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Natural fibers have the potential to replace glass fibers in fiber-reinforced composite applications. However, the natural fibers’ intrinsic properties cause these issues: 1) the mechanical property variation; 2) moisture uptake by natural fibers and their composites; 3) lack of sound, cost-effective, environmentriendly fiber-matrix compounding processes; 4) incompatibility between natural fibers and polymer matrices; and 5) low heat-resistance of natural fibers and their composites. This dissertation systematically studied the use of kenaf bast fiber bundles, obtained via a mechanical retting method, as a light-weight reinforcement material for fiber-reinforced thermoset polymer composites for automotive applications. Kenaf bast fiber bundle tensile properties were tested, and the effects of locations in the kenaf plant, loading rates, retting methods, and high temperature treatments and their durations on kenaf bast fiber bundle tensile properties were evaluated. A process has been developed for fabricating high fiber loading kenaf bast fiber bundle-reinforced unsaturated polyester composites. The generated composites possessed high elastic moduli and their tensile strengths were close to specification requirements for glass fiber-reinforced sheet molding compounds. Effects of fiber loadings and lengths on resultant composite’s tensile properties were evaluated. Fiber loadings were very important for composite tensile modulus. Both fiber loadings and fiber lengths were important for composite tensile strengths. The distributions of composite tensile, flexural and impact strengths were analyzed. The 2-parameter Weibull model was found to be the most appropriate for describing the composite strength distributions and provided the most conservative design values. Kenaf-reinforced unsaturated polyester composites were also proved to be more cost-effective than glass fiber-reinforced SMCs at high fiber loadings. Kenaf bast fiber bundle-reinforced composite’s water absorption properties were tested. Surface-coating and edge-sealing significantly reduced composite water resistance properties. Encapsulation was a practical method to improve composite water resistance properties. The molding pressure and styrene concentrations on composite and matrix properties were evaluated. Laser and plasma treatment improved fiber-to-matrix adhesion.

Telecommunication networks based on optical fiber technology have become a major information-transmission system, satisfying the growing demand for bandwidth due to increased internet traffic and other applications such as video on demand, etc. Fiber Bragg gratings (FBGs), in recent years, have emerged as critical components for enabling high-capacity transmission since their response can be tailored to meet the needs of specific applications. FBGs are currently the focus of intense research interest in both the fiber communications and sensing fields. Optical fiber Bragg grating structures in single-mode fiber (SMFBGs) have been studied extensively since the discovery of photosensitivity in germanium-doped silica fiber. They have been used in numerous applications ranging from wavelength-selective filtering in wavelength-division-multiple-access (WDMA) systems to temperature and strain sensing. To a lesser extent, Bragg gratings in multimode fibers have also received attention because of easy coupling with light sources. Most of the MMFBGs related research work has demonstrated the formation of a Bragg grating in a graded-index MMF and briefly reported the measured transmission spectrum. So far, there are few theoretical studies on Bragg gratings in multimode fibers. In this thesis, we investigate Bragg gratings in multimode optical fibers both theoretically and experimentally. A comprehensive numerical model for MMFBGs has been established and the corresponding computer simulation software (MMFBG simulator combined with mode solver) developed. The optical properties of MMFBGs were systematically studied for the first time using our own MMFBG numerical software package. It effectively assists the design modeling for MMFBG-based optical devices. Bragg gratings in multimode fiber were also investigated experimentally. Our theoretical simulation results show good agreement with experiments and offer the insightful explanations for the underlying physics of the device. First, the guided modes were modeled and simulated for step index multimode fibers and graded index multimode fibers with emphasis on parabolic fiber structure. These are popular, standard and commercially available MM fibers, and employed throughout our experiments. This allows us for the simulation of fiber characteristics such as cut-off wavelength, mode effective index, propagation constants and optical field distribution. It also allows for calculation of mode coupling coefficients by overlap integral between any chosen guided modes. Therefore, it serves as a powerful model for the design and analysis of optical fibers. Second, the generalized MMFBG coupled mode theory formalism is derived. The physical mechanism of the behavior of MMFBGs is studied and discussed. The general solution to the MMF Bragg grating problem is achieved by Runge-Kutta, Newton-Raphson and shooting numerical methods. Our theoretical treatment, in particular, offers the advantages which can deal with not only self-coupling but also more complicated cross-coupling interactions and can solve arbitrary large number of mode coupling problems throughout the entire spectra simultaneously for multimode FBGs, thus allowing for a precise and quantitative study of MMFBGs. Such an intensive multimode fiber Bragg grating physical modeling and simulations have not been reported previously. It provides an effective means for the design and analysis of optical fiber devices based on Bragg gratings. Third, the optical properties of multimode FBGs were studies experimentally. Numerical predications of the grating spectral characteristics under fabrication and experimental condition are calculated. The results of the numerical calculations are compared with experimentally measured spectra of multimode gratings written by ultraviolet irradiation of deuterium-sensitized fiber with grating reflectivities ranging from 78% to 99.39%. Good agreement is obtained between the theoretical simulations and the experimental results. Thus, we provide quantitative explanations for the observed experimental phenomena. These explanations give both physical insight and a more complete understanding of the nature of the interaction between the wave propagation and multimode fiber gratings. Furthermore, the spectral simulation of the actual experiments prepares a theoretical guidance for the advanced experimental investigation and also presents a step toward MMFBG device design. Finally, the optical properties of MMFBGs were also studied theoretically. To our knowledge, this is the first detailed analysis and thorough investigation on grating characteristics in MMF. It is demonstrated that the transmission and reflection spectra of fiber Bragg gratings in multimode optical fibers strongly depend on the length of grating, index modulation, period of grating, mode excitation condition and physical structure of MMF. The simulation results allow us to deeply comprehend and visualize the more sophisticated behavior within a multimode fiber grating, and will also allow us to confidently predict and evaluate the performance of more complex structure MMFBGs. It provides the fundamental principles for designing the targeted spectrum performance and settles the theoretical rationale for realizing the practical applications. Overall, the comprehensive numerical model and MMFBG solver package developed in this thesis opens a clear and broad window for understanding MMFBG mechanisms from the physical point of view. Various simulation results and spectral characteristics have been researched and discussed under both ideal and experimental conditions for the purpose of experimental analysis and device design. The results of our study indicate that a new class of potential applications based on MMFBGs can be expected in optical fiber sensors and advanced communication systems. / Thesis / Master of Applied Science (MASc)

To fulfill the objective of providing robust and reliable fiber optic pressure sensors capable of operating in harsh environments, this dissertation presents the detailed research work on the design, modeling, implementation, analysis, and performance evaluation of the novel fiber optic self-calibrated interferometric/intensity-based (SCIIB) pressure sensor system. By self-referencing its two channels outputs, for the first time to our knowledge, the developed SCIIB technology can fully compensate for the fluctuation of source power and the variations of fiber losses. Based on the SCIIB principle, both multimode and single-mode fiber-based SCIIB sensor systems were designed and successfully implemented. To achieve all the potential advantages of the SCIIB technology, the novel controlled thermal bonding method was proposed, designed, and developed to fabricate high performance fiber optic Fabry-Perot sensor probes with excellent mechanical strength and temperature stability. Mathematical models of the sensor in response to the pressure and temperature are studied to provide a guideline for optimal design of the sensor probe. The solid and detailed noise analysis is also presented to provide a better understanding of the performance limitation of the SCIIB system. Based on the system noise analysis results, optimization measures are proposed to improve the system performance. Extensive experiments have also been conducted to systematically evaluate the performance of the instrumentation systems and the sensor probes. The major test results give us the confidence to believe that the development of the fiber optic SCIIB pressure sensor system provides a reliable pressure measurement tool capable of operating in high pressure, high temperature harsh environments. / Ph. D.

In this report, detailed and systematic theoretical and experimental study of low-finesse extrinsic Fabry-Perot interferometric (EFPI) fiber optic sensors together with their signal processing methods for white-light systems are presented. The work aims to provide a better understanding of the operational principle of EFPI fiber optic sensors, and is useful and important in the design, optimization, fabrication and application of single mode fiber(SMF) EFPI (SMF-EFPI) and multimode fiber (MMF) EFPI (MMF-EFPI) sensor systems. The cases for SMF-EFPI and MMF-EFPI sensors are separately considered. In the analysis of SMF-EFPI sensors, the light transmitted in the fiber is approximated by a Gaussian beam and the obtained spectral transfer function of the sensors includes an extra phase shift due to the light coupling in the fiber end-face. This extra phase shift has not been addressed by previous researchers and is of great importance for high accuracy and high resolution signal processing of white-light SMF-EFPI systems. Fringe visibility degradation due to gap-length increase and sensor imperfections is studied. The results indicate that the fringe visibility of a SMF-EFPI sensor is relatively insensitive to the gap-length change and sensor imperfections. Based on the spectral fringe pattern predicated by the theory of SMF-EFPI sensors, a novel curve fitting signal processing method (Type 1 curve-fitting method) is presented for white-light SMF-EFPI sensor systems. Other spectral domain signal processing methods including the wavelength-tracking, the Type 2-3 curve fitting, Fourier transform, and two-point interrogation methods are reviewed and systematically analyzed. Experiments were carried out to compare the performances of these signal processing methods. The results have shown that the Type 1 curve fitting method achieves high accuracy, high resolution, large dynamic range, and the capability of absolute measurement at the same time, while others either have less resolution, or are not capable of absolute measurement. Very different from SMF-EFPI sensors, MMF-EFPI sensors with high fringe visibility usually are more difficult to obtain in practice because the fringe visibility of a MMF-EFPI sensor is much more sensitive to gap-length change and sensor head imperfections. %Previously, only geometric-optics are available to analyze MMF-EFPI sensors which approximate the light in MMF as rays propagating in different directions. Geometric-optics theory has fundenmental limitations because it is approximate and only valid for limited conditions. Moreover, geometric-optics theory is not capable of poviding the exact fringe pattern which is important in the signal processing of white light MMF-EFPI sensor systems. In this report, Previous mathematical models for MMF-EFPI sensors are all based on geometric optics; therefore their applications have many limitations. In this report, a modal theory is developed that can be used in any situations and is more accurate. The mathematical description of the spectral fringes of MMF-EFPI sensors is obtained by the modal theory. Effect on the fringe visibility of system parameters, including the sensor head structure, the fiber parameters, and the mode power distribution in the MMF of the MMF-EFPI sensors, is analyzed. Experiments were carried out to validate the theory. Fundamental mechanism that causes the degradation of the fringe visibility in MMF-EFPI sensors are revealed. It is shown that, in some situations at which the fringe visibility is important and difficult to achieve, a simple method of launching the light into the MMF-EFPI sensor system from the output of a SMF could be used to improve the fringe visibility and to ease the fabrication difficulties of MMF-EFPI sensors. Signal processing methods that are well-understood in white-light SMF-EFPI sensor systems may exhibit new aspects when they are applied to white-light MMF-EFPI sensor systems. This report reveals that the variations of mode power distribution (MPD) in the MMF could cause phase variations of the spectral fringes from a MMF-EFPI sensor and introduce measurement errors for a signal processing method in which the phase information is used. This MPD effect on the wavelength-tracking method in white-light MMF-EFPI sensors is theoretically analyzed. The fringe phases changes caused by MPD variations were experimentally observed and thus the MFD effect is validated. / Ph. D.

This work is concerned with mechanical property improvements to poly(ethylene terephthalate), PET, fibers by the addition of layered silicate nanoparticles and by drawing the un-oriented nanocomposite filaments in a second step. No previous studies on PET fibers filled with montmorillonite (MMT) nanoclay examined fiber drawability at temperatures above the glass transition. Therefore, the primary objective of this research was to determine 1) if PET nanocomposite fibers could be drawn to finer diameters and 2) whether drawing imparted improved Young's modulus and tenacity (i.e. strength) relative to un-filled PET fibers. Of equal importance to this work, the subsequent objective was to discern and understand the role of nanoclay in 1) the production of improved or reduced mechanical properties and 2) the ability to draw PET to lower or higher than normal draw ratios. In the first part of this thesis, the improvements in Young's modulus and tenacity of PET fibers filled with various types of organically modified montmorillonite is shown and the method to produce them is discussed. Greater improvements in mechanical properties occurred when the MMT stacks were intercalated with PET. A nominal 1 wt% loading of dimethyl-dehydrogenated tallow quaternary ammonium surface modified MMT in drawn PET fiber showed a 28% and 63% increase in Young's modulus and strength, respectively. Relative to an un-filled PET fiber, these results exceeded the upper-bound of the rule of mixtures estimate. Therefore, both the type of surface modification and concentration of MMT were shown to affect the degree of PET orientation and crystallinity. Furthermore, drawability above Tg and elongation-at-break increased upon the addition of organically modified MMT to un-oriented PET fibers, which was a key distinction of this work from others examining similar systems. Interestingly, the mechanical properties of modulus and tenacity showed a maximum with concentration of alkyl modified clay, but drawability did not show significant variation with increasing nanoclay content. Thermal analysis and Raman spectroscopy was used to examine the role of nanoclay in creating this maximum in mechanical properties. At low loadings, nanoclay was shown to intercalate with PET and enhance amorphous orientation. At higher concentrations of nanoclay the presence of large agglomerates prevented efficient orientation to the fiber axis and acted as stress concentrators to aid in cavitation and failure during testing. Raman spectroscopy showed that the as-spun unfilled PET fibers possessed significantly more trans conformer content of the ethylene glycol moiety than the nanocomposite fibers. The greater gauche content of the nanocomposite fibers delayed crystalline development during non-isothermal DSC scans to higher temperatures was associated with the increased drawability. / Ph. D.

In this dissertation the performance of a novel variant of a return-to-zero (RZ) modulation format, based on square-wave phase modulation and filtering of a continuous-wave (CW) signal, is investigated and compared with various modulation formats considered in the literature. We call this modulation format continuous-wave square-wave (CWSW). With CWSW an RZ pulse train is generated by phase modulating the CW signal by a periodic square-wave phase function having an amplitude of and frequency of half the bit rate, and then filtering the signal. The filter performs phase-to-amplitude conversion, resulting in an alternate-sign RZ pulse train, which is shown to be resistant to fiber dispersion. The alternate-sign RZ pulse train is then amplitude modulated with the data before the transmission. Alternate signs between adjacent pulses makes this signal format robust to impairments caused by the optical fiber, similar to a conventional alternate-sign RZ signal format. However, the unique property of the CWSW signal format is that individual pulses can induce peak intensity enhancement (PIE), a phenomenon by which the peak of a pulse increases during the initial propagation in the presence of dispersion. The PIE in effect delays the decrease in the pulse peak, which represents the signal level for bit 1. Thus, the eye opening at the receiver is improved. An analytically tractable model is developed to explain the occurrence of the PIE, which cannot be achieved with a conventional pulse shape. The sources of performance degradations for different modulation formats in single-channel 40 Gb/s systems are also discussed in this dissertation. Various transmission system configurations of practical interest are considered and the performance of CWSW is compared with alternative modulation formats. It is found that the CWSW signal format performs significantly better than the other considered modulation formats in systems not employing dispersion compensation and is comparable to the others in dispersion-managed systems. Furthermore, the transmitter configuration of the CWSW signal format is simpler than the other approaches. / Ph. D.

Optical fibers provide the means for transmitting large amounts of data from one place to another and are used in high precision sensors. It is important to have a good understanding of the fundamental properties of these devices to continue to improve their applications. A specially type of optical fiber known as a W-fiber has some desirable properties and unique characteristics not found in matched-cladding fibers. A properly designed W- fiber supports a fundamental mode with a finite cutoff wavelength. At discrete wavelengths longer than cutoff, the fundamental mode experiences large amounts of loss. The mechanism for loss can be described in terms of interaction between the fiber's supermodes and the lossy interface at the fiber's surface. Experiments and computer simulations support this model of W-fibers. The property of a finite cutoff wavelength can be used to develop various fiber devices. Under consideration here is the fiber polarizer. The fiber polarizer produces an output that is linearly polarized along one of the fiber's principal axes. Some of the polarizer properties can be understood from the study of W-fibers. / Master of Science