A scanning reference electrode technique (SRET) apparatus has been designed and commissioned to investigate the corrosion of friction stir spot welds (FSSW) made in AZ31 magnesium alloys. The operational parameters of the apparatus have been calibrated to give good spatial resolution. By combining the SRET data with material flow data and immersion test data it was found that the FSSW process caused the formation of distinct noble and active regimes within the weld area. The noble region was aligned with the stir zone (SZ) and was caused by a dynamically recrystallized grain structure which is void of dislocations / twins, and β Mg17Al12. Localized corrosion attack was observed in both SRET and immersion testing along the thermo-mechanically affected zone (TMAZ). The same effect was consistently observed with a flat versus concave shoulder tool, and dwell times of 1s and 4s.

A volumetric contact dynamics model has been proposed by Gonthier et al. [1, 2, 3] for the purpose of rapidly generating reliable simulations of space-based manipulator contact dynamics. By assuming materials behave as a Winkler elastic foundation model, forces and moments between two bodies in contact can be expressed in terms of the volume of interference between the undeformed geometries of the bodies. Friction between bodies is modelled by a dwell-time dependent bristle model for both tangential friction, and spinning friction torque. This volumetric model has a number of advantages. Unlike point-contact models, it allows for the modelling of contact between complex geometries and scenarios where the contact surface is relatively large, while being less computationally expensive than finite element methods. Rolling resistance is included in the model through damping effects across the volume of interference. The friction model accounts for dwell-time dependent slip-stick effects, spinning friction torque, and the Contensou effect. In this thesis, an experimental validation of the volumetric contact model is presented for the first time. Models for simple geometries in contact (e.g. cylinder-on-plane, sphere-on-plane) have been developed for stationary contact and for contact with motion normal and tangential to the contact surface. Tangential motion is modelled with pure translation, pure rotation about the normal axis, and combined motion, in order to separately consider friction forces, spinning friction torque, and the Contensou effect, respectively. An apparatus has been developed to experimentally validate these models for metal-on-metal contact. The apparatus has two configurations, one for validating the normal contact models and the other for the friction models. Experimental measurements of forces and displacements are used to identify model parameters (e.g. volumetric stiffness, friction coefficients, etc.). For normal force experiments, modelling the contact forces as proportional to volume of interference was found to be a reasonable approximation. A Hertzian model was compared with the volumetric model for spherical payloads loaded quasi-statically. Using stiffnesses estimated from spherical experiments, small misalignments of the cylindrical payloads were estimated that corresponded well with measured results. Dynamic experiments suggest an inverse relationship between impact velocity and the hysteretic damping coefficient. The high normal forces applied in the friction experiments were found to create significant wear on the contact surfaces. Coefficients of friction between titanium and aluminum were found to be consistent translationally and rotationally. Friction forces from combined translation and rotation demonstrate that the Contensou effect is accurately described by the volumetric contact model.

Effects of biomimetic micro-patterning of polymeric materials on their interfacial properties were studied experimentally. Micropillars of PDMS and SU-8 epoxy were fabricated through soft lithography and UV lithography techniques, respectively. PDMS pillars were topped by thin terminal films of the same material through dipping method with different thicknesses and viscosities. Adhesion and frictional properties of biomimetic microstructures were examined in two modes of contact, i.e. laid and conformal contact. In the first mode of contact, i.e. laid contact, the contact between adhesive and adherent is laid on top of the micro-protrusions or is in contact with side wall of micropillars. Adhesion properties of the smooth and patterned PDMS were characterized through micro-indentation test. Moreover, the friction properties of the smooth PDMS sample and PDMS micropillars with different aspect ratios were examined in unidirectional friction testing. JKR theory of continuum contact mechanics was utilized to interpret the obtained data. To study the effect of second mode of contact, peeling behaviour of a conformal contact between solidified liquid PDMS and SU-8 micropillars was monitored. Kendall’s model of elastic peeling was used to interpret the peeling data. It was found that patterning of the materials would decrease the real area of contact and accordingly adhesion and friction to the mating surface. Termination of the micropillars with a thin layer of the same material result in increment of adhesion as reduction of the real contact area could be compensated and the compliance of the near surface increases. Elastic energy dissipation as a result of enhanced compliance and crack trapping and crack propagation instabilities are the main reasons behind increment of adhesion of thin film terminated structures. Viscoelasticity of the terminal thin film remarkably increased the adhesion as a result of coupling mentioned mechanisms and viscoelastic loss on the surface. Decline of the overall friction could be tailored through use of different aspect ratios. Higher aspect ratios pillars show higher friction comparing to lower aspect ratio pillars. 550 folds enhancement of adhesion was observed for peeling of the PDMS tape from rigid micropillars with aspect ratio ranging from 0 to 6. It is concluded that for the lower aspect ratio micropillars, the elastic energy dissipation is playing the key role in adhesion enhancement. This role shifts toward side-wall friction during separation by increase in aspect ratio. These all give in hand a versatile tool to control and fine tune the interfacial properties of materials, whether they are concerned with adhesion or friction.

The aim of this thesis is to compare various simulation models of orthogonal cutting process with each other as well as with various experiments. The effects of several process parameters, such as friction and separation criterion, on the results are analyzed. As simulation tool, commercial implicit finite element codes MSC.Marc, Deform2D and the explicit code Thirdwave AdvantEdge are used. Separation of chip from the workpiece is achieved either only with continuous remeshing or by erasing elements according to the damage accumulated. From the results cutting and thrust forces, shear angle, chip thickness and contact length between the chip and the rake face of the tool can be estimated. For verification of results several cutting experiments are performed at different cutting conditions, such as rake angle and feed rate. Results show that commercial codes are able to simulate orthogonal cutting operations within reasonable limits. Friction is found to be the most critical parameter in the simulation, since good agreement can be achieved for individual process variables by tuning it. Therefore, simulation results must be assessed with all process variables and friction parameter should be tuned according to the shear angle results. Plain damage model seems not appropriate for separation purposes of machining simulations. On the other hand, although remeshing gives good results, it leads to the misconception of crack generation at the tip of the tool. Therefore, a new separation criterion is necessary to achieve both good physical modeling and prediction of process variables.

Tribological properties of a mica glass-ceramic designed for use in dental applications were assessed experimentally in accord with the ASTM pin on disk technique. The glass ceramic was produced through controlled crystallization of the glass in the system SiO2, Al2O3, CaO, MgO, K2O, and F. Crystallization was accomplished by subjecting the parent glass to a regulated heat treatment that resulted in the nucleation and growth of crystal phases formed in the glass. The tests were conducted by sliding a zirconia ball against the glass and glass ceramic disk. The friction coefficient and wear rate were determined as functions of the applied load, sliding speed and sliding time in ambient laboratory conditions and in acidic and basic solutions. The friction coefficient was monitored during the tests. The wear volumes determined from surface profile traces obtained on the wear tracks after completion of the tests were used for calculation of the wear rates. The wear rates increased with increasing applied load and sliding speed but decreased with increasing sliding distance. Results were correlated with the tribological properties of the parent glass, and tribological properties of selected glasses, glass-ceramics and ceramics reported in the literature.

The general trend in the car body manufacturing industry is towards low-series production and reduction of press lubricants and car weight. The limited use of lubricants, in combination with the introduction of high and ultrahigh-strength sheet materials, continuously increases the demands on the forming tools. The major cause for tool failure during the forming process is transfer and accumulation of sheet material on the tool surfaces, generally referred to as galling. The adhered material creates unstable frictional conditions and scratching of the tool/sheet interface. To provide the means of forming new generations of sheet materials, development of new tool materialswith improved galling resistance is required, which may include tailored microstructures introducing specific carbides and nitrides, coatings and improved surface finish. In the present work, the galling wear mechanisms in real forming operations have been studied and emulated at a laboratory scale by developing a test equipment. The wear mechanisms, identified in the real forming process, were distinguished into a sequence of events. At the initial stage, local adhesive wear of the sheets led to transfer of sheet material to the tool surfaces. Successive forming operations resulted in growth of the transfer layer with initiation of scratching of the sheets. Finally, scratching changed into severe adhesive wear, associated withgross macroscopic damage. The wear process was successfully repeated in the laboratory test equipment in sliding between several tool materials, ranging from cast iron and conventional ingot cast tool steels, to advanced powder metallurgy tool steel, sliding against medium and high-strength steel sheets. By use of the test equipment, selected tool materials were ranked regarding galling resistance. The controlling mechanism for galling in sheet metal forming is adhesion. The initial sheet material transfer was found to occur, preferably, to the metallic matrix of the tool steels. Hence, the carbides in the particular steels appeared less prone to adhesion as compared to the metallic matrix. Therefore, an improved galling resistance was observed for a tool steel comprising a high amount of small homogeneously distributed carbides offering a low-strength interface to the transferred sheet material.Further, atomic force microscopy showed that nanoscale adhesion was influenced by temperature, with increasing adhesion as temperature increases. A similar dependence was observed at the macroscale where increasing surface temperature led to initiation of severe adhesive wear. The results were in good agreement to the nano scale observations and temperature-induced high adhesion was suggested as a possible mechanism.

In this work, wear and scratch behavior of four different bulk metallic glasses (BMGs) namely Zr41.2Cu12.5Ni10Ti13.8Be22.5 (LM 1), Zr57Cu15.4Ni12.6Al10Nb5 (LM 106), Ni60Pd20P17B3 (Ni-BMG), and Pt57.5Cu14.7Ni5.3P22.5 (Pt-BMG) were compared. Shear band formation on the edges of the scratch groove with spallation was found to be the primary failure mechanism in progressive scratch tests. The wear behavior and the scratch response of model binary Ni-P metallic glasses was systematically studied as a function of composition, with amorphous alloy formation over the narrow range of 10 at% to 20 at% phosphorus. Pulsed current electrodeposition was used to obtain these binary amorphous alloys, which offers a facile and versatile alternative to conventional melt quenching route. The electrodeposited metallic glasses (EMGs) showed hardness values in the range of 6.6-7.4 GPa, modulus in the range of 155-163 GPa, and friction coefficient around 0.50. Among the studied alloys, electrodeposited Ni80P20 showed the lowest wear rate. The wear mechanism was determined to be extensive plastic deformation along with mild ploughing, micro tears, and formation of discontinuous lubricious oxide patches. The effect of phosphorus content on the structure, mechanical properties, and the tribological response was systematically investigated for biocompatible Co-P metallic glasses. With increase in phosphorus content, there was an increase in hardness, hardness/modulus, wear resistance, and scratch resistance following the trend: Co80P20 > Co90P10 > Pure Co. The Co-P electrodeposited amorphous alloys showed enhanced wear resistance that was two orders of magnitude better than SS 316 and Ti-based alloys in simulated physiological environment. The wear mechanisms were determined to be a combination of abrasive and surface fatigue wear in both dry and physiological environments. Decreased platelet adhesion and more extracellular matrix deposition indicated that Co80P20 electrodeposited alloy had excellent blood compatibility and pre-osteoblast adhesion response. These results suggest the potential use of Co-P metallic glasses as superior bio implant materials with better durability compared to the state-of-the-art.

In order to control the vibration response of high rise buildings during seismic events, energy absorbing passive damping devices are most commonly used for energy absorption. Today there are a number of types of manufactured dampers available in the market, which use a variety of materials and designs to obtain various levels of stiffness and damping. Some of these include friction, yielding, viscoelastic and viscous dampers. These dampers are usually installed between two load bearing elements (walls or columns) in new buildings. In existing buildings, which require retrofitting, they could be installed in cut-outs of shear walls, as evidenced from recent investigations. An effective damping system can result in higher levels of safety and comfort, and can also lead to considerable savings in the total cost of a building. This thesis treats seismic mitigation of multistorey buildings using embedded dampers. Three types of damping mechanisms, viz, friction, viscoelastic, and combined friction-viscoelastic were investigated. Finite element methods were employed in the analysis using the program ABAQUS version 6.3. A direct integration dynamic analysis was carried out to obtain the damped and undamped responses of the structure in terms of deflections and accelerations at all storeys in order to evaluate the effectiveness of the damping system in mitigating the seismic response. The damping mechanisms have been modelled as (i) a linear spring and dash-pot in parallel for the viscoelastic damper, (ii) a contact pair with friction parameter for a friction damper and (iii) a hybrid damper consisting of both a viscoelastic and a friction damper. The earthquake events used in this study have been applied as acceleration time-histories at the base of the structure in the horizontal plane. Concrete material properties were chosen to represent the model as many high-rise buildings are constructed by using reinforced concrete. Several medium and high-rise building structures with embedded dampers in different configurations and placed in various locations throughout the structure were subjected to different earthquake loadings. Influence of damper type and properties, configuration and location were investigated. Results for the reduction in tip deflection and acceleration for a number of cases demonstrate the feasibility of the technique for seismic mitigation of these structures for a range of excitations, even when the dominant seismic frequencies match the natural frequency of the structure. Results also provide information which can be used for optimal damper placement for seismic mitigation.

In considering the concept of surface-immobilised liposomes as a drug release system, two factors need to addressed, the interfacial surface density of the liposomes for maximum drug loading and the stability of these liposomes to allow for controlled drug release. This thesis investigates a multilayer system for the affinity immobilisation of liposomes and their stability to various applied stresses. In the work presented here an allylamine monomer was used to create plasma coatings that were stable, thin and amine-rich. The aging studies using AFM showed these films to rapidly oxidise on exposure to water. The freshly deposited films were used for further surface modifications, by the covalent grafting of PEG layers of different interfacial densities under the conditions of varying polymer solvation. The AFM was used to measure the interaction forces between the grafted PEG layers and modified silica interfaces. It was found that the polydispersity of the PEG species resulted in bridging interactions of ???brush???-like PEG layers with the silica surface. These interactions were screened minimised by increasing the ionic strength of the solution. Although the densely grafted PEG layers were found to be highly protein-resistant by the XPS and QCM-D some minor protein-polymer adhesions were observed by the AFM. The densely anchored biotinylated PEG chains served as an optimum affinity platform for affinity-docking of NeutrAvidinTM molecules, which assembled in a rigid, 2-D layer as confirmed by the QCM-D. The submonolayer surface density of NeutrAvidin, as determined by Europium-labelling, was attributed to steric hindrance of the immobilised molecules. The final protein layer enabled specific binding of biotin-PEG-liposomes as a highly dissipative, dense and stable layer verified by tapping mode AFM and QCM-D. We found that these liposomes were also stable under a range of stresses induced by the shearing effects of water, silica probe and HSA layer at increased loads and velocities. The frictional response of the liposome layer also demonstrated the viscoelasticity and stability of these surface immobilised liposomes. Finally, the minimal adhesive interaction forces, as measured by the AFM, demonstrated the repellency of these liposomes to commonly found proteins, such as HSA.

It has been well proven that as the skid resistance of a road surfacing decreases, the number of loss of control type crashes increases, causing road death and injuries. However, the management of skid resistance of road surfacings continues to be difficult due to the inherent and sometimes random variation in skid resistance levels over time. This study is an investigation and analysis of seasonal and short term variation of measured skid resistance in two phases. Phase 1: Regular field monitoring was undertaken using the GripTester and the Dynamic Friction Tester measurement devices on seven sites in the Auckland and Northland Regions of New Zealand was undertaken over a three year period. The effects of temperature, rainfall, contaminants, new surfacings, geometric elements and aggregate properties were analysed to investigate factors that initiate changes in the measured skid resistance of pavement surfacings. Phase 2: Laboratory prepared samples were constructed for accelerated polishing and skid resistance testing of four different aggregates (two greywackes, a basalt and an artificial iron-making melter slag aggregate). The samples were polished in an accelerated polishing machine to an ‘equilibrium skid resistance’ level (Stage 1 polishing). Contaminants were then added to the accelerated polishing process to determine the effect of varying additive, particle size and hardness in an attempt to simulate seasonal and/or short-term variations that occur in the field. The results have demonstrated that significant and previously unpredictable variations (greater than 30%) in measured skid resistance can occur over short time periods. These variations cannot be explained by any one factor. They are the result of a number of inter-related factors, including the geological properties of the aggregates and the contaminants themselves, the previous rainfall history, the road geometry, the calendar month of the year and (depending upon the measurement device), the temperature during testing. The laboratory tests demonstrate that accelerated polishing tests of aggregate samples could be prepared for testing by the Dynamic Friction Tester and that significant variations in measured skid resistance could be simulated on various aggregates in the laboratory by the addition of contaminants. The results of the testing and addition of contaminants on various aggregates resulted in significant behavioural differences which were related to the geological properties of the aggregates themselves, as well as the contaminants used in the accelerated polishing process. The findings of the research have specific relevance to three areas of industry; Road Controlling Authorities who are primarily interested in skid resistance policy, standards and management, Road Asset Managers who operate, maintain and manage condition level and the safety aspects of the road network and Crash Investigators who collect and analyse crash data primarily for legal proceedings. All three of these industry organisations need to clearly understand the inherent variability of skid resistance, the factors involved and the effects that geological and environmental variations have on skid resistance measurement. / Specific appreciation (as outlined below) is given to the significant industry partners/supporters that have helped support the research in many different ways. Firstly, I must give special thanks to Works Infrastructure Limited who have supported the research both financially and with resources almost from the outset of the research programme. The field testing data collection in the Northland Region of New Zealand would not have been possible without the support of the Whangarei Works Infrastructure team which included Peter Houba, Peter King, Matthew Findlay, Glen Kirk and the temporary traffic control team headed by Derek Phillips. Thanks also go to the Auckland Works Infrastructure testing laboratory which supplied aggregate supplies for laboratory sampling and testing and whose technicians also undertook Polished Stone Value tests on the aggregate samples. Special thanks are also given to Michael Haydon and David Hutchison from the technical management team of Works Infrastructure who have always been willing to listen to my requests and the many discussions that we have had on aspects of skid resistance, policy and technical matters. Pavement Management Services and especially Dr John Yeaman and Daniel Rich for their support for the research programme from the beginning, and secondly for financially contributing to the purchase of the Dynamic Friction Tester for the static field testing and the laboratory tests. Achnowledgement is also given to The Ports of Auckland and especially Jo Campbell of the AXIS Intermodal group that allowed access to the rail grid site as a field-testing site outside of normal port operation hours. Transit New Zealand head office staff (Mark Owen, David Cook and Chris Parkman) are also thanked for their support of the research and in enabling access to historic SCRIM and RAMM data on the Transit New Zealand state Highway network. Land Transport New Zealand (formerly Transfund New Zealand) are acknowledged for their significant financial support of the research, in terms of the Land Transport New Zealand Research project that allowed the field research data collection and analysis programme to continue for a further year and for the extension to the controlled laboratory testing.