The potential of atmospheric dust aerosols to modify the Earth's environment and climate has been recognized for some time. However, predicting the diverse impact of dust has several significant challenges. One is to quantify the complex spatial and temporal variability of dust burden in the atmosphere. Another is to quantify the fraction of dust originating from human-made sources. This thesis focuses on the spatiotemporal characterization of sources and dust outbreaks in Central and East Asia by integrating ground-based data, satellite multi-sensor observations, and modeling. A new regional dust modeling system capable of operating over a span of scales was developed. The modeling system consists of a dust module DuMo, which incorporates several dust emission schemes of different complexity, and the PSU/NCAR mesoscale model MM5, which offers a variety of physical parameterizations and flexible nesting capability. The modeling system was used to perform for the first time a comprehensive study of the timing, duration, and intensity of individual dust events in Central and East Asia. Determining the uncertainties caused by the choice of model physics, especially the boundary layer parameterization, and the dust production scheme was the focus of our study. Implications to assessments of the anthropogenic dust fraction in these regions were also addressed. Focusing on Spring 2001, an analysis of routine surface meteorological observations and satellite multi-sensor data was carried out in conjunction with modeling to determine the extent to which to this integrated data set can be used to characterize the spatiotemporal distribution of dust plumes at a range of temporal scales, addressing the active dust sources in China and Mongolia, mid-range transport and trans-Pacific, long-range transport of dust outbreaks on a case-by-case basis. This work demonstrates that adequate and consistent characterization of individual dust events is central to establishing a reliable climatology, ultimately leading to improved assessments of dust impacts on the environment and climate. This will also help to identify the appropriate temporal and spatial scales for adequate intercomparison between model results and observational data as well as for developing an integrated analysis methodology for dust studies.

This study collected relevant data of construction sites between January 1990 and December 2011 to estimate the emission factors of various construction projects for Kaohsiung City using Jhang¡¦s equations. The emission factors of various construction projects are as follows: about 0.121 kg/m2/month for reinforced concrete construction, about 0.141 kg/m2/month for steel constructed buildings, 0.228 kg/m2/month for road (tunnel) works, 0.126 kg/m2/month for bridge works, 0.101 tons/ha/month for regional construction projects, and 0.223 kg/m2/month for others. Based on these emission factors, the total fugitive dust emissions for 2,011 construction projects is estimated to be about 22,087.98 tons, and the exposure of per unit area to the fugitive dust pollution is approximately 11.98 ton/km2/month. The total fugitive dust emissions of 2,011 construction projects is estimated about 10528.14 tons (based on Kaohsiung City construction information database). According to the Department of Land, Kaohsiung City Government, Kaohsiung city is 27.8 kilometers from south to north, 10.4 kilometers from west to east, and the administrative area is 153.6029 square kilometers. The exposure of per unit area to the fugitive dust pollution is about 5.71 ton/km2/months.

Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered questions about the levels of PAHs in the environment, the potential for human exposure to PAHs, the health effects associated with exposure, and how genetic susceptibility influences the extent of health effects in individuals. The first objective of this research was to quantify concentrations of PAHs in samples of settled house dust collected from homes in Azerbaijan, China, and Texas. The trends of PAH surface loadings and percentage of carcinogenic PAHs were China > Azerbaijan > Texas, indicating that the risk of health effects from exposure to PAHs in house dust is highest in the Chinese population and lowest in the Texas population. PAHs in China and Azerbaijan were derived mainly from combustion sources; Texas PAHs were derived from unburned fossil fuels such as petroleum. The second objective of this research was to investigate the effect of pregnane X receptor (PXR) on the genotoxicity of benzo[a]pyrene (BaP). BaP treatment resulted in significantly lower DNA adduct levels in PXR-transfected HepG2 cells than in parental HepG2 cells. Total GST enzymatic activity and mRNA levels of several metabolizing enyzmes were significantly higher in cells overexpressing PXR. These results suggest that PXR protects cells against DNA damage by PAHs such as BaP, possibly through a coordinated regulation of genes involved in xenobiotic metabolism. The third objective of this research was to investigate biomarkers of exposure in house mice (Mus musculus) exposed to PAH mixtures in situ. Mice and soil were collected near homes in Sumgayit and Khizi, Azerbaijan. Mean liver adduct levels were significantly higher in Khizi than in Sumgayit. Mean lung and kidney adduct levels were similar in the two regions. The DNA lesions detected may be a combination of environmentally-induced DNA adducts and naturally-occurring I-compounds. PAHs were present at background levels in soils from both Khizi and Sumgayit. It appears that health risks posed to rodents by soil-borne PAHs are low in these two areas.

A high-volume air sampler (PS-1) was used to measure the concentrations of polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of Kaohsiung coast, PAHs diagnostic ratios,Hierarchical Cluster Analysis (HCA) and Principal Component Analysis (PCA) were employed to determine the potential sources of PAHs. The results show that the lowest concentrations of PAHs occurred in May (2.62 ngm-3), while the highest occurred in December (36.4 ngm-3). The nighttime concentrations of PAHs are higher than daytime with average night / day ratio of 1.65. The PAHs was more distributed in gas phase with proportions between 64.1 to 93.7 %. The 2, 3-Ring PAHs were mostly present in the gaseous phase (96.2 and 96.5 % respectively), 4-Ring also present dominantly in the gaseous phase (73.0 %), 5-Ring present mostly in the particle phase (80.2 %), 6, 7-Ring PAHs were mostly present in particulate phase (97.4 and 97.7 % respectively). During the Ghost Festiva and Asian dust storm events, atmospheric concentrations of PAHs and PAHs/TSP ratios were both found increased. It is found that gaseous and particulate PAHs correlate negatively with ambient temperature(r=-0.62, -0.57). Results from analyses of diagnostic ratios, HCA and PCA, the major sources of pollution include gasoline, diesel exhaust and industrial emission.

Mineral dust is ubiquitous in the atmosphere and represents a dominant type of particulate matter by mass. Despite its well-recognized importance, assessments of dust impacts on clouds and climate remain highly uncertain. This thesis addresses the role of dust as cloud condensation nuclei (CCN) and giant CCN (GCCN) with the goal of improving our understanding of dust-warm cloud interactions and their representation in climate models. We investigate the CCN-relevant properties of mineral dust samples representative of major regional dust sources experimentally in the laboratory conditions to determine their respective affinity to water. Based on the experimental exponent derived from the dependence of critical supersaturation with particle dry diameter, we determine the dominant physics of activation (i.e., adsorption activation theory (AT) or traditional Köhler theory (KT)) for dust particles from different global regions. Results from experimental measurements are used to support the development of a new parameterization of cloud droplet formation from dust CCN for climate models based on adsorption activation mechanism. The potential role of dust GCCN activating by AT within warm stratocumulus and convective clouds is also evaluated.

Thesis--Lund. / Includes bibliographical references (p. 221-228).

Carbon and nitrogen cycles, the energy cycle, and the hydrological cycle interact with each other; all are crucial to atmosphere–land studies. Carbon and nitrogen cycle from the atmosphere to vegetation communities and soil micro-organisms through their transformation in inorganic and organic pools. Ecosystem equilibrium, which is usually disturbed by extreme events (e.g., fires or drought), depends on the speeds of carbon and nitrogen uptake and decomposition. Terrestrial biogeochemistry models typically require hundreds to thousands of years for carbon and nitrogen in various pools to reach steady-state solutions, which are generally a function of soil temperature and soil water. Hydrological processes such as the root transpiration/water removal and the cold-region infiltration with the soil ice freeze/thaw status involved affect soil water content and soil temperature, and regulate carbon- and nitrogen-stock variations. Last but not least, mineral dust, a type of atmospheric aerosol, alters surface radiation/energy balance, and may act as cloud condensation nuclei to modify precipitation rates and eventually the hydrological cycle. Therefore, we were motivated to investigate these processes in different ecosystems. Specifically, this research aims to 1) to elucidate the carbon- and nitrogen-pool adjustment processes in different ecosystems, 2) to evaluate how the root transpiration process affects ecosystem carbon exchange patterns in Amazonia, 3) to analyze the influence of soil impermeability, which is affected by the landscape freeze/thaw status in cold regions, on hydrological cycles at high latitudes, and 4) to explore the effects of surface vegetation distribution and model resolution on surface dust emissions. The Community Land Model version 4 (CLM4) was used in this study. We did numerical experiments in three environments: forest and grassland ecosystems, river basins in cold regions, and the Arabian Peninsula. Our main scientific findings are: 1) the adjustment time of the biogeochemistry components in CLM4 is longer for boreal forests than for other ecosystems, 2) with more water is lifted from deep soil, Amazonia ecosystems start to take up carbon during dry seasons, 3) the timing of boreal spring runoff simulations is improved by reducing the impermeable area underneath the snowpack, and 4) model-simulated dust emissions increase with model resolution as a result of the heterogeneities of vegetation cover and wind speed. / text

We present results studying the distribution and properties of the diffuse dust in the Milky Way Galaxy using large optical surveys—specifically, the Sloan Digital Sky Survey (SDSS) and the Panoramic Survey Telescope and Rapid Response System 1 (Pan-STARRS1). This work has resulted in accurate measurements of dust reddening in regions of low extinction over large regions of sky. We present maps of reddening from dust covering the footprint of the SDSS, which covers one quarter of the sky. We present preliminary maps of dust covering the Pan-STARRS1 footprint, which covers three-quarters of the sky, including most of the plane of our Galaxy. We use these maps of dust to decisively exclude some simple parameterizations of dust extinction (Cardelli et al., 1989) in favor of others (Fitzpatrick, 1999). We show that the extinction predicted by the widely-used far-infrared dust map of Schlegel et al. (1998) is overestimated by 18%, and recalibrate that map using our extinction measurements. We further map variation in the properties of the dust, as indicated by variation in the amount of extinction relative to the amout of far-infrared dust extinction, and by variation in the ratio of dust extinction at different frequencies. We confirm these results by measuring reddening using two independent techniques and data sets, the SDSS photometry and spectroscopy. We further present the photometric calibration of the Pan-STARRS1 data—a necessary step to studying the dust with that ongoing survey. We achieve photometric precision unprecedented in a large optical survey, accurate to better than 1%. We additionally show the suitability of the calibrated photometry for studying the distribution of dust. Finally, we present preliminary three-dimensional maps of the dust in the Galaxy using our calibrated data from Pan-STARRS1. These maps will provide by far the most extensive information yet achieved about the three-dimensional distribution of extinction in the Galaxy. / Physics

The Helium isotopic system provides novel tools to probe the sedimentary record of the earth over the last few hundred million years. Radiogeneically derived \(^4He\) and solar wind implanted \(^3He\) is delivered to sediments by weathered continental material and interplanetary dust particles, respectively. The purpose of research presented in this thesis is to use \(^4He\) of terrestrial and \(^3He\) of extraterrestrial origins as tools to investigate the relationship between global climate and surface processes on earth. I measured \(^4He\) in annual growth bands in a Porites coral from the northern Red sea, lacustrine carbonate sediments from the Bahamas and marine sediments in the North Atlantic (Ocean Drilling Program site 1313). Terrestrially derived fraction of the measured \(^4He\) in the Red Sea Porites coral and carbonates of the Bahamas together provide accurate information about changes in dust export rates from North Africa over the last millennium; dust fluxes are intimately tied to droughts in North Africa at decadal to centennial time scales over the last millennium that in turn, appears to be modulated by sea surface temperatures (SSTs) in the Indian and the Atlantic Ocean. On the other hand, \(^4He\) content in marine sediments in the North Atlantic provide information about changes in sources of detrital over the last six million years that in turn appears to reflect changes in ocean circulation in the sub-polar north Atlantic. Accretion rates of solar wind implanted \(^3He\) provide independent constraints on time distribution and physical processes operational during the deposition of marine sedimentary sequences. I measured extraterrestrial \(^3He\) in sediments from the late Cretaceous through the early Danian at one site in the North Pacific (Ocean Drilling Program site 1209 on the Shatsky Rise) and in three sites from the South Atlantic (Deep Sea Drilling Projects sites 516F on Rio De Grande Rise and 528 on the Walvis Ridge). The high-resolution record of extraterrestrial \(^3He\) at the Shatsky Rise demonstrates that there was no increase in solar system dustiness associated with the meteorite impact thought to be responsible for the end cretaceous mass extinction. The assumption of constant delivery of extraterrestrial material therefore resulted in independent constraints on sediment accumulation rates and resultant age model through the early Danian, the latter marking the recovery of ocean system following the events of the end Cretaceous mass extinction. On the other hand, the extraterrestrial \(^3He\) derived mass accumulation rates in the south Atlantic sites demonstrate that carbonate-clay cyclicity in sediments—used by cyclostratigraphy to derive age models—are generated by different physical processes at different sites. It is therefore, crucial to understand processes underlying the carbonate-clay cyclicity before interpreting sediment couplets in terms of age model. / East Asian Languages and Civilizations

The effect of increased stratospheric dust on the polarization and intensity of sunlight scattered by the terrestrial atmosphere in the spectral region near the ultraviolet transmission cutoff is examined. Particular interest is given to radiation reflected to space or transmitted to the surface in the direction perpendicular to the incident solar beam in a plane containing the sun and the local vertical. Theoretical results are presented from radiative transfer calculations using a simple single scattering model and a four layer model in which ground reflection and multiple scattering were treated. Results show that the polarization state of transmitted radiation of .2975 μ for an incident solar zenith angle of 70° is sensitive to dust loading above 50 mb. The depolarization caused by a moderate increase in stratospheric dust loading is found to be roughly comparable to that caused by ground reflection and tropospheric aerosol. The polarization of light reflected to space is found to be very sensitive to high altitude dust scattering while being much less sensitive to other sources of depolarization. Results show that increasing the amount of stratospheric dust can cause either an increase or a decrease in the daily dosage of ultraviolet radiation at the surface, depending on the altitude profile of the dust, the latitude and the season. Preliminary experimental results or polarization monitoring by a ground-based instrument are presented and discussed. Sky light polarization ratios in the direction normal to the solar beam at .2975 μ and .300 μ based on data collected in the spring and summer of 1980 from the roof of the Physics-Atmospheric Sciences building on the campus of The University of Arizona are presented and discussed. The stratospheric dust problem is considered in terms of stratospheric aerosol enhancement resulting from volcanic activity.