The use of waste (or recycled) wood as a fuel in heat and power stations is becoming more widespread in Sweden (and Europe), because it is CO2 neutral with a lower cost than forest fuel. However, it is a heterogeneous fuel with a high amount of chlorine, alkali and heavy metals which causes more corrosion than fossil fuels or forest fuel. A part of the boiler which is subjected to a high corrosion risk is the furnace wall (or waterwall) which is formed of tubes welded together. Waterwalls are made of ferritic low-alloyed steels, due to their low price, low stress corrosion cracking risk, high heat transfer properties and low thermal expansion. However, ferritic low alloy steels corrode quickly when burning waste wood in a low NOx environment (i.e. an environment with low oxygen levels to limit the formation of NOx). Apart from pure oxidation two important forms of corrosion mechanisms are thought to occur in waste environments: chlorine corrosion and alkali corrosion. Although there is a great interest from plant owners to reduce the costs associated with furnace wall corrosion very little has been reported on wall corrosion in biomass boilers. Also corrosion mechanisms on furnace walls are usually investigated in laboratories, where interpretation of the results is easier. In power plants the interpretation is more complicated. Difficulties in the study of corrosion mechanisms are caused by several factors such as deposit composition, flue gas flow, boiler design, combustion characteristics and flue gas composition. Therefore, the corrosion varies from plant to plant and the laboratory experiments should be complemented with field tests. The present project may thus contribute to fill the power plant corrosion research gap. In this work, different kinds of samples (wall deposits, test panel tubes and corrosion probes) from Vattenfall’s Heat and Power plant in Nyköping were analysed. Coated and uncoated samples with different alloys and different times of exposure were studied by scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDX), X-ray diffraction (XRD) and light optical microscopy (LOM). The corrosive environment was also simulated by Thermo-Calc software. The results showed that a nickel alloy coating can dramatically reduce the corrosion rate. The corrosion rate of the low alloy steel tubes, steel 16Mo3, was linear and the oxide scale non-protective, but the corrosion rate of the nickel-based alloy was probably parabolic and the oxide much more protective. The nickel alloy and stainless steels showed good corrosion protection behavior in the boiler. This indicates that stainless steels could be a good (and less expensive) alternative to nickel-based alloys for protecting furnace walls. The nickel alloy coated tubes (and probe samples) were attacked by a potassium-lead combination leading to the formation of non-protective potassium lead chromate. The low alloy steel tubes corroded by chloride attack. Stainless steels were attacked by a combination of chlorides and potassium-lead. The Thermo-Calc modelling showed chlorine gas exists at extremely low levels (less than 0.1 ppm) at the tube surface; instead the hydrated form is thermodynamically favoured, i.e. gaseous hydrogen chloride. Consequently chlorine can attack low alloy steels by gaseous hydrogen chloride rather than chlorine gas as previously proposed. This is a smaller molecule than chlorine which could easily diffuse through a defect oxide of the type formed on the steel. / <p>QC 20130423</p>

In the thesis researches of overall performance of the polymerization furnace of Uralasbest plant are executed. The existing thermal scheme and a design of the furnace is considered, thermal calculation is carried out and technical solutions on improvement of thermal and ecological characteristics of the furnace operation are proposed. Researches showed that ecological characteristics mineral-wool production doesn't satisfy to requirements to environmental standards, and for decrease in emissions of nitrogen oxides more effective burner system is proposed. On the basis of the executed measurements and balance calculations technical actions on decrease in thermal losses with the leaving gases are offered. / В диссертации выполнены исследования эффективности работы печи полимеризации цеха ОАО «Ураласбест». Рассмотрена существующая тепловая схема и конструкция печи, проведен тепловой расчет и предложены технические решения по совершенствованию тепловых и экологических характеристик работы печи. Исследования показали, что с точки зрения экологических характеристик минераловатное производство не соответствует требованиям к экологическим нормам, и для снижения выбросов оксидов азота предложена более эффективная горелочных система..На основе выполненных измерений и балансовых расчетов предложены технические мероприятия по снижения тепловых потерь с уходящими газами.

Камерная нагревательная печь усовершенствована путем реконструкции каркаса, применением новых теплоизоляционных материалов, использованием новых газовых горелок, работающих в импульсном режиме, и оснащенных системой автоматики. Решена задача нагрева массы металла до заданной температуры. Рассмотрен импульсный нагрев этой массы по заданной программе. Проведен тепловой расчет печи, гидравлические расчеты газопроводов, воздухопроводов, тракта дымовых газов, дана оценка экономической эффективности. Приведено описание системы автоматики. / A chamber furnace has been renovated with using some new technologies, as well as: reconstruction of the skeleton, using new thermoinsulation materials and installation of new gas burners operating at pulse mode with automatical control system. A task of metal mass heating up to the given temperature was solved. Heating processes at the pulse mode with set program was considered. The thermal calculation of furnace, hydraulic calculations of gas pipelines, air and flue gases supply systems were held. Economical efficiency estimation was given. Automatical control system was described.

The master's thesis is devoted to the design development, the calculation of the thermal and gas-dynamic modes of operation of a furnace furnace of the baraban type, designed to heat metal products before quenching. In the course of work, heat engineering calculations were carried out for a new drum-type furnace design, the heat balance of the furnace was obtained, and computer simulation of gas dynamics in the working space of the chamber furnace was carried out in the Ansys Fluent software module. The results of the work can be used in the performance of research and development work at metallurgical enterprises, as well as in the educational process for training bachelors and undergraduates in the direction of “Metallurgy” (bachelor’s and master’s level). / Магистерская диссертация посвящена разработке конструкции, расчету теплового и газодинамического режимов работы камерной печи барабанного типа, предназначенной для нагрева металлических изделий перед закалкой. В ходе работы проведены теплотехнические расчеты для новой конструкции печи барабанного типа, получен тепловой баланс печи, в программном модуле Ansys Fluent проведено компьютерное моделирование газодинамики в рабочем пространстве камерной печи. Результаты работы могут быть использованы при выполнении научно-исследовательских работ на металлургических предприятиях, а также в учебном процессе для обучения бакалавров и магистрантов по направлению «Металлургия» (уровень бакалавриата и магистратуры).

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[pt] As jazidas mundiais de minérios de ferro tendem ao empobrecimento dos teores de ferro, aumento das gangas (sílica, alumina, fósforo, etc.) e maiores ocorrências de minérios hidratados. Esta mudança vem gerando um esforço no sentido de aprimorar as técnicas de extração e beneficiamento. O fósforo é um contaminante que em certos teores provoca a fragilização dos aços, sendo, portanto, restritivo ao aproveitamento de importantes jazidas minerais, principalmente as ricas em minérios de origens intempéricas ou supergênicas. Vários trabalhos foram e estão sendo conduzidos visando desenvolver tecnologias capazes de reduzir o teor de P durante o processo de beneficiamento. Porém, até o momento não têm mostrado viabilidade econômica, face à escala de produção e a efeitos danosos ao ambiente. No caso da Samarco, os minérios foram gerados principalmente por processos de enriquecimento supergênico, nos quais é comum a presença de considerável goethita, que é apontada como principal mineral portador do fósforo. O objetivo deste trabalho foi, de forma original, a formulação de uma pelota para redução direta de forma que o fósforo se encontrasse fluxado em fases escorificadas. Essas fases, produzidas através de um adequado ciclo térmico de endurecimento e com composição química otimizada, resultaria em pelotas onde este elemento se mantivesse estável, tanto na produção do DRI quanto na fusão e refino oxidante deste no FEA. Para tanto foram realizados, além de uma ampla revisão bibliográfica, concebido um procedimento analítico original para quantificação apenas do fósforo liberado; planejado experimentos para: a avaliação cinética da migração deste fósforo em pellet feed, nas pelotas e no DRI quando submetido a diferentes aportes térmicos e auto-fluxagens; analise da influência das variáveis do processo de endurecimento sobre a liberação do fósforo e sua escorificação; e comprovação da estabilidade das fases escorificadas durante a redução, em escala de laboratório, e durante a fusão e refino conduzido em um FEA semi-industrial. Os resultados obtidos mostraram ser viável a produção de pelotas para redução direta com o fósforo auto-fluxado em fases estáveis. / [en] Actually the iron ore deposits in the world have the tendency to decrease the iron content, increasing the gangue (silica, alumina, phosphorus, etc.) and to further occurrence of hydrated ores. This change demands improvements in concentration processing techniques for feasible mining operations. The phosphorus is a contaminant that, in some contents, causes the embrittlement of steels, been, wherefore, a limitative to the use of important ore deposits, mostly regarding the weathered iron ores or supergene origins. Several studies were and have been conducted aiming to develop technologies capable of decreasing the P content during the beneficiation process. However, until now, the economic viability of such studies has not been feasible, considering the production scale and the harmful effects to the environment. In Samarco’s case, the mine geological formation is mostly supergene, which is responsible for the presence of the goethite ores, pointed as the main phosphorus carrier. The main point of this work was, with an innovating approach, formulate a new type of pellet addressed to direct reduction processes in a manner that the P could be fluxed into the slag phases. These phases, produced through an adequate thermal cycle of induration and with an optimized chemical composition, resulted in pellets with stable slags containing, as well as in the produced DRI and in the melted bath generated during the primary refining performed in the EAF. For this purpose, it was done, further to a wide bibliographic review, an original analytical procedure to quantify the released phosphorus and a series of planned experiments, such as: the kinetic evaluation of the phosphorus migration from the mineral phases of the pellet feed when subjected to different thermal treatments; analysis of the induration process variables which could affect the phosphorus release and its fluxing into the slag ; Finally, the stability of the fluxing phases during the reduction in a laboratory scale and the melting and refining process in a semi-industrial EAF, were performed. The obtained results showed the feasibility of this new approach produce DR pellets with self-fluxed phosphorus trapped in stable phases.

Gas stirring is currently the most commonly used method of homogenizing liquid steel in commercial processes. However, due to the harsh environment during the process, physical models built out of e.g. plexiglass have been used to easier understand the complex phenomenon occurring in the process. The models are also used to optimize stirring conditions and estimate mixing times. Instead of liquid steel, water has been used for modelling, to increase safety and reduce costs. The water models are usually scaled down to sizes that are easier to handle. Scaling correctly requires fulfilling commonly used criteria and dimensionless numbers. This report investigated the accuracy of these dimensionless numbers and the relations commonly used for scaling. Existing studies and relations were evaluated, and the theoretically best suitable scaling equations were tested. Three bottom blown vessels were built, in order to test the existing relations. By applying scaling criteria and calculating gas flow rates accordingly, the correlation between theoretical mixing time and measured mixing time could be investigated. This thesis concluded that the correlation between the measured mixing times was not significant, however, by implementing the scale factor λ1/2 a better approximation seems to be given. / Gasomrörning är för tillfället den vanligaste metoden som används för att homogenisera flytande stål i kommersiella processer. På grund av de svåra förhållandena under processen har fysiska modeller, byggda av exempelvis plexiglas, använts. Detta för att enklare förstå de komplexa fenomen som uppstår under processen. Modellerna används också för att optimera omrörningsförhållandena och för att uppskatta blandningstider. Istället för flytande stål har vatten använts vid modellering för att öka säkerheten och minska kostnaderna. Vattenmodellerna är vanligtvis nedskalade till storlekar som är lättare att hantera. En korrekt skalning kräver att vanliga kriterier och dimensionslösa tal uppfylls. Denna rapport undersökte noggrannheten för dessa dimensionslösa tal samt relationer som vanligtvis används vid skalning. Befintliga studier och relationer utvärderades och de teoretiskt mest lämpliga skalningsekvationerna testades. Tre stycken kärl med bottenblåsning byggdes för att testa dessa relationer. Genom att tillämpa skalningskriterier och beräkna gasflödeshastigheterna, kunde korrelationen mellan de teoretiska och uppmätta blandningstiderna undersökas. Denna avhandling drog slutsatsen att korrelationen mellan de uppmätta blandningstiderna inte var signifikant. Dock verkade en bättre approximation fås när skalfaktorn λ1/2 implementerades.

The electric power supply industry has evolved into one of the largest industries. Even though secure and reliable operation of the electric power system is fundamental to economy, social security and quality of modern life, the complicated power grid is now facing severe challenges to meet the high-level secure and reliable operation requirements. New technologies will play a major role in helping today's electric power industry to meet the above challenges. This dissertation has focused on some key technologies among them, including the emerging technologies of energy storage, controlled power electronics and wide area measurement technologies. Those technologies offer an opportunity to develop the appropriate objectives for power system control. The use of power electronics based devices with energy storage system integrated into them, such as FACTS/ESS, can provide valuable added benefits to improve stability, power quality, and reliability of power systems. The study in this dissertation has provided several guidelines for the implementation of FACTS/ESS in bulk power systems. The interest of this study lies in a wide range of FACTS/ESS technology applications in bulk power system to solve some special problems that were not solved well without the application of FACTS/ESS. The special problems we select to solve by using FACTS/ESS technology in this study include power quality problem solution by active power compensation, electrical arc furnace (EAF) induced problems solution, inter-area mode low frequency oscillation suppression, coordination of under frequency load shedding (UFLS) and under frequency governor control (UFGC), wide area voltage control. From this study, the author of this dissertation reveals the unique role that FACTS/ESS technology can play in the bulk power system stability control and power quality enhancement in power system. In this dissertation, almost all the studies are based on the real system problems, which means that the study results are special valuable to certain utilities that have those problems. The study in this dissertation can assist power industry choose the right FACTS/ESS technology for their intended functions, which will improve the survivability, minimize blackouts, and reduce interruption costs through the use of energy storage systems. / Ph. D.

The task of the diploma thesis named VBA and Maple Application on Process Engineering Problems is to show the possibilities of using these programming languages for various engineering tasks. Particularly the programming language Visual Basic for Application (VBA), which is a part of MS Office package, is very little used in practise. That´s why this thesis solves the complex task of a furnaces design process; the topic was reccomended by the supervisor prof. Ing. Josef Kohoutek, CSc. Specifically, the thesis deals with calculations of heat transfer and optimization of the height of extended surfaces of tubes in the convection section of process furnaces. The entire task is elaborated in VBA and runs in Excel. After entering the input information, the created program first calculates the size and heat output of the convection section, but it can also optimize the height of extended surfaces in different parts of the convection section and thus minimize investment costs.

Sr₃Ru₂O₇ is a quasi-two-dimensional metal and has a paramagnetic ground state that is heavily renormalised by electron-electron correlations and magnetic exchange interactions. Inextricably linked to this renormalisation is the metamagnetism of Sr₃Ru₂O₇ - a rapid rise in uniform magnetisation over a narrow range of applied magnetic field. Knowledge of the zero-field physics is essential to any description of the metamagnetism. Light may be shed on the enigmatic ground state of Sr₃Ru₂O₇ by doping the crystal lattice with foreign cations: this is the primary purpose of the original research referred to in this thesis, in which studies of some of the electronic properties of crystals of cation-doped Sr₃Ru₂O₇ are reported. Single crystals of Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ and Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇ have been synthesised in an image furnace and some of the properties of these crystals have been measured. Evidence that indicates the emergence of a spin density wave as a function of Ti-doping in Sr₃(Ru[subscript(1-x)]Ti[subscript(x)])₂O₇ is presented. Time-dependent magnetic irreversibility has been observed in samples of Sr₃(Ru[subscript(1-x)]Cr[subscript(x)])₂O₇, thus hinting at the involvement of the RKKY mechanism in these materials. Regarding cation doping out of the conducting RuO₂ planes, samples of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ have been grown and investigated. Both the Sommerfeld coefficient and the Fermi liquid A coefficient of (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ are found to decrease as a function of y (0 ≤ y ≤ 0.02); these observations point towards a reduction in the thermodynamic mass of the Landau quasiparticles. Results from magnetoresistance and magnetisation measurements indicate that the metamagnetism of the (Sr[subscript(1-y)]La[subscript(y)])₃Ru₂O₇ series probably cannot be explained by a rigid band-shift model. Also, some aspects of these data imply that the metamagnetism cannot be fully accounted for by a spin fluctuation extension to the Ginzburg-Landau theory of uniform magnetisation.