Aboard the International Space Station, potable water will likely be produced from recycled wastewater. The National Aeronautic and Space Administration (NASA) plans to use iodine as a disinfectant, and, consequently, the formation of iodinated disinfection by-products (IDBPs) requires investigation. Objectives of this research were to determine possible precursors of IDBPs, identify IDBPs formed, and apply flavor profile analysis (FPA) as a tool to evaluate water qaulity. Experiments were performed by separately reacting iodine with each of the following organic compounds: methanol, ethanol, 1-propanol, 2-propanol, 1-methoxy-2-propanol, acetone, and formaldehyde. NASA previously identified all of these compounds in wastewater sources under consideration for recycling into potable water. Experiments were performed at pH 5.5 and 8, iodine concentrations of 10 and 50 mg/L, and organic concentrations of 5 and 50 mg/L. Gas chromatography/mass spectrometry was used to identify and monitor the concentrations of organic species. Spectrophotometry was used to monitor the iodine concentration. Acetone was the only compound identified as an IDBP precursor and it reacted to produce iodoacetone and iodoform. Concentrations of iodoform from 0.34 mg/L to 8.637 mg/L were produced at conditions that included each pH level, iodine concentration, and acetone concentration. The greatest iodoform concentration was produced at pH 8 from 50 mg/L of iodine and acetone. FPA indicated that the odor threshold concentration (OTC) of iodoform was 1.5 ug/L, and the OTC of iodine was 500 ug/L. Both iodine and iodoform have medicinal odors, making it difficult to distinguish each compound when present in a mixture. / Master of Science

The National Aeronautics and Space Administration (NASA) is considering the use of iodine for disinfection of recycled wastewater and potable water in the International Space Station (ISS). Like Chlorine and other halogen compounds, iodine can form disinfection by-products (DBPs) in the presence of organic compounds. Recycled wastewater sources proposed for reuse in the space station include laundry, urine, and humidity condensate. These contain large concentrations of iodine-demanding compounds, including phenol (Barkely et al., 1992). Therefore, the potential for the formation of iodine disinfection by-products (IDBPs) is of concern. Based on the characteristics of the ISS recycled wastewater sources and potable water treatment system, a series of experiments was designed to evaluate the formation of IDBPs under different experimental conditions. Studies were conducted by reacting various concentrations of iodine with phenol at pH 5.5 and 8.0.Iodine concentrations of 10 and 50 mg/L and phenol concentrations of 5 and 50 mg/L were used. Reactions were monitored for up to 32 days for the formation of IDBPs. All reactions were maintained at 20 C in dark. High Performance Liquid Chromatography (HPLC) and Gas Chromatography/Mass Spectrometry (GC/MS) were used for identification and quantitative analysis of phenolic compounds. Spectrophotometry was used to monitor the iodine concentrations. Falvor Profile analysis (FPA) method was used to evaluate the odor characteristics of the phenolic compounds. Reactions of iodine with phenol resulted in the formation of the following by-products: 2-iodophenol, 4-iodophenol, diiodophenols, and 2,4,6-triiodophenol. Most reaction conditions studied resulted in the formation of all or some of the specified iodophenols. The initial mass ratio of iodine to phenol was the major determining factor in the concentrations and types of by-products formed. The IDBPs were formed within one hour after initiation of the reactions. Extended reaction times did not lead to significant increases in the concentration of IDBPs. Under most reaction conditions, mono-subsituted phenols were detected at significantly higher concentrations than di-substituted phenolic compounds; triiodophenol was the major by-product when iodine:phenol mass ratio was 10:1. The greatest number of IDBPs were formed when reaction solutions consisted of 1:1 mass ratio of iodine to phenol. FPA panel indicated the odor threshold concentrations for phenol, 2-iodophenol, and 4-iodophenol were 5 mg/L, less than 1 ug/L, and 1 mg/L respectively. The most common odor descriptions for all these compounds were "chemical", "phenolic", and "medicinal". / Master of Science

No description available.

As the bottled water trend continues to rise across the nation, drinking water utilities have become more concerned with ensuring consumer satisfaction of their product. Although public water supplies are safeguarded by regulations, aesthetically unappealing taste-and-odor problems have led consumers to search for alternative water sources, such as bottled water or tap water processed by point-of-use filters. Consequently, taste-and-odor monitoring has become important to the drinking water industry. Because many utilities use chlorine to disinfect the water, chlorine odor often masks other more subtle odors that may eventually cause consumer complaints. As treated water travels from the water treatment plant to the consumer, chlorine residual diminishes and may reveal a water's naturally less-pleasing odors. Consequently, odor monitoring at the water treatment plant, where chlorine concentrations are at a peak, may not identify potential displeasing smells. Proper evaluation of these odor-causing substances requires that the chlorine odor first be eliminated before evaluating any remaining odors. Dechlorinating agents can remove chlorine, but some will produce other unwanted odors or even remove certain odorous compounds. This research describes the efficiency of several of these agents (ascorbic acid, hydrogen peroxide, oxalic acid, sodium nitrite, and sodium thiosulfate) in dechlorinating chlorinated solutions of the earthy-smelling compound geosmin and musty-smelling MIB. Interfering odors in reusable containers pose another problem in drinking water odor analysis. The most common odor-analysis methods (TON and FPA) involve the use of glass flasks, which often either develop chalky odors or have persistent lingering odors from previous evaluations. Furthermore the glass flasks break easily and are difficult to clean. This research also evaluates the suitability of four types of disposable plastic containers for odor analyses. / Master of Science

In recent years, communities that source raw water from the Dan River experienced two severe and unprecedented outbreaks of unpleasant tastes and odors in their drinking water. During both TandO events strong 'earthy', 'musty' odors were reported, but the source was not identified. The first TandO event began in early February, 2015 and coincided with an algal bloom in the Dan River. The algal bloom was thought to be the cause, but after the bloom dissipated, odors persisted until May 2015. The second TandO in October, 2015 did not coincide with observed algal blooms. On February 2, 2014 approximately 39,000 tons of coal ash from a Duke Energy coal ash pond was spilled into the Dan River near Eden, NC. As there were no documented TandO events before the spill, there is concern the coal ash adversely impacted water quality and biological communities in the Dan River leading to the TandO events. In addition to the coal ash spill, years of industrial and agricultural activity in the Dan River area may have contributed to the TandO events. The purpose of this research was to elucidate causes of the two TandO events and provide guidance to prevent future problems. Monthly water samples were collected from August, 2016 to September, 2017 from twelve sites along the Dan and Smith Rivers. Multivariate analyses were applied to look for underlying factors, spatial or temporal trends in the data. There were no reported TandO events during the project but sensory analysis, Flavor Profile Analysis, characterized earthy/musty odors present. No temporal or spatial trends of odors were observed. Seven earthy/musty odorants commonly associated with TandO events were detected. Odor intensity was mainly driven by geosmin, but no relationship between strong odors and odorants was observed. / Master of Science / In recent years, communities that source water from the Dan River experienced two severe and unprecedented outbreaks of unpleasant tastes and odors (T&O) in their drinking water. During both odor events strong ‘earthy’, ‘musty’ odors were reported, but the source was not identified. The first event began in early February, 2015 and coincided with an algal bloom in the Dan River. The algal bloom was thought to be the cause, but after the bloom dissipated, odors persisted until May 2015. The odors returned in October, 2015 but did not coincide with an algal bloom. On February 2, 2014 approximately 39,000 tons of coal ash from a Duke Energy coal ash pond was spilled into the Dan River near Eden, NC. As no documented odor events occurred before the spill, there is concern the coal ash adversely impacted the water quality in the Dan River leading to the odor events. The purpose of this research was to elucidate causes of the two odor events and provide guidance to prevent future problems. Monthly water samples were collected from August, 2016 to September, 2017 from twelve sites along the Dan and Smith Rivers. Multivariate analyses were applied to look for important factors. There were no reported odor events during the project but sensory analysis characterized earthy/musty odors present. No temporal or spatial trends of odors were observed. Seven earthy/musty odorants commonly associated with odor events were detected.