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Extractive processes can permanently and significantly reduce the volume, toxicity and mobility of contaminated materials at affected sites. Ethylenediaminetetraacetic acid (EDTA), N-2 (acetamido)iminodiacetic acid (ADA), pyridine2,6-dicarboxylic acid (PDA), and hydrochloric acid (HC1) were evaluated in batch studies for their ability to remove lead (Pb) and cadmium (Cd) from a Superfund soil. The extraction of Pb as a function of time was limited and the order of Pb removal was EDTA > ADA > PDA > HC1. Repeated extractions did not treat the soil below the Pb regulatory limit (1,000 mg/kg); however, the Pb remaining occurs in an immobile form. All extractants treated the soil below the proposed Cd regulatory limit (40 mg/kg) within 1 h. Lead recovery from solution was accomplished by hydroxide precipitation in the presence of excess calcium, and recovery at pH 11 was 70%, 98%, and 97% from the EDTA, ADA, and PDA complexes, respectively. / Department of Natural Resources and Environmental Management

The quest for sustainable development has always involved the complex task of reconciling the need for socio-economic development with public health and environmental protection. This challenge has often emerged in the trade and environment debate but has most recently been evident in international trade in used electrical and electronic equipment (UEEE). While international trade in UEEE provides means for socio-economic development in the developing world, it also serves as a conduit for transboundary dumping of e-waste in the developing world giving rise to serious health and environmental concerns. This research investigates the socio-economic as well as health and environmental impacts of international trade in UEEE in two developing countries – Nigeria and Ghana. The research identifies a major loophole in the existing international legal framework as the primary factor responsible for e-waste dumping in the developing world. This loophole relates to the absence of a legal framework for differentiating between functional UEEE and junk e-waste. This has resulted in both functional UEEE and junk e-waste being concurrently shipped to the developing world as “used electrical and electronic equipment”. The research proposes two policy frameworks for addressing this problem. On the part of developing countries, the research proposes a trade policy framework crafted in line with WTO rules. This framework will entail the development of an international certification system which will serve to differentiate functional used electronics from junk e-waste. While the former may be eligible for import, the research proposes an import ban on the latter. On the part of developed countries, the research proposes the development of a policy framework which regulates the toxic and hazardous substances that go into the production of electrical and electronic equipment as well as enhance their reusability and recyclability at end-of-life. The framework should take into consideration the entire life cycle of the products from the design stage to end-of-life. The research argues that the implementation of this design framework will go a long way in reducing the health and environmental impacts of such equipment when subsequently shipped to the developing world at end-of-life.

In this study, hazardous waste inventory for Turkey is developed based on wastes identified as hazardous in European Waste Catalogue and Regulation on Control of Hazardous Wastes, Annex 7 Necessity of such inventory arises from importance of acquiring information on the amount of hazardous wastes generated and on their countrywide distribution for a sound hazardous waste management system for Turkey. Hazardous waste inventory is constructed by using waste generation factors obtained from literature which are coefficients that relate production with environmental emissions. Whenever possible, direct information obtained from generators was utilized. Both absolute and minor entries are covered. It is estimated that 4,940,000 &ndash / 5,110,000 t/yr of hazardous wastes are being generated in Turkey. 1,790,000 &ndash / 2,252,000 t/yr of these are classified as absolute entries and 3,146,000 &ndash / 3,160,000 t/yr of hazardous wastes are minor entries. It is observed that highest generation occurs from mining and thermal processes which involve high amounts of minor entries. Beside these industries highest generation occurs from wood preservation. Per capita hazardous waste generation is estimated as 30 &ndash / 77 kg/capita/yr which is in accordance with per capita generation range of EU. Highest hazardous waste generation occurs from Marmara Region with 527,730 t/yr followed by Aegean (524,580 t/yr), Central Anatolia (481,820 t/yr), Black Sea Region (277,850 t/yr), Mediterranean (211,580 t/yr), Southeast Anatolia (58,290 t/yr) and Eastern Anatolia (36,520 t/yr) excluding minor entries from mining industry and thermal processes. The trends in hazardous waste generation and GDP from manufacturing industry show the same trend. Contribution of regions are in the same order both in hazardous waste generation and GDP.

Thesis (Ph.D.)--Tufts University, 2000. / Submitted to the Dept. of Chemistry. Adviser: Albert Robbat, Jr. Includes bibliographical references. Access restricted to members of the Tufts University community. Also available via the World Wide Web;

Diss. (sammanfattning) Stockholm : Karol. inst., 2005. / Härtill 5 uppsatser.

Univ., Diss.--Hamburg, 2005.

Thesis (Ph. D.)--State University of New York at Binghamton, Department of Chemistry, 2009. / Includes bibliographical references.

Thesis (M. Sc.)--University of Hong Kong, 1997. / Includes bibliographical references (leaf 82-87).

Thesis (Ph. D.)--University of Texas at Austin, 1998. / Vita. Includes bibliographical references (leaves 418-432). Available also in a digital version from Dissertation Abstracts.