Current stoichiometric spark-ignited engine technologies require costly catalytic converters for reductions in tailpipe emissions. Load control is achieved by using a throttle, which is a leading contributor to reductions in efficiency. Spark-ignited lean burn natural gas engines have been proven to be more efficient and emit fewer pollutants than their stoichiometric counterparts. Load reduction in these engines can be achieved by regulating the air/fuel ratio of the intake charge thereby reducing the efficiency penalties inherent to throttling. Partially stratified charge (PSC) can provide further reductions in emissions and improvements in efficiency by extending the lean limit of operation. PSC is achieved by the ignition of a small quantity of natural gas in the vicinity of the spark plug. This creates an easily ignitable mixture at the spark plug electrodes, thereby providing a high energy ignition source for the ultra-lean bulk charge. Stratified charge engine operation using direct injection (DI) has been proposed as a method of bridging the throttleless load reduction gap between idle and ultra-lean conditions. A previous study was conducted to determine if PSC can provide a high-energy ignition source in a direct injected stratified charge engine. Difficulties with igniting the PSC injections in an air-only bulk charge were encountered. This study focuses on a fundamental Schlieren image-based analysis of PSC combustion. Natural gas was injected through a modified spark plug located in an optically accessible combustion bomb. The relationships between PSC injection timing, fuel supply pressure and spark timing were investigated. Spark timing is defined as the duration between commanded start of injection and the time of spark. As the fuel supply pressure was increased, the minimum spark timing that lead to successful combustion also increased. The largest spark timing window that led to successful combustion was determined to be 80 ms wide at an injection fuel supply pressure of 300 psi. The amount of unburned natural gas increased with increasing spark timing. A cold flow study of the PSC injection system was also conducted. The PSC injection solenoid was found to have a consistent average injection delay of 1.95 ms. The slope of the linear response region of observed injection duration to commanded injection duration was 8.4. Due to plenum effects, the average observed injection duration of the entire PSC system was an order of magnitude longer than the commanded injection duration and was found to vary significantly with fuel supply pressure.

In this Ph.D. thesis, we have carried out numerical simulations to study nanosecond repetitively pulsed discharges (NRPD) in a point-to-point geometry at atmospheric pressure in air and in H2-air mixtures. Experimentally, three discharge regimes have been observed for NRPD in air at atmospheric pressure for the temperature range Tg = 300 to 1000 K: corona, glow and spark. To study these regimes, first, we have considered a discharge occurring during one of the nanosecond voltage pulses. We have shown that a key parameter for the transition between the discharge regimes is the ratio between the connection-time of positive and negative discharges initiated at point electrodes and the pulse duration. In a second step, we have studied the dynamics of charged species during the interpulse at Tg = 300 and 1000 K and we have shown that the discharge characteristics during a given voltage pulse remain rather close whatever the preionization level (in the range 109-1011 cm��3) left by previous discharges. Then, we have simulated several consecutive nanosecond voltage pulses at Tg = 1000 K at a repetition frequency of 10 kHz. We have shown that in a few voltage pulses, the discharge reaches a stable quasi-periodic glow regime observed in the experiments. We have studied the nanosecond spark discharge regime. We have shown that the fraction of the discharge energy going to fast heating is in the range 20%- 30%. Due to this fast heating, we have observed the propagation of a cylindrical shockwave followed by the formation of a hot channel in the path of the discharge that expands radially on short timescales (t < 1 _s), as observed in experiments. Then we have taken into account an external circuit model to limit the current and then, we have simulated several consecutive pulses to study the transition from multipulse nanosecond glow to spark discharges. Finally the results of this Ph.D. have been used to find conditions to obtain a stable glow regime in air at 300 K and atmospheric pressure. Second we have studied on short time-scales (t_ 100_s) the ignition by a nanosecond spark discharge of a lean H2-air mixture at 1000 K and atmospheric pressure with an equivalence ratio of _ = 0:3. We have compared the relative importance for ignition of the fast-heating of the discharge and of the production of atomic oxygen. We have shown that the ignition with atomic oxygen seems to be slightly more efficient and has a completely different dynamics.

The performance characteristics of a diesel fuel piloted syngas compression ignition engine are presented in this thesis. A stock Hatz 1D81 engine was converted to operate in dual fuel mode through the elimination of the governor system and addition of an in-cylinder pressure transducer and custom intake system to facilitate the mixing of the gaseous fuel and combustion air. The engine was run on a Superflow water brake dynamometer and benchmarked with diesel to compare against manufacturer specifications. This was followed by dual fuel operation on methane and syngas, with the results being compared through performance characteristics. When operated on methane, the engine attained higher peak in-cylinder pressures along with higher torque, power, and thermal efficiency values for equal equivalence ratios. It was necessary to use greater amounts of syngas to reach comparable results with methane due to the lower energy content of syngas. The ignition delay was greater for syngas, and the onset of knock occurred earlier with syngas in comparison to methane. The heat release, Q, was comparable for both fuels and the exhaust gas emissions were significantly lower for operation with syngas. With emphasis on clean engine operation, syngas operation proved to be viable due to its renewable nature, significantly lower exhaust gas emissions, equal heat release characteristics, and larger useable operating range when compared to methane. / Thesis (Master, Mechanical and Materials Engineering) -- Queen's University, 2012-05-28 15:02:49.227

No description available.

A full-scale ASTM E 1321 Lateral ignition and Flame Transport (LIFT) apparatus was constructed and compared with a Reduced scale Ignition and Flame spread Test apparatus (RIFT) adaptation of the cone calorimeter in the vertical position. The objective was to find a low cost and simple alternative to the LIFT apparatus for measuring opposed flow flame spread. Ignition tests were conducted using the LIFT, RIFT and ISO 5657 ignitability apparatus and flame spread experiments were conducted in the LIFT and RIFT. Nine different types of timber based products were tested for ignition and flame spread, and Quintiere's flame spread model was applied to the results to obtain material properties, such as thermal inertia, flame spread parameter and the minimum heat flux required for flame spread. These materials included plywood, medium density fibreboard (MDF), hardboard, particle board flooring, Melamine (Melteca) covered MDF, New Zealand Rimu, and Beech and New Zealand grown Macrocarpa and Radiata (Monterey) Pine. Further limited tests were conducted on Melteca covered particle board, and a second brand of particle board. The materials in the RIFT were tried with and without preheating to equilibrium. In addition, a view factor for the RIFT was developed, based on earlier work for the cone calorimeter element. The view factor equation was experimentally tested against measured values, and the calculated value was consistently lower than the experimental values, with similar flux profile. The standard procedure is for the material to be preheated before ignition, so that the surface is at equilibrium. The spread of the flame front past points on the sample surface after ignition is recorded, and from the flame front velocity and the model by Quintiere, material specific properties can be derived. The lack of preheating was found to affect the final results, by reducing the flame spread velocity and increasing the scatter in the experimental results. The RIFT gives comparable results to the same materials tested in the LIFT and to the published literature. The results the flame spread parameter and the minimum flux for flame spread are usually higher for the RIFT against the same material in the LIFT. There proved to be an effective limit on suitable materials able to be successfully tested in the RIFT to those that have a minimum flux for flame spread of less than 7kW/m2, with this limitation is dictated by the flux profile along the sample, and the lower resolution dictated by the smaller size. It is approximately equivalent to a minimum ignition flux of 18kW/m2.

Current stoichiometric spark-ignited engine technologies require costly catalytic converters for reductions in tailpipe emissions. Load control is achieved by using a throttle, which is a leading contributor to reductions in efficiency. Spark-ignited lean burn natural gas engines have been proven to be more efficient and emit fewer pollutants than their stoichiometric counterparts. Load reduction in these engines can be achieved by regulating the air/fuel ratio of the intake charge thereby reducing the efficiency penalties inherent to throttling. Partially stratified charge (PSC) can provide further reductions in emissions and improvements in efficiency by extending the lean limit of operation. PSC is achieved by the ignition of a small quantity of natural gas in the vicinity of the spark plug. This creates an easily ignitable mixture at the spark plug electrodes, thereby providing a high energy ignition source for the ultra-lean bulk charge. Stratified charge engine operation using direct injection (DI) has been proposed as a method of bridging the throttleless load reduction gap between idle and ultra-lean conditions. A previous study was conducted to determine if PSC can provide a high-energy ignition source in a direct injected stratified charge engine. Difficulties with igniting the PSC injections in an air-only bulk charge were encountered. This study focuses on a fundamental Schlieren image-based analysis of PSC combustion. Natural gas was injected through a modified spark plug located in an optically accessible combustion bomb. The relationships between PSC injection timing, fuel supply pressure and spark timing were investigated. Spark timing is defined as the duration between commanded start of injection and the time of spark. As the fuel supply pressure was increased, the minimum spark timing that lead to successful combustion also increased. The largest spark timing window that led to successful combustion was determined to be 80 ms wide at an injection fuel supply pressure of 300 psi. The amount of unburned natural gas increased with increasing spark timing. A cold flow study of the PSC injection system was also conducted. The PSC injection solenoid was found to have a consistent average injection delay of 1.95 ms. The slope of the linear response region of observed injection duration to commanded injection duration was 8.4. Due to plenum effects, the average observed injection duration of the entire PSC system was an order of magnitude longer than the commanded injection duration and was found to vary significantly with fuel supply pressure.

Internal combustion engine emissions are currently a major source of air pollution. The harmful impact of engine emissions can be reduced when engines are fuelled by alternatives to petrol and diesel such as natural gas. The use of lean burn technology in spark-ignition engines has been dominant; however, the lean burn technique can not economically satisfy the increasingly restricted future emission standards particularly for NOx emissions. In this thesis, the use of the stoichiometric air-fuel mixture with exhaust gas recirculation (EGR) technique in a spark ignition natural gas engine is investigated. The aim of the research is to optimize the key engine operating conditions in order to obtain the lowest NO emissions accompanied with low fuel consumption and high power. This is achieved via both experimental and computer simulation research. / PhD Doctorate

The oxidation and ignition behaviour of the four major sulfide minerals present in the nickel concentrates smelted at the Kalgoorlie Nickel Smelter (KNS) has been established. These minerals are pyrite (FeS2), pyrrhotite (Fe1-nS, where n = 0 to 0.125), pentlandite ((FeNi)9S8) and violarite ( Ni2FeS4 ).The characteristic behaviour of these sulfides has been examined using Thermogravimetry-Differential Thermal Analysis (TG-DTA) under normal oxidation conditions ( l0ºC/min, air atmosphere). By increasing the heating rate to 40ºC/min and using an oxygen atmosphere, the tendency of the sulfides to ignite was established. Ignition was characterised by a highly exothermic reaction which occurred in association with a rapid mass loss over a short time span. Significant overheating of the samples beyond the temperature of the surroundings was observed. Pyrite, pyrrhotite and violarite all exhibited ignition behaviour while pentlandite did not.Using Isothermal Thermogravimetry (TG) the sulfides were subjected to shock heating conditions (heating rate = 3000-5000ºC/min, oxygen atmosphere) analogous to those which exist in an industrial flash smelter. The order of reactivity of the sulfides agreed with that observed during TG-DTA ignition trials. Even under these more intensely oxidising conditions pentlandite did not ignite. The effect of particle size on the ignition temperature was determined, larger particles igniting at a higher temperature. The magnitude of this effect varied according to the characteristics of the minerals.Products collected during Isothermal TG were examined by optical microscopy, Scanning Electron Microscopy (SEM) and Electron Probe Microanalysis (EPMA). Using these techniques it was possible to establish the morphology of the products and hence, to propose mechanisms for the reaction of the four sulfide minerals under ignition conditions.In order to ++ / simulate the thermal environment which exists in the KNS, a pilot scale model of the reaction shaft was used. Nickel sulfide concentrates of varying mineralogy and particle size distribution were smelted under various conditions. The effect of larger particle size and increasing oxygen partial pressure on the reactivity of these concentrates was established.The products were quenched at the base of the shaft and collected for examination by optical microscopy, SEM and EPMA. Products ranged from unreacted to completely oxidised particles. The morphology and composition of these species were identified. Approximately 30 particles in each of 26 samples were examined with a view to establishing the frequency of occurrence of the particular product types in concentrates of differing mineralogy and particle size. This allowed proposals to be made regarding the fate of the individual sulfide minerals during ignition in the pilot scale flash reactor.

Thesis (M.S.)--University of Nevada, Reno, 2006. / "August, 2006." Includes bibliographical references. Online version available on the World Wide Web.

Thesis (M.S.)--University of Missouri--Rolla, 1982. / Vita. The entire thesis text is included in file. Title from title screen of thesis/dissertation PDF file (viewed ) Includes bibliographical references (p. 57-58).