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  • About
  • The Global ETD Search service is a free service for researchers to find electronic theses and dissertations. This service is provided by the Networked Digital Library of Theses and Dissertations.
    Our metadata is collected from universities around the world. If you manage a university/consortium/country archive and want to be added, details can be found on the NDLTD website.
1

Modelling the Occurrence and Fate of Microplastics Caused by Tyre Wear on Highway E18 / Modellering av förekomsten och transportenav mikroplaster från däckslitage på motorväg E18

Kshirsagar, Aniruddha January 2023 (has links)
The accumulation of microplastics (MPs) are a growing concern for the environment, the maximum contributor to the MP pollution is tyre wear particles or TWPs. TWPs can accumulate in the environment and remain there for long periods of time and hence have the ability to disrupt ecosystems. With nearly 6,000,000 tons of TWPs being emitted each year globally there is a need to study theiroccurrence and fate in terms of why and how these particles get created and where they end up in the environment. The occurrence and fate of tyre wear particles (TWPs) were investigated, and a model was created in Python to simulate the flow of TWPs in a stormwater system at a test site on Highway E18 in Sweden. In the literature review it was found that the generation of TWPs is highly dependent on annual average daily traffic and the type of the road; it is also dependent on the driving behaviour such as acceleration, making unnecessary turns and the use of studded tyres in the winter. The TWPs are generally transported via stormwater but wind also plays a crucial role in transporting TWPs which are of a smaller size than 10 µm. Although the common notion is that the TWPs get washed into rivers,the literature review also suggests that most TWPs get trapped in soil that is covered with vegetation. Three processes were simulated in the developed model, namely transport, hetero-aggregation and settling. The results clearly show that a rainfall with an intensity of 40 mm during 15 min providesminimum settling in the stormwater system, and a 10 mm rainfall with a duration of more than 30 hasmaximum settling. Hetero-aggregation and settling is directly dependent on particle size and hence larger particle sizes have a higher probability of attaching to another particle or to settle in the pipes or wells of the stormwater system. It was also observed that the flow patterns such as depth, discharge and velocity of flow largely affect the settling and hetero-aggregation in the stormwater system. Most particles remain unaffected in short duration and high intensity rainfalls; the opposite is true for the longer duration and lower intensity rainfalls. Using the model, a stormwater system can be designed to trap or to flush out TWPs from the system. Also, the concentration of TWPs in the sinks can be known using the model that is created in this study
2

The influence of adsorbed polymer on clay and copper mineral particles' interactions

He, Mingzhao January 2009 (has links)
Attractive particle interactions which lead to the hetero-aggregation or 'sliming' of silicate clay gangue and valuable sulphide mineral particles are encountered in a number of hydrometallurgical and flotation processes. Sliming leads to poor recovery of the valuable minerals and high recovery of the clay gangue minerals in flotation concentrates. In the present work, the hetero-aggregation mechanism of hydrophilic mica clay mineral sericite (or muscovite) and hydrophobic chalcocite was investigated by probing the particle interactions and the prevailing interfacial chemistry under dispersion conditions where the individual chalcocite and sericite particles displayed negative zeta potentials. The mitigation/suppression of the hetero-aggregation was examined via the prudent control of dispersion conditions and pulp chemistry (i.e., pH modification and solution speciation control) and the use of two, anionic, polymeric dispersants with different molecular weight and functionality (carboxylate-substituted polyacrylamide, Cyquest 3223 and sulphonate-substituted polymaleic acid, P80 co-polymers) as dispersants. The adsorption behaviour of both polymers onto both minerals under industrially relevant suspension conditions have been quantified in terms of the polymer adsorption density and the adsorbed layer characteristics. These interfacial layer properties which impact on the mineral particles' zeta potentials and interactions, and also underpin the dispersion efficacy of polymers were characterized, using interfacial and solution analytical methods and TM-AFM imaging analysis.

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