This thesis considered three types of new and improved high-performance energy absorbing devices for either compression or bending applications. These improvements were achieved by only altering their initial geometries for desired failure modes.

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Vertical drop testing of transport aircraft fuselage sections indicates that the frames play a major role in the process of absorbing the impact energy in the crushing of the substructure below the main passenger deck. Hence, static tests are performed on individual circumferential frames under a radially inward load to assess their progressive failure response and energy absorption characteristics. The test articles in the first series of tests are six-foot diameter, semicircular, I-section frames fabricated from graphite-epoxy unidirectional tape. The test articles in the second series of tests are J-section frames subtending a forty-eight degree circular arc, having an inside radius of 118 inches, a depth of 4.8 inches, and manufactured by resin transfer molding into a 2x2 2D triaxial braided composite preform made of AS4 graphite yarns. Frames of both materials exhibit fractures at the pint of load application and at selected locations around the circumference, but the delamination prevalent in the tape layup frames is not evident in the textile frames. A mathematical model developed to optimize open section curved composite frames for improved energy absorption is used to redesign the I-section frames by resizing the flanges. The test results of the redesigned frames show that the mathematical model predicted the correct sequence and locations of the failure events. However, the mathematical model does not predict the magnitude of the force and displacement at the first major failure event, which maybe due to the fact that delamination is not included in the progressive failure model Tests results from two of the J-section frames are compared with a beam finite element analysis using the computer code ABAQUS. Effective elastic moduli for the textile material are obtained from the computer code TEXCAD. The ABAQUS results correlate reasonably well with the experimental results prior to the first major failure event. / Master of Science

<div>Thin walled tubular structures are widely used in the automotive industry because of its weight to energy absorption advantage. A lot of research has been done in different cross sectional shapes and different tapered designs, with design for manufacturability in mind, to achieve high specific energy absorption. </div><div><br></div><div>In this study a novel type of tubular structure is proposed, in which predesigned origami initiators are introduced into conventional square tubes. The crease pattern is designed to achieve extensional collapse mode which results in decreasing the initial buckling forces and at the same time acts as a fold initiator, helping to achieve a extensional collapse mode. The influence of various design parameters of the origami pattern on the mechanical properties (crushing force and deceleration) are extensively investigated using finite element modelling. Thus, showing a predictable and stable collapse behavior. This pattern can be stamped out of a thin sheet of material. </div><div><br></div><div>The results showed that a properly designed origami pattern can consistently trigger a extensional collapse mode which can significantly lower the peak values of crushing forces and deceleration without compromising on the mean values. Also, a comparison has been made with the behavior of proposed origami pattern for extensional mode verses origami pattern with diamond fold.</div>

A novel aluminum foam-polymer hybrid material was developed by filling a 10 pore per inch (0.39 pores per millimeter), 7 % relative density Duocel® open-cell aluminum foam with a thermoplastic polymer of trade name Elvax®. The hybrid was developed to be completely recyclable and easy to process. The foam was solution treated, air quenched and then aged for various times at 180˚C and 220˚C to assess the effect of heat treatment on the mechanical properties of the foam and to choose the appropriate aging condition for the hybrid fabrication. An increase in yield strength, plateau height and energy absorbed was observed in peak-aged aluminum foam in comparison with underaged aluminum foam. Following this result, aluminum foam was utilized either at the peak-aged condition of 4 hrs at 220˚C or in the as-fabricated condition to fabricate the hybrid material. Mechanical properties of the aluminum foam-polymer hybrid and the parent materials were assed through uniaxial compression testing at static ( de/dt = 0.008s-1 ) and dynamic ( de/dt = 100s-1 ) loading rates. The damping characteristics of aluminum foam-polymer hybrid and aluminum foam were also obtained by compression-compression cyclic testing at 5 Hz. No benefit to the mechanical properties of aluminum foam or the aluminum foam-polymer hybrid was obtained by artificial aging to peakaged condition compared to as-fabricated foam. Although energy absorption efficiency is not enhanced by hybid fabrication, the aluminum foam-polymer hybrid displayed enhanced yield stress, densification stress and total energy absorbed over the parent materials. The higher densification stress was indicative that the hybrid was a better energy absorbing material at higher stress than the aluminum foam. The aluminum foam was found to be strain rate independent unlike the hybrid where the visco-elasticity of the polymer component contributed to its strain rate dependence. The damping properties of both aluminum foam and the aluminum foam-polymer hybrid materials were found to be amplitude dependant with the hybrid material displaying superior damping capability.

A novel aluminum foam-polymer hybrid material was developed by filling a 10 pore per inch (0.39 pores per millimeter), 7 % relative density Duocel® open-cell aluminum foam with a thermoplastic polymer of trade name Elvax®. The hybrid was developed to be completely recyclable and easy to process. The foam was solution treated, air quenched and then aged for various times at 180˚C and 220˚C to assess the effect of heat treatment on the mechanical properties of the foam and to choose the appropriate aging condition for the hybrid fabrication. An increase in yield strength, plateau height and energy absorbed was observed in peak-aged aluminum foam in comparison with underaged aluminum foam. Following this result, aluminum foam was utilized either at the peak-aged condition of 4 hrs at 220˚C or in the as-fabricated condition to fabricate the hybrid material. Mechanical properties of the aluminum foam-polymer hybrid and the parent materials were assed through uniaxial compression testing at static ( de/dt = 0.008s-1 ) and dynamic ( de/dt = 100s-1 ) loading rates. The damping characteristics of aluminum foam-polymer hybrid and aluminum foam were also obtained by compression-compression cyclic testing at 5 Hz. No benefit to the mechanical properties of aluminum foam or the aluminum foam-polymer hybrid was obtained by artificial aging to peakaged condition compared to as-fabricated foam. Although energy absorption efficiency is not enhanced by hybid fabrication, the aluminum foam-polymer hybrid displayed enhanced yield stress, densification stress and total energy absorbed over the parent materials. The higher densification stress was indicative that the hybrid was a better energy absorbing material at higher stress than the aluminum foam. The aluminum foam was found to be strain rate independent unlike the hybrid where the visco-elasticity of the polymer component contributed to its strain rate dependence. The damping properties of both aluminum foam and the aluminum foam-polymer hybrid materials were found to be amplitude dependant with the hybrid material displaying superior damping capability.

UV radiation can cause harmful effects to human skin, including premature skin ageing and skin cancer. Historically, sunscreens were developed to filter out UVB (290 nm-320 nm), but now the importance of UVA (320 nm-400 nm) sunscreens is realised. The most common UVA sunscreens are based on dibenzoylmethane (1,3-diphenyl propan-l,3-dione, DBM), of which the most common is Parsol 1789 (4'- methoxy 4'-tertiarybutyl DBM). The photochemistry of these materials has, however, been poorly understood. In this work the photophysics and photochemistry of DBM, Parsol 1789, Parsol DAM and ditertiarybutyl DBM have been studied, along with the respective 0-methylated and C-methylated compounds of DBM and Parsol 1789.DBMs exist primarily as an intra-molecularly bonded enol, which absorbs strongly at λ≈340 nm due to a π,π* transition. The absorption spectra of DBMs also exhibit a smaller peak at λ≈250 nm, due to an n,π* transition of the diketone content. At low temperature the main absorption band of DBMs shifts to longer wavelengths and vibrational structure can be observed. The enol form of DBMs fluorescence at low temperature, (v(_0)’→v’’(_0) at λ≈385 nm), and phosphorescence can be observed from both the diketone (λ(_em)≈495 nm,) and enol forms (λ(_em)≈425 nm). Thus the triplet energies of the diketones and enols of the DBMs studied have been measured. 0-methylated DBMs do not possess an intra-molecular H-bond, and the π,π* absorption band falls to lower wavelengths than for chelated DBMs. C-methylated DBMs exist as a diketone structure, and display photophysics typical of an aromatic ketone. It has been suggested that the main process on irradiation of DBM is the formation of a short-lived non-chelated enol, however no direct evidence as to the structure of this species is reported in the literature. Formation of the diketone form of DBM on prolonged irradiation in acetonitrile solution has also been reported, and in this work the quantum yield of this process has been measured; ɸ≈0.01 ± 0.004. In this work, direct (low temperature) IR spectroscopic evidence is presented to prove that the short-lived species produced on irradiation is indeed a non-chelated enol. The infra-red studies also suggest that the non-chelated enol form of DBM form complexes with polar solvents, as has been proposed in the literature. Quantum yields of non-chelated enol formation in cyclohexane at room temperature have been measured to be approximately ɸ=0.5 + 0.07. This work indicates that the rate of transient decay is enhanced by the interaction of the transient molecules with chelated enol molecules or other transient molecules. IR studies of low temperature transient formation confirm the interaction of transient molecules by the observation of inter-molecular hydrogen-bonding. By comparison with the E and Z isomers of 0-methylated DBM it is suggested that at low temperature DBM initially forms a Z-cis non-hydrogen bonded enol, which then converts to an E-trans non-hydrogen bonded enol with further irradiation. The kinetics and the temperature variation of the enol recovery support the theory that there is more than one species formed. The photochemistry of DBM in emulsions has also been studied in this work. It has been shown that the photochemistry occurring on irradiation is similar to that observed in solutions. This indicates that simple solutions are a good model for actual sunscreen formulations. Singlet oxygen is a highly reactive species capable of causing serious biological damage, however this work shows that DBM sunscreens generate singlet oxygen by photosensitisation, with quantum yields ɸ∆≈0.005-0.01. It has also been shown that the lifetime of the excited state of DBM involved in singlet oxygen production is very short, approximately τ <1 µs.