Since the beginning of the 20th century indoor air has produced distinctive pollution problems. The most critical pollutants in relation to indoor air quality (IAQ) are chemical contaminants which, in the form of volatile organic compounds (VOCs), have been identified as arising mainly from building materials. Conventional solutions such as ventilation systems and bake-out processes have been developed, but the IAQ problem, often reported as sick building syndrome (SBS), still persists. This study set out to establish to what extent VOCs may affect the health of occupants in a particular built environment, and how much architectural design factors, the use of particular building materials, and human activities may contribute to the problem of SBS. A further question was to establish to what extent current attempted solutions to IAQ problems, namely ventilation and bake-out, were in practice effective in a specific built environment. While previous research and attempted solutions have focused on work places as areas of concern for SBS, the problem is especially significant in residential housing and is particularly concentrated in post-disaster public housing (PDPH). For this reason the research was based on the case of a PDPH project in Abuta, Japan. To analyse the separate components of the problem, several distinct studies were undertaken. The level of pollutants in the air was analysed by means of chemical sampling of VOCs in two units of the PDPH, while the a SBS survey and assessment of the residents of the entire project, as well as interviews with the building professionals involved was designed to identify the human causes and effects of the situation. The effectiveness of the attempted solutions to the problem were considered by means of a study of the bake-out procedure, and finally an airflow simulation by computational fluid dynamics (CFD) was conducted to consider the design and ventilation features of the units in relation to IAQ. The study results have indicated that IAQ problems existed after the completion of construction. It was found that certain VOC levels were far above the guidelines, and the health hazard symptoms known for these VOCs matched the SBS symptoms found in participants??? health complaints. Interviews with building professionals involved in the project revealed that the lifestyles of the occupants were not seriously considered in the project design. The results of the airflow simulation also revealed problematic aspects of the planning design, exacerbating rather than limiting the pollution problem as intended. The study concludes with a number of recommendations for taking these inter-related aspects of the problem into consideration in future, so that the health of residents is not adversely affected.

Graduation date: 1998

The issue of odour, greenhouse gas emissions and indoor air quality in swine buildings have become a great concern for the neighbouring communities as well as governments. Air dispersion models have been adopted widely as an approach to address these problems which determine science-based distance between livestock production site and neighbours. However, no existing model considers the diurnal and seasonal variations of odour, gas (ammonia, hydrogen sulphide, greenhouse gas), and dust concentrations and emissions, which may cause great uncertainty. The primary objective of this project is to monitor and model the diurnal and seasonal variations of odour, gases, and dust concentrations and emissions from nursery, farrowing, and gestation rooms. Additionally, this study tried to quantify the greenhouse gas contribution from swine buildings and evaluate the indoor air quality of swine barns. <p>Strip-block experimental design was used to measure the diurnal variation of odour and gas concentrations and emissions in PSC Elstow Research Farm. It was found that: 1) odour and gas concentrations in winter were significantly higher than those in mild and warm weather conditions for all three rooms (P<0.05); 2) the nursery room had higher level of odour and gas concentration and emission than the other two types of rooms, no significant difference existed between the farrowing and gestation rooms (P>0.05); 3) significant diurnal variations occurred in August and April (P<0.05) for odour and some gas concentrations and emissions, while no significant diurnally variations were found in February (P>0.05); 4) apparent diurnal variation patterns were observed in August and April for NH3, H2S and CO2 concentrations, being high in the early morning and low in the late afternoon; 5) positive correlation was found between odour concentrations and NH3, H2S, and CO2 concentrations, respectively. <p>A whole year ( August 2006 to July 2007) monitoring of odour, gas and dust concentrations and emissions revealed that: 1) significant seasonal effect on odour and gas concentrations and emissions, total dust concentrations and dust depositions were observed (P<0.05), but no specific variation pattern was discovered for odour and gas emissions; 2) the total greenhouse gas emission from all the rooms in the gestation, nursery and farrowing area was 2956 CO2 equivalent tons per year, where gestation area, nursery area, and farrowing area accounted for 39.3 %, 37.2% and 23.5%, respectively; the CO2 emission contributed 53.4% to the total greenhouse emission, and CH4 contributed to 43.9%, 2.7% for N2O; N2O could be considered negligible; 3) indoor air quality of the swine barn met the requirements set by the Occupational Health and Safety Regulations (1996) of Saskatchewan for NH3, H2S, and CO2. <p>Statistical models were developed for each type of room to predict the odour and gas concentrations and emissions based on four variables: ventilation rate, room temperature, ambient temperature, and animal unit. The predicted results showed agreeable with measured values for most models (R2 = 0.56-0.96). Generally, gas prediction models performed better (R2=0.61-0.96) than odour prediction models (R2=0.56-0.85).<p>This study was conducted in the province of Saskatchewan throughout one year and the results could be used as representative data for Canada Prairies. Due to the large diurnal and seasonal variabilities of odour emissions, it was recommended to take multiple measurements of odour emission rate under different weather conditions in order to improve the accuracy of air dispersion modeling.

The issue of odour, greenhouse gas emissions and indoor air quality in swine buildings have become a great concern for the neighbouring communities as well as governments. Air dispersion models have been adopted widely as an approach to address these problems which determine science-based distance between livestock production site and neighbours. However, no existing model considers the diurnal and seasonal variations of odour, gas (ammonia, hydrogen sulphide, greenhouse gas), and dust concentrations and emissions, which may cause great uncertainty. The primary objective of this project is to monitor and model the diurnal and seasonal variations of odour, gases, and dust concentrations and emissions from nursery, farrowing, and gestation rooms. Additionally, this study tried to quantify the greenhouse gas contribution from swine buildings and evaluate the indoor air quality of swine barns. <p>Strip-block experimental design was used to measure the diurnal variation of odour and gas concentrations and emissions in PSC Elstow Research Farm. It was found that: 1) odour and gas concentrations in winter were significantly higher than those in mild and warm weather conditions for all three rooms (P<0.05); 2) the nursery room had higher level of odour and gas concentration and emission than the other two types of rooms, no significant difference existed between the farrowing and gestation rooms (P>0.05); 3) significant diurnal variations occurred in August and April (P<0.05) for odour and some gas concentrations and emissions, while no significant diurnally variations were found in February (P>0.05); 4) apparent diurnal variation patterns were observed in August and April for NH3, H2S and CO2 concentrations, being high in the early morning and low in the late afternoon; 5) positive correlation was found between odour concentrations and NH3, H2S, and CO2 concentrations, respectively. <p>A whole year ( August 2006 to July 2007) monitoring of odour, gas and dust concentrations and emissions revealed that: 1) significant seasonal effect on odour and gas concentrations and emissions, total dust concentrations and dust depositions were observed (P<0.05), but no specific variation pattern was discovered for odour and gas emissions; 2) the total greenhouse gas emission from all the rooms in the gestation, nursery and farrowing area was 2956 CO2 equivalent tons per year, where gestation area, nursery area, and farrowing area accounted for 39.3 %, 37.2% and 23.5%, respectively; the CO2 emission contributed 53.4% to the total greenhouse emission, and CH4 contributed to 43.9%, 2.7% for N2O; N2O could be considered negligible; 3) indoor air quality of the swine barn met the requirements set by the Occupational Health and Safety Regulations (1996) of Saskatchewan for NH3, H2S, and CO2. <p>Statistical models were developed for each type of room to predict the odour and gas concentrations and emissions based on four variables: ventilation rate, room temperature, ambient temperature, and animal unit. The predicted results showed agreeable with measured values for most models (R2 = 0.56-0.96). Generally, gas prediction models performed better (R2=0.61-0.96) than odour prediction models (R2=0.56-0.85).<p>This study was conducted in the province of Saskatchewan throughout one year and the results could be used as representative data for Canada Prairies. Due to the large diurnal and seasonal variabilities of odour emissions, it was recommended to take multiple measurements of odour emission rate under different weather conditions in order to improve the accuracy of air dispersion modeling.

Retail stores are an environment with a rich diversity of toxic chemicals typically found in consumer products. Among these chemicals, semi-volatile organic compounds (SVOCs) are an important class with great health concerns. Phthalates and polybrominated diphenyl ethers (PBDEs) are high production volume SVOC chemicals pervasively used in plastics and other consumer products. Exposure to them may cause serious adverse health effects, including endocrine disruption. They, however, have not been widely studied in retail environments. In this study, indoor air samples were collected from 15 retail stores in Austin, TX and University Park, PA. Some of these stores were revisited on different temperate seasons to account for weather variability. Indoor concentrations of the most ubiquitous pollutants were correlated with several building characteristics, including retailer type, temperature, and building use characteristics. Collected data shows a wider variety of phthalates and PBDEs, as well as higher indoor airborne concentrations for large department stores as compared to grocery stores, which typically have fewer sources in comparison. / text

Calcined clay and fly ash supplementary cementitious materials (SCMs) used in cement based materials were examined for their chemical and mechanical performance, as well as their pollutant interaction. This dissertation addresses three primary research questions, namely: (i) can zincite additions facilitate the use of calcined clay as SCMs by compensating for reductions in early-age mechanical performance or by compensating for their reduced pozzolanic reactivity, (ii) can cement renders, containing metakaolin calcined clays, be engineered for passive carbon dioxide and ozone removal, and (iii) how do the specific activity and emanation fractions of concrete constituents, including fly ash and metakaolin, as well as assembled concretes impact concrete radon emanation and indoor radon concentrations? The first question relates directly to the development of new, sustainable material options, which can replace a portion of cement in a concrete mixture. Results from the experiments with zincite showed that the treatment method removed the dilution effect that occurs when using less reactive materials to substitute a portion of portland cement, but did not considerably influence mechanical properties. Therefore, zincite additions are not a good means of enhancing the utilization of non-kaolinite clays in concrete. As an integrated system, the latter two questions of this dissertation investigate the interaction between airborne pollutants and the cement based materials containing SCMs. The use of SCMs in render and concrete systems resulted in different pollutant uptake and exhalation behavior, relative to non-SCM control systems. For pollutant uptake, render systems containing metakaolin increased the carbon dioxide ingress while decreasing the ozone uptake. For radon exhalation rates, modeling results demonstrated that concretes without fly ash have a higher probability of containing less total radium and lower radon exhalation rates, when compared to samples with fly ash, assuming an emanation fraction of 5%, as suggested in the literature. Experimental results demonstrated that metakaolin, fly ash and control concretes had emanation fractions of 7%, 9% and 13%, respectively, confirming that (i) an assumed fraction of 5% would underpredict indoor radon concentrations and potential health consequences, and (ii) SCMs can reduce the total concrete emanation fraction. This dissertation demonstrates how the use of sustainable material selections, such as calcined clays and fly ashes, not only influences the microstructure and mechanical performance of the cement based materials, but also alters the interaction of the material with its surrounding environment. / text

Studies show that the use of cleaning products is related to adverse respiratory health effects ranging from irritation to asthma. Yet exposure to these chemicals is poorly understood. This dissertation summarizes the current state of knowledge of inhalation exposure to toxic chemicals in consumer cleaning products. An improved two-zone model that treats personal air space as distinct from bulk room air is presented. The model accounts for air exchange between the two zones, dynamic source characteristics (i.e., the time-varying liquid concentrations and emission rates of pollutants within a mixture), and the characteristics of chemical use (e.g., how frequently a cleaning chemical is applied to a new area). To assess exposure to cleaning products and validate the improved two-zone model twenty-three experiments, encompassing six cleaning scenarios, were completed in an environmentally-controlled chamber with a thermal mannequin. Then, the model was used to predict exposure for four hypothetical cleaning scenarios and compared against other models. The model's applicability is restricted by limited data available for parameterization. At low air exchange rates gas-phase experimental results show concentrations in the breathing-zone of the mannequin exceeded concentrations predicted by the well-mixed model by factors up to 2.1. Breathing-zone concentrations also exceed those measured at centralized room monitors by factors up to 6.1. Thus, studies that use the centralized room monitors or the well-mixed model as a surrogate for breathing-zone concentrations could potentially underpredict exposure at low air exchange rates. The two-zone model provides the best prediction of exposure to cleaning tasks, at low air exchange rates. The next best model is the well-mixed model with an exponentially decreasing emission rate, followed by the well-mixed model with a constant emission rate. At high air exchange rates the well-mixed assumption appears to be valid. The inner-zonal volume and inter-zonal air exchange were independent of fresh air ventilation rate. But both were dependant on the mannequin's body position, with standing having the highest inner-zonal volume and lowest intra-zonal air exchange rate of the three body positions investigates (standing, bent over 45°, and hands and knees). / text

Indoor air is associated with substantial health risks and is estimated to be responsible for the loss of over 4.7 million healthy life years (years lost due to morbidity and mortality) annually in the U.S. The highest indoor air-related health benefits can be expected from policies and strategies that efficiently target pollutants having the greatest contribution to the burden of disease. This burden is caused by indoor sources as well as by outdoor pollutants transported to the indoors. The diversity of pollutants, pollutant sources, and the resulting health effects challenge the comparison of the impacts of different control strategies on energy consumption and indoor air quality. To address this challenge, this work presents a quantitative framework for reaching the optimal energy cost for the maximum achieved exposure benefits, specifically for retail buildings and their understudied energy, economic, and health risk influence. The main objectives of this dissertation are to 1) determine pollutants of concern in retail buildings that contribute the greatest to the burden of disease, and 2) determine energy-efficient, exposure-based control strategies for different retail types and locations. The research in this dissertation is divided into four specific aims that fulfill these two objectives. The first specific aim (Specific aim 1.a) addresses Objective 1 by applying available disease impact models on pollutant concentrations taken from 15 literature studies (150 stores, a total of 34 pollutants). Of those pollutants, there was little data reported on particulate matter (PM) concentrations and none on emission rates for PM, limiting our understanding of exposure to this pollutant. The second specific aim (Specific aim 1.b) also addresses Objective 1 by characterizing particulate matter (PM) concentrations, emission rates, and fate of ambient and indoor-generated particles in retail buildings. The tasks of this specific aim consisted of particulate matter and ventilation measurements in 14 retail buildings. Among the findings of Objective 1, PM2.5 and acrolein are the main contaminants of concern for which control methods should be prioritized, contributing to 160 disability-adjusted life years (DALYs; years lost due to premature mortality and disability) per 100,000 persons annually. Employees in grocery stores mainly drove this burden. An efficient indoor exposure reduction strategy should take into account all mechanisms that influence pollutant concentrations: indoor and outdoor sources (highlighting the importance of retail type and location), infiltration, ventilation, and filtration. The remaining specific aims address Objective 2 by investigating the energy and air quality impact of two commonly used exposure control scenarios, ventilation (Specific aim 2.a) and filtration (Specific aim 2.b). The tasks of Specific aim 2.a consisted of modeling the impact of multiple ventilation strategies on contaminants of concern for six major U.S. cities and two retail types. The tasks for Specific aim 2.b consisted of conducting field measurements on 15 rooftop units to determine the fan energy impacts of filter pressure drop. These results are used in combination with a large dataset of 75 filters commonly installed in commercial buildings to estimate the energy consequences of filtration. Results for Objective 2 are presented from the quantitative comparison of the impact on energy usage and DALYs lost of three main approaches: (1) adjusting ventilation only; (2) adjusting filtration only; and (3) adjusting ventilation and filtration together. All approaches were able to provide substantial reductions in the health risks (19-26% decrease in DALYs lost); the magnitude of the reductions depended on the ventilation/filtration scenario, the retail type, and the city. The magnitude of energy cost to achieve the maximum health benefits depended on the city and the retail type (for example for a 10,000 m2 grocery store, the energy cost ranged from $1,100 for the annual cost of filtration energy in Los Angeles to $24,000 for the annual cost of ventilation in Austin). The uncertainties of the estimates driving these findings are discussed throughout the results section. The finding that emerges from this analysis is the pollutant exposure control ventilation (PECV) strategy. This strategy is superior to the ventilation rate procedure (VRP; ASHRAE Standard 62.1-2010) and the indoor air quality procedure (IAQP; ASHRAE Standard 62.1-2010) as it decides on a range of ventilation rates by weighing the exposures of contaminants of concern found in retail buildings. Then, among the range of ventilation rates identified, the PECV recommends the optimal ventilation rate that leads to energy usage savings in the climate considered. Overall, the work presented here prioritizes specific contaminants of concern in retail buildings and proposes an exposure-based, energy-efficient control strategy for different retail types and locations. Policy makers, engineers, and building owners can use these results to decide amongst appropriate control strategies that will lead to minimum energy consumption and, at the same time, will not compromise occupant health. This work can be repeated for different types of buildings, notably for residences, schools, and offices where abundant information is available on both pollutant concentrations and ventilation rates, but where information is lacking on how to optimize the control strategies for better indoor air quality. / text

Retail buildings have potential for both short-term (customer) and long-term (occupational) exposure to indoor pollutants. A multitude of sources of volatile organic compounds (VOCs) are common to the retail environment. Volatile organic compounds can be odorous, irritating or carcinogenic. Through a field investigation and modeling study, this dissertation investigates exposure to, and control of, VOCs in retail buildings. Fourteen U.S. retail stores were tested one to four times each over a period of a year, for a total of twenty-four test visits. Over a hundred parameters were investigated to characterize each of the buildings, including ventilation system parameters, and airborne pollutants both indoors and outdoors. Concentrations of VOCs were simultaneously measured using five different methods: Summa canisters, sorbent tubes, 2,4-dinitrophenylhydrazine (DNPH) tubes, a photoionization detector (PID), and a colorimetric real-time formaldehyde monitor (FMM). The resulting dataset was analyzed to evaluate underlying trends in the concentrations and speciation of VOCs, identify influencing factors, and determine contaminants of concern. A parametric framework based on a time-averaged mass balance was then developed to compare strategies to reduce formaldehyde concentrations in retail stores. Mitigation of exposure to formaldehyde through air cleaning (filtration), emission control (humidity control), and targeted dilution (local ventilation) were assessed. Results of the field study suggested that formaldehyde was the most important contaminant of concern in the retail stores investigated, as all 14 stores exceeded the most conservative health guideline for formaldehyde (OEHHA TWA REL = 7.3 ppb) during at least one sampling event. Formaldehyde monitors were strongly correlated with DNPH tube results. The FMM showed promising characteristics, supporting further consideration as real-time indicators to control ventilation and/or environmental parameters. The vast majority of the remaining VOCs were present at low concentrations, but episodic activities such as cooking and cleaning led to relatively high indoor concentrations for ethanol, acetaldehyde, and terpenoids. Results of the modeling effort demonstrated that local ventilation caused the most uniform improvements to indoor formaldehyde concentrations across building characteristics, but humidity control appeared to have a very limited impact. Filtration used under specific conditions could lead to larger decreases in formaldehyde concentrations than all other strategies investigated, and was the least energy-intensive. / text

Not available / text