The theme of this work is to monitor the effect of zinc on the properties of blended Portland cements. Zinc was tested in the form of two-soluble salts: Zn(NO3)22 H2O and ZnCl2 and a very slightly soluble compound ZnO. Blended cements were prepared by partial replacement with finely ground granulated blast furnace slag, high-temperature and fluidized bed combustion filter fly ash. Flow properties were studied on the prepared pastes. Impact on hydration reactions was examined by using of isothermal and isoperibolic calorimetry. Flexural and compressive strength were measured as mechanical properties of the prepared test specimens. The phase composition of the prepared composites and incorporation of zinc ions in the cement matrix via leaching tests and FTIR analyzes were also studied. Microstructure development of cement samples was tested by SEM analysis with EDS. Influence on ecotoxicity was also measured.

Autoclaved aerated concrete is long-time ecological building material with usefull properties. There needs to be done research of its mineralogical compound for reengineering the production. The main mineral compound of AAC is tobermorite, it increases its mechanical properties. In the presence study, we examine the usage of nature and artificial silicious materials. Also, we investigate the influence of sulfate and alumina admixtures, as well as fluidized bed combustion ash, which can be used as the lime and gypsum replacement. Closure of the study is design of the optimal raw material composition, also hydrothermal treatment of autoclaved aerated concrete. In relation to its mechanical properties, mineralogical composition and cost.

The disses thesis is focused on usage of secondary raw materials from the electric power industry, specifically fly ash as a component for the building industry, concentrated on concrete. Two main streams are covered, environmental and economical. Reasons, which led to focus on the selected subject are coming mainly from the scarcity and availability of high-quality mineral resources, environmental pressure for usage of industry byproduct, reducing emissions and economical pressure to reduce production cost, especially raw materials. The main purpose of the work was to verify the possibility of increasing the usability of fly ash as a mineral additive in the technology of concrete production with materials retrieved from coal fired power plants and applying mechanical activation of fly ash. The main goal of the experimental part of work was to demonstrate improvement of fresh and hardened concrete properties as a main condition to support economic efficiency of mechanical activated fly ash. Base on previous facts the methodology was covering two main areas, the experimental and the assessment. Relatively large sets of tests were performed, using a wide range of tested high temperature fly ash and fluidized bed combustion fly ash granulometrically treated, by mixing and grinding. Results of the testing confirmed focused parameters for concrete and mortar mechanical properties, total economical efficiency of the targeted solution and the subject of the dissertation. In the experiment section has been retrieved valuable findings contributing to the overall knowledge of the faculty, also for the practical application. The results of the tests confirmed the achievement of the planned target parameters, both in terms of physical and mechanical properties of experienced mortars and concretes, as well as the overall economic efficiency of the proposed design and the topic of the disses thesis. Within the experimental work, valuable professional knowledge and benefits w

<p>  </p> <p>Concrete is the second most consumed material in the world after water and is an essential element of constructed infrastructure. Over 14 billion m3 of concrete are being produced annually, resulting in a serious impact on the environment. The production of cement, which is the main component of concrete, is responsible for 5 – 8 % of global CO2 emissions. As a result, several global initiatives have been undertaken to achieve carbon neutrality by 2050. This carbon neutrality target coincides with the Paris Agreement's goal to limit global warming to 1.5 °C. A well-known, and successful strategy to reduce CO2 emissions in the concrete industry is to use supplementary cementitious materials (SCMs) as a partial replacement for cement. However, it is projected that in 2030 the demand for two of the most commonly used SCMs, fly ash and slag cement, will exceed their supply. Using nontraditional and natural pozzolans (NNPs) can help to close this supply gap, but there is a lack of knowledge regarding the reactivity and long-term performance of these materials.</p> <p>The purpose of this research was to perform experiments on several NNPs, some of which can be supplied in commercially viable quantities with the objective of evaluating their performance in cementitious systems (mortars and concretes) with the goal of accurately assessing their potential for use as alternative SCMs. The mortar study was performed using a total of 11 different NNPs, belonging to 4 distinctive groups and distributed as follows: 3 from the group of calcined clays (CCs) - CC1, CC2, and CC3, 3 from the group of natural pozzolans (NPs) - NP1, NP2 and NP3, 2 from the group of fluidized bed combustion (FBCs) ashes - FBC1 and FBC2, and 3 from the group of bottom ashes (GBAs) - GBA1, GBA2, and GBA3.</p> <p>The concrete study was performed on 4 different materials, one from each of the previously mentioned groups. The materials selected for concrete study were the worst-performing members of each group, as determined by the analysis of the test results obtained from mortars. These included CC2, NP3, FBC1, and GBA3 materials. This approach was adopted under the assumption that achieving adequate concrete characteristics with lowest-quality materials will all but assure satisfactory performance of concretes with higher-quality materials. </p> <p>The findings generated from this research indicate that several of the NNPs used in this study present a viable alternative to traditional SCMs. As an example, out of the 11 NNPS, 9 were found to conform to the requirements of the ASTM C618-19, the standard specification currently used to assess the suitability of coal fly ash and raw or calcined natural pozzolans for use in concrete. Results obtained from tests performed on mortars demonstrated that, when used at the replacement level of 25%, all 11 NNPs produced mixtures with characteristics similar to those obtained from the plain cement (OPC) mortar. For that reason, this level of replacement was selected to prepare concrete specimens. The results collected from concrete specimens showed that, when compared to plain concrete, mixtures with all 4 NNPs attained comparable (or improved) mechanical (compressive and flexural strength), durability (freeze-thaw resistance), and transport (formation factor and rate of water absorption) properties. As in the case of traditional SCMs, the mixtures with NNPs were found to require extended curing times to fully realize their property-enhancing potential associated with pozzolanic reactions. Overall, the best performing materials were those from the CCs group, followed by those belonging to, respectively, NPs, GBAs, and FBCs groups. </p>