Student Number : 0009815Y - PhD thesis - School of Physics - Faculty of Science / Determining the properties of composites and how these relate to those of the components and the microstructure is extremely useful as it enables the understanding of existing materials and the design of new materials with a variety of applications. However, the link between the ac conductivity data and the microstructure and composition of the composite is not a simple one. Simulations of binary composites are presented which show that from relatively simple component properties arise complex composite properties. Accurate identi¯cation of the components of composites, using characteristic frequencies, is demonstrated for simulated and actual experimental data. The Maxwell-Wagner and Brick Layer Models, which are often applied beyond the range of their original derivation, are found to consistently ¯t the data of yttria-stabilized zirconia ceramics measured at various tempera- tures. The results from ¯tting single crystal and polycrystalline sample data indicate that accurate modeling of the properties of the polycrystalline sam- ples requires more theoretical work on the conduction mechanisms in single crystals and the grains of the ceramics. Data from a polyester-resin/silicon system is found to be best ¯tted us- ing the Single Exponent Phenomenological Percolation Equation (SEPPE) with experimentally measured component properties as input. The percola- tion threshold obtained suggests a system where the insulator tends coat the conductor. The results show that, with the actual component properties as input, the SEPPE can be used to qualitatively and semi-quantitatively model and ¯t composite ac conductivity data. Analysis of the ac conductivity of liquid-phase-sintered silicon carbide ce- ramics showed that for this system, the features often observed in the imped- ance spectra are all due to a multi-component grain bondary/binder phase and not the SiC grains. This multi-component grain boundary phase can be ¯tted accurately to the Brick Layer Model, indicating a microstructure where an insulating component coats a more conducting component.

Energy quantities, which are calculated from pressure and particle velocity, yield a great deal of information about acoustic fields. Errors in pressure or particle velocity estimation lead to bias errors the estimation of energy quantities. The bias errors arise from different probe configurations and processing methods. Two processing methods are examined: the traditional method and the recently developed Phase and Amplitude Gradient Estimation (PAGE) method. These two methods are compared to investigate how each estimates pressure and particle velocity and the subsequent bias errors in a plane wave, standing wave, and spherical spreading wave field. Analytical expressions are derived for the energy quantity estimation using ideal one-dimensional probes. A simulation of the field from a baffled circular piston and measurements using ideal two-dimensional probes is computed. Compared to the traditional method, the PAGE method significantly extends the range of frequencies for which the results are accurate. It is found that a probe with a center microphone significantly reduces the estimation error and extends the usable range of frequencies. The PAGE method with unwrapping, perfectly matches the analytical results for plane waves, while the traditional method is only good at wavelengths that are large compared to the probe size. Furthermore, the PAGE method has a constant bias error in spherical wave fields due to the 1/r decrease in pressure. The traditional method has a frequency dependent bias error that is much worse at higher frequencies. Lastly, the PAGE method has the same or worse error for the standing wave. As an application of energy quantities, acoustic intensity is used to develop an equivalent source model for jet noise from an F-22 at military and afterburner engine conditions. An optimization is used to find the best-matching wavepacket model for measured intensity vectors. The results are compared to another intensity method of estimating the source region and source directivity, and the two methods have good agreement.

The middle ear system is a vital component in the propagation mechanism of otoacoustic emissions. As such, investigation of the effect of variation in middle ear impedance on the measurement of emissions is warranted. Distortion product otoacoustic emissions (DPOAEs) have gained recognition as a means of gaining frequency specific information on auditory function. As the effects of changes in middle ear impedance will vary as a function of frequency, a clear definition of the relationship between middle ear impedance and DPOAE amplitude across the frequency spectrum is needed. Twenty adults (ages 20-37) with normal hearing and normal middle ear function were selected as subjects. Commercially available equipment (Virtual 330) was used to measure the DPOAEs on all subjects. The unit was modified to change canal pressure by coupling the probe to the pressure pump of a clinical acoustic immittance system. One ear from each subject was randomly selected for measurement and each subject was tested under five pressure conditions: +200, O, -200, -300, -400 daPa. The mean frequency of the fl/f2 tone pairs swept from 500 to 8000 Hz. Results indicate that changes in ear canal pressure can effect the amplitude of DPOAEs. Alteration of ear canal pressure resulted in decreased emission amplitude. This effect was found to differ as a function of eliciting frequency with the greatest reduction in amplitude with the mean of the primaries at 500 Hz. Less variation was noted across the ear canal pressures with the higher frequency stimuli. These results are consistent with previous findings reported regarding the effects of impedance changes on spontaneous and transiently evoked otoacoustic emissions.

Philosophiae Doctor - PhD / Investigation of the acoustic impedance variations in the upper shallow marine sandstone reservoirs was extensively studied from 10 selected wells, namely: F-O1, F-O2, E-M4, E-CN1, E-G1, E-W1, F-A10, F-A11, F-A13, and F-L1 in the Bredasdorp Basin, offshore, South Africa. The studied wells were selected randomly across the upper shallow marine interval with the purpose of conducting a regional study to assess the variations in the acoustic impedance across the reservoirs using wireline log and core data. The datasets used in this study were geophysical wireline logs, conventional core analysis, geological well completion reports, core plugs, and core samples. The physical rock properties such as lithology, fluid type, and hydrocarbon bearing zone were identified while different parameters like the volume of clay, porosity, and water saturation were quantitatively estimated. The reservoirs were penetrated at a different depth ranging from a shallow depth of 2442m at well F-L1 to a deeper depth of 4256.7m at well E-CN1. The average volume of clay, average effective porosity from wireline log, and average water saturation ranged from 8.6%- 43%, 9%- 16% and 12%- 68%, respectively. Porosity distribution was fairly equal across the field from east to west except in well F-A10, F-A13, and F-A11 where a much higher porosity was shown with F-A13 showing the highest average value of 16%. Wells E-CN1, E-W1, F-O1, F-L1 and E-G1 had lower porosity with E-CN1 showing the lowest average value of 9%. The acoustic properties of the reservoirs were determined from geophysical wireline logs in order to calculate acoustic impedance and also investigate factors controlling density and acoustic velocities of these sediments. The acoustic impedance proved to be highest on the central to the western side of the field at E-CN1 with an average value of 11832 g/cm3s whereas, well F-A13 reservoir in the eastern side of the field proved to have the lowest average acoustic impedance of 9821 g/cm3s. There was a good linear negative relationship between acoustic impedance and porosity, compressional velocity vs porosity and porosity vs bulk density. A good linear negative relationship between acoustic impedance and porosity was obtained where the reservoir was homogenous, thick sandstone. However, interbedded shale units within the reservoir appeared to hinder a reliable correlation between acoustic impedance and porosity. The cross-plots results showed that porosity was one of the major factors controlling bulk density, compressional velocity (Vp) and acoustic impedance. The Gassmann equation was used for the determination of the effects of fluid substitution on acoustic properties using rock frame properties. Three fluid substitution models (brine, oil, and gas) were determined for pure sandstones and were used to measure the behaviour of the different sandstone saturations. A significant decrease was observed in Vp when the initial water saturation was substituted with a hydrocarbon (oil or gas) in all the wells. The value of density decreased quite visibly in all the wells when the brine (100% water saturation) was substituted with gas or oil. The fluid substitution affected the rock property significantly. The Vp slightly decreases when brine was substituted with water in wells F-A13, F-A10, F-O2, F-O1 F-A11, F-L1, and E-CN1. Wells E-G1, E-W1, and E-M4 contain oil and gas and therefore showed a notable decrease from brine to oil and from oil to gas respectively. Shear velocity (Vs) remained unaffected in all the wells. The acoustic impedance logs showed a decrease when 100% water saturation was replaced with a hydrocarbon (oil or gas) in all the wells. Clay presence significantly affects the behaviour of the acoustic properties of the reservoir rocks as a function of mineral type, volume, and distribution. The presence of glauconite mineral was observed in all the wells. Thirty-two thin sections, XRD and SEM/EDS from eight out of ten wells were studied to investigate lithology, diagenesis and the effect of mineralogy on porosity and acoustic properties (Compressional velocity and bulk density) within the studied reservoir units. Cementation (calcite and quartz), dissolution, compaction, clay mineral authigenesis, and stylolitization were the most significant diagenetic processes affecting porosity, velocity, and density.Well E-CN1 reservoir quality was very poor due to the destruction of intergranular porosity by extensive quartz and illite cementation, and compaction whereas well F-A13 show a highly porous sandstone reservoir with rounded monocrystalline quartz grain and only clusters of elongate to disc-like, authigenic chlorite crystals partly filling a depression within altered detrital grains. Overall, the results show that the porosity, lithology mineralogy, compaction and pore fluid were the major factors causing the acoustic impedance variations in the upper shallow marine sandstone reservoirs. / 2021-09-01

Electrochemical noise refers to the spontaneous fluctuations in potential and current that can be observed on a corroding metal. The use of electrochemical noise for obtaining information on the corrosion process generates much interest in research fields. One important application is the measurement of corrosion rate. This can be achieved using the electrochemical noise of a pair of electrically coupled corroding metals to obtain an estimate of electrochemical impedance - an abstract quantity that reflects various aspects of the corrosion process.There are a number of problems associated with estimation of impedance information from the electrochemical noise data, particularly regarding data pre-treatment, accuracy and precision. In addition, the present methods are incomplete: current literature does not offer information regarding the phase of the impedance; and assumptions regarding symmetry of an electrode pair cannot be tested without additional measurements.The thesis addresses the above mentioned problems. Specifically,analysis of the impedance estimation process is given to determine how precision can be affected by various factors;a novel signal processing technique is described that is shown to yield a local optimum precision;the application of the proposed signal processing to time varying systems is demonstrated by use of a time varying, frequency dependent impedance estimate;a technique for recovering phase information, given certain conditions, is suggested so that Nyquist impedance diagrams can be constructed; anda technique for testing the symmetry of a coupled pair of corroding metals is described.An integral part of electrochemical noise analysis is the software used for numerical computation. The Matlab package from MathWorks inc. provides an extensible platform for electrochemical noise analysis. Matlab code is provided in Appendix A to implement ++ / much of the theory discussed in the thesis.Impedance analysis and many other electrochemical corrosion monitoring techniques are primarily used for uniform corrosion, where the corrosion patterns occur uniformly over the exposed surface. In order to map localised corrosion, where the corrosion is typically concentrated within a small area, a wire beam electrode can be used. A wire beam electrode is a surface that is divided into a matrix of mini-electrodes so that the corrosion rate at different points can be monitored. However, manual connection of each mini-electrode to the measurement device can prove cumbersome. The final chapter of this thesis describes the design and testing of specialised multiplexing hardware to automate the process.In general, the thesis shows that by careful conditioning of the electrochemical noise prior to analysis, many of the problems with the technique of impedance estimation from the electrochemical noise data can be overcome. It is shown that the electrochemical noise impedance estimation can be extended to encompass a time varying, frequency dependent quantity for studying dynamic systems; that phase information can be recovered from electrochemical noise for the purpose of constructing Nyquist impedance diagrams; and that asymmetric electrodes can be detected without requiring additional measurements.

Boundary value problems required for modelling plane wave propagation in electrically anisotropic and inhomogeneous media relevant to the surface impedance methods in electromagnetic geophysics are formally posed and treated. For a homogeneous TM-type wave propagating in a half space with both vertical and horizontal inhomogeneities where the TM-type wave is aligned with one of the elements of the conductivity tensor, it is shown using exact solutions that the shearing term in the homogeneous Helmholtz equation for inclined anisotropic media: [Equation 1], unequivocally vanishes and solutions need only be sought to the homogeneous Helmholtz equation for biaxial media: [Equation 2]. This implies that those problems posed with an inclined uniaxial conductivity tensor can be identically stated with a fundamental biaxial conductivity tensor, provided that the conductivity values are the reciprocal of the diagonal terms from the Euler rotated resistivity tensor: [Equation 3], [Equation 4], [Equation 5]. The applications of this consequence for numerical methods of solving arbitrary two-dimensional problems for a homogeneous TM-type wave is that they need only to approximate the homogeneous Helmholtz equation and neglect the corresponding shearing term. The self-consistent impedance method, a two-dimensional finite-difference approximation based on a network analogy, is demonstrated to accurately solve for problems with inclined uniaxial anisotropy using the fundamental biaxial anisotropy equivalence. The problem of a homogeneous plane wave at skew incidence upon an inclined anisotropic half space is then formally treated. In the half space, both TM- and TE-type waves are coupled and the linearly polarised incident TM- and TE-type waves reflect TE- and TM-type components. Equations for all elements of the impedance tensor are derived for both TM- and TE-type incidence. This offers potential as a method of predicting the direction of anisotropic strike from tensor impedance measurements in sedimentary environments.

<p>Industrial robots have been used for a long time in the industry. Despite this thedevelopment of advanced force control system using industrial robots is relativelylimited. Using force controlled robot systems expands the possibility of what canbe done with industrial robots.Previously a force feedback system for a standard industrial robot from ABBhas been developed. The system is developed towards the aircraft industry, where amounted drill machine on the robot has to fulfill the requirements in robot drillingin aircraft structures. This thesis presents experimental results and improvementsof this industrial robot system. Mechanical modifications and tests of a new endeffector are analyzed.</p>

E. Maxwell, P.M. Marcus, J.C. Slater. / "This paper is based on a thesis submitted in partial fulfillment of the Degree of Doctor of Philosophy at M.I.T." "May 2, 1949." / Bibliography: p. 55. / Army Signal Corps Contract No. W36-039-sc-32037 Project No. 102B Dept. of the Army Project No. 3-99-10-022

[by] W.B. Nowak. / "May 27, 1949." / Bibliography: p. [146]. / Army Signal Corps Contract No. W-36-039 sc-32037, Project no. 102B. Dept. of the Army Project No. 3-99-10-022.

R.M. Fano. / "January 2, 1948." / Bibliography: p. 34. / Army Signal Corps Contract W-36-039 sc-32037.