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Polymer-silica Hybrids for Separation of CO2 and Catalysis of Organic ReactionsSilva Mojica, Ernesto 15 May 2014 (has links)
No description available.
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Improved inspection and micrometrology of embedded structures in multi-layered ceramics : Development of optical coherence tomographic methods and toolsSu, Rong January 2014 (has links)
Roll-to-roll manufacturing of micro components based on advanced printing, structuring and lamination of ceramic tapes is rapidly progressing. This large-scale and cost-effective manufacturing process of ceramic micro devices is however prone to hide defects within the visually opaque tape stacks. To achieve a sustainable manufacturing with zero defects in the future, there is an urgent need for reliable inspection systems. The systems to be developed have to perform high-resolution in-process quality control at high speed. Optical coherence tomography (OCT) is a promising technology for detailed in-depth inspection and metrology. Combined with infrared screening of larger areas it can solve the inspection demands in the roll-to-roll ceramic tape processes. In this thesis state-of-art commercial and laboratory OCT systems, operating at the central wavelength of 1.3 µm and 1.7 µm respectively, are evaluated for detecting microchannels, metal prints, defects and delaminations embedded in alumina and zirconia ceramic layers at hundreds of micrometers beneath surfaces. The effect of surface roughness induced scattering and scattering by pores on the probing radiation, is analyzed by experimentally captured and theoretically simulated OCT images of the ceramic samples, while varying surface roughnesses and operating wavelengths. By extending the Monte Carlo simulations of the OCT response to the mid-infrared the optimal operating wavelength is found to be 4 µm for alumina and 2 µm for zirconia. At these wavelengths we predict a sufficient probing depth of about 1 mm and we demonstrate and discuss the effect of rough surfaces on the detectability of embedded boundaries. For high-precision measurement a new and automated 3D image processing algorithm for analysis of volumetric OCT data is developed. We show its capability by measuring the geometric dimensions of embedded structures in ceramic layers, extracting features with irregular shapes and detecting geometric deformations. The method demonstrates its suitability for industrial applications by rapid inspection of manufactured samples with high accuracy and robustness. The new inspection methods we demonstrate are finally analyzed in the context of measurement uncertainty, both in the axial and lateral cases, and reveal that scattering in the sample indeed affects the lateral measurement uncertainty. Two types of image artefacts are found to be present in OCT images due to multiple reflections between neighboring boundaries and inhomogeneity of refractive index. A wavefront aberration is found in the OCT system with a scanning scheme of two galvo mirrors, and it can be corrected using our image processing algorithm. / <p>QC 20140428</p> / Multilayer (FP7-NMP4-2007-214122)
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Role of AGN feedback in galaxy evolution at high-redshiftCollet, Cédric 28 April 2014 (has links) (PDF)
There is growing evidence that supermassive black holes may play a crucial role for galaxy evolution, in particular during the formation of massive galaxies at high redshift (z ~ 2 - 3). Our work focuses on quantifying the effects of jets of radiogalaxies and of large bolometric luminosities of quasars on the interstellar gas in their host galaxies. To this end, we studied the kinematics of the ionized gas in 12 moderately powerful radio galaxies and 11 quasars (6 radio-loud and 5 radio-quiet) at high redshifts with rest-frame optical imaging spectroscopy obtained at the VLT with SINFONI. We searched for outflows and other signatures of feedback from the supermassive black holes in the centers of these galaxies to evaluate if the AGN may plausibly quench star formation. In our sample of moderately powerful radiogalaxies, we observe velocity dispersions nearly as large as those observed in the most powerful ones (with FWHM ~ 1000 km/s), but the quantity of ionized gas is decreased by one order of magnitude (Mion gas ~ 10^8 - 10^9 Msun) and velocity gradients tend to be less dramatic (Δv < 400 km/s), when they are observed. In our sample of quasars, we had to carefully subtract the broad spectral component of emission lines to have access to its narrow, and spatially extended, component. We detect truly extended emission line regions in 4/6 sources of our radio-loud subsample and in 1/5 source of our radio-quiet subsample. We estimate that masses of ionized gas in these sources are smaller than in our sample of high-redshift radiogalaxies (with Mion gas ~ 10^7 - 10^8 Msun) and kinematics tend to be more quiescent, akin to what is observed in local quasars. Finally, detailed observations of two outliers among our sample of high-redshift radiogalaxies revealed that one of them is closely surrounded by 14 companions galaxies, hence lying in an overdensity. We therefore interpret the presence and morphology of ionized gas around these galaxies as evidence for repeated cycles ouf AGN outbursts, akin to what can be observed in local clusters of galaxies, which are prime examples of AGN feedback in the nearby Universe.
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