Student Number : 9707408V - MSc(Eng) research report - School of Mechanical, Industrial and Aeronautical Engineering - Faculty of Engineering and the Built Environment / This research is an investigation into the performance and combustion characteristics of a two-cylinder, four-stroke compression ignition engine fuelled on diesel and then on dimethyl ether (DME). Baseline tests were performed using diesel. The tests were then repeated for dimethyl ether fuelling. All DME tests were performed at an injection opening pressure of 210 bar, as recommended for diesel fuelling. The tests were all carried out at constant torque with incremental increases in speed and an improved method of measuring the DME flow rate was devised. It was found that the engine’s performance characteristics were very similar, regardless of whether the engine was fuelled on diesel or DME. Brake power, indicated power and cylinder pressure, during the highest loading condition of 55 Nm, were virtually identical for diesel and DME fuelling, with the most significant finding being that the engine was more efficient when fuelled on DME than when fuelled with diesel. Another interesting finding was that the energy release of diesel decreases with increasing load, whilst the energy release of DME increases with increasing load. At the highest loading condition of 55 Nm, the energy release of DME was approximately 210 joules higher than that of diesel. This investigation concluded that DME may definitely be a suitable substitute fuel for diesel.

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This dissertation develops a systematic targeting method based on the C-H-O ternary diagram for the conceptual design of gasification-based biorefineries. The approach is applied using dimethyl ether (DME) as case study. A stoichiometric equilibrium model is presented for calculation of the C-H-O chemical equilibria to evaluate and predict equilibrium syngas composition, operating temperature, type and amount of oxidant required in biomass gasification. Overall atomic species balances are developed and process targets are plotted on the C-H-O ternary diagram. Sustainability metrics are incorporated to provide useful insights into the efficiency of biorefinery process targets. It was found that syngas at 1200 and 1500 K is predominantly H2 and CO. Moreover, DME biorefineries have two main process targets, based on the indirect and direct synthesis routes. Gasification at 1200 K and 1 atm. using H2O/CO2 = 2.642 (w/w) and H2O/CH4 = 1.645 (w/w) achieved syngas composition targets for the direct and indirect methods respectively. Comparatively, the integrated biorefinery based on indirect route was more efficient, producing 1.903 ton of DME per ton of biomass feedstock. The process is 100% carbon-efficient and recycles 1.025 tons of H2O. / Civil and Chemical Engineering / M. Tech. (Chemical Engineering)

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