mainly used the control questions for arousal to find a significance level. The study was deemed successful though, in that after calculating positive pretests for validity, the results showed that the aroused participants had a significantly more extreme attitude than the non-aroused participants. In that the experiment and results are original, it allows for further related research. Finally, to insure the validity of the results of this study, it is pertinent that the experiment’s results are replicated by future studies.

The temperature distribution in the vicinity of the laser used in direct metal deposition (DMD) plays a critical role in determining the final microstructure and properties of the deposit and the heat-affected zone within the substrate. A system of deposition samples were studied consisting of AISI 1018 steel powder deposited onto an AISI 1018 steel substrate as a single pass or as overwritten multiple passes. The laser power and speed were varied to influence the heat input and the rate of cooling. The use of idealized one dimensional lines allowed for the solution of a quasi-steady state analytical temperature distribution. Numerical predictions were made using the commercial software SysWeld™ for single pass depositions. Peak temperatures and cooling rates were determined at selected locations experimentally using micro-hardness measurements which were supplemented by obtaining thermocouple data taken during deposition. The analytical model, numerical predictions, and experimental results are compared for single pass depositions to determine the extent to which existing commercial codes can accurately model the thermal environment for DMD. / text