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A stereodynamical study of the H+Nâ†2O reactionGatenby, Simon David January 1999 (has links)
No description available.
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IMPLANTACAO DE UM SISTEMA DE DIAGNOSTICOS POR ESPECTROSCOPIA E MEDIDA DE TEMPERATURA IONICA NO TBR-1 / Implementation of a diagnostic system for ion spectroscopy and temperature measure at TBR - IChamaa Neto, Ibrahim El 10 April 1992 (has links)
Um sistema de diagnóstico por espectroscopia no visível foi implantado no tokamak TBR-I. O diagnóstico consiste de um espectrógrafo (do tipo Czerny-Turner), um sistema de acoplamento óptico e um detetor multicanal (MCP). O diagnóstico foi usado para observar e identificar impurezas presentes no plasma do TBR-I. As principais impurezas observadas foram oxigênio (O-II) e nitrogênio (N-II). Foi feito um estudo no alargamento das linhas do hidrogênio e dos íons para se obter a temperatura a partir do efeito Doppler. As intensidades das linhas espectrais foram observadas de descarga em descarga. / A visible spectroscopic diagnostic was implemented on TBR-I tokamak. The diagnostic system consist of a 1,5 m spectrograph (Czerny-Turner type), an optical coupling system and a microchannel plate (MCP) detector. The diagnostic system was used to examine and document the impurity content of the plasma in TBR-I. The main impurities discovered were oxygen (O-II) and nitrogen (N-II). Line broadening experiments were performed on hydrogen and ions to obtain the temperatures using Doppler broadening effects. The intensities of the spectral lines were measured on a shot to shot basis.
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Visible spectroscopic diagnostics : application and development in fusion plasmasMenmuir, Sheena January 2007 (has links)
Diagnostic measurements play a vital role in experiments. Without them we would be in the dark with no way of knowing what was happening; of understanding the processes and behaviour occurring; or even of judging the success or failure of our experiments. The development of fusion plasma devices is no different. In this thesis we concentrate on visible spectroscopy based diagnostics: examining the techniques for measurement and analysis; the breadth of plasma parameters that can be extracted from the spectroscopic data; and how the application of these diagnostic techniques gives us a broader picture of the plasma and the events taking place within. Techniques are developed and applied to plasmas in three fusion experiments, EXTRAP T2R, ASDEX Upgrade and JET. The diagnostic techniques exploit different features of the measurements of the emitted photons to obtain various useful plasma parameters. Determination of the ion temperature and rotation velocity of oxygen impurity ions in the EXTRAP T2R plasma is achieved through measurement and analysis of, respectively, the Doppler broadening and the Doppler wavelength shift of visible wavelength atomic spectral lines. The evolution of the temperature and rotation is studied as a function of the discharge parameters, in particular looking at the effect of applying active feedback control schemes to the resistive wall modes and/or pulsed poloidal current drive. Measurements of multiple ionisation stages are used to estimate radial profiles of the toroidal rotation and the ion temperature and correlations between the ion rotations and the rotation velocities of tearing modes are also established. Radial profiles of the emissivity and density (or concentration) of the oxygen ions are obtained by means of measurements of the spectral line intensities on a small array of linesof- sight through the plasma. Changes to the profiles for different plasma schemes and the implications for particle transport are investigated. The derived emissivity profiles are used in the analysis for some of the other spectroscopic diagnostics. Spectral line intensity measurements (in this case of neutral ions) are also the basis for calculations of both the electron temperature and the particle fluxes at the plasma edge. The latter is an indicator of the degree and type of interaction between the plasma and the surrounding surfaces. Particle fluxes of the operating gas hydrogen and of chromium and molybdenum impurities are investigated in EXTRAP T2R for different operating scenarios, in particular changes in the metallic influx with the application of active feedback mode control are examined along with the correspondence between spectroscopic and collector probe results. In the ASDEX Upgrade divertor estimates of the particle flux of the deuterium operating gas are also made through analysis of spectral intensities. Molecular D2 band structure is explored in addition to the Balmer Dα spectral line intensity to acquire both atomic and molecular particle fluxes, investigate the contribution of the dissociating D2 to the Dα line and study the effect of changes in the divertor. Analysis of the D2 molecular band structure (the relative intensities of the rotational lines and vibrational bands) also enables calculation of the upper state rotational and ground state vibrational temperatures. The locations of emitting atomic ions in JET are estimated from Zeeman splitting analysis of the structure of their spectral lines. The measurement and analysis of visible wavelength light is demonstrated to be a sensitive diagnostic tool in the quest for increased knowledge about fusion plasmas and their operating scenarios. / QC 20100810
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IMPLANTACAO DE UM SISTEMA DE DIAGNOSTICOS POR ESPECTROSCOPIA E MEDIDA DE TEMPERATURA IONICA NO TBR-1 / Implementation of a diagnostic system for ion spectroscopy and temperature measure at TBR - IIbrahim El Chamaa Neto 10 April 1992 (has links)
Um sistema de diagnóstico por espectroscopia no visível foi implantado no tokamak TBR-I. O diagnóstico consiste de um espectrógrafo (do tipo Czerny-Turner), um sistema de acoplamento óptico e um detetor multicanal (MCP). O diagnóstico foi usado para observar e identificar impurezas presentes no plasma do TBR-I. As principais impurezas observadas foram oxigênio (O-II) e nitrogênio (N-II). Foi feito um estudo no alargamento das linhas do hidrogênio e dos íons para se obter a temperatura a partir do efeito Doppler. As intensidades das linhas espectrais foram observadas de descarga em descarga. / A visible spectroscopic diagnostic was implemented on TBR-I tokamak. The diagnostic system consist of a 1,5 m spectrograph (Czerny-Turner type), an optical coupling system and a microchannel plate (MCP) detector. The diagnostic system was used to examine and document the impurity content of the plasma in TBR-I. The main impurities discovered were oxygen (O-II) and nitrogen (N-II). Line broadening experiments were performed on hydrogen and ions to obtain the temperatures using Doppler broadening effects. The intensities of the spectral lines were measured on a shot to shot basis.
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Estudo da distribuição de momento de elétrons ligados por correlação ângulo-energia da radiação de aniquilação elétron-pósitron / Study of the momentum distribution of bound electrons by angle-energy correlation of electro-positron annihilation radiationMariano, Leandro 04 November 2010 (has links)
Neste trabalho foi medido o alargamento Doppler de uma aniquilação elétron pósitron com o uso de um filtro angular. O Filtro angular reduz, substancialmente, a detecção de fótons provenientes de aniquilações de elétrons com baixo momento, enfatizando, desta forma, a contribuição de aniquilações com elétrons fortemente ligados. Foram medidos os espectros de coincidência para os ângulos de corte de 0,28°, 0,42° e 1.2°. Os resultados obtidos mostram que, conforme se aumenta o ângulo de corte, há uma redução das aniquilações com elétrons de valência em proporção muito maior do que para elétrons fortemente ligados. Foi determinada a transmissibilidade do filtro em função do ângulo entre as direções de emissão dos gamas, levando em conta todos os elementos do arranjo experimental para cada ângulo crítico, assim como a distribuição espacial da atividade da fonte radioativa. Um modelo simples foi utilizado para estimar teoricamente a dependência da dispersão da energia em função do ângulo de corte. Este modelo permitiu calcular o alargamento Doppler da radiação de aniquilação elétron pósitron. Os resultados obtidos mostram um bom acordo com os dados experimentais. Geralmente, estudos de aniquilação de pósitrons com elétrons fortemente ligados dependem de uma modelagem detalhada do espectro de coincidência, ou da medida dos fótons provenientes da aniquilação em coincidência com elétrons Auger. O filtro angular, desenvolvido neste trabalho se coloca como uma boa alternativa a estes métodos. / This work reports the measurement of the Doppler broadening of the electron-positron annihilation radiation using an angular filter. The angular filter substantially reduces the number of detected gamma-rays from positron annihilation with low momentum electrons, therefore emphasizing the contribution of bound electron. Four coincidence measurements of the emitted gamma-rays were done with arrangements corresponding to critical angles of 0.28°, 0.42°, 1.2°. The obtained results show that the relative intensity of annihilation with valence electrons decreases as the critical angle increases. The filter transmissibility as a function of the angle between the two gamma-rays emission directions was determined taking into account all the elements of the experimental arrangement for every critical angle as well as the spatial distribution of the source activity. A simple model was used to theoretically estimate the dependence of the energy dispersion on the critical angle. The model allows us to calculate the Doppler broadening of the electron-positron annihilation radiation, and the obtained results show good agreement with the experimental data. Usually, the study of positrons annihilation with inner electrons requires good detectors\' energy resolution and depends on either sophisticated modeling and statistical analysis of the coincidence spectra or the measurement of the annihilation gamma-rays in coincidence with Auger electrons. The use of the angular filter developed in this work is a good alternative to those procedures.
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Spontaneous and stimulated X-ray Raman scatteringSun, Yu-Ping January 2011 (has links)
The present thesis is devoted to theoretical studies of resonant X-ray scattering and propagation of strong X-ray pulses. In the first part of the thesis the nuclear dynamics of different molecules is studied using resonant X-ray Raman and resonant Auger scattering techniques. We show that the shortening of the scattering duration by the detuning results in a purification of the Raman spectra from overtones and soft vibrational modes. The simulations are in a good agreement with measurements, performed at the MAX-II and the Swiss Light Source with vibrational resolution. We explain why the scattering to the ground state nicely displays the vibrational structure of liquid acetone in contrast to excited final state. Theory of resonant X-ray scattering by liquids is developed. We show that, contrary to aqueous acetone, the environmental broadening in pure liquid acetone is twice smaller than the broadening by soft vibrational modes significantly populated at room temperature. Similar to acetone, the "elastic" band of X-ray Raman spectra of molecular oxygen is strongly affected by the Thomson scattering. The Raman spectrum demonstrates spatial quantum beats caused by two interfering wave packets with different momenta as the oxygen atoms separate. It is found that the vibrational scattering anisotropy caused by the interference of the "inelastic" Thomson and resonant scattering channels in O2. A new spin selection rule is established in inelastic X-ray Raman spectra of O2. It is shown that the breakdown of the symmetry selection rule based on the parity of the core hole, as the core hole and excited electron swap parity. Multimode calculations explain the two thresholds of formation of the resonant Auger spectra of the ethene molecule by the double-edge structure of absorption spectrum caused by the out-of- and in-plane modes. We predict the rotational Doppler effect and related broadening of X-ray photoelectron and resonant Auger spectra, which has the same magnitude as its counterpart-the translational Doppler effect. The second part of the thesis explores the interaction of the medium with strong X-ray free-electron laser (XFEL) fields. We perform simulations of nonlinear propagation of femtosecond XFEL pulses in atomic vapors by solving coupled Maxwell's and density matrix equations. We show that self-seeded stimulated X-ray Raman scattering strongly influences the temporal and spectral structure of the XFEL pulse. The generation of Stokes and four-wave mixing fields starts from the seed field created during pulse propagation due to the formation of extensive ringing pattern with long spectral tail. We demonstrate a compression into the attosecond region and a slowdown of the XFEL pulse up to two orders of magnitude. In the course of pulse propagation, the Auger yield is strongly suppressed due to the competitive channel of stimulated emission. We predict a strong X-ray fluorescence from the two-core-hole states of Ne created in the course of the two-photon X-ray absorption. / QC 20110426
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Estudo da distribuição de momento de elétrons ligados por correlação ângulo-energia da radiação de aniquilação elétron-pósitron / Study of the momentum distribution of bound electrons by angle-energy correlation of electro-positron annihilation radiationLeandro Mariano 04 November 2010 (has links)
Neste trabalho foi medido o alargamento Doppler de uma aniquilação elétron pósitron com o uso de um filtro angular. O Filtro angular reduz, substancialmente, a detecção de fótons provenientes de aniquilações de elétrons com baixo momento, enfatizando, desta forma, a contribuição de aniquilações com elétrons fortemente ligados. Foram medidos os espectros de coincidência para os ângulos de corte de 0,28°, 0,42° e 1.2°. Os resultados obtidos mostram que, conforme se aumenta o ângulo de corte, há uma redução das aniquilações com elétrons de valência em proporção muito maior do que para elétrons fortemente ligados. Foi determinada a transmissibilidade do filtro em função do ângulo entre as direções de emissão dos gamas, levando em conta todos os elementos do arranjo experimental para cada ângulo crítico, assim como a distribuição espacial da atividade da fonte radioativa. Um modelo simples foi utilizado para estimar teoricamente a dependência da dispersão da energia em função do ângulo de corte. Este modelo permitiu calcular o alargamento Doppler da radiação de aniquilação elétron pósitron. Os resultados obtidos mostram um bom acordo com os dados experimentais. Geralmente, estudos de aniquilação de pósitrons com elétrons fortemente ligados dependem de uma modelagem detalhada do espectro de coincidência, ou da medida dos fótons provenientes da aniquilação em coincidência com elétrons Auger. O filtro angular, desenvolvido neste trabalho se coloca como uma boa alternativa a estes métodos. / This work reports the measurement of the Doppler broadening of the electron-positron annihilation radiation using an angular filter. The angular filter substantially reduces the number of detected gamma-rays from positron annihilation with low momentum electrons, therefore emphasizing the contribution of bound electron. Four coincidence measurements of the emitted gamma-rays were done with arrangements corresponding to critical angles of 0.28°, 0.42°, 1.2°. The obtained results show that the relative intensity of annihilation with valence electrons decreases as the critical angle increases. The filter transmissibility as a function of the angle between the two gamma-rays emission directions was determined taking into account all the elements of the experimental arrangement for every critical angle as well as the spatial distribution of the source activity. A simple model was used to theoretically estimate the dependence of the energy dispersion on the critical angle. The model allows us to calculate the Doppler broadening of the electron-positron annihilation radiation, and the obtained results show good agreement with the experimental data. Usually, the study of positrons annihilation with inner electrons requires good detectors\' energy resolution and depends on either sophisticated modeling and statistical analysis of the coincidence spectra or the measurement of the annihilation gamma-rays in coincidence with Auger electrons. The use of the angular filter developed in this work is a good alternative to those procedures.
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Spectroscopy study of hydrogen particle reflection at helium-induced fuzzy tungsten surface / ヘリウム誘起微細構造化タングステン表面での水素粒子反射の分光法による研究 / ヘリウム ユウキ ビサイ コウゾウカ タングステン ヒョウメン デノ スイソ リュウシ ハンシャ ノ ブンコウホウ ニヨル ケンキュウ土居 謙太, Kenta Doi 22 March 2018 (has links)
本研究では、低粒子エネルギー領域における金属表面からの反射水素原子を水素原子バルマーアルファ(Hα)発光ドップラー分光計測によって検出する実験系を構築し、ヘリウムによるタングステン表面の微細構造化が水素粒子反射特性に与える影響を調査した。表面構造を持たないタングステンと比較して、Fuzz構造をもつタングステン試料では200 - 300 eVの入射粒子エネルギー領域にて粒子反射係数が1/2程度まで減少することが明らかになった。 / In this study, the author developed a measurement technique to detect hydrogen atoms reflected from a metal surface based upon the Doppler-spectroscopy of hydrogen Balmer-(Hα) emission. The developed measurement technique is a promising method to investigate the hydrogen particle reflection properties in low incident particle energy range, which has been considered difficult. The author applied the developed method into practice to clarify the effects of helium (He) induced tungsten (W) surface nanostructure upon the low energy hydrogen particle reflection. A W-fuzz sample was found to reduce the particle reflection coefficient by 1/2 of the flat reference W surface in low incident particle energy range of 200-300 eV. / 博士(工学) / Doctor of Philosophy in Engineering / 同志社大学 / Doshisha University
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Ultracold Neutral Plasma Evolution in an External Magnetic FieldPak, Chanhyun 26 June 2023 (has links) (PDF)
We study the expansion velocity and ion temperature evolution of ultracold neutral plasmas (UNPs) of calcium atoms under the influence of a uniform magnetic field that ranges up to 200 G. In the experiments, we use a magneto-optical trap (MOT) to capture the neutral atoms and laser-induced fluorescence (LIF) to take images of the plasma. We vary the magnetic field strengths and the initial electron temperatures and observe the plasma evolution in time. We compare the ion temperature evolution to the theory introduced in the paper by Pohl et. al. [Phys. Rev. A 70, 033416 (2004)]. The evolution of the gradient of expansion velocity suggests the presence of ion acoustic waves (IAWs). We speculate that our measurements showing that the ion temperature remains relatively high throughout the evolution is a biproduct of the IAW.
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