Hydrogen is known as a clean energy carrier which has the potential to play a major role in addressing the climate change and global warming, and thermochemical water splitting via the copper-chlorine cycle is a promising method of hydrogen production. In this research, thermal management of the copper-chlorine cycle for hydrogen production is investigated by performing analytical and experimental analyses of selected heat recovery options. First, the heat requirement of the copper-chlorine cycle is estimated. The pinch analysis is used to determine the maximum recoverable heat within the cycle, and where in the cycle the recovered heat can be used efficiently. It is shown that a major part of the potential heat recovery can be achieved by cooling and solidifying molten copper(I) chloride exiting one step in the cycle: the oxygen reactor. Heat transfer from molten CuCl can be carried out through direct contact or indirect contact methods. Predictive analytical models are developed to analyze a direct contact heat recovery process (i.e. a spray column) and an indirect contact heat recovery process (i.e. a double-pipe heat exchanger). Characteristics of a spray column, in which recovered heat from molten CuCl is used to produce superheated steam, are presented. Decreasing the droplet size may increase the heat transfer rate from the droplet, and hence decreases the required height of the heat exchanger. For a droplet of 1 mm, the height of the heat exchanger is predicted to be about 7 m. The effect of hydrogen production on the heat exchanger diameter was also shown. For a hydrogen production rate of 1000 kg/day, the diameter of the heat exchanger is about 3 m for a droplet size of 1 mm and 2.2 m for a droplet size of 2 mm. The results for axial growth of the solid layer and variations of the coolant temperature and wall temperature of a double-pipe heat exchanger are also presented. It is shown that reducing the inner tube diameter will increase the heat exchanger length and increase the outlet temperature of air significantly. It is shown that the air temperature increases to 190oC in a heat exchanger with a length of 15 cm and inner tube radius of 10 cm. The length of a heat exchanger with the inner tube radius of 12 cm is predicted to be about 53 cm. The outlet temperature of air is about 380oC in this case. The length of a heat exchanger with an inner tube diameter of 24 cm is predicted to be about 53 cm and 91 cm for coolant flow rates of 3 g/s and 4 g/s, respectively. Increasing the mass flow rate of air will increase the total heat flux from the molten salt by increasing the length of the heat exchanger. Experimental studies are performed to validate the proposed methods and to further investigate their feasibility. The hazards involving copper(I) chloride are also investigated, as well as corresponding hazard reduction options. Using the reactant Cu2OCl2 in the oxygen production step to absorb CuCl vapor is the most preferable option compared to the alternatives, which include absorbing CuCl vapor with water or CuCl2 and building additional structures inside the oxygen production reactor. / UOIT

The Marnoch Heat Engine (MHE) is a recently patented type of new heat engine that produces electricity from lower temperature heat sources. The MHE utilizes lower temperature differences to generate electricity than any currently available conventional technologies. Heat can be recovered from a variety of sources to generate electricity, i.e., waste heat from thermal power plants, geothermal, or solar energy. This thesis examines the performance of an MHE demonstration unit, which uses air and a pneumatic piston assembly to convert mechanical flow work from pressure differences to electricity. This thesis finds that heat exchangers and the piston assembly do not need to be co-located, which allows benefits of positioning the heat exchangers in various configurations. This thesis presents a laboratory-scale, proof-of-concept device, which has been built and tested at the University of Ontario Institute of Technology, Canada. It also presents a thermodynamic analysis of the current system. Based on the MHE results, component modifications are made to improve the thermal performance and efficiency. The current configuration has an efficiency of about thirty percent of the maximum efficiency of a Carnot heat engine operating in the temperature range of 0oC to 100oC. The analysis and experimental studies allow future scale-up of the MHE into a pre-commercial facility for larger scale production of electricity from waste heat. / UOIT

Proefschrift (doctoral)--Technische Universiteit Eindhoven, 1990. / Includes bibliographical references (p. 265-275).

An analytical transport/reaction model was developed to simulate the catalytic performance of ZnO nanowires as a catalyst support. ZnO nanowires were chosen because they have easily characterized, controllable features and a spatially uniform morphology. The analytical model couples convection in the catalyst flow channel with reaction and diffusion in the porous substrate material; it was developed to show that a simple analytical model with physics-based mass transport and empirical kinetics can be used to capture the essential physics involved in catalytic conversion of hydrocarbons. The model was effective at predicting species conversion efficiency over a range of temperature and flow rate. The model clarifies the relationship between advection, bulk diffusion, pore diffusion, and kinetics. The model was used to optimize the geometry of the experimental catalyst for which it predicted that maximum species conversion density for fixed catalyst surface occurred at a channel height of 520 [mu]m. A modeling study of thermoelectric (TE) vehicle waste heat recovery was conducted based on abundant and inexpensive Mg₂ Si[subscript 0.5] Sn[subscript 0.5] and MnSi[subscript 1.75] TE materials with consideration of performance at the system and TE device levels. The modeling study identified a critical TE design space of fill fraction, leg length, n-/p-type leg area ratio, and current; these parameters needed to be optimized simultaneously for positive TE power output. The TE power output was sensitive to this design space, and the optimal design point was sensitive to engine operating conditions. The maximum net TE power for a 29.5 L strip fin heat exchanger with an 800 K exhaust flow at 7.9 kg/min was 2.25 kW. This work also includes two generations of TE waste heat recovery systems that were built and tested in the exhaust system of a Cummins 6.7 L turbo Diesel engine. The first generation was a small scale heat exchanger intended for concept validation, and the second generation was a full scale heat exchanger that used the entire exhaust flow at high speed and torque. The second generation heat exchanger showed that the model could accurately predict heat transfer, and the maximum experimental heat transfer rate was 15.3 kW for exhaust flow at 7.0 kg/min and 740 K. / text

This study is centered on modeling and experimental efforts to simulate and optimize the performance of thermoelectric generators (TEGs) for waste heat recovery systems for use in motor vehicles. TEGs are being studied and developed for applications in which waste heat, for example, from the exhaust of motor vehicles is converted into usable electricity. TEGs consisting of TE elements integrated with an exhaust heat exchanger require optimization to produce the maximum possible power output. Important optimization parameters include TE element leg length, fill fraction, leg area ratio between n- and p-type legs, and load resistance. A finite difference model was developed to study the interdependencies among these optimization parameters for thermoelectric elements integrated with an exhaust gas heat exchanger. The present study was carried out for TE devices made from n-type Mg₂Si and p-type MnSi[subscript 1.8] based silicides, which are promising TE materials for use at high temperatures associated with some exhaust heat recovery systems. The model uses specified convection boundary conditions instead of specified temperature boundary conditions to duplicate realistic operating conditions for a waste heat recovery system installed in the exhaust of a vehicle. A numerical model for a new waste heat recovery system configuration was proposed which showed an improvement of 40% in net power output over the conventional systems while using approximately 60% more TEG modules. The 1st generation, and an improved 2nd generation TEG module using n-type Mg₂Si and p-type MnSi[subscritp 1.8] based silicides were fabricated and tested to compare and correlate TE power generation with the numerical model. Important results include parameter values for maximum power output per unit area and the interdependencies among those parameters. Heat transfer through the void areas was neglected in the numerical model. When thermal contact resistance between the TE element and the heat exchangers is considered negligible, the numerical model predicts that any volume of TE material can produce the same power per unit area, given the parameters are accurately optimized. Incorporating the thermal contact resistance, the numerical model predicts that the peak power output is greater for longer TE elements with larger leg areas. The optimization results present strategies to improve the performance of TEG modules used for waste heat recovery systems. / text

Heat Recovery Steam Generator (HRSG) systems in conjunction with a primary gas turbine and a secondary steam turbine can provide advanced modern power generation with high thermal efficiency at low cost. To achieve such low cost efficiencies, near optimal settings of parameters of the HRSG must be employed. Unfortunately, current approaches to obtaining such parameter settings are very limited. The published literature associated with the Tabu Search (TS) metaheuristic has shown conclusively that it is a powerful methodology for the solution of very challenging large practical combinatorial optimization problems. This report documents a hybrid TS-direct pattern search (TS-DPS) approach and applied to the thermoeconomic optimization of a three pressure level HRSG system. To the best of our knowledge, this algorithm is the first to be developed that is capable of successfully solving a practical HRSG system. A requirement of the TS-DPS technique was the creation of a robust simulation module to evaluate the associated extremely complex 19 variable objective function. The simulation module was specially constructed to allow the evaluation of infeasible solutions, a highly preferable capability for methods like TS-DPS. The direct pattern search context is explicitly embodied within the TS neighborhoods permitting different neighborhood structures to be tested and compared. Advanced TS is used to control the associated continuum discretization with minimal memory requirements. Our computational studies show that TS is a very effective method for solving this HRSG optimization problem. / text

I detta examensarbete undersöktes möjligheten att installera värmeåtervinningssystem för ett flerfamiljehus i Hovgården som ligger en bit utanför Borlänge. I rapporten redovisas två olika sätt för energibesparingar som är aktuella för att ersätta borttagning av oljepannan som används i huset i dag. En rad svårigheter dök upp under undersökningen för installation av nytt värmesystem. Lämpliga lösningar kunde hittas efter mycket analys. Syftet med rapporten var att undersöka möjligheten och lönsamheten för installation av något av följande system; FVP eller VBX-modul som kan återvinna värme ur frånluften. Undersökningen visade att varken VBX eller FVP kan ersätta oljepannans värmeavgivning på ett tillfredsställande sätt. Med VBX ökas COP från 2,8 till 3,11 vilket leder till 17 MWh/år elbesparing. Däremot FVP kan försörja huset med 59 MWh/år men kan inte täcka effektbehovet för gården under kallaste dagarna. Resultatet blev att de båda undersökta systemen inte har möjlighet att ersätta oljeeldning. / In this thesis, we have studied a building located in Hovgården in Borlänge. The report investigates two energy saving installations that can help to reduce the amount of oil used today in the house. The purpose of the report was to examine the possibilities and viability of exhaust heat pump (FVP) and VBX module that can recover heat from the exhaust air. The investigation showed that neither VBX nor FVP can replace the oil-fired boiler in an acceptable way. With VBX the COP of the existing heat pump is increased from 2.8 to 3.11 leading to 17 MWh/year electricity saving. However FVP can recycle 59 MWh/year from the exhaust air but still cannot cover the power demand of the building during the coldest days. The result was that the two investigated systems are not able to replace oil heating.

Urban sprawl, global warming and overused landfills are conditions around the world today, and while people are concerned about these issues they have few practical solutions to them. This creative project seeks to devise a way for a specific sector of business (restaurants), to have a practical way to help reduce global warming and waste while utilizing unused or under-used land in urban areas. While life cycle models are available that address such issues as these, very few case examples are actually in use in this country. Based on existing life cycle models, this project will seek to reuse the wastes from a restaurant and recycle them into a garden/greenhouse (called an urban farm throughout this paper) which will produce food for the restaurant. The three main waste categories from the restaurant to be looked at are the organic kitchen food wastes, water and the heat that is always being expelled from the kitchen while it is operation. Additional ways to make a restaurant more sustainable will also be given. This project will show what the benefits are when a sustainable system is in operation. / Department of Landscape Architecture

This study explores ways to determine the energy efficiency of a pyrometallurgical ore reduction plant and measures to improve it. The feasibility of building a commercial plant - that is more energy efficient, has a low energy cost, and can operate independently and cost-effectively of external electricity supply - is determined. The need for energy efficiency is expanded to three questions: how should the energy efficiency of the plant be determined, what is the efficiency of the existing plant and to what level it can be improved. Literature and other relevant sources were consulted. Twenty potential energy conservation measures were identified through a literature study. A multi-criteria decision-making approach resulted in the selection of ten measures for conceptual implementation. The measures ranged from high-efficiency motors, solar power, heat recovery with thermal oil and various heat engines, to pressure recovery with turbo-generators. A case study approach was followed with the energy efficiency of an existing prototype plant the subject being studied. The energy usage of the existing plant and feasible measures to improve the performance were empirically observed. The impact of these measures was modelled and the results of the conceptual implementation determined. Two measures that were implemented during the study are also described and the results reported. The study found that the energy efficiency of the plant could be determined by the ratio of product exergy to input energy. By incorporating a number of energy conservation measures conceptually the internal efficiency of the prototype plant was conceptually improved from the current 17% to 22% and as a result externally supplied electricity reduced by 47%. The results were extrapolated to a future commercial plant and energy efficiencies of 26% on-grid and 21% off-grid predicted. This study suggests that a significant improvement in energy efficiency and energy cost can be achieved by integrating appropriate energy conservation measures into the existing and future plants. / MIng (Mechanical Engineering), North-West University, Potchefstroom Campus, 2014

Thesis (M.S.)--University of Texas at El Paso, 2008. / Title from title screen. Vita. CD-ROM. Includes bibliographical references. Also available online.