No description available.

M.Ing. (Mechanical Engineering) / Fossil fuels have been the backbone for the world in terms of fulfilling energy requirements. One of the best used types of fuel is the coal due to its availability throughout the globe. However, the coal resources cannot be reproduced hence the future generation may be negatively affected by the present method of generating energy. Unfortunately, these resources have undesirable effects to the environment which may lead to global warming. Other various sources may include oil and gas, nuclear, and the renewables. Oil and gas have diverse use currently especially in the transportation of goods and people across the continents. Nuclear energy is a mature technology but recent disasters have led to the public to be anti-nuclear. This perception is also fuelled by the in NGOs who are staunch supporters of renewable power. In addition, the issue about nuclear energy revolves around the undesirable side effect like the production of atomic bombs which are dangerous weapons ever. To produce nuclear energy, usually uranium is used which is also not available in abundance. Therefore, limiting their use will ensure that our future generations enjoy these benefits. Renewable sources like wind, wave, and solar, hydro, geothermal and tidal energies needs to be explored further for the sake of our future generations. The challenges which are faced by policy makers regarding the fossil fuels include catastrophic disasters which require billions of dollars in the form reconstruction after heavy drought and floods which damage the infrastructure and the economy at large. These disasters can be prevented if all governments are working together to eliminate or reduce the causes of climate change due to global warming. Unfortunately climate change must be addressed by all nations as it is no use for say one country to reduce emissions while others are not doing enough as we share the same atmosphere. The cost of renewable energy has been on the decline as the technology becomes more mature and the installed capacity across the globe increases. Thus more data is available to obtain understanding about the operations and maintenance of these systems. The other advantages of renewable sources are input costs are minimal for example wind energy comes from wind which is free. Same applies to solar energy which uses radiant energy from the sun which is also freely available. The coal and nuclear fuel power stations are currently in the forefront due to the fact that both stations may be used as based load to maintain grid stability in terms of power frequency. The renewable energy sources are very unreliable as they heavily dependent on weather. Unfortunately weather cannot be controlled.The renewable power is derived from biomass, geothermal, hydroelectric, solar, wave and wind. The renewable power tends to be the most expensive option in comparison to the traditional sources (coal, oil and gas, and nuclear). Technology for electricity generation from these renewable sources is now becoming mature and both maintenance and operating cost are decreasing. However, the costs of electricity from the traditional sources may further be increased by the cost of modifying the existing plants in order to comply with the new regulations which will then give renewable power a breakthrough. The renewable technologies appears to be winning the hearts and minds of those who care about environment and the future of the world at large as all sources of renewable are 100% recyclable.

Low Temperature Combustion (LTC) is a strategy that harnesses the properties of exhaust gas, through the use of large quantities of exhaust gas recirculation (EGR), to reduce the peak combustion temperatures below that favoured by the formation processes of oxides of nitrogen (Ox) and those of soot. There is interest within the fuels research community in investigating the effects of diesel fuel formulations on LTC, using a suitable engine test platform. The objective of this study was to design and set up a test apparatus capable of achieving LTC in a diesel research engine, that could subsequently be used to study LTC behaviour with different fuels. In addition, it was necessary to present test data demonstrating the engine's performance, in terms of engine-out emissions and indicated specific fuel consumption (ISFC), transitioning between conventional diesel combustion (CDC) and LTC. The mechanical, electrical and control requirements for attaining CDC and LTC conditions were investigated in the literature and through consultations with experts in the fuels research field. These requirements were distilled into a definitive System Requirement Specification.

M.Phil. (Energy Studies) / Liquid fuels provide in a large percentage of South Africa's energy requirements. Because of the vastness of the country no other means of propelling transport could take the place of liquid fuel. South Africa who has for a substantial period found herself being officially cut-off from international crude oil (embargo) and other commodities such as capital, had up to ± 1991 survive this onslaught. Alternatives for the substitution of crude oil derived products (mostly liquid fuels) has been under investigation for many years, internationally as well as locally~ Because of the recent change in the situation, the approach to new investment in this field will now only be effected should it be economically more attractive than investment in the traditional crude oil processes. This study was specifically aimed at, from a South African viewpoint, summarizing various applicable liquid fuel manufacturing processes and related raw material resources, and comparing these processes both from an economic and technological angle with that of crude oil refining. The following resources were investigated: Coal, torbanite, sugar (from sugar cane), natural gas and sunflower seeds. Processes such as coal to fuels (Fischer-Tropsch, coal hydrogenation, solvent extraction), metanol to fuels (MTG-process), metanol ex natural gas (Mobil-M), methanol ex coal, ethanol ex sugar, natural gas to fuels (Fischer-Tropsch, Shell-SMOS), esters (diesel) ex sunflower seeds, fuels ex torbanite via retorting were researched. Aspects covering the availability of resources, degree of commercialisation of processes, product quality and fuel/engine compatibility and general economic and technological guidelines were covered in the study.

Thesis (M.S.)--University of Wisconsin--Madison, 1983. / Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references (leaves 104-105).

Thesis (MSc)--Stellenbosch University, 2015. / ENGLISH ABSTRACT: With worldwide emissions standards becoming more stringent over the last decade, the South African market seems set to follow suit. Older technology engines are however unable to attain these stringent standards and will require cleaner burning fuels. Biofuels like biodiesel and bioethanol-diesel blends are an attractive option as a result of their inherently oxygenated nature and renewable, low carbon footprint. Oxygenated fuels have been found to lower particulate and soot emissions without any significant increase in NOx, thus alleviating the usual particulate-NOx trade-off. In this study an existing diesel engine test facility has been upgraded to include emission equipment, and a low cost pressure indicating system. Fuel-to-fuel comparative testing was done with pump diesel and splash blended fuels consisting of pump diesel blended with varying amounts of ethanol and also biodiesel without including any cetane enhancing or blend stability additives. Emission analysis of the blended fuels showed a marked reduction in soot emission with little to no increase in NOx emission for all oxygenated fuels. This type of soot reduction without NOx increase is difficult to obtain through any other method. Blend stability was however a problem with the 15% ethanol-diesel blends. / AFRIKAANSE OPSOMMING: Met wêreldwye uitlaatgas standaarde wat al hoe strenger geword het oor die laaste dekade, lyk dit asof dit net ‘n kwessie van tyd is voor Suid-Afrika dieselfde roete volg. Ouer tegnologie binnebrandenjins kan egter nie hierdie streng standaarde handhaaf nie en sal dus vereis dat die brandstof skoner brand. Biobrandstowwe, soos biodiesel en bio-etanol-diesel mengsels, blyk ‘n aantreklike opsie te wees vanweë hul natuurlike inhoud van suurstof en as hernubare hulpbron. Wanneer suurstof houdende brandstowwe soos hierdie verbrand word, word daar gevind dat daar ‘n daadwerklike afname in rook uitlaat is sonder enige merkbare toename in NOx uitlaatgasse. Dit is teenstrydig met die gewoonlike wisselwerking wat daar tussen hierdie twee uitlaatgas produkte is. In hierdie studie word die bestaande diesel enjin toetssel opgegradeer om uitlaatgas analiese toerusting asook ‘n lae-koste silinderdruk meettoestel te bevat. Brandstof-tot-brandstof vergelykings toetse word gedoen met gewone diesel asook toets diesel wat gemengde konsentrasies biodiesel of bio-etanol bevat. Die toets diesel bevat egter geen aanvullings om mengselstabiliteit of cetaan te verbeter nie. Toetsresultate toon dat daar merkbare vermindering in rook uitlaat is met min tot geen toename in NOx. Hierdie tipe van resultaat met produkte van ontbranding is moeilik om op enige ander manier te bewerkstellig. Daar word ook gevind dat diesel met 15 % bio-etanol nie ‘n stabiele mengsel is nie en dat fase skeiding plaasvind.

Mastication is a fuel management technique that disrupts the vertical continuity of forest fuels by mechanical shredding of trees and understory vegetation into a highly-compacted surface fuelbed. The particle size distributions, bulk density and arrangements differ from natural and slash fuel types, thus resulting in fuelbeds with potentially different moisture dynamics and fire behaviour. We conducted three experiments, the first of which examined differences in in-stand micrometeorology and fuelbed moisture content between differing levels of stand thinning via mastication. In the second experiment, a fuel moisture model was created, validated with an independent dataset, and compared with pre-existing models that are incorporated in the Canadian Forest Fire Danger Rating System. In the third experiment, we compared the results of standard ignition tests performed on masticated fuelbeds in the laboratory and field to determine probability of sustained flaming, and compared our findings with pre-existing models of ignition for other forest fuels.

The possibility of using waste vegetable oil from deep-frying processes as a fuel for long term use in diesel engines was investigated. Research was aimed at using existing technology in terms of engine design in order to utilize a maximum amount of waste vegetable oil as the energy source with a minimum of processing. A small swirl-chamber diesel engine was selected and used to run the 200-hour test recommended by the EMA for testing vegetable oil-based fuels. A blend of 20/80 (waste oil/diesel fuel) was tested as well as a 50/50 blend. BSFC data for both blends did not indicate any significant deterioration in engine performance during the 200 hour tests for ail the fuels tested. However, the 50/50 blend BSFC data had more spread than the data from the 20/80 or the diesel baseline test. This was attributed to variable amounts of deposits on the injector nozzle throughout this test Carbon deposits on all other parts of the combustion chamber were comparable for all the fuels tested. Wear of the engine parts was also comparable except for the piston rings. Piston ring wear was greater with diesel fuel and smaller when burning the 50/50 blend. This was attributed to a film of unburned fuel on the cylinder wall that improved lubrication. Lower -lubricating oil consumption was also attributed to this film. The alternate fuel blends completed the 200 hour EMA screening test and could be considered as possible candidates for long-term use in I.D.I, engines. / Applied Science, Faculty of / Graduate

Thermal conductivity is a critical fuel performance property not only for current UO2 oxide fuel based light water reactors but also important for next-generation fast reactors that use U-Zr based metallic fuels. In this work, the thermal transport properties of both UO2 based oxide fuels and U-Zr based metallic fuels have been studied. At first, molecular dynamics (MD) simulations were conducted to study the effect of dispersed Xe fission gas atoms on the UO2 thermal conductivity. Numerous studies have demonstrated that xenon (Xe) fission gas plays a major role on fuel thermal conductivity degradation. Even a very low Xe concentration can cause significant thermal conductivity reduction. In this work, the effect of dispersed Xe gas atoms on UO2 thermal conductivity were studied using three different interatomic potentials. It is found that although these potentials result in significant discrepancies in the absolute thermal conductivity values, their normalized values are very similar at a wide range of temperatures and Xe concentrations. By integrating this unified effect into the experimentally measured thermal conductivities, a new analytical model is developed to predict the realistic thermal conductivities of UO2 at different dispersed Xe concentrations and temperatures. Using this new model, the critical Xe concentration that offsets the grain boundary Kapitza resistance effect on the thermal conductivity in a high burnup structure is studied. Next, the mechanisms on how Xe gas bubbles affect the UO2 thermal conductivity have been studied using MD. At a fixed total porosity, the effective thermal conductivity of the bubble-containing UO2 increases with Xe cluster size, then reaches a nearly saturated value at a cluster radius of 0.6 nm, demonstrating that dispersed Xe atoms result in a lower thermal conductivity than clustering them into bubbles. In comparison with empty voids of the same size, Xe-filled bubbles lead to a lower thermal conductivity when the number ratio of Xe atoms to uranium vacancies (Xe:VU ratio) in bubbles is high. Detailed atomic-level analysis shows that the pressure-induced distortion of atoms at bubble surface causes additional phonon scattering and thus further reduces the thermal conductivity. For metallic fuels, temperature gradient and irradiation induced constituent redistribution in U-Zr based fuels cause the variation in fuel composition and the formation of different phases that have different physical properties such as thermal conductivity. In this work, a semi-empirical model is developed to predict the thermal conductivities of U-Zr alloys for the complete composition range and a wide range of temperatures. The model considers the effects of (a) scattering by defects, (b) electron-phonon scattering, and (c) electron-electron scattering. The electronic thermal resistivity models for the two pure components are empirically determined by fitting to the experimental data. A new mixing rule is proposed to predict the average thermal conductivity in U-Zr alloys based on their nominal composition. The thermal conductivity predictions by the new model show good agreement with many available experimental data. In comparison with previous models, the new model has further improvement, in particular for high-U alloys that are relevant to reactor fuel compositions and at the low-temperature regime for the high-Zr alloys. The average thermal conductivity model for the binary U-Zr fuel is also coupled with finite element-based mesoscale modeling technique to calculate the effective thermal conductivities of the U-Zr heterogeneous microstructures. For a U-10wt.%Zr (U-10Zr) fuel at temperatures below the ɑ phase transition temperature, the dominant microstructures are lamellar δ-UZr2 and ɑ-U. Using the mesoscale modeling, the phase boundary thermal resistance R (Kapitza resistance) between δ-UZr2 and ɑ-U has been determined at different temperatures, which shows a T-3 dependence in the temperature range between 300K and 800K. Besides, the Kapitza resistance exhibits a strong dependence on the aspect ratio of the δ-UZr2 phase in the alloying system. An analytical model is therefore developed to correlate the temperature effect and the aspect ratio effect on the Kapitza resistance. Combining the mesoscale modeling with the newly developed Kapitza resistance model, the effective thermal conductivities of many arbitrary δ-UZr2 + ɑ-U heterogeneous systems can be estimated. / Doctor of Philosophy / Thermal transport in nuclear fuels is critical for both energy conversion efficiency and nuclear energy safety. Therefore, understanding the thermal transport properties such as thermal conductivity of nuclear fuels is not only important for current UO2 oxide fuel-based light water reactors but also critical for next-generation fast reactors that use U-Zr based metallic fuels. The thermal transport mechanisms in the two fuel types are fundamentally different: the predominant heat carriers in UO2 are phonons while they are electrons in U-Zr. This work studies the thermal transport properties for both types of nuclear fuels. At first, molecular dynamics (MD) simulations were conducted to study the effect of dispersed xenon (Xe) fission gas atoms on the UO2 thermal conductivity, because Xe is the major fission gas product and even a small concentration of Xe can cause significant fuel thermal conductivity reduction. In this work, three different interatomic potentials were used to study the Xe effect. It is found that although these potentials result in significant discrepancies in the absolute thermal conductivity values, the normalized values are very similar at a wide range of temperatures and Xe concentrations. By integrating this unified effect into the experimentally measured thermal conductivities, a new analytical model is developed to predict the thermal conductivities of UO2 at different Xe concentrations and temperatures. Then this new model is used to study how dispersed Xe influences the effective thermal conductivity of heterogeneous UO2 microstructures with different grain sizes. Next, we focused on how the presence of Xe bubbles degrades the effective UO2 thermal conductivity using MD. The effects of both Xe gas bubble size and pressure were examined. Our results show that dispersed Xe gas atoms or small Xe clusters result in a lower thermal conductivity than clustering them into larger bubbles if the total porosity is fixed. In comparison with empty voids of the same sizes, a Xe-filled bubble leads to a lower thermal conductivity when the bubbles pressure is high, because the distorted bubble surface can cause additional phonon scattering effect. Besides the UO2 based oxide fuels, U-Zr based metallic fuels are promising fuel forms for next-generation fast reactors due to their high thermal conductivity. In this work, a semi-empirical model with a single set of parameters is developed to predict the average thermal conductivities of U-Zr alloys for the complete composition range and a wide range of temperatures. The thermal conductivities predicted by the new model have good agreement with many available experimental data, even if some experimental data are not included in the model fitting. The above thermal conductivity model for the binary U-Zr alloy has been coupled with finite element-based mesoscale modeling to calculate the effective thermal conductivities of U-Zr heterogeneous microstructures containing ɑ-U and δ-UZr2 lamellar phases. Using the mesoscale modeling, the phase boundary thermal resistance R (Kapitza resistance) between δ-UZr2 and ɑ-U has been determined for a wide range of temperatures as well as the aspect ratio of the lamellar δ-UZr2 phase. An analytical model is therefore developed to correlate the effects of temperature and aspect ratio on the Kapitza resistance. Combining the mesoscale modeling with the newly developed Kapitza resistance model, the effective thermal conductivities of many U-Zr heterogeneous systems can be accurately estimated.

Submitted in complete fulfillment for the Degree of Master of Technology: Biotechnology, Durban University of Technology, Durban, South Africa, 2014. / Global warming is a major concern to the world’s population. It is caused by greenhouse gases that result from the burning of fossil fuel. The fossil fuel reserves are rapidly depleting as the needs and wants of man in the world increases. Biodiesel is one of the solutions proposed to remedy this environmental crisis facing the world today. The aim of this study was to characterise the biodiesel that can be produced from the oil of Litsea glutinosa by transesterification. Biodiesel can be used in a diesel engine without modification and be produced from many different natural renewable oil sources such as algae, plants and kitchen waste material. Jatropha curcas has been identified as a potential producer of oil for biodiesel. The biodiesel properties of Jatropha curcas meet the required American Society for Testing and Materials (ASTM) standards. The fruit of Jatropha curcas contains 40.0% lipids. The oil has a saponification number of 202.6 and an iodine value of 93.0. However Jatropha curcas cannot be grown in South Africa because it is a highly invasive plant. Cetane number is the most important parameter of biodiesel. The higher the cetane value, the better the quality of the biodiesel. Oil from Jatropha curcas has a cetane number of 57.1. An alternative is the oil from Litsea glutinosa, which is found as a naturalised free forest along the South African coastline, and is also found in many Asian countries. It has many medicinal properties, however, it is not edible and hence its use for biodiesel does not add to the debate of fuel versus food production. The cetane number of oil from Litsea glutinosa is 64.79, which is ideal for ignition, and the fruit with 61.29% lipids can yield valuable quantities of biodiesel. Thus, the aim of the research was to determine the potential of Litsea glutinosa as a source of biodiesel. Furthermore, to maintain a sustainable source, Litsea glutinosa was micropropagated, and transformation of Litsea glutinosa was attempted for hairy root cultures. The Clevenger apparatus was used to extract fatty acids from dried crushed fruit of Litsea glutinosa. Fatty acids were converted to fatty acid methyl esters by transesterification. Transesterification was conducted in the presence of nitrogen and the reaction was catalysed with a mixture of methanol and sodium hydroxide (NaOH). The ratio 1 : 3 of oil to catalyst mixture was used for optimum transesterification to ensure a forward reaction and it was transferred to a separating funnel to allow the glycerol and fatty acid methyl esters to separate. GC-MS was used to determine the fatty acids. The iodine number, saponification number, acid value, viscosity, kinematic viscosity, density, specific gravity, thermostability, distillation point and sulphur content were determined. The seeds of Litsea glutinosa were germinated and tissue culture callus was produced from the seeds and leaves. The leaves and stems were used to produce hairy root cultures by inoculating them with Agrobacterium rhizogenes. Litsea glutinosa yielded 61% oil, which included 47 fatty acids in the fruit and 24 fatty acids in the seeds. The fatty acid profile of the oils indicated that the predominant fatty acids present were those that are essential for good quality biodiesel. The dominant fatty acids found in the fruit were 65.4% 9-octadecenoic acid and 13.6% hexadecanoic acid. The dominating fatty acids found in the seeds contained 36.3% 9-octadecenoic acid, 13.9%, hexadecanoic acid and 39.1%, dodecanoic acid. The iodine value was 6.3. The saponification value was 274. The acid value was 0.45 mg KOH. g-1. The viscosity was 22.48 mm2. s-1 and the kinematic viscosity was 23.84 mm2. s-1. The density was 942.69 kg. m-3 and the specific gravity was found to be 0.9 g. cm-3. The distillation temperature ranged between 52.2°C to 610.2°C. The sulphur content was found to be 383 µg. ml-1. These characteristics indicate that Litsea glutinosa can be used as a source of biodiesel, because the properties meet the required ASTM standards. However, the production of biodiesel from Litsea glutinosa has not been commercialised because the production of fuel is dependent on the fruit of the plant, which is seasonal. To overcome this, a part of this study investigated micropragation of Litsea glutinosa and transformation of Litsea glutinosa by Agrobacterium rhizogenes into hairy roots and attempts where made to determine whether fatty acid could be produced by these techniques. Callus cultures were grown on MS media and McCowns woody plant media supplemented with 1 ml BAP and 1 ml 2,4-D per 1 L of media. Callus cultures were obtained in the light. However, Litsea glutinosa resisted transformation by Agrobacterium rhizogenes.