Historically, Devonian Corniferous hydrocarbon production in south-central Kentucky has been a major contributor to the total hydrocarbon resources within Butler, Edmonson, and Warren counties. The Corniferous adds to the already large hydrocarbon totals produced from the Illinois Basin; however, this hydrocarbon contribution does not come without major pitfalls and inconsistencies. The south-central Kentucky Devonian Corniferous rocks comprise a diverse and complex hydrocarbon system made up of multiple migration pathways, trapping mechanisms, and seals. The multiple Corniferous units all derive production from the same source rock: the New Albany Shale. A Geographic Information System (GIS) containing data on surface elevations, structure contours and faults, geophysical well logs, well-scale oil and gas production, and lease to regional-scale oil and gas production has been compiled to produce a threedimensional (3-D) model using kriging with barriers to explain spatially the complexities of the Devonian Corniferous in south-central Kentucky. This model identifies the potential source rocks, the hydrocarbon charging and migration pathways, reservoirs, and reservoir seals. This model also utilizes kernel density estimation for developing an understanding of the spatial relationship of stratigraphic units being targeted within the Devonian relative to the spatially modeled Devonian Corniferous structures. This model also indicates locations and depths of key producing zones within south-central Kentucky. This project also explains the potential reasoning leading to the development of the Devonian Corniferous as a major hydrocarbon resource by placing it in the context of the underlying Silurian Corniferous and the multiple Siluro-Devonian unconformities positioned throughout the entire Siluro-Devonian section. This project bridges the gap between: 1) potential buried Silurian-age reef systems located south of the Pennyrile Fault zone, 2) the pervasive high porosity sections found in the lower Clear Creek Limestone unit, and 3) the development of expansive secondary partial dolomitization related to unconformable surfaces in the Middle and Upper Devonian Corniferous.

Reservoir management strategies traditionally attempt to combine and balance complex geophysical, petrophysical, thermodynamic and economic factors to determine an optimal method to recover hydrocarbons from a given reservoir. Reservoir simulators have traditionally been too large and run times too long to allow for rigorous solution in conjunction with an optimization algorithm. It has also proven very difficult to marry an optimizer with the large set of nonlinear partial differential equations required for accurate reservoir simulation. A simple capacitance-resistance model (CRM) that characterizes the connectivity between injection and production wells can determine an injection scheme maximizes the value of the reservoir asset. Model parameters are identified using linear and nonlinear regression. The model is then used together with a nonlinear optimization algorithm to compute a set of future injection rates which maximize discounted net profit. This research demonstrates that this simple dynamic model provides an excellent match to historic data. Based on three case studies examining actual reservoirs, the optimal injection schemes based on the capacitance-resistive model yield a predicted increase in hydrocarbon recovery of up to 60% over the extrapolated exponential historic decline. An advantage of using a simple model is its ability to describe large reservoirs in a straightforward way with computation times that are short to moderate. However, applying the CRM to large reservoirs with many wells presents several new challenges. Reservoirs with hundreds of wells have longer production histories – new wells are created, wells are shut in for varying periods of time and production wells are converted to injection wells. Additionally, ensuring that the production data to which the CRM is fit are free from contamination or corruption is important. Several modeling techniques and heuristics are presented that provide a simple, accurate reservoir model that can be used to optimize the value of the reservoir over future time periods. In addition to optimizing reservoir performance by allocating injection, this research presents a few methods that use the CRM to find optimal well locations for new injectors. These algorithms are still in their infancy and represent the best ideas for future research. / text

The Scotland Formation onshore Barbados is often called the only example of a successful hydrocarbon producing accretionary prism reservoir. In spite of this, the hydrocarbon system elements of the BAP have nevertheless not been well studied. Seven outcropping locations of the Scotland were examined to document stacking patterns, key surfaces, depositional element geometries, facies occurrences their vertical and lateral extent, and the unit’s gamma response. Six facies were identified in outcrop: silty muds; laminated, centimeter-scale sandstones interbedded with silts and muds; cross-stratified sandstones; massive, medium to coarse-grained sandstones; very coarse grained sands with gravel or pebbles; and rare conglomerates. These facies combine to form architectural elements—channels, levees, and depositional lobes. Observations from petrographic, outcrop and seismic data suggest that the Scotland Formation was never deeply buried within the prism proper and was possibly deposited within the much larger proto-Tobago Basin. / text

Salt can be removed by viscous flow and dissolution to form a salt weld. A complete weld forms when salt is completely removed by these processes. Where salt removal is incomplete, a partial weld forms. Though welds are frequently mentioned in the literature, the details of weld formation and the properties of salt welds are poorly understood. In Chapter 1, I use analytical and numerical models to quantify the role of viscous flow during salt welding. Where salt flow is limited by boundary drag against the salt contacts, evacuation is slow and up to ~50 m of salt will be left behind in a partial weld. Where salt flow is laterally unrestricted, a vanishingly thin (<< 1 m) smear of salt will remain. I conclude that layer-parallel wall rock translation or dissolution must act to remove any remnant salt to create a complete weld. In Chapter 2, I characterize partial welds containing halite and anhydrite on reflection seismic data by treating welds as thin beds. Below the temporal resolution of reflection seismic data, typically ~25-50 m for modern surveys with peak frequencies of ~10-30 Hz, reflections from the upper and lower evaporite contacts converge and interfere to form a single composite reflection. Thus, partial and complete welds are typically indistinguishable using travel-time differences alone. I then use amplitude information from synthetics and seismic examples to estimate remnant evaporite thickness. In Chapter 3, I investigate fluid flow near and through salt welds. I conclude dissolution during boundary flow can remove up to a few meters of salt per million years. Though dissolution plays a volumetrically insignificant but important role in weld formation, as runaway dissolution can create pathways for focused cross-weld migration of subsurface fluids. I identify features that influence cross-weld migration of subsurface fluids and then develop an empirical relationship between weld geometry and the tendency seal or leak hydrocarbons. I find that in the Campos Basin, offshore Brazil, salt welds containing remnant evaporites thinner than ~50 m that are broader than ~25 km2 in area are likely to leak. / text

Numerous epidemiology studies suggest a correlation between exposures to polychlorinated biphenyls (PCBs) and the development and severity of type 2 diabetes (T2D); however, mechanisms remain largely unknown. Previous studies demonstrated that PCBs that are ligands of the aryl hydrocarbon receptor (AhR) promote the expression of proinflammatory cytokines, including tumor necrosis factor-α (TNF-α), that are linked to insulin resistance in adipocytes. To explore potential mechanisms linking PCB exposures to diabetes, we developed a mouse model of glucose and insulin intolerance induced by acute and chronic exposures to PCB-77. We hypothesized that PCB ligands of AhR result in adipocyte-specific elevations in TNF-α and dysregulated glucose homeostasis. Results demonstrated that PCB77 resulted in rapid and sustained glucose and insulin intolerance in low fat (LF)-fed mice, and that these effects were associated with adipose-specific elevations in TNF-α. When mice were made obese from consumption of a high fat (HF) diet, effects of PCB77 were lost presumably due to concentration of the toxin in adipose lipids. However, upon weight loss, mice exposed to PCB77 exhibit impaired glucose homeostasis. These results suggest that lipophilic PCBs redistribute from adipose lipids with weight loss and mitigate beneficial effects to improve glucose homeostasis. To define the role of adipocyte AhR in PCB-induced diabetes, we created a mouse 3 model of adipocyte AhR deficiency using the Cre/LoxP system. Adipocyte-AhR deficiency conferred protection from the development of PCB-77-induced impairments in glucose and insulin tolerance in obese mice undergoing weight loss. Unexpectedly, adipocyte-AhR deficient mice fed the HF diet exhibited adipocyte hypertrophy, increased adipose mass and elevated body weight. These results suggest that (1) adipocyte AhRs are responsible for effects of PCB77 to impair glucose homeostasis during weight loss and (2) adipocyte AhRs respond to the HF diet to regulate adipose mass and body weight. We used resveratrol as a putative AhR antagonist to determine if the polyphenol confers protection against PCB-77-induced diabetes. Resveratrol abolished acute effects of PCB77 to impair glucose and insulin tolerance in LF-fed mice. Notably, PCB77 administration abolished insulin-induced phosphorylation of Akt in adipose tissue and these effects were abolished by resveratrol. Resveratrol also abolished marked suppressions in glucose uptake in adipocytes exposed to PCB77. These studies suggest the adipocyte AhR plays a potentially significant role in the development of diabetes and obesity, and that resveratrol may represent a novel therapeutic for PCB exposed populations.

<p>The Bredasdorp Basin is one of the largest hydrocarbon producing blocks within Southern Africa. The E-M field is situated approximate 50 km west from the FA platform and was brought into commission due to the potential hydrocarbons it may hold. If this field is brought up to full producing capability it will extend the lifespan of the refining station in Mosselbay, situated on the south coast of South Africa, by approximately 8 to 10 years. An unexpected pressure drop within the E-M field caused the suite not to perform optimally and thus further analysis was imminent to assess and alleviate the predicament. The first step within the project was to determine what might have cause the pressure drop and thus we had to go back to cores drilled by Soekor now known as Petroleum South Africa, in the early 1980&rsquo / s.</p> <p><br> <br /> </br>Analyses of the cores exposed a high presence of granulation seams. The granulation seams were mainly subjected within sand units within the cores. This was caused by rolling of sand grains over one another rearranging themselves due to pressure exerted through compaction and faulting, creating seal like fractures within the sand. These fractures caused these sand units to compartmentalize and prohibit flow from one on block to the next. With advance inquiry it was discovered that there was a shale unit situated within the reservoir dividing the reservoir into two main compartments. At this point it was determined to use Petrel which is windows based software for 3D visualization with a user interface based on the Windows Microsoft standards. This is easy as well as user friendly software thus the choice to go with it. The software uses shared earth modeling tool bringing about reservoir disciplines trough common data modelling. This is one of the best modelling applications in the available and it was for this reason that it was chosen to apply within the given aspects of the project A lack of data was available to model the granulation seams but with the data acquired during the core analyses it was possible to model the shale unit and factor in the influences of the granulation seams to asses the extent of compartmentalization. The core revealed a thick shale layer dividing the reservoir within two sections which was not previously noted. This shale layer act as a buffer/barrier restricting flow from the bottom to the top halve of the reservoir. This layer is thickest at the crest of the 10km&sup2 / domal closure and thins toward the confines of the E-M suite. Small incisions, visible within the 3 dimensional models could serve as a guide for possible re-entry points for future drilling. These incisions which were formed through Lowstand and Highstand systems tracts with the rise and fall of the sea level. The Bredasdorp Basin consists mainly of tilting half graben structures that formed through rifting with the break-up of Gondwanaland. The model also revealed that these faults segregate the reservoir further creating bigger compartments. The reservoir is highly compartmentalized which will explain the pressure loss within the E-M suite. The production well was drilled within one of these compartments and when the confining pressure was relieved the pressure dropped and the production decrease. As recommendation, additional wells are required to appraise the E-M structure and determine to what extent the granulation seems has affected fluid flow as well as the degree of sedimentation that could impede fluid flow. There are areas still containing untapped resources thus the recommendation for extra wells.</p>

Background: The International Agency for Research on Cancer has classified diesel exhaust as a carcinogen, and specific polycyclic aromatic hydrocarbons (PAHs) as probable carcinogens. Urban air pollution is one source of PAH exposure. These facts provided motivation to pursue three thesis objectives: 1) to critically review environmental inequity research in Canada and methods used in previous studies; 2) to determine associations between socio-demographic factors and residential traffic exposure; and, 3) to assess correlations between two PAH biomarkers and their relationship with a newer geographic information system (GIS) method (a proxy of PAH exposure measurement), and explore determinants of these two PAH biomarkers. Methods: The first objective was achieved through an extensive and critical literature review. The second and third objectives were achieved through conducting a cross-sectional study in Montreal where 107 female and 93 male volunteers completed a questionnaire and provided a urine sample for measurement of 1-hydroxypyrene (1-OHP) and 1-hydroxypyrene glucuronide (1-OHPG). GIS-based distance-weighted traffic density (DWTD) at participants’ residences and time- and distance-weighted traffic density (TDWTD) for all participants’ locations in the 48 hours before urine collection were calculated. Results: Participants with lower household income and unemployment/student status were more likely to be exposed to higher traffic density at their residence. DWTD was related to self-reported living within 100 meters of highway/major roads. Detection rates for the two biomarkers were over 95%, and females have higher 1-OHP and 1-OHPG levels (exp β: 1.56, 95% CI: 1.17 to 2.09; exp β: 1.49, 95% CI: 1.05 to 2.11, respectively) than males. Smoking in the 48-hour period before urine collection significantly predicted levels of biomarkers, and among non-smokers barbecued/grilled meat consumption was implicated in increases in 1-OHP. Conclusions: Those with lower household income and unemployment/student status experienced increased traffic exposure, while education, marital status and ethnicity were not associated with traffic exposure. While higher levels among females and an interaction with sex needs further study, PAH biomarkers are useful in capturing recent PAH exposure from smoking, and barbecued/grilled meat consumption. PAH biomarkers can be easily used in epidemiologic studies to assess general population exposures. / Thesis (Ph.D, Community Health & Epidemiology) -- Queen's University, 2013-07-30 10:41:50.321

ABSTRACT To compare the degree of biodegradation of petroleum hydrocarbons in sediments from Ikarama and Okwori in the Niger delta, Nigeria, concentrations of n-alkanes and polycyclic aromatic hydrocarbons in the sediments were measured. Analysis was conducted with gas chromatography using mass spectrometry detector. While the decrease in concentrations of n-alkanes and polycyclic aromatic hydrocarbons confirmed the process of biodegradation in the sediments it was not solely fit to substantiate the degree of biodegradation in the sediments. Hence the percentage proportion of n-alkanes and polycyclic aromatic hydrocarbons was used. The degree of biodegradation of n-alkanes in both Okwori and Ikarama was almost similar. However, it was observed that polycyclic aromatic hydrocarbons were biodegraded in Okwori sediments than Ikarama sediments and this indicates the degree of biodegradation of petroleum hydrocarbons impacted sediments in Okwori is greater than that of Ikarama.

The vertical and lateral aggradation of terminal and crevasse splay deposits in continental environments can form extensive fine-grained, sheet-like sandstone bodies which may form an important but often overlooked component of subsurface hydrocarbon reservoirs. This study examines splay deposits on the modern day Distributive Fluvial System (DFS), of the Parapeti River, Bolivia, using remote sensing techniques and geographic information system (ArcGIS) to characterise both lateral and terminal modern splay systems. Overall emphasis is given to the spatial and temporal relationship between sedimentary facies at the distal part of the Parapeti DFS over the past 42 years. A sedimentary facies evolution model is created to account for the development of the distal part of the Parapeti DFS. A number of splay deposits have formed and developed during this period and the Parapeti channel has prograded ~17 km basinward by short-term deposition in one location, followed by either repeated local avulsion or coeval downstream progradation of the terminal channel and associated splays. Rock record examples from the Miocene aged Huesca DFS in the Ebro Basin, Spain were studied in order to compare dimensional data as well as understand the relationship between splays and associated channel bodies. The study area is characterized by thin sandstone sheets (0.05-2.6 m thick; 100s m wide) interbedded with mudstones and siltstones interpreted to represent a terminal splay complex based on the distribution of facies, architectural elements and paleocurrent data. There is a strong resemblance between the model developed for the Parapeti DFS and the splay complexes recorded in the Miocene Huesca DFS. Sedimentary models are proposed in which terminal splay formation through avulsions is considered to be the dominant process in the distal parts of both systems. Avulsions control sediment distribution, resulting in stacking of splay deposits to form extensive sandstone sheets. However, it is suggested that different types of avulsion successions (i.e. progressive or abrupt) recognized by previous workers, may not be distinguishable in the rock record as they can produce a similar stratigraphic signature.

The East Shetland Basin is a superb natural laboratory in which to study the role that normal fault growth and linkage has in determining petroleum prospectivity. Use of several high density 3D seismic volumes and over 250 boreholes permits key aspects of the Late Jurassic rift and its Permo-Triassic precursor to be analysed and its role on hydrocarbon trap formation, reservoir distribution and migration determined. The regional interpretation has revealed the generation of a North Sea archipelago of Upper Jurassic islands, the role of relay ramps in controlling syn-rift sediment dispersal patterns and the impact of normal faults of the later episode crossing and offsetting those generated by the earlier phase. The uplift, erosion and meteoric flushing of Upper Jurassic and older strata within the exposed fault blocks could potentially have huge consequences for the Brent play by enhancing reservoir properties and hence, help identify new play opportunities down-dip of major structures. Fault control on sediment dispersal can also be documented in a more localized study on the Cladhan Field, the site of a pronounced basin-margin relay ramp. This recent discovered set of syn-rift density flows illustrates how the development and distribution of depositional gradients and transport pathways form subtle play types. The Cladhan area is just one of several locations throughout the East Shetland Basin where the interaction of multiple rift phases is influential in the structural feedback after the Upper Jurassic rifting event. The delicate interaction and reactivation of underlying structural trends creates a series of multi-tiered fault block systems which can define several aspects of a petroleum system, depending upon the strike, polarity and level of reactivation of faults from one rift to another. The observations of fault growth and linkage in the Northern North Sea may provide generic lessons that help in determining petroleum prospectivity in other hydrocarbon rift basins (e.g. E. Africa and the N. Atlantic seaboard of North America).