The introduction of fibre-reinforced polymers (FRPs) to the field of civil engineering has led to numerous research efforts focusing on a wide range of applications where properties such as high strength, light weight or corrosion resistance are desirable. In particular, FRP materials have been especially attractive for use as internal reinforcement in reinforced concrete (RC) structures exposed to aggressive environments due to the rapidly deteriorating infrastructure resulting from corrosion of conventional steel reinforcement. While FRPs have been successfully implemented in a variety of structural applications, little research has been conducted on the use of FRP reinforcement for short span slab bridges. Furthermore, the behaviour of FRP-RC flexural members cast with self-consolidating concrete (SCC) is largely absent from the literature. The present study investigates the behaviour of an all-FRP reinforcement system for slab bridges which combines lower cost glass FRP (GFRP) reinforcing bars with high performance carbon FRP (CFRP) prestressed tendons in SCC to produce a structure which is both cost-efficient and characterized by excellent structural performance at the serviceability, ultimate and fatigue limit states. An extensive experimental program comprised of 57 large or full-scale slab strips was conducted to investigate the effects of reinforcement type, reinforcement ratio, prestressing level and shear reinforcement type on the flexural performance of slab bridges under both monotonic and fatigue loading. The proposed reinforcement system was found to display excellent serviceability characteristics and high load capacities as well as significant deformability to allow for sufficient warning prior to failure. Lastly, the use of post-tensioned CFRP tendons limited the stresses in the GFRP reinforcing bars leading to significantly longer fatigue lives and higher fatigue strengths compared to non-prestressed slabs. Analytical models were used to predict the behaviour of the slab bridge strips at service and at ultimate. Where these models failed to accurately represent the experimental findings, simple modifications were proposed. The results from ancillary tests were also used to modify existing analytical models to predict the effects of fatigue loading on the deflection, crack width, shear resistance and flexural capacity of each of the tested slabs.

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Strong light can cause damage and be lethal for photosynthetic organisms. An increase of thermal dissipation of excess absorbed energy at the level of photosynthetic antenna is one of the processes protecting against deleterious effects of light. In cyanobacteria, a soluble photoactive carotenoid binding protein, Orange Carotenoid Protein (OCP) mediates this process. The photoactivated OCP by interacting with the core of phycobilisome (PB; the major photosynthetic antenna of cyanobacteria) triggers the photoprotective mechanism, which decreases the energy arriving at the reaction centres and PSII fluorescence. The excess energy is dissipated as harmless heat. To regain full PB capacity in low light intensities, theFluorescence Recovery Protein (FRP) is required. FRP accelerates the deactivation of OCP.In this work, I present my input in the understanding of the mechanism underlying the OCPrelated photoprotection. I further characterized the FRP of Synechocystis PCC6803, the model organism in our studies. I established that the Synechocystis FRP is shorter than what it was proposed in Cyanobase and it begins at Met26. Our results also revealed the great importance of a high OCP to FRP ratio for existence of photoprotection. The most remarkable achievement of this thesis is the in vitro reconstitution of the OCPrelated mechanism using isolated OCP, PB and FRP. I demonstrated that light is only needed for OCP photoactivation but OCP binding to PB is light independent. Only the photoactivated OCP is able to bind the PB and quench all its fluorescence. Based on our in vitro experiments we proposed a molecular model of OCP-related photoprotection. The in vitro reconstituted system was applied to examine the importance of a conserved salt bridge (Arg155-Glu244) between the two domains of OCP and showed that this salt bridge stabilises the inactive form of OCP. During photoactivation this salt bridge is broken and Arg155 is involved in the interaction between the OCP and the PB. The site of OCP binding in the core of a PB wasalso investigated with the in vitro reconstituted system. Our results demonstrated that the terminal energy emitters of the PB are not needed and that the first site of fluorescence quenching is an APC trimer emitting at 660 nm. Finally, we characterised the properties of excited states of the carotenoid in the photoactivated OCP showing that one of these states presents a very pronounced charge transfer character that likely has a principal role in energy dissipation. Our results strongly suggested that the OCP not only induces thermal energy dissipation but also acts as the energy dissipator.

Baigiamajame magistro darbe atliekami eksperimentiniai gelžbetoninių sijų, sustiprintų pneumatiniu montažiniu pistoletu mechaniškai tvirtinama anglies pluošto juosta, elgsenos tyrimai, nagrinėjama jungių skaičiaus ir išdėstymo įtaka sijos elgsenai. Darbą sudaro: įvadas, trys pagrindiniai skyriai, pasiūlymai ir išvados, literatūros sąrašas. Įvade aptariama tiriamoji problema, darbo aktualumas ir naujumas, pristatomas darbo objektas, formuluojami tikslai ir uždaviniai, pateikiama tyrimų metodika. Pirmajame skyriuje pateikiamos bendros žinios apie sijų stiprinimą, apžvelgiama stiprinimo metodų raida, aptariamos statybiniams kompozitams gaminti naudojamos medžiagos ir aprašomi populiariausi metodai, naudojami statybiniais kompozitais sustiprintų sijų skaičiavimui. Antrajame skyriuje plačiau aptariamas sluoksnių skaičiavimo metodas, atliekama jo parametrinė analizė. Trečiajame skyriuje plačiai aprašomas bandinių paruošimas ir jų bandymo metodika, pateikiami eksperimentinių tyrimų rezultatai, jie palyginami su teoriniais skaičiavimais bei kitų autorių gautais rezultatais. Darbo pabaigoje pateikiami sijų stiprinimo pneumatiniu montažiniu pistoletu mechaniškai tvirtinama anglies pluošto juosta pasiūlymai, formuluojamos išvados. Darbo apimtis – 69 p. teksto be priedų, 33 paveikslai, 5 lentelės, 32 bibliografiniai šaltiniai. / This thesis presents the analysis based on experimental testing of reinforced concrete beams, strengthened by mechanically fastened fiber reinforced polymer strips, when high pressure air powered pinner was used to fasten the strips. The influence of the number and arrangement of fasteners is investigated. Thesis consists of introduction, three main chapters, recommendations and conclusions, literature list. The introduction presents an overview, objectives, scope, methodology and significance of thesis. The first chapter shows the development of beam strengthening, introduces composite materials and methods used for calculating beams strengthened using FRP strips. In the second chapter the chosen calculation method is described in detail and its parametric analysis is performed. Third chapter gives a detailed description on the test specimen preparation and the methodology of testing. Experimental results and their comparison with theoretically obtained values and values obtained by other researchers are given here. The recommendations on the technology of strengthening the beams using mechanically fastened fiber reinforced polymer strips are given and the conclusions are drawn. Thesis contains 69 pages. There are 33 pictures, 5 tables and 32 references in the thesis.

A theory is developed for the analysis of composite systems consisting of steel wide flange sections reinforced with GFRP plates connected to one of the flanges through a layer of adhesive. The theory is based on an extension of the Gjelsvik theory and thus incorporates local and global warping effects but omits shear deformation effects. The theory captures the longitudinal transverse response through a system of three coupled differential equations of equilibrium and the lateral-torsional response through another system of three coupled differential equations. Closed form solutions are developed and a super-convergent finite element is formulated based under the new theory. A comparison to 3D FEA results based on established solid elements in Abaqus demonstrates the validity of the theory when predicting the longitudinal-transverse response, but showcases its shortcomings in predicting the torsional response of the composite system. The comparison sheds valuable insight on means of improving the theory. A more advanced theory is subsequently developed based on enriched kinematics which incorporates shear deformation effects. The shear deformable theory captures the longitudinal-transverse response through a system of four coupled differential equations of equilibrium and the lateral-torsional response through another system of six coupled differential equations. A finite difference approximation is developed for the new theory and a new finite element formulation is subsequently to solve the new system of equations. A comparison to 3D FEA illustrates the validity of the shear deformable theory in predicting the longitudinal-transverse response as well as the lateral-torsional response. Both theories are shown to be computationally efficient and reduce the modelling and running time from several hours per run to a few minutes or seconds while capturing the essential features of the response of the composite system.

This study presents a new approach for nonlinear multi-scale constitutive models using artificial neural networks (ANNs). Three ANN classes are proposed to characterize the nonlinear multi-axial stress-strain behavior of metallic, polymeric, and fiber reinforced polymeric (FRP) materials, respectively. Load-displacement responses from nanoindentation of metallic and polymeric materials are used to train new generation of dimensionless ANN models with different micro-structural properties as additional variables to the load-deflection. The proposed ANN models are effective in inverse-problems set to back-calculate in-situ material parameters from given overall nanoindentation test data with/without time-dependent material behavior. Towards that goal, nanoindentation tests have been performed for silicon (Si) substrate with/without a copper (Cu) film. Nanoindentation creep test data, available in the literature for Polycarbonate substrate, are used in these inverse problems. The predicted properties from the ANN models can also be used to calibrate classical constitutive parameters. The third class of ANN models is used to generate the effective multi-axial stress-strain behavior of FRP composites under plane-stress conditions. The training data are obtained from coupon tests performed in this study using off-axis tension/compression and pure shear tests for pultruded FRP E-glass/polyester composite systems. It is shown that the trained nonlinear ANN model can be directly coupled with finite-element (FE) formulation as a material model at the Gaussian integration points of each layered-shell element. This FE-ANN modeling approach is applied to simulate an FRP plate with an open-hole and compared with experimental results. Micromechanical nonlinear ANN models with damage formulation are also formulated and trained using simulated FE modeling of the periodic microstructure. These new multi-scale ANN constitutive models are effective and can be extended by including more material variables to capture complex material behavior, such as softening due to micro-structural damage or failure.

The results of an experimental investigation are presented which examine the seismic adequacy of pre-1970 reinforced concrete (RC) corner beam-column joints and the efficacy of carbon fiber-reinforced polymer (CFRP) composites for both pre- and post-earthquake retrofit of such joints. Four full-scale corner beam-column-slab subassemblages built with identical dimensions and pre-1970 reinforcement details were subjected to a reverse-cycle bidirectional displacement history consisting of alternate and simultaneous cycles in the two primary frame directions before and/or after retrofit. Two of the specimens were first subjected to severe and moderate levels of damage, respectively, then repaired by epoxy injection, and strengthened by adding a #7 reinforcing bar within the clear cover at the column inside corner and by externally bonding multiple layers of carbon fabric to form a carbon-epoxy retrofit system. Two other specimens, one of which had a significantly lower concrete compressive strength, were strengthened in their as-built condition. The CFRP scheme was improved in light of the findings as the experimental program progressed. Pre-1970 RC corner beam-column joints were found to be severely inadequate in meeting seismic demands because of column bar yielding, joint shear failure, loss of anchorage of beam bottom bars, failure of column lap-splices, and the resulting loss of stiffness and strength that dominate their behavior even at relatively low interstory drift levels. Bidirectional loading played a significant role in such response. It was shown, however, that such joints can be strengthened easily both before and after earthquake damage by using CFRP composite schemes. Regardless of the level of existing damage and concrete strength, a "rigid" joint behavior up to interstory drift ratios of at least 2.4% and joint shear strength factors ranging from 1.06 to 1.41√MPa were achieved; such shear strength factors are larger than the value of 1.00√MPa recommended for use with seismically designed, code-conforming corner beam-column joints. A ductile beam hinging mechanism was achieved and energy dissipation capacity was improved efficiently for joints with concrete strengths ranging from 26 to 34 MPa. The subassemblage with significantly low-strength concrete (15 MPa) had low overall lateral stiffness and reduced reinforcement anchorages which prevented the formation of beam hinging. In cases of such low-strength concrete, more invasive operations may be required so that the improved joint shear strength can be mobilized. It is recommended that bidirectional loading be always considered in both pre- and post-retrofit evaluation of corner joints.

El uso de materiales compuestos de matriz polimérica (FRP) emerge como alternativa al hormigón convencionalmente armado con acero debido a la mayor resistencia a la corrosión de dichos materiales. El presente estudio investiga el comportamiento en servicio de vigas de hormigón armadas con barras de FRP mediante un análisis teórico y experimental. Se presentan los resultados experimentales de veintiséis vigas de hormigón armadas con barras de material compuesto de fibra de vidrio (GFRP) y una armada con acero, todas ellas ensayadas a flexión de cuatro puntos. Los resultados experimentales son analizados y comparados con algunos de los modelos de predicción más significativos de flechas y fisuración, observándose, en general, una predicción adecuada del comportamiento experimental hasta cargas de servicio. El análisis de sección fisurada (CSA) estima la carga última con precisión, aunque se registra un incremento de la flecha experimental para cargas superiores a las de servicio. Esta diferencia se atribuye a la influencia de las deformaciones por esfuerzo cortante y se calcula experimentalmente.Se presentan los aspectos principales que influyen en los estados límites de servicio: tensiones de los materiales, ancho máximo de fisura y flecha máxima permitida. Se presenta una metodología para el diseño de dichos elementos bajo las condiciones de servicio. El procedimiento presentado permite optimizar las dimensiones de la sección respecto a metodologías más generales. / Fibre reinforced polymer (FRP) bars have emerged as an alternative to steel for reinforced concrete (RC) elements in aggressive environments due to their non-corrosive properties. This study investigates the short-term serviceability behaviour of FRP RC beams through theoretical and experimental analysis. Twenty-six RC beams reinforced with glass-FRP (GFRP) and one steel RC beam are tested under four-point loading. The experimental results are discussed and compared to some of the most representative prediction models of deflections and cracking for steel and FRP RC finding that prediction models generally provide adequate values up to the service load. Additionally, cracked section analysis (CSA) is used to analyse the flexural behaviour of the specimens until failure. CSA estimates the ultimate load with accuracy, but it underestimates the experimental deflection beyond the service load level. This increment is mainly attributed in this work to shear induced deflection and it is experimentally calculated.A discussion on the main aspects of the SLS of FRP RC is introduced: the stresses in materials, maximum crack width and the allowable deflection. A methodology for the design of FRP RC at the serviceability requirements is presented, which allows optimizing the overall depth of the element with respect to more generalised methodologies.

Terrorism has become a serious threat in the world, with bomb attacks carried out both inside and outside buildings. There are already many unreinforced masonry buildings in existence, and some of them are historical buildings. However, they do not perform well under blast loading. Aiming on protecting masonry buildings, retrofitting techniques were developed. Some experimental work on studying the effect of retrofitted URM walls has been done in recent years; however, these tests usually cost a significant amount of time and funds. Because of this, numerical simulation has become a good alternative, and can be used to study the behaviour of masonry structures, and predict the outcomes of experimental tests. This project was carried out to find efficient retrofitting technique under blast loading by developing numerical material models. It was based on experimental research of strengthening URM walls by using retrofitting technologies under out-of-plane loading at the University of Adelaide. The numerical models can be applied to study large-scaled structures under static loading, and the research work is then extended to the field of blast loading. Aiming on deriving efficient material models, homogenization technology was introduced to this research. Fifty cases of numerical analysis on masonry basic cell were conducted to derive equivalent orthotropic material properties. To study the increasing capability in strength and ductility of retrofitted URM walls, pull-tests were simulated using interface element model to investigate the bond-slip relationship of FRP plates bonded to masonry blocks. The interface element model was then used to simulate performance of retrofitted URM walls under static loads. The accuracy of the numerical results was verified by comparing with the experimental results from previous tests at the University of Adelaide by Griffith et al. (2007) on unreinforced masonry walls and by Yang (2007) on FRP retrofitted masonry walls. To study the de-bonding behaviours of retrofits bonded to masonry, and find appropriate solution to protect certain masonry walls against blast loading, various retrofitting technologies were examined. The simulation covers explosive impacts of a wide range of impulses. Based on this work, pressure-impulse diagrams for different types of retrofitted URM walls were developed as a design guideline for estimating the blast effect on retrofitted masonry walls. The outcomes of this research will contribute to the development of numerical simulation on modelling retrofitted URM walls, improving the technique for explosion-resistant of masonry buildings, and providing a type of guideline for blast-resistant design. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1349719 / Thesis (M.Eng.Sc.) - University of Adelaide, School of Civil, Environmental and Mining Engineering, 2009

Terrorism has become a serious threat in the world, with bomb attacks carried out both inside and outside buildings. There are already many unreinforced masonry buildings in existence, and some of them are historical buildings. However, they do not perform well under blast loading. Aiming on protecting masonry buildings, retrofitting techniques were developed. Some experimental work on studying the effect of retrofitted URM walls has been done in recent years; however, these tests usually cost a significant amount of time and funds. Because of this, numerical simulation has become a good alternative, and can be used to study the behaviour of masonry structures, and predict the outcomes of experimental tests. This project was carried out to find efficient retrofitting technique under blast loading by developing numerical material models. It was based on experimental research of strengthening URM walls by using retrofitting technologies under out-of-plane loading at the University of Adelaide. The numerical models can be applied to study large-scaled structures under static loading, and the research work is then extended to the field of blast loading. Aiming on deriving efficient material models, homogenization technology was introduced to this research. Fifty cases of numerical analysis on masonry basic cell were conducted to derive equivalent orthotropic material properties. To study the increasing capability in strength and ductility of retrofitted URM walls, pull-tests were simulated using interface element model to investigate the bond-slip relationship of FRP plates bonded to masonry blocks. The interface element model was then used to simulate performance of retrofitted URM walls under static loads. The accuracy of the numerical results was verified by comparing with the experimental results from previous tests at the University of Adelaide by Griffith et al. (2007) on unreinforced masonry walls and by Yang (2007) on FRP retrofitted masonry walls. To study the de-bonding behaviours of retrofits bonded to masonry, and find appropriate solution to protect certain masonry walls against blast loading, various retrofitting technologies were examined. The simulation covers explosive impacts of a wide range of impulses. Based on this work, pressure-impulse diagrams for different types of retrofitted URM walls were developed as a design guideline for estimating the blast effect on retrofitted masonry walls. The outcomes of this research will contribute to the development of numerical simulation on modelling retrofitted URM walls, improving the technique for explosion-resistant of masonry buildings, and providing a type of guideline for blast-resistant design. / http://proxy.library.adelaide.edu.au/login?url= http://library.adelaide.edu.au/cgi-bin/Pwebrecon.cgi?BBID=1349719 / Thesis (M.Eng.Sc.) - University of Adelaide, School of Civil, Environmental and Mining Engineering, 2009