Thesis (MScEng (Process Engineering))--University of Stellenbosch, 2010. / ENGLISH ABSTRACT: Mass transfer efficiency in distillation, absorption and stripping depends on both thermodynamic efficiency and hydrodynamic behaviour. Thermodynamic efficiency is dependent on the system kinetics while hydrodynamics is the study of fluid flow behaviour. The focus of this thesis is the hydrodynamic behaviour in tray columns, which affects entrainment. In order to isolate hydrodynamic behaviour from the thermodynamic behaviour that occurs inside sieve tray columns, investigations are conducted under conditions of zero mass transfer. When the gas velocity is sufficiently high to transport liquid droplets to the tray above, entrainment occurs. The onset of entrainment is one of the operating limits that determines the design of the column and thus impacts on the capital cost. By improving the understanding of the parameters that affect entrainment, the design of the tray and column can be improved which will ultimately increase the operability and capacity while reducing capital costs. Existing correlations predicting entrainment in sieve tray columns are based on data generated mainly from an air/water system. Previous publications recommend that more testing should be performed over larger ranges of gas and liquid physical properties. An experimental setup was therefore designed and constructed to test the influence of the following parameters on entrainment: 1. gas and liquid physical properties 2. gas and liquid flow rates 3. tray spacing The experimental setup can also measure weeping rates for a continuation of this project. The hydrodynamic performance of a sieve tray was tested with air and water over a wide range of gas and liquid flow rates and at different downcomer escape areas. It was found that the downcomer escape area should be sized so that the liquid escaping the downcomer always exceeds a velocity of approximately 0.23 m/s in order to create a sufficient liquid seal in the downcomer. For liquid velocities between 0.23 and 0.6 m/s the area of escape did not have an effect on the percentage of liquid entrained. It was also established that entrainment increases with increasing gas velocity. The rate at which entrainment increases as the gas velocity increase depends on the liquid flow rate. As soon as the liquid flow rate exceeded 74 m3/(h.m) a significant increase in entrainment was noted and the gas velocity had to be reduced to maintain a constant entrainment rate. This is because the increased liquid load requires a longer flow path length for the froth to fully develop. The undeveloped froth, caused by the short (455 mm) flow path, then creates a non-uniform froth that is pushed up against the column wall above the downcomer. Consequently, the froth layer is closer to the tray above resulting in most of the droplets ejected from the froth reaching the tray above and increasing entrainment. By reducing the gas velocity, the froth height and ejecting droplet velocity is reduced, resulting in a decrease in entrainment. The results from the experiments followed similar trends to most of the entrainment prediction correlations found in literature, except for the change noted in liquid flow rates above 74 m3/(h.m). There was, however, a significant difference between the experimental results and the correlations developed by Hunt et al. (1955) and Kister and Haas (1988). Although the gas velocities used during the air/water experiments were beyond the suggested range of application developed by Bennett et al. (1995) their air/water correlation followed the results very well. The entrainment prediction correlation developed by Bennett et al. (1995) for non-air/water systems was compared with the experimental air/water results to test for system uniformity. A significant difference was noted between their non-air/water prediction correlation and the air/water results, which motivates the need for a general entrainment prediction correlation over a wider range of gas and liquid physical properties. Based on the shortcomings found in the literature and the observations made during the experiments it is suggested that the influence of liquid flow path length should be investigated so that the effect on entrainment can be quantified. No single correlation was found in the literature, which accurately predicts entrainment for a large range of liquid loads (17 – 112 m3/(h.m)), high superficial gas velocities (3 – 4.6 m/s) and different gas and liquid physical properties. It is therefore recommended that more work be done, as an extension of this project, to investigate the influence of gas and liquid physical properties on entrainment (under zero mass transfer conditions) for a large range of liquid (5 – 74 m3/(h.m)) and gas (2 – 4.6 m/s) flow rates. In order to understand the effect of droplet drag on entrainment, tray spacing should be varied and increased to the extent where droplet ejection velocity is no longer the mechanism for entrainment and droplet drag is responsible for droplet transport to the tray above. Since it is difficult and in most cases impossible to measure exact gas and liquid loads in commercial columns, another method is required to measure or determine entrainment. Since liquid hold-up was found to be directly related to the entrainment rate (Hunt et al. (1955), Payne and Prince (1977) and Van Sinderen et al. (2003) to name but a few), it is suggested that a correlation should be developed between the dynamic pressure drop (liquid hold-up) and entrainment. This will contribute significantly to commercial column operation from a hydrodynamic point of view.

Thesis (PhD (Earth Sciences))--University of Stellenbosch, 2010. / ENGLISH SUMMARY: S-type granite intrusions are extremely common in the continental crust and form from the partial melting of metasediments. Compositions of S-type granite range from leucogranite to granodiorite and have trace element contents that globally increase with increasing maficity (Fe + Mg). Models proposed for the formation of S-type granite do not answer satisfactorily all petrological and compositional requirements. In this study, S-type granite of the Cape Granite Suite (CGS), South Africa is used to discriminate between potential sources of compositional variation. Experimental studies show that melt produced from the partial melting of sediment is exclusively leucocratic. On this basis, the entrainment of up to 20 wt.% of peritectic garnet within S-type melt can be established to produce the observed major element variations. S-type CGS locally contains garnet. This garnet is in equilibrium with granite composition at P-T conditions (5kb and 750 C for the core of the garnet and 3kb and 720 C for the rim) well below conditions recorded by xenoliths from the same granite (10 kb and 850 C from a metabasite). From this result it seems that the originally entrained garnet no longer exists in the Stype CGS and it have been replaced by newly formed minerals (garnet, cordierite and biotite). Considering the short time necessary to emplace granites (about 100 000 years), it appears that garnet has been compositionnally re-equilibrated through a dissolution-precipitation process. The study of trace element variations in S-type CGS shows that most leucocratic compositions are undersaturated in Zr and Ce compared to predictions from experimental models for dissolution of accessory zircon and monazite in their source regions. Thus, S-type melts are likely to be formed in disequilibrium with respect to accessory phase stability. As a result the observed increase in trace element content with increasing maficity indicates that accessory minerals such as zircon and monazite are co-entrained with peritectic garnet in melt to produce the observed trace element variation in S-type granite. Trace element disequilibrium in the CGS S-type granitoids requires particularly short times of residence of melt within the source region. Together, these results provide for the first time, a fully comprehensive model for major and trace elements variations. Compositional variation in CGS S-type granite results from source processes by a selective entrainment of peritectic and accessory minerals. After entrainment, these minerals are likely to be re-equilibrated within the magma, through a dissolution-reprecipitation process. In addition, it appears that the construction of large S-type granitic bodies occurs through successive addition of magma batches of different composition that originates directly from the source region. / AFRIKAANSE OPSOMMING: S-tipe granietinstrusies is baie algemeen in die kontinentale kors en vorm deur die gedeeltelike smelting van metasedimente. Samestellings van S-tipe graniete strek vanaf leukograniet tot granodioriet en het spoorelementsamestellings wat global toeneem met ’n toenemende mafiese component (Fe + Mg). Modelle wat voorgestel is vir die formasie van S-tipe graniete beantwoord nie bevredigend al die petrologiese en komposisionele benodigdhede nie. In hierdie studie word S-tipe graniete van die Kaapse Graniet Suite (CGS), Suid Afrika, gebruik om te diskrimineer tussen potensiele bronne van komposisionele variasie. Eksperimentele studies wys dat smelt, geproduseer van die gedeeltelike smelting van sedimente, uitsluitlik leukokraties is. Op hierdie basis kan bewys word, dat die optel-en-meevoering van tot 20 wt% van peritektiese granaat in S-tipe smelt, die waargeneemde hoofelement variasies kan produseer. S-tipe CGS bevat lokale granaat. Hierdie granaat is in ekwilibrium met die graniet samestelling by P-T kondisies (5kb en 750circC vir die kern van die granaat en 3kb en 720circC vir die rand) ver onder kondisies waargeneem by xenoliete van dieselfde granite (10kb en 850circC van ’n metabasiet). Van hierdie resultaat kan afgelei word dat die oorspronklike opgetel-en-meegevoerde graniet bestaan nie meer in die S-tipe CGS en dat dit vervang is deur nuutgevormde minerale (granaat, kordieriet en biotiet). As in ag geneem word die kort tyd wat nodig is om graniete in te plaas (omtrent 100 000 jaar), wil dit voorkom dat granaat se samestelling geherekwilibreer word deur ’n oplossings-presipitasie proses. Die studie van spoorelement variasies in S-tipe CGS wys dat meeste leukokratiese samestellings is onderversadig in Zr en Ce in vergelyking met voorspellings deur eksperimentele modelle vir die oplossing van bykomstige zircon en monasiet in hulle brongebiede. Dus is S-tipe smelte meer geneig om gevorm te word in disekwilibrium in verhouding tot bykomstige mineraalstabilileit. Met die gevolg is dat die waargenome toename in spoorelementinhoud met toename in mafiese component wys dat bykomstige minerale, soos zirkoon en monasiet, word saam opgetel-enmeegevoer met peritektiese granaat in smelt om die waargenome spoorelement variasie in S-tipe graniete te verklaar. Spoorelement disekwilibrium in die CGS S-tipe granitoide benodig veral kort tye van residensie van die smelt binne die brongebied. Saam gee hierdie resultate vir die eerste keer ’n algehele antwoord vir hoof- en spoorelement variasies. Variasie in samestelling in CGS S-tipe graniete is die resultaat van bronprosesse deur ’n selektiewe optel-en-meevoer van peritektiese en bykomstige minerale. Na die optel-en-meevoer van hierdie minerale word hulle geherekwilibreer binne die magma deur ’n oplossings-presipitasie proses. Addisioneel wil dit voorkom of die konstruksie van groot S-tipe granietliggame plaasvind deur opeenvolgende toevoegings van magma lotte van verskillende samestellings wat direk uit die brongebied kom.

The objective of a coating operation is to transfer a defect free liquid film onto a continuous substrate in order to meet the requirements of the final products. Mainly two concerns govern the process. The first concern is the economics of the process and the second concern is the quality of the coated film. The economics of the process are dictated by the speed of coating and the film thickness. Clearly, higher speeds mean better productivity hence less cost of operation and thinner films are desirable because less material is being used. Quality is governed by film uniformity and integrity, indicating that the film will perform as designed. Film defects such as streaks or tiny air bubbles are indication that the film properties are not uniform rendering it unacceptable to customers. One of the most versatile coating systems to achieve thin films at high speeds is reverse roll coating which has been used for a long time all over the world. At low speed, typically 1m/s, this coating operation is inherently stable and with small gaps of order 100 microns can ii lead to film thickness of order 30-50 microns. Much research, theoretical and experimental, has been devoted to this coating flow but only at low speeds and for large gaps (>100 microns). There are no comprehensive data how very thin films, 20 microns and less (particularly lower limits in the region of 5 microns) can be achieved at high speeds, of 2 or more metres per second. This study is concerned precisely with this aim, that of investigating the effect of large speeds and small roller gaps (rollers nearly touching or in elastohydrodynamic contact) to achieve the very thin films desired by modern applications (electronics, medical and others). In order to achieve this aim, a rig was designed and built to enable to understand the effect of various coating conditions and liquid properties on the metered film thickness and coating instability. To achieve thin films at high speeds, small roll gap and low viscosity are needed, however flow instabilities will develop under these conditions. To achieve stable coating window at high speeds high surface tension is needed. It was found that the roll gap and the viscosity have complicated effect on the coating window. In the case of low viscosity liquid (7mPa.s), small roll gaps are needed, whereas in the case of high viscosity liquid (more than 30mPa.s), large gaps are needed. It was found that Weber number is better describer for ribbing instability in rigid reverse roll coating unlike in rigid forward roll coating in which capillary number is the one. In addition the potential of reverse deformable roll coating (rolls in elastohydrodynamic contact) was investigated in order to achieve much thinner films at higher speeds. As a result of the investigation of reverse deformable roll coating, it was found that there is a possibility to get much thinner stable films at much higher speeds compared to reverse rigid roll coating. The liquid transfer from an applicator roller to a PET film was investigated in this study. It was found that air stagnation at downstream meniscus and air entrainment at upstream meniscus depend on the liquid properties such as viscosity and surface tension and coating conditions such as web tension and wrap angle of web. As a result, wet film instability also depends on liquid properties and coating conditions. It was found that air stagnation causes streaks on the wet film and air entrainment caused bubbles on the wet film. To get a stable wet film, it was found that suitable viscosity and high surface tension were needed.

In all coating applications, a liquid film displaces air in contact with a dry solid substrate. At a low substrate speed a thin uniform wetting line is formed on the substrates surface, but at a high speed the wetting line becomes segmented and unsteady as air becomes entrained between the substrate and the liquid. These air bubbles affect the quality of the coated product and any means to postpone this at higher speeds without changing the specifications of the coating liquid is desirable. This research assesses the validity of a theoretically based concept developed by Blake and Rushack [1] and exploited by Cohu and Benkreira [2] for dip coating. The concept suggests that angling the wetting line by an angle ß would increase the speed at which air is entrained by a factor 1/cos ß. In practice, if achieved this is a significant increase that would result in more economical operation. This concept was tested in a fast coating operation that of curtain coating which is already enhanced by what is known as hydrodynamic assistance [2]. Here we are effectively checking an additional assistance to wetting. The work, performed on a purposed built curtain coater and a rotating die, with a range of fluids showed the concept to hold but provided the data are processed in a way that separate the effect of curtain impingement from the slanting of the wetting line.

La perception explicite du temps écoulé (la durée, l'ordre temporel¿) et les jugements implicites des dynamiques de notre environnement (percevoir le mouvement, la parole) nécessitent l'extraction des relations temporelles entre événements sensoriels. Alors que le temps physique est communément évalué en rapport à un référentiel externe (celui de l'horloge), le cerveau lui n'a pas accès à ce référentiel. Dans cette thèse, nous émettons l'hypothèse que le cerveau génère son propre référentiel temporel à partir des dynamiques neurales. Combinant la magnétoencéphalographie (MEG) aux données psychophysiques, les présents travaux suggèrent que les oscillations corticales sont impliquées dans l'encodage du temps perçu. Une première étude montre que la phase des oscillations corticales basse-fréquences peut encoder l'ordre temporel perçu entre événements sensoriels s'il y a entrainement neural, i.e. si l'activité cérébrale suit les régularités temporelles de la stimulation. L'implication des oscillations cérébrales en l'absence d'entrainement est testée dans une seconde expérience. Les résultats d'une troisième expérience suggèrent que l'entrainement neural n'a d'influence sur le traitement temporel des informations multisensorielles qu'à basse fréquence (1-2 Hz). Un dernier chapitre aborde le rôle de l'entrainement neural dans l'encodage des dynamiques du signal acoustique pour la perception de la parole. En conclusion, cette thèse suggère que le cerveau est capable de suivre la structure temporelle du monde extérieur, et que cet ajustement permet la construction d'un référentiel temporel interne pour la perception explicite et implicite du temps. / The timing of sensory events is a crucial perceptual feature, which affects both explicit judgments of time (e.g. duration, temporal order) and implicit temporal perception (e.g. movement, speech). Yet, while the relative external timing between events is commonly evaluated with a clock in physics, the brain does not have access to this external reference. In this dissertation, we tested the hypothesis that the brain should recover the temporal information of the environment from its own dynamics. Using magnetoencephalography (MEG) combined with psychophysics, the experimental work suggests the involvement of cortical oscillations in the encoding of timing for perception. In the first part of this dissertation, we established that the phase of low-frequency cortical oscillations could encode the explicit timing of events in the context of entrainment, i.e. if neural activity follows the temporal regularities of the stimulation. The implications of brain oscillations for the encoding of timing in the absence of external temporal regularities were investigated in a second experiment. Results from a third experiment suggest that entrainment does only influence audiovisual temporal processing when bound to low-frequency dynamics in the delta range (1-2 Hz). In the last part of the dissertation, we tested whether oscillations in sensory cortex could also ‘tag’ the timing of acoustical features for speech perception. Overall, this thesis provides evidence that the brain is able to tune its timing to match the temporal structure of the environment, and that such tuning may be crucial to build up internal temporal reference frames for explicit and implicit timing perception.

A new quasi-dimensional, multi-zone model has been developed to describe the combustion processes occurring inside a dual fuel engine. A dual fuel engine is a compression ignition engine in which a homogeneous lean premixed charge of gaseous fuel and air is ignited by a pilot fuel spray. The atomisation and preparation of the pilot leads to the formation of multiple ignition centres from which turbulent flame fronts develop. The energy release in a dual fuel engine is therefore a combination of that from the combustion of the pilot fuel spray and lean premixed charge. Hence, the dual fuel combustion process is complex, combining elements of both conventional spark and compression ignition engines. The dual fuel engine is beneficial as it can achieve significant reductions in emissions of carbon dioxide (CO2), as well as reducing emissions of oxides of nitrogen (NOx) and particulate matter (PM).

abstract: With advances in automatic speech recognition, spoken dialogue systems are assuming increasingly social roles. There is a growing need for these systems to be socially responsive, capable of building rapport with users. In human-human interactions, rapport is critical to patient-doctor communication, conflict resolution, educational interactions, and social engagement. Rapport between people promotes successful collaboration, motivation, and task success. Dialogue systems which can build rapport with their user may produce similar effects, personalizing interactions to create better outcomes. This dissertation focuses on how dialogue systems can build rapport utilizing acoustic-prosodic entrainment. Acoustic-prosodic entrainment occurs when individuals adapt their acoustic-prosodic features of speech, such as tone of voice or loudness, to one another over the course of a conversation. Correlated with liking and task success, a dialogue system which entrains may enhance rapport. Entrainment, however, is very challenging to model. People entrain on different features in many ways and how to design entrainment to build rapport is unclear. The first goal of this dissertation is to explore how acoustic-prosodic entrainment can be modeled to build rapport. Towards this goal, this work presents a series of studies comparing, evaluating, and iterating on the design of entrainment, motivated and informed by human-human dialogue. These models of entrainment are implemented in the dialogue system of a robotic learning companion. Learning companions are educational agents that engage students socially to increase motivation and facilitate learning. As a learning companion’s ability to be socially responsive increases, so do vital learning outcomes. A second goal of this dissertation is to explore the effects of entrainment on concrete outcomes such as learning in interactions with robotic learning companions. This dissertation results in contributions both technical and theoretical. Technical contributions include a robust and modular dialogue system capable of producing prosodic entrainment and other socially-responsive behavior. One of the first systems of its kind, the results demonstrate that an entraining, social learning companion can positively build rapport and increase learning. This dissertation provides support for exploring phenomena like entrainment to enhance factors such as rapport and learning and provides a platform with which to explore these phenomena in future work. / Dissertation/Thesis / Doctoral Dissertation Computer Science 2018

Vortex drop shafts are used to transport water or wastewater from over-stressed existing sewer systems to underground tunnels. During the plunge a large amount of air is entrained into the water and released downstream of the drop shaft into the tunnel. This air is unwanted and becomes costly to treat and move back to the surface. Determining the amount of air that will be entrained is a difficult task. A common method is to build a scale model and measure the air discharge and scale it back to prototype. This study investigated a possible relationship between the geometry of the drop structure, the water discharge and the amount of air entrained. The results have shown that air entrainment is still not entirely understood, however we are close to a solution. Using a relationship of the air core diameter, drop shaft length and terminal velocity of the water, a likely exponential relationship has been developed.

The majority of dams contain low-level outlet works, which typically consist of closed conduits that run through the dam, and are used to release water from the reservoir when the water level is below the level of the surface spillways. It is also used to flush the reservoir of sediments and to control the elevation of the reservoir. Low-level outlet works typically consist of a gate that controls the flow within a closed conduit that runs through the dam and an air vent that supplies air behind the gate. In the absence of properly designed air vents, negative pressures may develop downstream of the gate. These negative pressures could potentially lead to cavitation and vibration damage. Properly sized air vents help maintain the downstream air pressure at or near atmospheric pressure and/or provide air to absorb the energy generated by cavitation, reducing the potential for damage. The majority of research done on air vent sizing is for dams having large dam geometry, which consist of a pressurized conduit leading to a vertical slide gate that is followed by a discharge tunnel. The typical air vent design for these large dams uses the water flow rate and the Froude number measured at the vena contracta downstream of the gate. The low-level outlet works for small-to-medium-sized embankment dam geometries typically have an inclined slide gate, installed at the inlet on the upstream face of the dam slope, followed by an elbow that connects to a conduit that passes through the dam and discharges downstream. This type of outlet geometry does not produce the typical vena contracta. Consequently, the use of the Froude number, at the vena contracta , as a characteristic parameter for characterizing airflow demand is not practical. Recently a laboratory study was performed calculating the head-discharge characteristics of low-level outlets for small-to-medium sized dam geometries. In addition to validating some of the previous laboratory-scale air venting research, the objective of this study was field verification of air-demand/air vent sizing predicted by the laboratory-based method. The influence of conduit slope, air port location, and hydraulic jumps on air demand was also evaluated in the laboratory. The findings of this study can be found within this thesis.

L'une des principales missions de l'Ifremer consiste à étudier les ressources sous-marines et les fonds marins via une flotte océanographique importante, employée à travers le globe. Pour ce faire, les navires sont équipés d'équipements acoustiques de type SONAR afin d'obtenir les informations recherchées dans la colonne d'eau. Dans certaines conditions de navigation, la houle et les mouvements du navire génèrent un entraînement d'air conséquent sous la surface. Des nuages de bulles sont ainsi formés et entraînés sous la carène par l'écoulement. L'interaction entre ces bulles et les ondes acoustiques peuvent entraîner des pertes de données, et par conséquent une diminution importante de la productivité du navire. Les outils permettant l'étude du phénomène sont actuellement limités. Les modèles numériques ne sont pas suffisamment performants, pour simuler conjointement les mécanismes d'entraînement d'air à l'étrave puis l'écoulement dysphasique autour de la carène, et les essais classiques en bassin de traction ne donnent pas entière satisfaction. Dans le cadre de cette thèse, une méthode d'essai spécifique, pour l'étude de ce phénomène, a été développée et mise en place au bassin à houle et courant de l'Ifremer. Cette méthode nécessite la synchronisation entre un générateur de houle et un générateur de mouvement (hexapode), permettant d'imposer les mouvements calculés au préalable par simulation numérique à la maquette. Cette configuration permet d'étudier indépendamment les effets de la houle et des mouvements sur la génération des bulles. L'instrumentation employée permet de filmer et de caractériser l'entraînement d'air à l'étrave de la maquette. Deux mécanismes distincts ont été observés : la génération de bulles par entraînement tourbillonnaire ou par le déferlement de la vague d'étrave. Une méthode de traitement d'image a été élaborée pour analyser ces mécanismes pour de nombreuses configurations d'essais. Une étude paramétrique a été réalisée afin de calculer la fréquence de génération de bulles en fonction de chaque paramètre d'essai. Des mesures PIV de l'écoulement permettent de corréler la dynamique des nuages de bulles et de l'écoulement. L'ensemble des résultats obtenus permet d'apporter des éléments nouveaux pour la compréhension et l'étude du phénomène, avec la perspective d'obtenir un outil fiable facilitant la conception des navires océanographiques. / One of the main assignments of Ifremer is to study the seabed and the resources undersea, through a large oceanographic fleet used across the globe. For that purpose, ships are equipped with different kinds of SONAR (SOund Navigation And Ranging) to obtain the information sought in the water column. In some sea conditions, waves and ship motions generate significant air entrainment below the surface. Bubble clouds are then carried under the hull by the flow. The interaction between these bubbles and the acoustic waves may result in data loss, and therefore in a considerable reduction of the vessel’s productivity. The tools used to study this phenomenon are currently limited : the numerical models are not efficient enough to simulate at a time air entrainment at the bow and the two phase flow around the hull. On the other hand conventional towing tank tests are not entirely satisfactory. During this PhD research work, a specific test method to study this phenomenon has been developed and implemented at the Ifremer wave and current tank. This method requires the synchronization between a wave generator and a movement generator (hexapod) that enables to force the model motions, calculated in advance by numerical simulations. With this configuration, the effects of waves or motions characteristics on the bubbles generation can be studied independently. A complete instrumentation allowed to acquire images sequences to characterize the air entrainment at the bow of the model. Two distinct mechanisms have been observed : the generation of bubbles by vortex shedding or by the breaking bow wave. A post-processing method has been developed to analyse these mechanisms, for many test configurations. A parametric study was performed to calculate the frequency of bubbles generation for each test parameter. PIV measurements allowed to correlate the dynamic of bubbles clouds with the own flow dynamic. The overall results provide new elements for the understanding and the study of the phenomenon, with the final objective of obtaining a reliable tool that facilitates the design of research vessels.