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Synthesis and Electrical Behavior of VO2 Thin Films Grown on SrRuO3 Electrode LayersChengyang Zhang (12889487) 17 June 2022 (has links)
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<p>In this study, VO2 films were grown on conducting oxide SrRuO3 layers. Apart from applications in magnetism, SrRuO3 is a widely studied template material to create multi-functional oxide heterostructures. Here, SrRuO3 buffered SrTiO3 (111) and Si/SiO2 were selected as platforms for VO2 growth. The properties of VO2 thin films grown on SrRuO3 buffer layers, as well as thermally and electric-field induced metal-insulator transition were systematically studied. Numerous growth experiments were conducted to identify the optimal growth conditions. Utilizing the current shunting associated with the conductive underlayer, electric-field induced metal-insulator transition was investigated in both the in-plane and out-of-plane configurations. A distributed resistance network with general applicability to understanding metal-insulator transitions is proposed to predict the electrical behavior of VO2 grown on conducting layers.</p>
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LASER - LIQUID METAL INTERACTION AND ITS APPLICATIONSLicong An (7199099) 20 July 2022 (has links)
<p>Room-temperature liquid metal, such as eutectic gallium indium (EGaIn), has attracted significant attention for the fabrication of high-density electronics, functional composites, and two-dimensional nanomaterials due to the high electrical conductivity, high thermal conductivity, low toxicity, and its naturally formed oxide skin. Pulsed laser beams are proved to be promising to process liquid metal due to laser induced high temperature and high pressure. Although extraordinary progresses are made, limitations that remain in advanced manufacturing and material performance are crucial to overcome before liquid metal can be more practically used. The goal of this dissertation is to utilize the unique interaction between laser and liquid metal to design and fabricate nanomaterials with scalable functionalities towards potential device applications. </p>
<p>This dissertation is composed of a general review of related background and experimental methods, followed by three chapters of detailed research and one chapter of conclusion. In the first research chapter, liquid metal is used, due to its high electrical conductivity and high fluidity, to create self-packaged, high-resolution liquid metal patterns by the advanced pulsed laser lithography (PLL) technology. The PLL method here, for the first time, can directly generate self-packaged liquid metal nano-patterns with high resolution without being limited by laser beam size. The electrically self-packaged material is an intriguing candidate to serve in demanding applications with high integration densities. In the second research chapter, liquid metal is utilized to boost the thermal conductivity of porous metal-organic frameworks (MOFs) to realize a high energy-harvesting efficiency. In this work, a facile and straightforward manufacturing method, laser shock-induced evaporation, is devised to deposit liquid metal nanoparticle (LMNP) thin layers to the surface of MOFs, resulting in the MOF@LMNP nanocomposites with a boosted thermal conductivity. In the last research chapter, liquid metal is employed to create large-scale metal oxide thin film patterns by an advanced confined laser transfer printing (CLTP) technique. This technology can generate metal oxide thin films patterns with tunable thickness and electrical property in nano-second scale that were previously inaccessible with conventional methods. This room temperature confined laser transfer printing method is promising to provide the possibility to pattern metal oxide thin films into advanced electronic components. As a summary, these studies present different laser manufacturing approaches in addressing liquid metal fabrication challenges from fundamental materials perspective. </p>
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Electro-Optical Na0.5K0.5NbO3 FilmsBlomqvist, Mats January 2005 (has links)
Ferroelectric oxides are a group of advanced electronic materials with a wide variety of properties useful in applications such as memory devices, resonators and filters, infrared sensors, microelectromechanical systems, and optical waveguides and modulators. Among the oxide perovskite-structured ferroelectric thin film materials, sodium potassium niobate or Na0.5K0.5NbO3 (NKN) has recently emerged as one of the most promising materials in radio frequency (rf) and microwave applications due to high dielectric tenability and low dielectric loss. This thesis presents results on growth and structural, optical, and electrical characterization of NKN thin films. The films were deposited by rf-magnetron sputtering of a stoichiometric, high density, ceramic Na0.5K0.5NbO3 target onto single crystal LaAlO3 (LAO), Al2O3 (sapphire), SrTiO3, and Nd:YAlO3, and polycrystalline Pt80Ir20 substrates. By x-ray diffractometry, NKN films on c-axis oriented LaAlO3, SrTiO3 and Nd:YAlO3 substrates were found to grow epitaxially, whereas films on r-cut sapphire and polycrystalline Pt80Ir20 substrates were found to be preferentially (00l) oriented. The surface morphology was explored using atomic force microscopy. Optical and waveguiding properties of the Na0.5K0.5NbO3/substrate heterostructures were characterized using prism-coupling technique. Sharp and distinguishable transverse magnetic and electric propagation modes were observed for NKN thicknesses up to 2.0 μm. The extraordinary and ordinary refractive indices were calculated together with the birefringence of the NKN material. The electro-optic effect in transverse geometry was measured in transmission, where the effective linear electro-optic response was determined to reff = 28 pm/V for NKN/Al2O3 with an applied dc field up to 18 kV/cm. The ferroelectric state in NKN films on Pt80Ir20 at room temperature was indicated by a polarization loop with saturated polarization as high as 33.4 μC/cm2 at 700 kV/cm, remnant polarization of 10 μC/cm2, and coercive field of 90 kV/cm. Current-voltage characteristics of vertical Au/NKN/PtIr capacitive cells and planar Au/NKN/LAO interdigital capacitors (IDCs) showed very good insulating properties, with the leakage current density for an NKN IDC on the order of 30 nA/cm2 at 400 kV/cm. Rf dielectric spectroscopy demonstrated low loss, low frequency dispersion, and high voltage tunability. At 1 MHz, NKN/LAO showed a dissipation factor tan δ = 0.010 and a tunability of 16.5 % at 200 kV/cm. For the same structure the frequency dispersion was Δεr = 8.5 % between 1 kHz and 1 MHz. / QC 20100928
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ELECTRONID TEXTILES BY PROGRAMMABLE OVERCOAT OF FUNCTIONAL MATERIALSTae Hoo Chang (15307624) 17 April 2023 (has links)
<p>Textiles have gained popularity in wearable products due to their potential for wearability, comfort, flexibility, breathability, and seamless fit to the human body. The growing demand for remote telehealth monitoring has led to advancements in the field of e-textiles. Various approaches, such as dip coating, screen printing, inkjet printing, and vapor deposition, are utilized to overcoat fabrics with active nanomaterials. However, practical deployment still faces challenges due to a lack of rapid prototyping for scalable and customizable e-textiles. To meet the requirements of large-scale batch production, high-resolution electrode line width, and long-term durability, new platform technologies have been established to convert existing textiles into multifunctional e-textiles. These studies have also revealed the process-structure-property relationships of various e-textiles.</p>
<p>Chapter I overviews the recent results and current limitations of e-textiles in wearable sensing and display. Since people stay and work in various circumstances, continuous monitoring of physical, electrophysiological signals on skin in ambulatory manners is necessary to evaluate hazardous situation or chronicle symptoms. For these reasons, fabrication of smart e-textiles is crucial. In this chapter, various conductive materials, overcoating methods, and sensor structures for physical and electrophysiological sensors are reviewed. In addition, as a useful user communication tool with different sensor system, e-textile formats of displays are developed. The comprehensive e-textile displays from DC-driven to AC-driven are presented.</p>
<p>Chapter II introduces a dual-regime spray technique that enables the direct writing of functional nanoparticles onto commercial 4-way stretchable textiles up to a meter scale with high-resolution mask-free patterning. The resulting e-textiles maintain the intrinsic properties of the fabric and can conform to various body shapes, enabling high-fidelity recording of physiological and electrophysiological signals under ambulatory conditions. Field tests have shown the potential of these e-textiles for minimally obtrusive remote telehealth monitoring of large animals.</p>
<p>Chapter III presents an in-situ polymerization and patterning technique that utilizes the dual-regime spray method to synthesize conductive polymers directly onto commercial stretch textiles. The resulting e-textiles are utilized for strain sensors that conform closely to the human body, providing exceptional measurement accuracy and fidelity in capturing physical signals and motion detections.</p>
<p>Conclusion section summarizes this dissertation with pointing out important results and discussions of each study. As an innovative additive manufacturing technology, dual-regime spray system, was established and developed to open new field in manufacture of e-textile. At last of this section, the potential research opportunities and perspectives are addressed. </p>
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Lignin in Cosmetics: State of the Art : Discerning the value of lignin in the cosmetic industryHenriksson, Nellie, Nordell, Klas January 2023 (has links)
This study was carried out at the Department of Nanotechnology and Functional Materials,Uppsala University, one of several places where the interest of lignin in cosmetics is constantly growing. The functionalities of lignin have been studied to a great extent revealing its potential as a natural biopolymer to serve as a replacement for environmentally hazardous components in cosmetic formulations, namely UV-filters in sunscreens. Using ethnographic methods and qualitative interviews the lignin-cosmetic industry was observed and analyzed in order to discern how concerned the industry is with ecological andaesthetic value. Ecological value is a hallmark of the value proposition in the cosmetic industry, and leaders of the industry indeed share this view. The analysis further revealed that the actors of the lignin-cosmetic industry are at different stages of development and that as of this year we can expect the first product to be launched. Furthermore, the value chain of the lignin actors was identified and for the first time mapped out in detail from the qualitative analysis that was carried out targeting lignin actors within the lignin-cosmetic industry. Mapping the value chain revealed the actors included in the entire chain identified as biorefinery, manufacturer, modifier, formulator, distributor and retailer which together compose the lignin-cosmetic value chain. A qualitative, semi structured interview approach was used and adapted as we met with eleven actors interviewing them about ecological and aesthetic values in the lignin based product value proposition. The grounded theory was applied to analyze the data, generating eight categories representing the concepts comprising ecological and aesthetic values of the value proposition. The kernel category, Green Profile, explains the most important concepts valued by lignin actors in terms of what ecological and aesthetic value could be offered to be appealing to customers. The findings of this study reveals the current situation of lignin in the cosmetic market as of today, and discerns where the value of lignin lies. The understanding of lignin actors' values contributes to the current gray-area in biopolymer research, lacking information on the value chain of lignin in cosmetics. The findings therefore foster the advancement of sustainable innovative solutions for cosmetics and personal care.
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Complex Excitations in Advanced Functional MaterialsLüder, Johann January 2016 (has links)
Understanding the fundamental electronic properties of materials is a key step to develop innovations in many fields of technology. For example, this has allowed to design molecular based devices like organic field effect transistors, organic solar cells and molecular switches. In this thesis, the properties of advanced functional materials, in particular metal-organic molecules and molecular building blocks of 2D materials, are investigated by means of Density Functional Theory (DFT), the GW approximation (GWA) and the Bethe-Salpeter equation (BSE), also in conjunction with experimental studies. The main focus is on calculations aiming to understand spectroscopic results. In detail, the molecular architectures of lutetium-bis-phthalocyanine (LuPc2) on clean and hydrogenated vicinal Si(100)2×1, and of the biphenylene molecule on Cu(111) were analysed by means of X-ray Photoelectron spectroscopy (XPS) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy; DFT calculations were performed to obtain insights into the atomic and electronic structures. Furthermore, detailed information about the electronic states of the gas phase iron phthalocyanine (FePc) and of the gas phase biphenylene molecule were obtained through XPS and NEXAFS spectroscopy. I have studied by means of DFT, multiplet and GWA calculations the electronic correlation effects in these systems. Also the optical, electronic and excitonic properties of a hypothetical 2D material based on the biphenylene molecule were investigated by GWA and BSE calculations. Monolayers of metal-free phthalocyanine (H2Pc) on Au(111) and of FePc on Au(111) and Cu(100)c(2×2)-2N/Cu(111) with and without pyridine modifier were studied by XPS and final state calculations. A multiplet approach to compute L-edges employing the hybridizations function, known from dynamical mean field theory, was proposed and applied to transition metal oxides.
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Transition metal fluorides : from superconductors to multiferroicsDrathen, Christina January 2013 (has links)
Transition metal fluorides represent an important family of complex solids displaying a variety of different properties and interesting phenomena. Despite their remarkable behaviour, these classes of materials have not received much attention and the rationalization of their behaviour is still lacking a systematic approach. This thesis aims to contribute to the field by examining previously unknown or understudied complex fluorides. The compounds were selected for their intriguing physical properties that range from superconductivity to multiferroism. The discovery of superconductivity in the iron pnictides sparked new interest in materials with layered ZrCuSiAs-type structure. Herein the properties of one of these systems, namely SrFeAsF, will be discussed. We have found that it behaves as a poor metal and undergoes a tetragonal (P4/nmm) to orthorhombic (Cmma) structural transition at T = 180 K, accompanied by a spin density wave in magnetic susceptibility and electrical resistivity. Below T < 150 K, the Fe moments order in antiferromagnetic spin-stripes. Electron doping with La3+ is a successful route to obtain superconducting phases, with maximum Tc = 27 K (x = 0.2). The isostructural AeMnPnF series (Ae = Sr, Ba; Pn = P, As, Sb) was also investigated to elucidate the influence of transition metal d-electrons and size effects of Ae and Pn on the physical properties. The isoelectronic replacement of Ae and Pn leads to a significant distortion in the tetragonal building blocks. All d5 Mn fluorides investigated here are insulating antiferromagnets with TN ~ 350 K. Due to the coexistence of electronic and magnetic ordering, the tetragonal tungsten bronze (TTB) materials KxM2+ xM3+ 1-xF3 (x = 0.4 – 0.6; M = transition metal) are potential multiferroics. The type of structural distortion adopted by these systems is strongly dependant on the M2+/M3+ ratio. For instance, our high-resolution diffraction study on K0.5Mn0.5Cr0.5F3 has revealed a small orthorhombic distortion, which indicates full chemical order of Mn2+ and Cr3+ on all crystallographic sites. K0.5Mn0.5Cr0.5F3 remains orthorhombic Ccc2 on cooling through the ferromagnetic transition at TN = 23 K. On heating, the structure is acentric up to T = 373 K, where a change to tetragonal P42/mbc symmetry marks the transition from ferroelectric (polar) to paraelectric (apolar) states. High-pressure diffraction experiments have shown that the Ccc2 structure is robust upon pressurization with anisotropic axial compressibility up to the maximum pressure applied p = 18 GPa. The crystal structure of related mixed-valence TTB fluoride K0.6Cr2+ 0.6Cr3+ 0.4F3 is influenced by the presence of Jahn-Teller active Cr2+. The structural analysis described here revealed the presence of a small polar monoclinic distortion (P112) providing a clear signature of full charge order (CO). On heating, the gradual loss of CO leads to two consecutive structural phase transitions to orthorhombic (Pba2, T = 423 K) and then tetragonal (P42/mbc, T = 823 K) lattices, the latter is the signature of the ferro- to paraelectric transition. Below T = 150 K, increased X-ray exposure time leads to CO-melting and the stabilization of a new, charge-disordered orthorhombic phase (Cmm2), with a phenomenology similar to the CO manganites. In highpressure diffraction experiments, a further transition to tetragonal P4bm symmetry is found at p = 6 GPa. The magnetic susceptibility points towards a complex spin arrangement, with two transitions at TN = 33 K and 6 K. The results presented herein show the richness of the structural, electronic and magnetic phase diagrams of transition metal fluorides and clearly demonstrate that systematic studies on these systems will greatly enhance our current understanding of the underlying mechanisms of important phenomena such as superconductivity and ferroelectricity.
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P-type, misfit layered structure cobaltite for thermoelectric applicationsKulwongwit, Nuth January 2017 (has links)
The thermoelectric properties and microstructure of two families of misfit type layered structure cobaltites were investigated for thermoelectric applications. Firstly, Bismuth strontium cobaltite ceramics with the formulations Bi2+xSr2Co2Oy (x=0, 0.1 and 0.2), Bi1.74Sr2Co1.8Oy and Bi2Sr2Co1.8Oy were produced using solid-state reaction (MO) method. The same powders were also used to produce ceramics by Spark Plasma Sintering (SPS) fabrication technique. SEM, high resolution XRD and HRTEM techniques has been employed to characterise the microstructure and crystal structures of the ceramics. Figure of merit (ZT) was also determined from measurement of electrical resistivity, Seebeck coefficient and thermal conductivity. Together with the above, calcium cobaltite of formulation Ca3-xBixCo3O9 (x=0 and 0.3) was also produced via MO and SPS routes. The same characterisation techniques were used for characterisation of calcium cobaltite. For Bi2+xSr2Co2Oy ceramics, it was found that SPS fabrication is essential to obtain high density samples. Excess bismuth has a major role in the adjustment of the microstructure and thermoelectric properties. The room temperature microstructure contains two minor phases with compositions of CoO and Bi0.75Sr0.25O1.26. The crystal structure of the main phase was successfully indexed and refined as misfit type structure having monoclinic symmetry with I2/a space group. A high ZT of 0.12 was achieved in both x=0.1 and 0.2 MO samples. For Bi2Sr2Co1.8Oy ceramics, the microstructure contains only one minor phase, Bi0.75Sr0.25O1.26. A high ZT of 0.16 was obtained at 900 K for this composition. For Bi1.74Sr2Co1.8Oy, it was not possible to obtain high density ceramics by MO route and SPS fabrication was necessary. However, SPS sample showed a low ZT of 0.04 at 900 K.For ceramics of formulation Ca3-xBixCo3O9 (x=0 and 0.3), it was difficult to obtain high density calcium cobaltite ceramics by MO route and SPS fabrication was found to be essential. In addition to improved density, SPS produced textured microstructure. Similar to bismuth strontium cobaltite, excess bismuth played a major role in microstructure development and thermoelectric properties. Single phase and high density Ca3Co4O9 ceramics were obtained by SPS. A minor phase of Bi2Ca2Co2Oy was found in the microstructure of Ca3-xBixCo3O4 (x=0.3) samples. A high ZT of 0.25 was obtained for Ca3Co4O9 SPS samples at 900 K through improvement of power factor. In-situ synchrotron XRD in the temperature range of 300-1223 K was performed on both Bi2Sr2Co2Oy and Ca3Co4O9 to obtain their high temperature structural characteristics. The crystal structure of both compounds remains unchanged till 1223 K. For, Bi2Sr2Co2Oy the CoO and Bi0.75Sr0.25O1.26 minor phases disappear above 1073 K and a new minor phase containing (Bi-Sr-O) or (Bi-Co-O) starts forming. On heating, the lattice volume and coefficient of thermal expansion change linearly for both compounds. Thermal expansion coefficient was found to be 0.0000353-0.0000343 and 0.0000296-0.0000288 K-1 over the temperature range of 300-1223 K for Bi2Sr2Co2Oy and Ca3Co4O9 respectively.
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Comparative Study of APFO-3 Solar Cells Using Mono- and Bisadduct Fullerenes as AcceptorHsu, Yu-Te January 2010 (has links)
<p>The urgent need for new, sustainable energy source intrigues scientists to provide the solution by developing new technology. Polymer solar cell appears to be the most promising candidate for its low cost, flexibility, and massive producibility. Novel polymers have been constantly synthesized and investigated, while the use of PCBM as acceptor seems to be the universal choice. Here, we studied the use of four dierent fullerene derivatives - [60]PCBM, [70]PCBM, and their bisadduct analogues - as acceptor in APFO-3 solar cells. A series of investigations were performed to study how the processing parameters - blend ratio, spin speed, and choice of solvent - influence the device performance. Using bisadduct fullerenes results in an enhanced Voc, as predicted by the up-shift of energy levels, but a strongly reduced Jsc, hence a poor PCE. Photoluminescence study indicates that all APFO-3:fullerene devices are limited by the inefficient dissociation of fullerene excitations, while it becomes more influential when bisadduct fullerenes were used as acceptor. The best device in this study was fabricated by using [70]PCBM as acceptor and chlorobenzene as solvent, exhibits a PCE of 2.9%, for the strong absorption, ne morphology, and comparatively strong driving force.</p>
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Comparative Study of APFO-3 Solar Cells Using Mono- and Bisadduct Fullerenes as AcceptorHsu, Yu-Te January 2010 (has links)
The urgent need for new, sustainable energy source intrigues scientists to provide the solution by developing new technology. Polymer solar cell appears to be the most promising candidate for its low cost, flexibility, and massive producibility. Novel polymers have been constantly synthesized and investigated, while the use of PCBM as acceptor seems to be the universal choice. Here, we studied the use of four dierent fullerene derivatives - [60]PCBM, [70]PCBM, and their bisadduct analogues - as acceptor in APFO-3 solar cells. A series of investigations were performed to study how the processing parameters - blend ratio, spin speed, and choice of solvent - influence the device performance. Using bisadduct fullerenes results in an enhanced Voc, as predicted by the up-shift of energy levels, but a strongly reduced Jsc, hence a poor PCE. Photoluminescence study indicates that all APFO-3:fullerene devices are limited by the inefficient dissociation of fullerene excitations, while it becomes more influential when bisadduct fullerenes were used as acceptor. The best device in this study was fabricated by using [70]PCBM as acceptor and chlorobenzene as solvent, exhibits a PCE of 2.9%, for the strong absorption, ne morphology, and comparatively strong driving force.
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