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Environmetally Assisted Cracking in Metals under Extreme ConditionsPham, Hieu 2011 August 1900 (has links)
Environmentally Assisted cracking (EAC) is a very critical materials science problem that concerns many technological areas such as petrochemical engineering,
aerospace operations and nuclear power generation, in which cracking or sudden failure of materials may happen at stress far below the tensile strength. This type of
corrosion is initiated at the microscopic level and is complicated due to the combination of chemistry (reaction caused by corrosive agents) and mechanics (varying load).
As EAC is generally related to the segregation of impurity elements to defects (mainly grain boundaries), the symptoms of risk may not be apparent from the exterior of the metal components: hence EAC remains latent and gives no sign of warning until the failure occurs.
Due to its intricate nature, conducting experiments on this phenomenon involves difficulties and requires much effort. In this work, we employed advanced molecular simulation techniques to study EAC in order to give insight into its atomistic behavior. First, Density-Functional Theory (DFT) method was used to investigate the fundamental processes and mechanism of EAC-related issues at the nanoscale level, with two case studies concerning the stress corrosion in iron and hydrogen embrittlement in palladium. When segregating to the grain boundary (GB) of iron, different impurity elements such as sulfur, phosphorus and nitrogen raise corrosion failures in a variety of ways. Hydrogen atoms, due to their mobility and small atomic size, are able to form high occupation at crystal defects, but show different interactions to vacancy and GB. Then, we used the classical Molecular Dynamics (MD) method to gain an
understanding of the dynamic response of materials to mechanical load and the effects of temperature, strain and extreme conditions (high pressure shock compression) on structural properties. The MD simulations show that hydrogen maintains the highest localization at grain boundaries in the vicinity of ambient temperatures, and grain boundaries are the preferred nucleation sites for dislocations and voids. This computational work, using DFT and MD techniques, is expected to contribute to the better understanding on chemistry and mechanisms of complex environment-assisted cracking phenomenon at a fundamental level in order to beneficially complement
conventional laboratory approaches.
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Atomistic Modeling of Defect Energetics and Kinetics at Interfaces and Surfaces in Metals and AlloysAlcocer Seoane, Axel Emanuel 02 January 2024 (has links)
Planar defects such as free surfaces and grain boundaries in metals and alloys play important roles affecting many material properties such as fracture toughness, corrosion resistance, wetting, and catalysis. Their interactions with point defects and solute elements also play critical roles on governing the microstructural evolution and associated property changes in materials. This work seeks to use atomistic modeling to obtain a fundamental understanding of many surface and interface related properties and phenomena, namely: orientation-dependent surface energy of elemental metals and alloys, segregation of solute elements at grain boundaries and their impact on grain boundary cohesive strength, and the controversial sluggish diffusion in both the bulk and grain boundaries of high entropy alloys. First, an analytical formula is derived, which can predict the surface energy of any arbitrary (h k l) crystallographic orientation in both body-centered-cubic (BCC) and face-centered-cubic (FCC) pure metals, using only two or three low-index (e.g., (100), (110), (111)) surface energies as input. This analytical formula is validated against 4357 independent single element surface energies reported in literature or calculated by the present author, and it proves to be highly accurate but easy to use. This formula is then expanded to include the simple-cubic (SC) structure and tested against 4542 surface energies of metallic alloys of different cubic structures, and good agreement is achieved for most cases. Second, the effect of segregation of substitutional solute elements on grain boundary cohesive strength in BCC Fe is studied. It is found that the bulk substitution energy can be used as an effective indicator to predict the embrittlement or strengthening potency induced by the solute segregation at grain boundaries. Third, the controversial vacancy-mediated sluggish diffusion in an equiatomic FeNiCrCoCu FCC high entropy alloy is studied. Many literature studies have postulated that the compositional complexity in high entropy alloys could lead to sluggish diffusion. To test this hypothesis, this work compares the vacancy-mediated self-diffusion in this model high entropy alloy with a hypothetical single-element material (called average-atom material) that has similar average properties as the high entropy alloy but without the compositional complexity. The results show that the self-diffusivities in the two bulk systems are very similar, suggesting that the compositional complexity in the high entropy alloy may not be sufficient to induce sluggish diffusion in bulk high entropy alloys. Based on the knowledge learned from the bulk alloy, the exploration of the possible sluggish diffusion has been extended to grain boundaries, using a similar approach as in the study of self-diffusion in bulk. Interestingly, the results show that sluggish diffusion is evident at a Σ5(210) grain boundary in the high entropy alloy due to the compositional complexity, especially in the low temperature regime, which is different from the bulk diffusion. The underlying mechanisms for the sluggish diffusion at this grain boundary is discussed. / Doctor of Philosophy / Human beings have utilized metals and alloys for over ten millennia and learned much from them. Based on the accumulated knowledge, they have countless applications in our current daily life. However, there is still much to learn for improving our current technology and even opening new opportunities. Throughout most of history, our understanding of these materials was largely obtained through empirical experimentation and refining them into theories and scientific laws. Nowadays, due to the advancements in computer simulations, we can learn more by modeling the behaviors of metals and alloys at the length and time scales that are either be too arduous, costly, or currently impossible experimentally.
This work aims at using computer modeling to study some important surface/interface related physical behaviors and properties in metals and alloys at the atomistic scale. First, this work intends to develop a robust surface energy model in an analytical form for any crystallographic orientation. Surface energy is an important material property for many surface-related processes such as fracturing, wetting, sintering, catalysis, and crystalline particle shape. Surface energy is different at different surface orientations, and predicting this difference is important for understanding these surface phenomena. Second, the effect of solute segregation on grain boundary cohesive strength is studied. Most commonly used metallic materials consist of many small crystalline grains and the borders between them are called grain boundaries, which are weak spots for fracture. The minimum energy required to split a boundary is called the grain boundary cohesive strength. The presence of solutes or impurities at grain boundaries can further alter the cohesive strength. A better understanding of this phenomena will eventually help us develop more fracture-resistant materials. The third project deals with the possible sluggish/retarded diffusion in high entropy alloys, which contain five or more principal alloying elements and have many unique mechanical, radiation-resistant, and corrosion-resistant properties. Many researchers attribute these unique properties to the slow species diffusion in these alloys, but its existence is still controversial. This work studies the atomic-level diffusion mechanisms in an FeNiCrCoCu high entropy alloy both in bulk (grain interior) and at grain boundaries in order to determine if sluggish diffusion is present and its causes.
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Grain Boundary Segregation: the New SproutsBokstein, Boris, Itckovich, Alexei, Pokhvisnev, Yury, Rodin, Alexei 21 September 2022 (has links)
Some aspects of grain boundary segregation (GBS) are discussed. This paper adds two new
sprouts. The first is connected with formation of the atomic complexes in boundary region and their
effect on grain boundary diffusion (GBD). The second – with a nonhomogeneity of energy
distribution between boundary sites.
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Ultrasonic welding of aluminium to titanium : microstructure, properties, and alloying effectsZhang, Chaoqun January 2015 (has links)
Use of welded titanium alloy to aluminium alloy structures in the aerospace industry has a number of potential benefits for both cost and weight saving by enabling titanium to be used only in the most critical parts, with the cheaper and lighter aluminum alloy making up the rest of the structure. However, due to the formation of brittle intermetallic compounds (IMC) at interface and the enormous gap in melting point, the welding of titanium to aluminium remains a major challenge. Solid state welding processes are most likely to be successful since they do not involve any melting, and so issues associated with the large difference in melting point and the high reaction rate of the liquid phase are avoided. In this study, an emerging low energy input solid state welding process - high-power ultrasonic spot welding (USW) was applied to weld Al and Ti (AA6111-T4/Ti6Al4V and AA2139-T8/Ti6Al4V combinations). No obvious intermetallic reaction layer was observed on the Al/Ti interface even using transmission electron microscopy. As a result, the maximum joint strength measured reached the same level as similar Al-Al (AA6111) welds and greatly exceeded those observed in Al-Fe and Al-Mg joints made using the same technique, in which a brittle reaction layer forms rapidly. However, the Al/Ti welds always failed at the weld interface after natural ageing, which is not desirable due to the low fracture energy associated with interfacial fracture mode. By using high resolution STEM-EDS, residual oxides and Si segregation were detected on the as-welded Al/Ti interface, which are thought to be factors that result in the no reaction layer Al/Ti interface. The Si segregation is predicted to be able to increase the weld interface cohesion through thermodynamic calculation. A series of prolonged heat treatment experiments were performed to understand the Al-Ti reaction layer growth kinetics and to explain the lack of reaction layer in as-welded Al-Ti joint. Al3Ti (D022 structure) was the only Al-Ti intermetallic phase observed in the reaction layer (IMC layer). In pure Al/Ti joints, it is found that the very long slow-growth stage of IMC layer is probably caused by the residual oxides on the interface. Calculations show that grain boundary (GB) diffusion makes the major contribution to the effective diffusion coefficient in the Al3Ti layer. In AA2139/Ti joints, the IMC layer growth is significantly slower than that in pure Al/Ti joints. The effects of alloying elements on the IMC layer growth was studied in detail. Cu was observed to segregate on both the Al3Ti grain boundaries and the Al3Ti/Ti interface. Si also segregated on the the Al3Ti/Ti interface and enriched in the Al3Ti layer. Both Cu and Si are thought to retard IMC layer growth. Interestingly small patches of Al were found trapped in the IMC layer; its formation mechanism is discussed. In pure Al/Ti6Al4V joints, the IMC layer growth rate did not change significantly. The presence of V greatly retarded the Al3Ti grain growth at high annealing temperature (630 °C) and suppressed the anisotropic growth of Al3Ti at 600 °C. Overall this study successfully joined Al/Ti by USW and systematically investigated the grain size effect and alloying effects on the Al3Ti layer growth. The present study for the first time: (a) observed the no-IMC-layer Al/Ti weld interface; (b) observed Cu segeration on Al3Ti GBs; (c) quantitatively studied the grain size effect on Al3Ti layer growth kinetics; (d) observed the orientation relationship between trapped Al islands and the adjacent Al3Ti grains; (e) observed that V greatly retarded the anisotropic growth of Al3Ti grains.
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Grain Boundary Ridge Formation during High Temperature Oxiditation of Manganese Containing SteelsThorning, Casper January 2008 (has links)
QC 20100927
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The effect of recycling and processing routes on recrystallization in a secondary 3xxx aluminium alloyRolseth, Anton January 2023 (has links)
Aluminium alloys have the possibility to be infinitely recycled. By only generating 5% of the emissions compared to primary aluminium, great CO2 savings can be made. One of the issues in manufacturing components entirely from post-consumer scrap is the presence of trace elements and impurities. Such elements can be Fe, Cu, Cr, P and Pb. In sheet metal manufacturing, these elements can also react with process agents such as Ti, B, Na and Sr and affect the recrystallization behavior and in turn mechanical properties.In this work, a derivative of the 3003 alloy made entirely from post-consumer scrap has been analysed. The alloy achieved insufficient formability due to lack of recrystallization and grain growth. With the use of scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS) and electron backscatter diffraction (EBSD) together with focused ion beam (FIB) lamella preparation, the microstructure was characterized.The characterization shows both larger particles of α-Al15Si2M4 (M=Mn,Fe,Cr) from solidification and dispersoids from heat treatment, pinning the grain boundary movement together with Q-AlCuMgSi. With the use of high throughput computational thermodynamics, Thermo-Calc was used to effectively screen compositions lowering the amount of α-Al15Si2M4 and removing the Q-AlCuMgSi phase. The new alloy was cast using directional solidification at different cooling rates to study the particle morphology, which in turn plays a role in the particle break up and distribution during cold working as the interparticle spacing affects the grain growth.Varying cooling rates was seen to affect morphology and distribution. Hot compression was utilized to examine the particle redistribution before cold work. It was however shown that hot compression was not sufficient in redistributing the particles as would be the case in rolling.
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Heat Affected Zone Cracking of Allvac 718Plus Superalloy during High Power Beam Welding and Post-weld Heat TreatmentIdowu, Oluwaseun Ayodeji 08 April 2010 (has links)
The present dissertation reports the findings of a study of cracking behavior of a newly developed superalloy, Allvac 718Plus during high power beam welding and post-weld heat treatment. Microstructures of the base alloy, heat affected zone (HAZ) and fusion zone (FZ) of welded and post-weld heat treated (PWHT) coupons were examined by the use of standard metallographic techniques involving optical microscopy, analytical scanning electron microscopy (SEM) and analytical transmission electron microscopy. Moreover, grain boundary segregation behavior of boron atoms during pre-weld heat treatments was evaluated using secondary ion mass spectroscopic system.
In the first phase of the research, 718Plus was welded using a low and high heat input CO2 laser to assess its weld cracking response. Detailed examination of the welds by analytical electron microscopic technique revealed the occurrence of cracking in the HAZ of low heat input welds, while their FZ was crack free. However, both the FZ and HAZ of high heat input welds were crack-free. Resolidified constituents were observed along the cracked grain boundaries of the lower heat input welds, which indicated that HAZ cracking in this newly developed superalloy was associated with grain boundary liquation. However, despite a more extensive liquation of grain boundaries and grain interior in the HAZ of high heat input welds, no cracking occurred. This was attributed to the combination of lower welding stresses generated during cooling, and relaxation of these stresses by thick intergranular liquid.
Although HAZ cracking was prevented by welding with a high heat input laser, it resulted in a significant damage to the parent microstructure through its extensive liquation. Thus, the use of low heat input welding is desirable. However, this resulted in HAZ cracking which needs to be minimized or eliminated. Therefore, during the second phase of this research, the effects of pre-weld thermal processing on the cracking response of 718Plus were investigated. Results from the quantification of the cracking of the alloy showed that HAZ cracking may be significantly reduced or eliminated through an adequate selection of pre-weld thermal cycle.
In the third stage of this research, crack-free welds of 718Plus were post-weld heat treated using standard thermal schedules. A significant solid state cracking of the alloy occurred during the PWHT. The cracking was attributed to the presence of embrittling phases on HAZ grain boundaries, coupled with aging contraction stresses that are generated by a considerable precipitation of gamma prime phase during aging.
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Heat Affected Zone Cracking of Allvac 718Plus Superalloy during High Power Beam Welding and Post-weld Heat TreatmentIdowu, Oluwaseun Ayodeji 08 April 2010 (has links)
The present dissertation reports the findings of a study of cracking behavior of a newly developed superalloy, Allvac 718Plus during high power beam welding and post-weld heat treatment. Microstructures of the base alloy, heat affected zone (HAZ) and fusion zone (FZ) of welded and post-weld heat treated (PWHT) coupons were examined by the use of standard metallographic techniques involving optical microscopy, analytical scanning electron microscopy (SEM) and analytical transmission electron microscopy. Moreover, grain boundary segregation behavior of boron atoms during pre-weld heat treatments was evaluated using secondary ion mass spectroscopic system.
In the first phase of the research, 718Plus was welded using a low and high heat input CO2 laser to assess its weld cracking response. Detailed examination of the welds by analytical electron microscopic technique revealed the occurrence of cracking in the HAZ of low heat input welds, while their FZ was crack free. However, both the FZ and HAZ of high heat input welds were crack-free. Resolidified constituents were observed along the cracked grain boundaries of the lower heat input welds, which indicated that HAZ cracking in this newly developed superalloy was associated with grain boundary liquation. However, despite a more extensive liquation of grain boundaries and grain interior in the HAZ of high heat input welds, no cracking occurred. This was attributed to the combination of lower welding stresses generated during cooling, and relaxation of these stresses by thick intergranular liquid.
Although HAZ cracking was prevented by welding with a high heat input laser, it resulted in a significant damage to the parent microstructure through its extensive liquation. Thus, the use of low heat input welding is desirable. However, this resulted in HAZ cracking which needs to be minimized or eliminated. Therefore, during the second phase of this research, the effects of pre-weld thermal processing on the cracking response of 718Plus were investigated. Results from the quantification of the cracking of the alloy showed that HAZ cracking may be significantly reduced or eliminated through an adequate selection of pre-weld thermal cycle.
In the third stage of this research, crack-free welds of 718Plus were post-weld heat treated using standard thermal schedules. A significant solid state cracking of the alloy occurred during the PWHT. The cracking was attributed to the presence of embrittling phases on HAZ grain boundaries, coupled with aging contraction stresses that are generated by a considerable precipitation of gamma prime phase during aging.
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