Hurricanes have been considered one of the most costly disasters in United State, which lead to both economic loss and human fatalities. Therefore, understanding the characteristics of those who evacuated and of those who did not evacuate have been principal focus of some previous researches related to hurricane evacuation behavior. This research presents two sets of decision-making models for analyzing hurricane evacuation behavior, using two statistical methods: standard logistic model and mixed logistic model.The receipt of evacuation order, elevation, expenditure, the presence of children and elderly people, ownership of a house, and receipt of hurricane warning are found to be extremely important in evacuation decision making. When the mixed logistic model is applied, the rate of concern about hurricane threat is assumed to be random according to normal distribution. Mixed logistic models which account for the heterogeneity of household responses are found to perform better than standard logistic model.

De nombreux mécanismes de sécurité ont été proposés pour les réseaux fixes et mobiles. Bien que ces mécanismes aient pu répondre à un ensemble d'exigences de sécurité, ils demeurent uniquement efficaces dans un contexte spécifique lié aux hypothèses et aux exigences restrictives qui ont été émises lors de la conception. Dans un premier temps, nous définissons une liste d'exigences en sécurité qui permet d'analyser les solutions de sécurité les plus déployées. Dans un second temps, nous proposons d'étendre le protocole SSL/TLS avec de nouveaux services. SSL/TLS est une solution de sécurité générique et transparente aux applications. Ainsi, il ne couvre pas les besoins spécifiques à certaines classes d'application telles que les applications de paiement sur Internet. Notre propositions d'intégrer le protocole d'échange des clés ISAKMP avec SSL/TLS permet de fournir, entre autres, la protection d'identité des utilisateurs et l'unification des associations de sécurité. Afin d'étendre l'utilisation de SSL/TLS vers les systèmes de paiement sur Internet, nous intégrons un module générique pour la génération d'une preuve de non répudiation dans le protocole SSL/TLS. Par ailleurs, toutes ces propositions restent, cernées par le problème d'interopérabilité avec les anciennes versions de chaque protocole. Ce qui rend la satisfaction de tous les besoins à travers un des protocoles existants irréalisables. Pour cela, nous proposons finalement de concevoir et de valider un nouveau protocole de sécurité qui intègre nativement l'évolution des protocoles de sécurité des échanges et des réseaux d'une manière performante. Nous avons appelé ce protocole SEP (Secure and Extensible Protocol)

Annually, tropical cyclones do tremendous damage and are agents of long-term coastal change. To test this idea of different tropical cyclones delivering consistent coastal change, a landform with such evolution is needed. One such landform is a spit. What contributions do tropical cyclones give toward the evolution of a spit, and do tropical cyclones give the same kinds of impacts? To determine if tropical cyclones have similar impacts, shoreline and volumetric change from four storms impacting Bolivar Peninsula are considered. Being a southwest-trended spit at a length of 33.5 kilometers, storm impacts are measured in the form of one dimensional shoreline and two dimensional volumetric change. These impacts are abstracted into shoreline change and volumetric change patterns. These patterns are identified and compared for differences between each storm and similarity among all storms. Results indicate that shoreline accretionary zones vary alongshore. Results from Hurricane Ike indicate an accretionary zone ten kilometers from the distal end. Shoreline change patterns for Hurricane Rita show an unstable accretionary zone at four kilometers from the distal end. Results for Tropical Storm Fay indicate an unstable accretionary zone that begins at the distal end and continues to the middle of the spit. In terms of similarity for shoreline change, all patterns from storms demonstrated erosion near Rollover Fish Pass. One dimensional volumetric change patterns were entirely erosive for Hurricanes Rita and Ike, and Tropical Storm Fay had by small zones of accretion near the distal portion of the spit. Tropical Storm Josephine demonstrated an accretion zone between the middle and distal portion of the spit. Results from two dimensional volumetric change patterns suggest a threshold for inland penetration. Tropical Storm Fay showed a ten to twenty meter wide pattern of erosion around five kilometers from the distal end and near the proximal end of the spit, and Hurricane Rita demonstrated a twenty meter wide pattern of erosion near the distal end. Hurricane Ike had erosive penetration of up to 200 meters around fifteen kilometers from the distal end. Results suggest that certain storms reinforce the standard spit growth model, and others work against it.

This ethnographic analysis of the social and physical effects of Hurricane Ike in Galveston, Texas and the consequent recovery that emerged afterward is based on 20 months of field research conducted immediately before and after the storm’s landfall. The introductory chapter locates the ethnographer just prior to the hurricane as he prepared for an unexpected evacuation. It then presents the conceptual framework for a multi-sited ethnography of “disaster culture” and introduces analytic keywords of “vulnerability,” “resilience,” “dreamworlds,” and “catastrophe.” It concludes by discussing a set of historical and contemporary socio-economic conditions in Galveston. This provides a frame of reference of both the social formations of storm experiences and the public recovery dynamics that attended with Ike’s aftermath that are discussed throughout the text. This is further supplemented with an explanation of Ike’s flooding and the geographic distribution of storm damage. Chapter two begins with an ethnographic vignette of the first townhall meeting held in Galveston after Ike. This introduces several recurrent topics of concern that were formative of disaster-culture dynamics. It then provides a literature review of the anthropology of disaster before segueing into a presentation of storm narratives. It ends with an analysis that further elaborates on the formative dynamics of Galvestonian disaster culture. Chapter three provides an analysis of the public deliberations that emerged over long-term redevelopment initiatives; particularly, the advocacy practices of a faith-based consortium; advocacy on behalf of restoring the University of Texas Medical Branch; the public Long Term Recovery Committee, and a FEMA buyout program that benefited higher income property owners on the western end of the island. The fourth chapter provides an extended case study concerning the rebuilding of 569 units of public housing that were subsequently destroyed after the hurricane. The rebuilding of public housing became the most vitriolic public issue during the course of fieldwork. The concluding chapter invokes the concepts of “dreamworlds” and “catastrophe” used by historian and philosopher Walter Benjamin to show the processual dynamics between the initial hopes for collectively strengthening Galveston through federally funded redevelopment and the increasingly negative assessments of the city’s long-term urban fortunes. / text

In September 2008 Hurricane Ike hit the Texas Gulf Coast with a force stronger than the category 2 storm at which it was rated. With a 3.8 m (12.5 ft) storm surge, the agricultural industry in the area was devastated. The goal of this research was to determine the length of time required to reduce the salt levels brought by the storm surge to near pre-hurricane levels. To do this, four sets of samples were taken across two years and analyzed for salinity using the saturated paste extract method. The initial salt levels in November 2008 had an electrical conductivity (ECe) of the inundated soils as high as 26.7 dS/m. Fifty-four percent of the soils sampled in the 0-15 cm horizons and 9% in the 15-30 cm horizons of the edge area had an ECe >= 4 dS/m. In the surge area 79% of the soils sampled in the 0-15 cm horizons and 30% in the 15-30 cm horizons had an ECe >= 4 dS/m. In April 2009, 38% of the soils sampled in the 0-15 cm horizons and 13% in the 15-30 cm horizons of the edge area had an ECe >= 4 dS/m. In the surge area 71% of the soils sampled in the 0-15 cm horizons and 39% in the 15-30 cm horizons had an ECe >= 4 dS/m. By December 2009, none of the soils sampled in the edge area had an ECe >= 4 dS/m. In the surge area 21% of the soils sampled in the 0-15 cm horizons and 33% in the 15-30 cm horizons had an ECe >= 4 dS/m. By October 2010, all soils sampled had leached sufficient salts to be classified as non-saline to very slightly saline soils. Utilizing the November 2008 data set, 28 random samples were selected for exchangeable Na percent (ESP) in order to develop the ESP-SAR (Na adsorption ratio) predictive equation, ESP= 1.19(SAR)^0.82. The SAR-ESP relationship is statistically significant (95% confidence level), with a correlation coefficient of 0.964 (df=26).

The present thesis entitled “Design, Synthesis and Characterization of Novel Nanomaterials” is divided into five chapters, staring with a general introduction. The remaining chapters focus on four different areas/projects that I have worked on. Chapter 1: Introduction to nanomaterials This chapter reviews the basic concepts of nanomaterials and their fabrication methods. Nanomaterials are defined as materials whose dimensions (at least one) are below 100 nm. One of the most exciting aspects of nanomaterials is that their properties may differ significantly from those of the corresponding bulk materials. Nanomaterials fabrication methods can be broadly classified according to whether the assembly follows either i) the bottom-up approach or ii) the top-down approach. These methods have been discussed with various examples including the self-assembly of proteins, peptides and small molecules. In the top-down approach synthetic procedures for Graphene Oxide and its application are discussed. All characterization techniques that are used for characterizing the nanomaterials are also described briefly. Chapter 2 Section A: Self-assembly of 1-Hydroxy benzotriazole (HOBT) in water The studies presented in Chapter 2 identifies HOBT as the smallest non-peptide building block that spontaneously self-assembles into hollow micro tubular structures upon evaporation of water. The tubes form under ambient conditions by rolling over of crystalline sheets of HOBT. The packing of HOBT in the tubes seem to be predominantly driven by intermolecular π-stacking interactions between the aromatic rings of HOBT. These structural and packing patterns are similar to those found in nanotubes formed by the self-assembly of peptides and other larger molecules. The cavities of these thermolabile microtubes act as molds for casting gold nanoparticles for the synthesis of gold microrods with monodisperse dimensions. The non-reacting inner surfaces of the cavities have been used to uniquely synthesize R6G-functionalized gold microrods. With these features, HOBT is an important novel non-peptide building block for accessing micro and nanometric materials for their applications in medicine, biology and molecular biotechnology. Section B: Controlling the orientation of self-assembly of HOBT microtubes The studies presented in this chapter address the self-assembly of HOBT into microtubular structures in different solvents of varying polarities (H2O and DCM:MeOH) to understand the role of solvent volatility and its direction on the orientation of the HOBT microtubes. HOBT self-assembles from DCM:MeOH mixtures in its bipolar canonical form and is coordinated with its water of hydration, similar to its crystals obtained from water. FTIR and TGA data shows that MeOH is also integrated with the microtubes. We observe for the first time that the orientation of microtubular self-assembly is controlled in the direction of evaporation of the solvent. We demonstrate further this feature by controlling the orientation of HOBT self-assembly in exclusively vertical direction through controlled vertical evaporation of the solvent mixture DCM:MeOH (9:1). Additionally, the unique transition between vertical and horizontal orientations for self-assembled HOBT microtubes is achieved by simple change of solvation between aqueous and organic solvents. These results reveal a dynamic relationship between the rate of evaporation of solvent and the rates of formation of different self-assembled morphologies. The rate of evaporation of the solvent primarily governs the rate of formation of the tubes, rather than their orientations in three dimensions. Chapter 3: Chemical origins of debris in Graphene Oxide (GO) This chapter is focused on the investigation of the carbonyl rich fragments arising from GO and provides an understanding of its formation. The fragments are expelled from GO due to an uncontrolled nucleophile driven reaction in aqueous medium leaving the holes on the sheet. These fragments are carbonyl rich small (5 ± 2 nm) nonaromatic molecules that form as by-products of oxidative chemical reactions that occur at the sp3 clusters on the basal surface of GO sheets when they are treated with nucleophilic bases under aqueous conditions. The structure and size of the debris, and hence that of the hole, depend on the size of the sp3 cluster on the sheet. These debris fall out of the GO sheet surface, leading to formation of nanometer sized holes. Formation of debris and hence the holes can be avoided by using anhydrous polar solvents. This work sheds new light on the fundamental structure of GO and the prevention of debris from it during redox reactions enabling better control over functionalization of the GO surface. Chapter 4: Measurement of mechanical properties of polypeptide fragment from Insulin like growth factor binding protein nanotubes by the Peak Force QNM method This chapter describes the discovery of Polypeptide fragment from an IGFBP-2. This fragment self-assembles spontaneously and reversibly into nanotubular structures under oxidizing conditions. These nanotubes were characterized by using Transmission electron microscopy. Notably as compared to the monomer, an increase in intrinsic fluorescence upon self-assembly. The thermal stability of these nanotubes is realized form the fluorescence studies. Peak Force Quantitative Nanomechanical Mapping method of AFM was used to measure the Young’s modulus of the nanotubes. These nanotubes were found to have Young’s modulus value of ~10 Gpa, which is comparable to those of bones presumably due to intermolecular disulphide bonds. These nanotubes will have potential applications in tissue engineering. Chapter 5: Probing the pathways of n→π* interaction in peptides This chapter deals with the theoretical study of n→π* interaction in designed peptidomimetics. The n→π* interaction involves the delocalization of the lone pair of the donor group into the antibonding orbital (π*) of a carbonyl group. However despite beeing extensively studied there exists a debate over the validation of these n→π* interaction which is reminiscent to Bürgi and Dunitz trajectory. This chapter present our findings that peptidomimetics containing the 5,6-dihydro-4H-1,3-oxazine (Oxa) and 5,6-dihydro-4H-1,3-thiazine (Thi) functional groups at the C-terminus of Pro selectively stabilizes the cis conformer by reverse n→πi-1* interaction. These systems have been used to study the n→πi1* interaction using Natural Bond Orbital (NBO) method. Our study reveals that the energetically most favorable trajectory of a nucleophile for a favorable n→π* interaction presumably to facilitate the overlap between the lonepair of the nucleophile and the antibonding orbital of the carbonyl group. The geometrical requirements for the optimum n→π* interaction depends on the relative orientations of the orbitals that are involved. This study has implications for more accurately identifying long distant n→π* interaction.

This study uses the storm surge sediment beds deposited by Hurricanes Audrey (1957), Carla (1961), Rita (2005) and Ike (2008) to investigate spatial and temporal changes in sedimentation rates on the McFaddin National Wildlife Refuge in Southeast Texas. Fourteen sediment cores were collected along a transect extending from 90 to 1230 meters inland from the Gulf Coast. Storm-surge-deposited sediment beds were identified by texture, organic content, carbonate content, the presence of marine microfossils, and Cesium-137 dating. The hurricane-derived sediment beds are marker horizons that facilitate assessment of marsh sedimentation rates from nearshore to inland locations as well as over decadal to annual timescales. Near the shore, on a Hurricane Ike washover fan, where hurricane-derived sedimentation has increased elevation by up to 0.68 m since 2005, there was no measurable marsh sedimentation in the period 2008-2014. Farther inland, at lower elevations, sedimentation for the period 2008-2014 averaged 0.36 cm per year. The reduction in sedimentation in the period 2008-2014 on the nearshore part of the marsh is likely due to reduced flooding in response to increased elevation from hurricane storm surge sediment deposition. These results provide valuable knowledge about the sedimentary response of coastal marshes subject to storm surge deposition and useful guidance to public policy aimed at combating the effects of sea level rise on coastal marshes along the Gulf of Mexico.