Typescript (photocopy). / Digitized by Kansas Correctional Industries

"The performance of a series of mineral oil based quenchants has been investigated using the CHTE Quench Probe System and probe tips of 4140 steel to determine the cooling rate, heat transfer coefficient, Hardening Power (HP) and Tamura’s V indices in terms of the physical properties of quenchants; e.g. viscosity and oil start temperature. The Quench Factor, Q, was also calculated in terms of the hardness of the quenched parts. The lumped parameter approximation was used to calculate the heat transfer coefficient as a function of temperature during quenching. The results revealed that the maximum cooling rate increases with decrease in quenchant viscosity. As viscosity increases, Tamura’s V is nearly constant, while the HP decreases. For the selected oils, cooling ability of quenching oil increases with the increase in oil operating temperature, reaches a maximum and then decreases. The heat transfer coefficient increases with the increase in hardening power and maximum cooling rate. As the viscosity increases, the quench factor increases, which indicates the cooling ability of the oil decreases since the higher quench factor means the lower cooling ability of the oil. The hardness decreases with the increase in quench factor. Also the effect of surface oxides during quenching in commercial oils is studied. It was found that for 4140 steel probes the formation of oxide in air increases the cooling rate and heat transfer coefficient, the cooling rate curve of 4140 steel probe heated in argon shows clear Leidenfrost temperature, the oxide layer may require a significant thickness to cause the decrease in heat transfer coefficient. For 304 stainless steel probes the cooling rate and heat transfer coefficient are quite similar in air and in argon."

Thesis. 1976. Ph.D.--Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science. / Microfiche copy available in Archives and Engineering. / Vita. / Includes bibliographical references. / Ph.D.

Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Electrical Engineering and Computer Science, 1980. / MICROFICHE COPY AVAILABLE IN ARCHIVES AND ENGINEERING. / Vita. / Includes bibliographical references. / by Weng Cho Chew. / Ph.D.

Thesis. 1976. B.S.--Massachusetts Institute of Technology. Dept. of Electrical Engineering and Computer Science. / Microfiche copy available in Archives and Engineering. / Includes bibliographical references. / by Lindsay Asbury Weaver, Jr. / B.S.

This thesis incorporates an array of Contact Potential Difference (CPD) sensors to measure and monitor the degree of skew in the rolling elements of a spherical roller bearing. Skewing is the motion of a roller as it turns about an axis normal to the roller race interface. Roller skew is generated as part of the kinematic effects of roller bearings. Skew monitoring is important for bearing design as it is an indirect measure of bearing life. For the purpose of this thesis, roller skew was measured utilizing multiple pairs of CPD probes located around the bearings outer raceway at varying points of the loading zone. These CPD probes are not in direct contact with the rollers, but in close proximity to their surface (through the bearing outer ring). The skew angle measured is related to different operating conditions such as applied load, shaft speed, and lubrication. The pair of CPD probes detected a signal as the roller surface passed by and the phase difference between the two distinct signals measured the skew angles in the range of 0.016 to 1.10. The shaft is rotated both clockwise and counterclockwise to capture any probe misalignment which was in the range of 0.5 up to 2.0 . This thesis also provides a model for the probe signal as a spherical roller surface passes the probe surface.

This research is dedicated to develop novel batch fabrication procedures for two distinct AFM (Atomic Force Microscope) probes integrated with electrodes enabling electrical sample characterization and electrochemical sample surface profiling respectively. These AFM probes allow for highly accurate control of the probe positioning, low contact force and sample surface imaging with high lateral resolution. As an electrical characterization tool, a nickel micro four-point probe integrated with solid nickel tips was developed. Low electrical resistance of the probe and contact resistance were achieved due to the solid nickel cantilever and tips. Low aspect ratio solid metal tips reduced contact resistance resulting in stable electrical measurement. Conductivity loss easily experienced while using metal coated AFM cantilevers was overcome by solid nickel tip integration to the electrically conductive AFM cantilevers. The fabrication method introduces selective conical nickel tip etching in silicon dioxide etching chambers. A novel batch fabrication method for SECM-AFM (Scanning Electrochemical Microscope-Atomic Force Microscope) tip integrated with a ring electrode was developed as a tool for electrochemical imaging as well as topological imaging. The electroactive area at an exactly defined distance above the apex of the AFM tip is fabricated using an inverse silicon mold technique. The electrode at a deliberately chosen distance from the end of a scanning probe tip allowing electrochemical sample imaging separated from sample topology imaging. The ring electrode coated with polymer entrapping enzymes enabled the probe to detect ATP from living epithelial cells.

Oil analysis is a broad field comprised of hundreds of individual tests that provide meaningful benefit by assessing one or more properties of lubricants or machines. Many tests are performed on new types of oil during research and development. The lubricants chemical, physical, or lubricating properties are validated for quality control purposes and product performance classification. Much of the research in this area is devoted to the online oil degradation systems which allow getting a prompt response about the condition of lubricant. This thesis investigates the concept for monitoring oil degradation with a vibrating Kelvin probe technique. The Vibrating Kelvin probe method for measuring the work function of metals has been used since 1932. Among the applications of this technique are adsorption, corrosion, friction and other studies. A novel application of this method is proposed in this thesis. The vibrating Kelvin system was created with one static surface acting as a sampling surface and the other one electrically isolated. The interaction of the oil with one of the surfaces of a capacitor results in a signal which is synchronously measured. The oil molecules adsorb on the surface of one of the plates and form a space charge layer which changes the work function of that surface. Oil prepared by intentional oxidation was used to evaluate and to monitor the ability to see changes in oil.

Atomic Force Microscopy (AFM) has become an indispensable metrology tool for nanoscale surface characterization. Today, research and industry demand faster and more accurate metrology and these demands must be met expediently. Traditional AFM cantilevers and associated actuators (i.e. piezoelectric) are limited in regards to actuation speed and resonance frequency presenting the user with an undesired trade-off of speed versus resolution. Based on a pre-existing technology known as the FIRAT (Force Sensing Integrated Readout and Active Tip) AFM probe, this work aims to remedy actuation and response issues by implementing a cantilever-on-cantilever probe as well as a novel seesaw probe. Both cases implement electrostatic actuation, eliminating the need for piezoelectrics while demonstrating large - micron scale - actuation and sensitive displacement detection. These new probe designs can potentially demonstrate a wide bandwidth frequency response (e.g. 100 kHz) ideal for high-speed video-rate imaging. Unlike traditional AFM cantilevers, this is realized by mechanically coupling two physically separate structures to provide a soft resonator sensor atop a stiff actuator structure. Common surface-micromachining techniques are utilized to solve the logistical challenge of fabricating these stacked structures. By manipulating the viscous damping and mechanical mode coupling it becomes feasible to attain the aforementioned desired dynamic characteristics.

This work presents the novel applications of heated AFM tip in nanolithography. Different strategies were investigated for patterning materials using heated AFM tip. New materials were developed for these new nanolithography methods. Simulation and modeling work was done to further understand the heat transfer and chemical reactions involved in the thermal writing process. The selective thermal decomposition of polymer was the first thermal patterning method we¡¯ve investigated. A couple of different sacrificial polymers were used as the writing materials. Among these materials, the cross-linked amorphous polycarbonate (CPC-IV) was the best material for this application. The effect of cross-linking density on the performance of the material was investigated. A novel 3D thermal writing technology was developed by using cross-linked polymer as the writing material. A combined method utilizing the heated cantilever probe to pattern a polymer masking layer that can serve as a template for area selective atomic layer deposition techniques was developed. Another thermal probe nanolithography method, thermal probe top surface imaging, was also developed. In this method, the heated AFM tip was used to generate functional groups on the polymer surface, and ALD was used to selectively deposit TiO2 on the surface where contains those functional groups. A new poly (hydroxyl styrene) based copolymer was developed for this method. We also investigated self assembly monolayers (SAMs) as the thermal writing material. Two different SAMs were investigated. One the APTES and the other one is THP-MPTES. We demonstrated that the APTES can be patterned using thermal AFM probe, and other materials can be selectively deposited on the patterned APTES SAMs. Thermal AFM probe was used to selectively generate thiol groups from THP-MPTES SAMs, and then use these thiol groups to guide the deposition AuNPs. Some simulation and modeling works were also done to further understand these processes. FemLab was used to analyze the heat transfer in the thermal cantilever and between the heated tip and substrate. Based on kinetics of polymer thermal decomposition, we built a simple model for the selective thermal decomposition nanolithography. The experimental results can be very well fitted by this model.