Thesis (M. Tech.) - Central University of Technology, Free State, 2011 / The objectives of this research were to investigate and establish a procedure to determine the self-damping characteristics of transmission line conductors subjected to free and forced vibrations. The TERN and Aero-Z IEC62219-REV240609 conductor cables were the transmission line conductors that were readily available at the Vibration Research and Testing Centre (VTRC) of the University of KwaZulu-Natal (UKZN). The question to be answered was whether the self-damping characteristics of the TERN and Aero-Z IEC62219-REV240609 conductors were adequate to suppress Aeolian or wake-induced vibrations. In other words, is it necessary for external damping mechanisms to be used with these conductors? This study confirmed that the self-damping characteristics of conductors are not adequate to suppress Aeolian or wake-induced vibrations. Governing partial differential equations describing the characteristics of the catenary and parabolic cable conductors were developed to validate the experimental results. The experimental tests involved both conductors being subjected to an impulse function (a free vibration method) and also to a harmonic function (a forced vibration method). Measurements were carried out using accelerometers, and the recording equipment consisted of oscilloscopes and the PUMA system. With both the free and forced vibration methods, the damping factor of the TERN conductor was confirmed to be ζ ≤ 0.05, whereas the damping factor of the Aero-Z IEC62219-REV240609 was confirmed to be ζ ≤ 0.2. A procedure for determining the self-damping characteristics of the TERN and Aero-Z IEC62219-REV240609 conductors was developed, with the damping factor found to be ζ ≤ 0.2 for both conductors. These methods can assist in the implementation of procedural analysis of the self-damping behaviour of different types of transmission conductors and in finding the most suitable mass absorber (damper) to use in reducing the rate of failure of transmission line conductors. The results of this study can be used to improve the mathematical modelling of Aeolian and wind-induced vibrations where both self-damping properties and a mass absorber are incorporated.

This study concerned the preparation, characterisation and evaluation of different proton conductors for the Reverse Water Gas Shift Reaction (RWGS) and their evaluation as electrolytes for Solid Oxide Fuel Cells (SOFC) under H₂ and O₂. Materials with both catalytic and conductive properties are of a great interest, as their use in electrocatalytical systems may be very important. Sr₃CaZr₀.₅Ta₁.₅O₈.₇₅ (SCZT), BaCe₀.₉Y₀.₁O₂.₉₅ (BCY10) and Ba₃Ca₁.₁₈Nb₁.₈₂O₈.₇₃ (BCN18), were the initial materials in this study. Thermogravimetric analysis under different atmospheres (5%H₂/Ar, Ar, 5%CO₂, etc), were performed on SCZT and BCN18; with both materials being shown to be stable under reducing and oxidising conditions. Conductivity measurements by two terminal a.c. impedance were also conducted on SCZT and BCN18 under oxidising and reducing atmospheres. As found in literature, BCN18 showed mixed conductivity; with electronic conductivity at high temperatures and pure ionic conductivity below 550ºC, This behaviour was shown in chapter 3, where the change on conduction process was observed upon different gas feeds. Its maximum conductivity values for the different atmospheres were: 8.50x10⁻⁵ S/cm (Dry 5%H₂/Ar at 200ºC), 4.24x10⁻⁴ S/cm (Wet 5%H₂/Ar at 500ºC) and 4.48x10⁻³ S/cm (Air at 900ºC). SCZT proton conducting behaviour was also measured (wet and dry 5%H₂/Ar). Exhibiting an order of magnitude higher in total conductivity upon hydration of the gas feed (σdry=1.01x10⁻⁶ and σwet=1.07x10⁻⁵ at 450ºC). The doping of barium cerate with Zr and Zn by Tao and Irvine, lead to a more stable and easily sinterable BaCe₀.₅Zr₀.₃Y₀.₁₆Zn₀.₀₄O₃ (BCZYZ). Following this work, the introduction of ZnO as a sintering aid to SCZT and BCN18 resulted in Sr₃CaZr₀.₄Ta₁.₅Zn₀.₁O₈.₇₅ (SCZTZ), and Ba₃(Ca₁.₁₈Nb₁.₇₀Zn₀.₁₂)O₈.₅₅ (BCNZ); with higher final densities (above 90% dense). As with BCN18, BCNZ also exhibited mixed conductivity; with higher total conductivity values than BCN18. A maximum of total conductivity of 1.85x10⁻³ S/cm at 900ºC for BCNZ was measured against 6.99x10⁻⁴ S/cm at 900ºC for BCN18. A change in conductivity process was observed when using air or wet 5%H₂/Ar, achieving a maximum of 3.85x10⁻⁴ S/cm at 400ºC when under wet hydrogen. All materials (as powders) have shown catalytic activity for the reverse water gas shift (RWGS) reaction, with the lowest conversion temperature onset at 400ºC for SCZT and a maximum conversion of CO₂ to CO of 42%, with circa 0.52 and 0.59 mmol/s.m² of CO produced at 900ºC by BCN18 and BCZYZ, respectively. No relation between mechanisms for the RWGS and σ for these materials were expected below 10% conversion, as no correlation was found between their activation energies. BCY10 as shown a partial decomposition when exposed to the RWGS reaction, for what BCZYZ After fuel cell testing under H₂ and O₂ both SCZTZ and BCNZ showed mixed conductivity. SCZTZ under different hydrogen partial pressures, exhibited a behaviour close to a pure proton conductor, however, when exposed to both reducing and oxidising conditions, its behaviour did not follow the theoretical values. On the other hand, BCNZ behaves as a pure ionic conductor below 500ºC; with increasing influence of the electronic conductivity on temperature increase. However, as seen for BCNZ conductivity data from 2 terminal a.c. impedance, below 650ºC wet 5%H₂ exhibited the highest conductivity values. This, in additions to the pure ionic conductive behaviour below 400ºC (from the effective ionic transport number), suggests that BCNZ becomes closer to a pure proton conductor with temperature decrease.

Materials for extreme electrical contacts need to have high electrical conductivity coupled with good structural properties. Potential applications include motor contacts, high power switches, and the components of electromagnetic launch (EML) systems. In particular, the lack of durability of these materials in rail components limits practical EML implementation. These rails experience significant amounts of Joule heating, due to extreme current densities, and subsequent thermally-assisted wear. New more durable materials solutions are needed for these components. A systematic materials selection study was executed to identify and compare candidate materials solutions. Several possible candidate non-dominated materials as well as hybrid materials that could potential fill the "white spaces" on the Ashby charts were identified. A couple potential candidate materials were obtained and evaluated. These included copper-tungsten W-Cu, "self-lubricating" graphite-impregnated Cu, and Gr-W-Cu composites with different volume fractions of the constituents. The structure-property relations were determined through mechanical and electrical resistivity testing. A unique test protocol for exposing mechanical test specimens to extreme current densities up to 1.2 GA/m2 was developed and used to evaluate these candidate materials. The systematic design of multi-functional materials for these extreme electrical contacts requires more than an empirical approach. Without a good understanding of both the tribological and structural performance, the optimization of the microstructure will not be quickly realized. By using micromechanics modeling and other materials design modeling tools coupled with systematic mechanical and tribological experiments, the design of materials for these applications can potentially be accelerated. In addition, using these tools, more complex functionally-graded materials tailored to the application can be systematically designed. In this study, physics- and micromechanics-based models were used to correlate properties to the volume fraction of the constituents of the evaluated candidate materials. Properties correlated included density, elastic modulus, hardness, strength, and electrical resistivity of the W-Cu materials.

Mémoire (M.Sc.A.)--Université du Québec à Chicoutimi, 1985. / Document électronique également accessible en format PDF. CaQCU

Mémoire (M.Sc.A)-- Université du Québec à Chicoutimi, 1993. / Document électronique également accessible en format PDF. CaQCU

Functional materials, particularly metal oxides, have been the focus of much attention in solid state chemistry for many years and impact every aspect of modern life. The approach adopted in this thesis to access desirable functionality for enhanced fundamental understanding is via modifying existing materials by deploying reducing synthetic procedures. This work spans several groups of inorganic crystalline materials, but is unified by the development of new properties within host compounds of particular relevance to solid oxide fuel cell technology, which allow interstitial oxide ion conduction at elevated temperatures. The Ca₁₂Al₁₄O₃₂e₂ electride was successfully synthesized by replacing the mobile extra-framework oxygen ions with electrons acting as anions. The high concentration of electrons in the C12A7 electride gives rise to an exceptionally high electronic conductivity of up to 245 S cm⁻¹ at room temperature. Making use of the high density of electrons in Ca₁₂Al₁₄O₃₂e₂ electride, the strong N-N bonds in N₂ was found to be broken when heating Ca₁₂Al₁₄O₃₂e₂ in a N₂ atmosphere. A reaction between silicate apatites and the titanium metal yielded another completely new electride material La₉.₀Sr₁.₀(SiO₄)₆O₂.₄e₀.₂ which was found to be a semiconductor. To fully understand the role of oxygen interstitials in silicate apatites, high-resolution transmission electron microscopy (HRTEM) was employed as the main technique in probing how the oxygen nonstoichiometry is accommodated at the atomic level. Atomic-resolution imaging of interstitial oxygen in La₉.₀Sr₁.₀(SiO₄)₆O₂.₅ proved to be a success in this thesis. Substitution of oxygen in 2a and interstitial sites with fluoride ions in La[subscript(8+y)]Sr[subscript(2- z)](SiO₄)₆O[subscript(2+(3y-2z)/2)] (0<y<2, 0<z<2) could be an approach to enriching the functionalities in the apatite structure. A wide range of fluoride substitution levels was tolerated in La[subscript(10-x)]Sr[subscript(x)](SiO₄)₆O[subscript(3-1.5x)]F[subscript(2x)] (x= 0.67, 1, 1.5, 2) and AC impedance measurements were found in support of a tentative conclusion that fluoride ions could be mobile in fluorinated apatites. The last part of this thesis was focused on a new class of fast oxide ion conductors based on Ge₅P₆O₂₅ whose performance was superior to both La₉.₀Sr₁.₀(SiO₄)₆O₂.₅ and Ca₁₂Al₁₄O₃₃ in the low temperature range.

This dissertation deals with the challenge of power utility in South Africa which is on proactive detection of fallen power line conductors and real time sagging measurement together with slipping of such conductors. Various methods which are currently used for sag detection were characterized and evaluated to the aim of the research. A mathematical reconstruction done to estimate the lowest point of the conductor in a span is presented. Practical simulations and application of radio frequency identification (RFID) for sag detection is attempted through matlab software. RFID radar system is then analyzed in different modes and found to give precision measurement for sag in real time as opposed to global positioning system (GPS) if one dimension of the tag assumed fixed on the power line. Lastly errors detected on the measurements are corrected using a trainable artificial neural network. A conclusion is made by making recommendations in the advancement of the research. / Electrical Engineering / M. Tech. (Electrical Engineering)

A construção de linhas de transmissão são obras de grande impacto ambiental e requerem grandes investimentos financeiros. Este projeto de pesquisa, visa por meio de ensaios de laboratório, conceber uma ferramenta sistêmica para o aperfeiçoamento do método de determinação da fluência em cabos condutores de energia e OPGW (Optical Ground Wire), que tem sido utilizada no Brasil durante os últimos 30 anos, e analisar os efeitos na construção das linhas aéreas de transmissão. Visa também, proporcionar ganhos de confiabilidade ao sistema de transmissão de energia elétrica, pois o projeto, a construção, a operação e a manutenção de linhas de transmissão dependem de parâmetros de desempenho mecânico dos condutores. Conclui–se que a metodologia de ensaio proposta proporciona resultados finais mais confiáveis quando comparado com o atual procedimento normatizado, utilizado no Brasil, e sua utilização em projetos de linhas aéreas de transmissão de energia podem reduzir custos de construção, aumentar a ampacidade das linhas já existentes, bem como, diminuir os riscos ao a que pessoas estão sujeitas quando expostas a campos elétricos e eletromagnéticos gerados por linhas de transmissão. / Overhead Transmission Line construction projects have a great environmental impact and require a large financial investment. This research aims, through laboratory tests, to improve the method of determining the creep of power cables and OPGW (Optical Ground Wire) that has been utilized in Brazil for the last thirty years, as well as analyze the effects on the construction of overhead transmission lines. It will provide greater reliability to the overhead transmission line system, since the design, construction, operation and maintenance of transmission lines depend on the mechanical performance of the conductors. In conclusion, the proposed methodology provides more reliable final results compared to the current standardized procedure and its use in overhead transmission line projects could reduce construction costs, increase the ampacity, as well as reduce the risks to which people are subject when exposed to electric and electromagnetic fields generated by power lines.

Electromagnetic effects of lightning currents during a direct hit to tall communication towers, other instrumented towers and chimneys can be hazardous to associated cables, as well as, electrical and electronics systems. The standard practice in telecommunication and other related fields is to bond the cable sheath to the tower and ground connection is made before it enters the base station. However, in some specific cases when power, signal and data logging cables are to be supported on the same tower, isolation of power cables is demanded. In a totally different situation, attempts are also made to have a dedicated isolated down conductor. A critical review of the situation demanded a more quantitative answer to the following questions: (i) whether it is possible to electrically isolate a dedicated down conductor, (ii) is it possible to electrically isolate the cables and their terminal equipment both mounted on towers serving as down conductor and if so, what will be the nature of current induced in the cables and (iii) as per the standard practice, if the cable sheaths are connected to the tower/structure, what will be the nature of the current shared by them. Addressing these important issues formed the scope of the present work. For the tall structures considered in this work, for the critical time periods, wave nature of the current dominates. This called for electromagnetic modeling covering Transverse Magnetic (TM) mode of the wave propagation. Owing to the complex geometrical features involved with the problem, both experiments on electromagnetically scaled laboratory models, as well as, theoretical simulation is attempted. An electromagnetically scaled laboratory model is employed for the time domain experimental investigation. This approach, which has been validated earlier, is further scrutinized to ensure its adequacy. In order to achieve generality and noting the fact that the associated parameters are rather difficult to be varied in the experimentation, theoretical investigation is also employed. For this, both NEC-2, as well as, an in-house thin wire time domain code developed for this work is employed. NEC-2 could handle multi-wire multi-radius junctions, while in-house time domain code could handle proximity and non-cylindrical shapes encountered with tower lattice elements. The investigation of induction to isolated cables on simple down conductors and towers is considered first. The induced current is shown to be bipolar oscillatory with the period of oscillation governed by the length of the cable. It is shown that the level of induction for good earth termination is below 5 – 10 % while that with moderate inductance in the earth termination can enhance the induction to higher levels. The level of induction is shown to be not critically dependent on the length of the cable, gap between cable and down conductor/tower. When multiple cables are mounted, they seem to influence each other and individually carry currents of lower amplitude. Also, the effect of shape and proximity of the tower lattice elements on induction is investigated. If the cable is housed inside a metallic tray, the amplitude of induced current is shown to be quite small. Subsequently, the evaluation of electrical stress between the isolated down conductor on tower and simplified representation of the structure is considered. A suitable definition of the electric stress for the wave regime is evolved and then it is shown that, at present, the voltage difference defined by the path integral of electric field across shortest path between the two entities is the best indicator for the stress. The electrical stress in the case of isolated down conductor on tower, as well as, down conductor with isolated cable is shown to reach very dangerous levels. On the other hand, the stress on the isolated cables on towers also serving as down conductors is shown to be relatively moderate. Interestingly, it is shown that the electrical stress and the voltage difference is dependent on the gap and for the critical time period, can be much lower than that calculated as a product of equivalent tower surge impedance and the stroke current, even before the arrival of ground end reflections. Finally, the current shared by cables connected to the down conductor is investigated. For the case of simple cylindrical down conductor with cable connected to it at the top, it is shown that the amount of current shared by the cable is not dependent on its length and the relative radii (cross section) have only a weak influence. For the case with down conductor formed by L and + angles, it is shown that the placement of cable at their interior corner can reduce the initial current shared by the cable. In order to model best possible situation with towers, experiments are conducted with cable inside an aluminum pipe. Even in this case, cable current builds up with successive reflections to become comparable with the current through the pipe itself. Subsequent investigation with 1:40 and 1:20 tower models lead to several interesting observations. Cables running along leg/face of the tower whether placed inside or outside the tower, always shares good amount of current. Further, frequent bonding of the sheath to the tower increases the current shared by the cable. Cable when housed in a metallic tray shares less than 50% of the current shared without the tray. Even though a complete quantification is not to be achieved in this work, it has made a good beginning with some significant contribution towards lightning protection issues pertaining to tall towers and structures.

Indiana University-Purdue University Indianapolis (IUPUI) / The prevalent applications of energy storage devices have incited wide-spread efforts on production of thin, flexible, and light-weight lithium-ion batteries. In this work, lithium-ion batteries using novel flexible paper-based current collectors have been developed. The paper-based current collectors were fabricated from carbon nanotube (CNT)-coated wood microfibers (CNT-microfiber paper). This thesis presents the fabrication of the CNT-microfiber paper using wood microfibers, coating electrode materials, design and assemblies of battery, testing methodologies, and experimental results and analyses. Wood microfibers were coated with carbon nanotubes and poly(3,4-ethylenedioxythiophene) (PEDOT) through an electrostatic layer-by-layer nanoassembely process and formed into a sheet, CNT-microfiber paper. The CNT loading of the fabricated paper was measured 10.1 μg/cm2 subsequently considered. Electrode material solutions were spray-coated on the CNT-microfiber paper to produce electrodes for the half and full-cell devices. The CNT current collector consists of a network structure of cellulose microfibers at the micro-scale, with micro-pores filled with the applied conductive electrode materials reducing the overall internal resistance for the cell. A bending test revealed that the paper-based electrodes, compared to metal ones, incurred fewer damages after 20 bends at an angle of 300o. The surface fractures on the paper-based electrodes were shallow and contained than metallic-based electrodes. The micro-pores in CNT-microfiber paper structure provides better adherence to the active material layer to the substrate and inhibits detachment while bending. Half-cells and full-cells using lithium cobalt oxide (LCO), lithium titanium oxide (LTO), and lithium magnesium oxide (LMO) were fabricated and tested. Coin cell assembly and liquid electrolyte was used. The capacities of half-cells were measured 150 mAh/g with LCO, 158 mAh/g with LTO, and 130 mAh/g with LMO. The capacity of the LTO/LCO full-cell also was measured 126 mAh/g at C/5 rate. The columbic efficiency of the LTO/LCO full-cell was measured 84% for the first charging cycle that increased to 96% after second cycle. The self-discharge test of the full-cell after charging to 2.7 V at C/5 current rate is showed a stable 2 V after 90 hours. The capacities of the developed batteries at lower currents are comparable to the metallic electrode-based devices, however, the capacities were observed to drop at higher currents. This makes the developed paper-based batteries more suitable for low current applications, such as, RFID tags, flexible electronics, bioassays, and displays. The capacities of the batteries at higher current can be improved by enhancing the conductivity of the fibers, which is identified as the future work. Furthermore, fabrication of an all solid state battery using solid electrolyte is also identified as the future work of this project.