acase@tulane.edu

There is growing evidence that natural disasters can trigger technological disasters, and that these joint events (also known as natechs) may pose tremendous risks to regions which are unprepared for such events. The recent floods across Europe in the summer of 2002 and the unprecedented multiple hazardous materials releases triggered by the Turkey earthquake of August 1999 were examples showing the potential danger of a natech disaster occurring near populated areas. However, there is scarce information available on the interactions between natural disasters and simultaneous technological accidents This dissertation provides an overview of the natech problem through the development of five related but independent research studies that identify natech disaster scenarios at industrial facilities subject to natural hazards, documents and analyzes natech incidents and risk management and emergency response practices for earthquake triggered hazardous materials releases during the Turkey earthquake of August 17, 1999, and assess risk management and emergency response for earthquake-induced chemical accidents in the US The dissertation demonstrates that the likelihood of joint natural and technological disasters is high, while preparedness for joint natechs is low Both the study of potential hurricane-triggered hazmat release scenarios and the study of hazmat releases during the Turkey earthquake demonstrated that joint natural disasters and technological disasters act synergistically to produce a much greater threat than either type of hazard alone. Furthermore, the different natural hazards associated with natechs all have the potential to produce a high amount of property damage, economic loss, and a high level of potential health threats to workers and the surrounding communities / acase@tulane.edu

acase@tulane.edu

The compounds 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-N, N-dimethyldithiocarbamoylethoxy) calix (4) arene, 25,26,27,28-tetra-(2-N, N-dimethyldithiocarbamoylethoxy)calix (4) arene, 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-mercaptoethoxy)calix (4) arene, 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-(methylthio)ethoxy)calix lbrack 4) arene, 25,26,27,28-tetra-(2-(methylthio)ethoxy)calix (4) arene, 25,26,27,28-tetra-(2-(2-pyridylthio)ethoxy)calix (4) arene tetra-N-oxide and 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-(2-thiophenecarboxy)ethoxy)calix (4) arene have been synthesized. They have been characterized by proton NMR spectroscopy, carbon-13 NMR spectroscopy, infrared spectroscopy and elemental analysis. In addition, the crystal structures of 25,26,27,28-tetra-(2-hydroxyethoxy)calix (4) arene, 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-bromoethoxy)calix (4) arene, 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetra-(2-N,N-dimethyldithiocarbamoylethoxy) calix (4) arene, 25,26,27,28-tetra-(2-N,N-dimethyldithiocarbamoylethoxy)calix (4) arene and 25,26,27,28-tetra-(2-(methylthio)ethoxy)calix (4) arene have been determined by single crystal X-ray diffraction. These sulfur derivatized calixarene derivatives have been found to be selective extractants for heavy and precious metal ions such as Hg(II), Ag(I), Pd(II), Au(III) into chloroform from water. The potential of these ligands as extraction agents in environmental cleaning operations and industrial separations are discussed / acase@tulane.edu

acase@tulane.edu

acase@tulane.edu

Environmental awareness and legislative pressures have made manufacturers responsible for the take-back and end-of-life treatment of their products. Therefore, manufacturers are struggling to find ways to recover maximum value from returned products. This goal can best be achieved by promoting multiple reuse programs as reuse is one of the most effective ways to enhance a sustainable engineering economy. Since the essential goal of the reuse strategy is to reuse parts, the reliability of used parts becomes a core issue. Research indicates that reuse is technologically feasible, associated with a significant manufacturing cost saving, and it does not compromise product quality. However, it is not easy to be applied in reality. There are several uncertainties associated with reuse, the most common is the uncertainty of the product???s quality after use. A widespread implementation of the reuse strategy could be triggered, subject to the availability of reliable methods to assess the useful remaining life of parts. The evolution of such a methodology would play a pivotal role in making decisions on the supply chain process and the recovery value of returned products. Reliability assessment by life cycle data analysis is the basis of this research. The proposed methodology addresses the problem of reliability assessment of used parts by considering two important aspects. It performs statistical as well as condition monitoring data analysis for decision-making on reuse. The analysis is carried out in two stages. Firstly, a wellknown reliability assessment procedure, the Weibull analysis, is applied to analyse time-tofailure data to assess the overall reuse potential of components. In the second stage, the used capacity (actual life) of components is determined by analysing their operating history (condition monitoring data). The linear and nonlinear regression analysis, Kriging procedures and artificial neural networks (ANN) are employed in this stage. Finally, the Weibull analysis and ANNs are integrated to estimate the remaining useful life of components/assemblies of a product at the end of its first life cycle. The model was validated by using life cycle data from consumer products.

<p>Spatial variability of the Earth's surface has a considerable impact on the atmosphere at all scales and understanding the mechanisms involved in land-atmosphere interactions is hindered by the scarcity of appropriate observations. A measurement gap exists between traditional point sensors and large aircraft and satellite-based sensors in collecting measurements of atmospheric quantities. Point sensors are capable of making long time series of measurements, but cannot make measurements of spatial variability. Large aircraft and satellites make measurements over large spatial areas, but with poor spatial and temporal resolution. A helicopter-based platform can make measurements on scales relevant for towers, especially close to the Earth's surface, and can extend these measurements to account for spatial variability. Thus, the Duke University Helicopter Observation Platform (HOP) is designed to fill the existing measurement gap. </p><p>Because measurements must be made in such a way that they are as uncontaminated by the platform itself as much as is possible, it is necessary to quantify the aerodynamic envelope of the HOP. The results of an analytical analysis of the location of the main rotor wake at various airspeeds are shown. Similarly, the results of a numerical analysis using the commercial Computational Fluid Dynamics software Fluent are shown. The optimal flight speed for the sampling of turbulent fluxes is found to be around 30 m/s. At this airspeed, the sensors located in front of the nose of the HOP are in advance of the wake generated by the main rotor. This airspeed is also low enough that the region of high pressure due to the stagnation point on the nose of the HOP does not protrude far enough forward to affect the sensors. Measurements of differential pressures, variables and turbulent fluxes made while flying the HOP at different airspeeds support these results. No systematic effects of the platform are seen at airspeeds above about 10 m/s.</p><p>Processing of HOP data collected using the current set of sensors is discussed, including the novel use of the Empirical Mode Decomposition (EMD) to detrend and filter the data. The EMD separates the data into a finite number of Impirical Mode Functions (IMFs), each of which is unique and orthogonal. The basis is determined by the data itself, so that it need not be known a priori, and it is adaptive. The EMD is shown to be an ideal tool for the filtering and detrending of HOP data using data gathered during the Cloud and Land Surface Interaction Campaign (CLASIC). </p><p>The ability of the HOP to accurately measure atmospheric profiles of potential temperature is demonstrated. During experiments conducted in the marine boundary layer (MBL) and the convective boundary layer (CBL), HOP profiles are evaluated using profiles from an elastic backscatter lidar. The HOP and the lidar agree on the height of the boundary layer in both cases, and the HOP effectively locates other atmospheric structures.</p><p>Atmospheric sensible and latent heat fluxes, turbulence kinetic energy (TKE) and horizontal momentum fluxes are also measured, and the resulting information is used to provide context to tower-based data collected concurrently. A brief comparison made over homogeneous ocean conditions yields good results. A more exhaustive evaluation is made using short HOP flights made over an orchard during the Canopy Horizontal Turbulence Study (CHATS).</p> / Dissertation

<p>In order to meet disinfection guidelines, wastewater utilities must achieve a high level of treatment before discharging treated water for irrigation or industrial use. However, public pressure to reduce disinfection by-products and pharmaceutically-active compounds, recently-promulgated regulations on chlorine-resistant microorganisms such as Cryptosporidium parvum, and growth in population and water demand have driven an interest in alternatives to chlorination. The WateReuse Foundation has funded WRF 02-009 (Innovative Treatment Technologies for Reclaimed Water), which is a survey of current and emerging reuse water treatment technologies. The goal of the project is to evaluate treatment technologies can provide adequate recycled water effluent without the cost of reverse osmosis (RO) or the disinfection by-products (DBPs) formed during chlorination.</p><p>The inactivation of indigenous microorganisms (total and fecal coliform bacteria, and total aerobic spores) and spiked surrogate, respiratory, and enteric viruses (MS-2 bacteriophage, adenovirus type 4, reovirus type 3, and coxsackievirus type B5) and chemical degradation by wastewater treatment technologies was evaluated on the bench-scale. These include: low- and medium-pressure UV, LPUV/H₂O₂, ozonation, O₃/H₂O₂, peracetic acid (PAA), LPUV/PAA, chlorination, chloramination, and ultrafiltration. The applicability of the candidate disinfection methods, especially emerging and comparatively untested methods such as PAA and advanced oxidation processes (AOPs), was studied through comparison of their performance and the important water matrix parameters (e.g., alkalinity, BOD, TSS, etc.).</p><p>Of the chemical disinfectants, molecular ozone and free chlorine were the most effective, with substantial coliform and virus kill at low doses. Combined chlorine in the form of monochloramine had a reduced disinfectant capacity than free chlorine, and peracetic acid (PAA) performed equally as well as free chlorine with respect to coliform bacteria in some instances but had little to no impact on spiked MS2 bacteriophage. None of the aforementioned disinfectants had an appreciable impact on indigenous aerobic spore-forming bacteria due to their physiology. UV and O₃ rapidly killed human enteric and respiratory viruses, but a consistent benefit by AOPs over their base technologies was not observed for any of their base technologies.</p><p>Low and medium-pressure UV inactivated free-floating indigenous coliform bacteria almost immediately, while slower inactivation rates at higher UV fluences illustrated the "tailing" behavior observed when bacteria are embedded in or shielded by particulate matter. Log-linear inactivation of spiked viruses and indigenous aerobic spores by UV was consistent across the utility waters. The UV-based advanced oxidation processes (UV/H₂O₂ and UV/PAA) destroyed spiked organic compounds at much higher rates than direct UV photolysis, while O₃, with or without H₂O₂ , oxidized spiked compounds and reduced estrogenicity (EEQ) at low doses. Recalcitrant chlorinated hydrocarbons such as TCEP were only moderately removed by the tested AOPs, but low doses of O₃ (3 ppm residual O₃) reduced estrogenic activity by 99%. Like other disinfection processes, AOP performance is dependant on pretreatment, especially concerning particulates.</p> / Dissertation

<p>Large amounts of human pharmaceutical products are consumed worldwide. Many drugs and their metabolites, referred to as pharmaceutically active compounds (PhACs), are not fully metabolized prior to household discharge resulting in their common occurrence in wastewater treatment plants (WWTPs). In most instances, WWTPs present the first treatment opportunity for removing PhACs and preventing significant environmental exposure. Because most municipal WWTPs rely on the microbial component of the activated sludge process, there is a need to estimate the influence of PhACs in wastewater influent on the activated sludge microbial communities and the treatment performance of WWTPs. The objective of this dissertation was to determine the impact of selected PhACs (i.e., ketoprofen, naproxen, clofibric acid, carbamazepine and gemfibrozil) on activated sludge microorganisms and key individual microbial species in domestic wastewater treatment. Analyses were performed in batch reactors initially and then in laboratory-scale sequencing batch reactors (SBR) which mimic WWTP operations. Ammonia oxidizing bacteria (AOB) were selected as indicator organisms because of their importance in wastewater treatment and demonstrated sensitiveness to toxic compounds. </p><p>The batch experiments results suggested that microbial growth inhibition was correlated to organic loadings. In the presence of 0.2% (v/v) ethanol, significant inhibition, ranging from 34 to 43%, was observed for all PhACs other than clofibric acid. </p><p>Nitrification inhibition studies using Nitrosomonas europaea, a model AOB strain showed that ketoprofen, naproxen, carbamazepine and gemfibrozil inhibited nitrite production. The corresponding maximum nitrification inhibition rates were 25, 29, 22 and 26%, respectively. Inhibition was shown to increase with PhAC concentration for concentrations greater than 0.1 µM. Results from membrane integrity tests suggest that the inhibition may be due to the disturbance of the cell membrane by PhACs and such inhibition was shown to be irreversible. </p><p>Even though PhACs were shown to inhibit the nitrification rate in pure culture studies, the performance of SBRs exposed to individual PhACs was not adversely affected neither in terms of COD nor ammonia removal. Microbial fingerprinting for both total bacteria and AOB confirmed that no significant shifts occurred when microbial communities were exposed to PhACs. However, some PhACs introduced in binary mixture were found to both inhibit the nitrification of N. europaea as well as the performance of SBRs. The mixture composed of 0.5 &#956;M ketoprofen and 0.5 &#956;M naproxen showed significant inhibition (25%) on the nitrite production of N. europaea although neither 0.5 &#956;M ketoprofen nor 0.5 &#956;M naproxen had significant effect when presented alone. Similarly, both COD and ammonia removal were significantly impacted by binary mixtures of PhACs. These results suggest that mixture effects can play an important role in an overall treatment's nitrification potential and this phenomenon should be further investigated.</p> / Dissertation