Stars form when filaments and dense cores in molecular clouds fragment and collapse due to self-gravity. In the most basic analyses of gravitational stability, the competition between self-gravity and thermal pressure sets the critical (i.e. maximum stable) mass of spheres and the critical line density of cylinders. Previous work has considered additional support from magnetic fields and turbulence. Here, we consider the effects of non-ionizing radiation, specifically the inward radiation pressure force that acts on dense structures embedded in an isotropic radiation field. Using hydrostatic, isothermal models, we find that irradiation lowers the critical mass and line density for gravitational collapse, and can thus act as a trigger for star formation. For structures with moderate central densities, similar to 10(3) cm(-3), the interstellar radiation field in the Solar vicinity has an order unity effect on stability thresholds. For more evolved objects with higher central densities, a significant lowering of stability thresholds requires stronger irradiation, as can be found closer to the Galactic centre or near stellar associations. Even when strong sources of ionizing radiation are absent or extincted, our study shows that interstellar irradiation can significantly influence the star formation process.

Context. Ammonia and its deuterated isotopologues probe physical conditions in dense molecular cloud cores. The time-dependence of deuterium fractionation and the relative abundances of different nuclear spin modifications are supposed to provide a means of determining the evolutionary stages of these objects. Aims. We aim to test the current understanding of spin-state chemistry of deuterated species by determining the abundances and spin ratios of NH2D, NHD2 and ND3 in a quiescent, dense cloud. Methods. Spectral lines of NH3, NH2D, NHD2, ND3 and N2D+ were observed towards a dense, starless core in Ophiuchus with the APEX, GBT and IRAM 30-m telescopes. The observations were interpreted using a gas-grain chemistry model combined with radiative transfer calculations. The chemistry model distinguishes between the different nuclear spin states of light hydrogen molecules, ammonia and their deuterated forms. Different desorption schemes can be considered. Results. High deuterium fractionation ratios with NH2D = NH3 similar to 0 : 4, NHD2 = NH2D similar to 0 : 2 and ND3 = NHD2 similar to 0 : 06 are found in the core. The observed ortho/para ratios of NH2D and NHD2 are close to the corresponding nuclear spin statistical weights. The chemistry model can approximately reproduce the observed abundances, but consistently predicts too low ortho/para-NH2D, and too large ortho/para-NHD2 ratios. The longevity of N2H+ and NH3 in dense gas, which is prerequisite to their strong deuteration, can be attributed to the chemical inertia of N-2 on grain surfaces. Conclusions. The discrepancies between the chemistry model and the observations are likely to be caused by the fact that the model assumes complete scrambling in principal gas-phase deuteration reactions of ammonia, which means that all the nuclei are mixed in reactive collisions. If, instead, these reactions occur through proton hop/hydrogen abstraction processes, statistical spin ratios are to be expected. The present results suggest that while the deuteration of ammonia changes with physical conditions and time, the nuclear spin ratios of ammonia isotopologues do not probe the evolutionary stage of a cloud.

The gas kinetic temperature (T-K) of various interstellar environments is often inferred from observations that can deduce level populations of atoms, ions, or molecules using spectral line observations; H I 21 cm is perhaps the most widely used, and has a long history. Usually the H I 21 cm line is assumed to be in thermal equilibrium. and the populations are given by the Boltzmann distribution. A variety of processes, many involving Ly alpha, can affect the 21 cm line. Here we show how this is treated in the spectral simulation code Cloudy, and present numerical simulations of environments where this temperature indicator is used, with a detailed treatment of the physical processes that determine level populations within H-0. We discuss situations where this temperature indicator traces TK, cases where it fails, as well as the effects of Lya pumping on the 21 cm spin temperature. We also show that the Lya excitation temperature rarely traces the gas kinetic temperature.

Using a set of high-resolution hydrodynamical simulations run with the Cholla. code, we investigate how mass and momentum couple to the multiphase components of galactic winds. The simulations model the interaction between a hot wind driven by supernova explosions and a cooler, denser cloud of interstellar or circumgalactic media. By resolving scales of Delta x < 0.1 pc over > 100 pc distances, our calculations capture how the cloud disruption leads to a distribution of densities and temperatures in the resulting multiphase outflow and quantify the mass and momentum associated with each phase. We find that the multiphase wind contains comparable mass and momenta in phases over a wide range of densities and temperatures extending from the hot wind (n approximate to 10(-2.5) cm(-3), T approximate to 10(6.5) K) to the coldest components (n approximate to 10(2) cm(-3), T approximate to 10(2) K). We further find that the momentum distributes roughly in proportion to the mass in each phase, and the mass loading of the hot phase by the destruction of cold, dense material is an efficient process. These results provide new insight into the physical origin of observed multiphase galactic outflows and inform galaxy formation models that include coarser treatments of galactic winds. Our results confirm that cool gas observed in outflows at large distances from the galaxy (greater than or similar to 1 kpc) likely does not originate through the entrainment of cold material near the central starburst.

We present a (CO)-C-12 (2-1) mosaic map of the spiral galaxy NGC 6946 by combining data from the Submillimeter Array and the IRAM 30m telescope. We identify 390 giant molecular clouds (GMCs) from the nucleus to 4.5 kpc in the disk. GMCs in the inner 1 kpc are generally more luminous and turbulent, some of which have luminosities > 10(6)K. km. s(-1) pc(2) and velocity dispersions > 10. km s(-1). Large-scale bar-driven dynamics likely regulate GMC properties in the nuclear region. Similar to the MilkyWay and other disk galaxies, GMC mass function of NGC 6946 has a shallower slope (index > -2) in the inner region, and a steeper slope (index < -2) in the outer region. This difference in mass spectra may be indicative of different cloud formation pathways: gravitational instabilities might play a major role in the nuclear region, while cloud coalescence might be dominant in the outer disk. Finally, the NGC 6946 clouds are similar to those inM33 in terms of statistical properties, but they are generally less luminous and turbulent than the M51 clouds.

We sort 4683 molecular clouds between 10 degrees < l < 65 degrees from the Bolocam Galactic Plane Survey based on observational diagnostics of star formation activity: compact 70 mu m sources, mid-IR color-selected YSOs, H2O and CH3OH masers, and UCH II. regions. We also present a combined NH3-derived gas kinetic temperature and H2O maser catalog for 1788 clumps from our own GBT 100 m observations and from the literature. We identify a subsample of 2223 (47.5%) starless clump candidates (SCCs), the largest and most robust sample identified from a blind survey to date. Distributions of flux density, flux concentration, solid angle, kinetic temperature, column density, radius, and mass show strong (>1 dex) progressions when sorted by star formation indicator. The median SCC is marginally subvirial (alpha similar to 0.7) with >75% of clumps with known distance being gravitationally bound (alpha < 2). These samples show a statistically significant increase in the median clump mass of Delta M similar to 170-370 M-circle dot from the starless candidates to clumps associated with protostars. This trend could be due to (i) mass growth of the clumps at (M) over dot similar to 200-440 M-circle dot Myr(-1) for an average freefall 0.8 Myr timescale, (ii) a systematic factor of two increase in dust opacity from starless to protostellar phases, and/or (iii). a variation in the ratio of starless to protostellar clump lifetime that scales as similar to M-0.4. By comparing to the observed number of CH3OH maser containing clumps, we estimate the phase. lifetime of massive (M > 10(3) M-circle dot) starless clumps to be 0.37 +/- 0.08 Myr (M/10(3) M-circle dot)(-1); the majority (M < 450 M-circle dot) have phase. lifetimes longer than their average freefall time.

In this thesis we address the problem of understanding the star formation process in giant molecular clouds in a galactic context. Most simulations of molecular clouds to date use an oversimplified set of initial conditions (turbulent spheres/boxes or colliding flows). Full galactic scale models are able to generate molecular clouds with complex morphologies and velocity fields but they fail to reproduce in detail the effects that occur at sub-pc scales (e.g. stellar feedback). Our goal is to build the bridge between these two scenarios, and to model the star formation process in molecular clouds produced in a galactic context. We extract our molecular clouds from full-scale galactic simulations, hence we need to increase the resolution by two orders of magnitude. We introduce the details of the program used to simulate molecular clouds in Chapter 2, and describe in detail the method we follow to increase the resolution of the galactic clouds. In Chapter 3 we compare our simulated galactic clouds with the more conventional approach of using turbulent spheres. We create turbulent spheres to match the virial state of three galactic clouds. We perform isothermal simulations and find that the velocity field inherited from the full-scale galactic simulations plays an important role in the star formation process. Clouds affected by strong galactic shear produce less stars compared with clouds that are compressed. We define (and test) a set of parameters to characterise the dynamical state of our clouds. To include stellar feedback in our simulations we need to introduce a cooling/heating algorithm. In Chapter 4 we analyse how the different velocity fields of our clouds change the temperature distribution even in the absence of feedback. To study the formation of molecules we need to model the chemistry of H2 in our clouds. We also add CO chemistry, and produce synthetic observations of our clouds. The effect of feedback from winds and supernovae in galactic clouds is studied in Chapter 5. We analyse the effect of winds in clouds with very different velocity fields. We find that the effect of winds is stronger in highly virialised, high star forming clouds, with clouds with weak galactic shear, compared to unbound shear-dominated clouds. The steady and continuous action of the winds appears to have a greater effect than the supernovae. In summary, the inherited properties from the galaxy have an impact on many relevant processes in star formation, influencing gravitational collapse, the formation of filamentary structures, the temperature field of the cloud, and have a considerable effect on the impact of feedback in the clouds.

We present HST Goddard High Resolution Spectrograph and Space Telescope Imaging Spectrograph observations of five quasi stellar objects that probe the prominent high-velocity cloud (HVC) Complex C, covering ∼10% of the northern sky. Based upon a single sight-line measurement (Mrk 290), a metallicity [S/H] = -1.05 ± 0.12 has been associated with Complex C by Wakker et al. When coupled with its inferred distance (5 ≲ d ≲ 30 kpc) and line-of-sight velocity (v ∼ -100 to -200 km s-1), Complex C appeared to represent the first direct evidence for infalling low-metallicity gas onto the Milky Way, which could provide the bulk of the fuel for star formation in the Galaxy. We have extended the abundance analysis of Complex C to encompass five sight lines. We detect S n absorption in three targets (Mrk 290, 817, and 279); the resulting [S II/H I] values range from -0.36 (Mrk 279) to -0.48 (Mrk 817) to -1.10 (Mrk 290). Our preliminary O I FUSE analysis of the Mrk 817 sight line also supports the conclusion that metallicities as high as 0.3 times solar are encountered within Complex C. These results complicate an interpretation of Complex C as infalling low-metallicity Galactic fuel. Ionization corrections for H II and S III cannot easily reconcile the higher apparent metallicities along the Mrk 817 and Mrk 279 sight lines with that seen toward Mrk 290, since Hα emission measures preclude the existence of sufficient H II. If gas along the other lines of sight has a similar pressure and temperature to that sampled toward Mrk 290, the predicted Hα emission measures would be ∼900 mR. It may be necessary to reclassify Complex C as mildly enriched Galactic waste from the Milky Way or processed gas torn from a disrupted neighboring dwarf, as opposed to low-metallicity Galactic fuel.

Massive star formation takes place in the dense cores of molecular clouds where the stars may be obscured at optical wavelengths. An excellent signpost of a massive young stellar object is the presence of an ultra-compact HII region (UCHii), which is a dense photo-ionised cocoon of gas surrounding the newly formed star. The aim of this project is to develop an assembly of numerical tools, caravela, that can simulate realistic data streams representing high-mass star forming regions in our Galaxy. The synthetic output consists in images and photometric point source catalogues, in the IRAS and Herschel wavebands. In an era when large observational surveys are increasingly important, this tool can produce simulated infrared point-source catalogues of high-mass star forming regions on a Galactic scale. The approach used is to construct a synthetic Galaxy of star-forming regions represented by SED templates. The star-forming regions are distributed randomly along a four spiral arm morphology, although a wide range of geometries can be used including rings and different numbers of spiral arms. The caravela code then observes the synthetic Galaxy to produce simulated images and point source catalogues with appropriate sensitivity and angular resolution. caravela was first used to model the simulated Galaxy by constraining the synthetic output to observations made by IRAS. This numerical tool will allow the user to infer physical properties of the Galactic population of high-mass star forming regions from such observations. Second, the selected model was again observed with caravela in Herschel mode. These are therefore predictive results for the future Herschel observations. A model with 4.0×104 compact proto-stars embedded in larger grey-body envelopes (with T = 40 K and linear size scale lIII = 5.0 × 106 AU) is the best-fit model to the IRAS observational data set studied. We found a level of contamination from low- and intermediate-mass objects of " 90%. The modelled data set resulting from the Herschel simulation resulted in the detection of approximately twice as many Herschel objects than IRAS, which is consistent, in a limited way, with the real observed companion clump fraction (CCF) of 0.90 ± 0.07 (Thompson et al., 2006) means that on average there were observed 2 sources per one IRAS source. Our caravela and the real observed CCF are therefore consistent. caravela was coupled with an independent diffuse emission model (Paladini et al., 2007) and the resulting analysis is presented as an interesting seed for the future.

We present spectral line mapping observations towards four massive star-forming regions Cepheus A, DR21S, S76E and G34.26+0.15 - with the IRAM 30-m telescope at the 2 and 3 mm bands. In total, 396 spectral lines from 51 molecules, one helium recombination line, 10 hydrogen recombination lines and 16 unidentified lines were detected in these four sources. An emission line of nitrosyl cyanide (ONCN, 14(0), 14-13(0), (13)) was detected in G34.26+0.15, as the first detection in massive star-forming regions. We found that c-C3H2 and NH2D show enhancement in shocked regions, as suggested by the evidence of SiO and/or SO emission. The column density and rotational temperature of CH3CN were estimated with the rotational diagram method for all four sources. Isotope abundance ratios of C-12/C-13 were derived using HC3N and its C-13 isotopologue, which were around 40 in all four massive star-forming regions and slightly lower than the local interstellar value (similar to 65). The N-14/N-15 and O-16/O-18 abundance ratios in these sources were also derived using the double isotopic method, which were slightly lower than in the local interstellar medium. Except for Cep A, the S-33/S-34 ratios in the other three targets were derived, which were similar to that in the local interstellar medium. The column density ratios of N(DCN)/N(HCN) and N( DCO+)/N(HCO+) in these sources were more than two orders of magnitude higher than the elemental [D]/[H] ratio, which is 1.5 x 10(-5). Our results show that the later stage sources, G34.26+0.15 in particular, present more molecular species than earlier stage sources. Evidence of shock activity is seen in all stages studied.