Mechanical components operating at elevated temperatures can be identified in the aerospace industry as well as in metal forming. Hot stamping is a metal forming technique utilized for manufacturing high strength lightweight components for the automotive industry. Three types of Ni-based hardfacings doped with solid lubricants were manufactured using laser cladding. An additional hardfacing was also manufactured using the Ni-based alloy only as a reference. Solid lubricants added were Ag+WS2, WS2 and Cu+MoS2. These hardfacings were manufactured and tribologically evaluated for potential application in hot stamping tooling. Direct diode laser was used for the cladding process. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used for characterization of the microstructure after deposition. Tribological testing was done using a reciprocating pin-on-disk tribometer under dry sliding conditions at temperatures in the range between RT and 600°C. Bearing steel ball and a flat pin made of the same material were used as counterbodies. Wear volume loss was measured using a 3D optical interferometer. For identification of the wear mechanisms SEM/EDS techniqueswere used. Formation of a lubricious CrxSy phase was detected after deposition, additionally encapsulation of silver particles by CrxSy was also observed. Reduction of friction coefficient was observed for every self-lubricating hardfacing compared to the reference. Lowest friction coefficient (0.23-0.3) was observed when the testing temperature was set to 400°C using a pin-on-flat configuration. Lowest wear rate was observed at 400°C, with the coating containing Ag and WS2 having a specific wear rate of 3.04 · 10−5mm3/Nm. The lubricity of the self-lubricating hardfacings was attributed to the CrxSy phase observed on the worn surface. At low to moderate temperatures abrasive wear is the main wear mechanism. At the highest testing temperature, oxidative wear was dominant.

Many automotive components are made of Al-Si coated ultra-high strength boron steel (UHSS) and are produced by hot stamping process. In this process, the workpiece is heated to an austenitizing temperature and is then formed and quenched simultaneously between the tools to achieve the desired shape and high strength. During hot stamping process, friction and wear occur which affect formability and maintenance intervals for tool replacement and repair. To repair worn tools, metal is deposited by fusion welding technique. The tribological behaviour of repair welded tool steel sliding against Al-Si coated UHSS has not been studied in detail and there is a need to investigate if the modified tool surface will affect friction and wear. Hot stamping, similar to many manufacturing processes, is affected by the global mega trend of digitalization and Industry 4.0. To monitor the process and optimize the control and operation are the main aims. In view of this, tribological condition monitoring is a promising approach that can allow measurement of physical properties such as vibrations, temperatures, and acoustic emission to be coupled to the tribological response of the system. The aim is to monitor the hot stamping process and enable early detection of changes in friction and wear which can be used for e.g. optimized maintenance and minimized scrap. The aim of this M.Sc. thesis was to improve the robustness of hot forming processes by studying the tribological behaviour of repair welded tool steel sliding against Al-Si coated UHSS under conditions relevant for hot stamping. Another aim was to obtain more predictable tool maintenance by the implementation of acoustic emission measurement system on a hot-strip tribometer and correlating condition monitoring signals to friction and wear phenomena. The tribological tests were carried out using a hot-strip tribometer in conditions representative of a hot stamping process of automotive components. Acoustic emission during sliding between hot work tool steel and different automotive component material surfaces was measured at room temperature in the same strip drawing tribometer and correlated to friction and wear of the surfaces to get more predictable maintenance intervals. Tool steel specimens were welded with the same material as the base material QRO90. Before conducting the tribological test, the repair welded tool steel pin cross-section was polished, etched, and observed under optical microscope and SEM to analyze the effect of Tungsten Inert Gas (TIG) welding process on the microstructure. The analysis was completed with EDS to study the elements in the microstructure. Microhardness was measured to obtain the microhardness profile from the repair welded tool steel pin surface to the bulk in order to study the effect of different microstructures on the mechanical properties. The weight and surface roughness of the pins were measured before the tribological test. After the test was finished, the weight of the pins was measured to calculate the weight difference. The sliding surface of the pins and the strips were photographed. The sliding surface of the pins was also observed and analyzed using SEM and EDS after the test to study wear characteristic of the repair welded tool steel at high temperatures. Acoustic emission signal from the sliding was studied using Toolox44 pins with surface roughness 300-400 nm and with lay direction parallel and perpendicular to sliding direction. Toolox44 pins were sliding against uncoated UHSS, as-delivered Al-Si coated UHSS, and heat-treated Al-Si coated UHSS strips. Acoustic emission was measured during the sliding at the same time as COF measurement. Weight of the pins was measured before and after the test and the wear damage on both surfaces was photographed. COF, AE signals in the time and frequency domain, and wear damage were compared and analyzed. It is found that repair welded tool steel has similar COF compared to the original hot work tool steel with the largest weight gain from the test at 700 ⁰C due to compaction galling mechanism with slower lump formation and the presence of wear particles, transfer layer, and formation of lumps. The weight gain is smaller from the test at 750 ⁰C due to faster lump formation. The weight loss from the test at 600 ⁰C is due to abrasive wear mechanism. SEM micrographs revealed that the repair welded tool steel surface and transfer layers can be found beneath a transfer layer. Wear particles adhered on the repair welded tool steel surface come from broken transfer layer or directly from Al-Si coated UHSS. A change in wear mechanism is indicated by acoustic emission burst signals or gradual amplitude change in the time domain. Frequency analysis of AE signals revealed a change in wear mechanism due to the formation of transferred material in the form of a lump causes AE signals with peaks at higher frequencies above 0.3 MHz to shorten.

The purpose of the project work was to build knowledge of the tribological behaviour of self-lubricating laser cladding, with and without external solid lubricant during conditions relevant for hot metal forming of aluminium. The materials used during the project were plates coated with a Ni-based self-lubricating clad and a reference sample of work tool steel. The self-lubricating laser clad was applied using a high power direct diode laser. The external solid lubricant used was a graphite dispersion. The external solid lubricant was applied on the samples using a spraying technique, leaving a dry layer of solid graphite on the plates. To test the tribological behaviour of the plates, linear reciprocating friction and wear tests were performed both under lubricated and dry conditions. During the dry tests, different surface roughness of the plates where investigated. The pins for the tribological test were made of AA7075. Parameters chosen for the tribological tests were based on conditions during hot forming of aluminium. After having taken images of the plates using scanning electron microscopy, and using a 3D optical profiler, the wear volume and material transfer was evaluated, and wear mechanism analysis was performed.   The tribological behaviour of polished Ni-based laser clad under dry conditions is comparable to that of the reference sample at its best performance. Using a mirror polished Ni-based laser clad under dry condition can be an option to not using external solid lubricant during hot forming of aluminium. Also, the surface roughness of the self-lubricating clad under dry conditions does not affect the coefficient of friction.

Over the last decade, the application of ultra-high strength steel as safety components and structural reinforcements in automobile applications has increased due to their favourable high-strength-to-weight ratio. The complex shaped components are widely produced using hot stamping. However, this process encounters problems such as galling and increased wear of the tools due to harsh operating conditions associated to the elevated temperatures. Moreover, quenching is a critical step that affects the hot formed components. Slow cooling rates results in inhomogeneous mechanical properties and increased cycle time. Therefore, fast and homogeneous quenching of the formed components in combination with reduction of wear rates during hot forming are important targets to ensure the quality and efficiency of the process. The use of additive manufacturing (AM) technologies opens up potential solutions for novel tooling concepts. The manufacturing of complex shape cooling channels and integration of high-performance alloys at the surface could benefit the tribological performance in the forming operation. However, the research into high temperature tribological behaviour of AM materials in hot forming applications is very limited. The aim of this work is to study the tribological performance of additively manufactured materials. Two steels were used – a maraging steel and modified H13 tool steel. The hot work tool steel H13 is commonly applied for dies in metal forming processes. In this thesis it was used to study additive manufacturing as the processing route instead of conventional casting. The choice of a maraging steel is motivated by a possible application of high-performance alloys as a top layer on dies. The materials were post-machined and studied in milled, ground and shot-blasted conditions. The different post-machining operations were applied to study the effect of surface finish on the tribological behaviour and also to evaluate different methods of post-machining an AM surface. As fabricated dies are usually manufactured with milled surface. During its use, the dies undergo refurbishment after certain number of cycles and the surface condition is changed to a ground surface. These surface finishes are commonly tested for hot forming applications. The shot blasted operation was chosen as alternative surface finish. The process allows to prepare large sized tools easily and the surface has beneficial compressive stresses. The tribological behaviour of AM steels was studied using a hot strip drawing tribometer during sliding against a conventional Al-Si coated 22MnB5 steel. The workpiece temperature during the tests was 600 and 700°C. The results of the tribological performance of AM materials were compared to conventionally cast tool steel QRO90.The results have shown that the friction behaviour of both maraging and H13 steels at 600°C was stable and similar whereas at 700°C the COF was more unstable and resulted in an earlier failure of the tests due to increased material transfer of Al-Si coating from the workpiece surface.The main wear mechanisms for AM materials were galling and abrasion at both temperatures. Abrasion is more severe for the AM steels in comparison to cast tool steel QRO90. The galling formation on milled and ground surfaces showed similar behaviour to cast steel and it increased with higher workpiece temperatures. The shot-blasted surfaces showed less build-up of transferred material on the surface but folding of asperities and entrapment of Al-Si particles within surface defects generated during shot-blasting.

To minimize global carbon emissions, having efficient jet engines and internal combustion engines necessitates utilizing lightweight alloys such as Al, Ti, and Mg-based alloys. Because of their remarkable strength/weight ratio, these alloys have received a lot of attention. Nonetheless, they have very poor tribological behavior, particularly at elevated temperatures beyond 200 °C, when most liquid lubricants begin to fail in lubrication. Over the last two decades, there has been a lot of interest in protecting Al, and Ti-based alloys by developing multiphase solid lubricants with a hard sublayer that provide mechanical strength and maintain the part's integrity while providing lubricity. The development of novel coatings with superior lubricity, high toughness, and high-temperature tolerance remains a challenging and hot topic to research and provide new engineered solutions for. To address and provide solutions to protect light-weight, i.e., Al, and Ti alloys at high-temperature and bestow superior tribological properties to such alloys, three types of adaptive lubricious coatings have been studied in this thesis: Nb-Ag-O self-healing lubricious ternary oxide, PEO-chameleon a self-adaptive multi-phase coating, and Sb2O3-MSH-C lubricious adaptive coatings to address this challenge. The development of the Nb-Ag-O ternary resulted in a coefficient of friction as low as 0.2 at 600 °C and crack healing at 900 °C. PEO-chameleon coatings demonstrated a remarkably low COF, as low as 0.07 at 300 °C and 1.4 GPa applied pressure. Finally, the Sb2O3-MSH-C multi-phase lubricious solid lubricant revealed superlubricity, with a CoF of 0.008 at 300 °C, providing a potentially promising contender for high-temperature, high-load applications.

Hot stamping of aluminium alloys allows for increased formability, decreased springback and the possibility of integrating age-hardening heat treatments into the process. However, it can be challenging due to the occurrence of material transfer of aluminium onto the tool, as aluminium is prone to adhesion even at low temperatures. Hence, lubrication is always necessary when forming aluminium, but lubricants can still fail, leading to direct interaction between tool and workpiece and thus material transfer. This phenomenon reduces the efficiency of the process, as interruptions are necessary for the refurbishment of the tools. Understanding of how material transfer takes place is important in order to find new or improved solutions, in terms of lubrication and surface engineering, to prevent adhesion. Nevertheless, current research in high temperature tribology of aluminium, mainly in terms of material transfer mechanisms, is very limited, as many of the works focus on lubricated conditions and do not look into the fundamental interactions between aluminium alloys and tool steels. In this context, the aim of this work is to investigate the mechanisms behind the occurrence of aluminium alloy transfer onto tool steel during sliding at high temperature and in dry conditions. A hot-strip drawing tribometer was used to perform tests at room temperature, 300°C, 400°C, and 500°C, directly after solubilizing the aluminium alloy at 520°C. Two different topographies for the tool steel were used: ground and polished. Material transfer characterization was performed mainly through scanning electron microscopy. It was found that grinding marks (ground tool steel) and carbides (polished tool steel) act as initiation sites for the transfer to occur. Temperature plays a role on the growth mechanisms of the transfer films during sliding, as thermal softening of the aluminium alloy is the dominant factor in determining the growth direction of the transfer layers. A growth towards the trailing edge (shearing and smearing of the transferred aluminium) or a growth towards the leading edge (build-up of transferred aluminium, leading to a thicker and more localized transfer material).

Internal Combustion Engine (ICE) exhaust components are exposed to extreme operating temperatures. Thus, it is necessary that they are designed with materials that can sustain thermal and vibrational stresses. This study investigates the wear mechanisms and tribological performance of the exhaust manifold joint in Scania CV diesel trucks, focusing on the lip seal ring between the exhaust and turbo manifolds. The joint is prone to wear due to thermal and vibrational stresses, impacting its service life and raising environmental concerns. The manifold material, ductile cast iron SiMo51, offers good thermal resistance, while the lip seal ring, made of Inconel 718c, provides excellent thermal fatigue and corrosion resistance, coated with AlTiN for wear and oxidation resistance. However, the tribological performance of this joint and material combination remains unknown, necessitating further research.  This work aims to understand wear initiation mechanisms and their relationship with temperature. Test setups were established using an oscillating cylinder on disc configuration in the SRV 3 tribometer. SiMo51 uncoated/coated with Tribaloy 400 and Inconel 718c uncoated/coated with AlTiN were tested against each other to identify the best material pair. Analysis involved coefficient of friction, visual inspection, wear volume measurements, SEM micrographs, and EDS for surface chemical composition. Results indicated that friction behaviour is temperature-dependent, with oxide layer formation reducing the coefficient of friction when the manifold is uncoated, while the opposite occurs when coated with Tribaloy 400. Wear behaviour varied based on material combinations and temperature. Uncoated manifold exhibited dominant adhesion (galling) accompanied by tribo-oxidation at higher temperatures, with maximum wear volumes at room temperature. Introduction of T-400 on the manifold initiated galling on the lip seal, leading to abrasion on the manifold surface, accompanied by tribo-oxidation at elevated temperatures. Wear increased until 500°C, followed by a decrease at 700°C. Further explanations of T-400 wear behaviour are lacking in the literature.

High-performance materials such as stainless steels and nickel based super alloys are widely used in demanding applications where high mechanical and thermal properties are required. The applications of super alloys are mainly found in jet engines, power plants and gas turbines demanding high fatigue strength, corrosion and oxidation resistance as well as wear resistant properties. In order to use them, they go through various machining processes such as milling, turning, cutting, polishing etc. until the final product is achieved. Modern manufacturing industries employs various machining tools and technologies to improve the machining process of heat resistant super alloys. However, there are still challenges which needs to be addressed. Among them, adhesive wear of the machining tools is one of the main wear mechanism during the tribological interaction of tool and workpiece, preventing them to achieve the desired quality and surface finish of the end product. Moreover, it damages the tool reducing its lifecycle and in return, increasing the production cost. Among the cutting tools tungsten carbide (WC/Co) tools coated with TiAlN coating due to their good high temperature performance are extensively used. Nonetheless, these coatings still face issue like adhesive wear, abrasion, oxidation at higher temperature damaging the tools and subsequent machining. Therefore, it is imperative to understand the initiation mechanism of adhesive wear during the tribological interaction of super alloys and coated cutting tool material. In this research work, the tribological response of two coatings deposited by physical vapour deposition (PVD), having the composition Ti60Al40N and Ti40Al60N have been studied against two super alloys material, i.e. Inconel 718 and stainless steel 316L. A high temperature SRV (Schwingung (Oscillating), Reibung (Friction), Verschleiß (Wear)) reciprocation friction and wear test set up was employed to investigate the friction behaviour, wear rate and dominant wear mechanisms.  For Ti60Al40N coating, the experimental results revealed that generally, friction increases in case of sliding against Inconel 718 up to 400 °C and drops at 760 °C. A high wear volume at room temperature and a decrease to a minimum at 760 °C has been observed for Inconel 718. On the other side, Stainless steel 316L (SS 316L) faces a continuous rise in friction coefficient with highest value at 760 °C during sliding against Ti60Al40N coating. Wear is highest at 400 °C for SS 316L pin. The worn surfaces shows that both workpiece materials experience increase in material transfer due to adhesive wear with rise in temperature. At 400 °C, adhesion is the primary wear mechanism for both workpiece materials. A further rise in temperature to 760 °C promotes the adhesive wear through oxides formation on both material surfaces.  Similarly, Ti40Al60N coating shows the same friction behaviour with change in average steady state friction values for both material of Inconel 718 and SS 316L. Both workpiece materials responds in a similar way to wear volume loss, i.e. lowest at room temperature and highest at 760 °C. For Inconel 718, transfer of coating constituents on to the Inconel 718 pin surface was detected and associated with coating rupture and peeling, exacerbating with rise in temperature. Adhesion, abrasion, and oxidation are primary wear mechanisms at 400 °C and 760 °C. For SS 316L, coating transfer only happen at 400 °C. No damage of coating at 40 °C, a complete damage at 400 °C, and formation of dense porous oxides layers at 760 °C have been noticed. At 400 °C, adhesion, abrasion, and chipping while at 760 °C, adhesion, three body abrasion, ploughing and oxidation are the main wear mechanisms.