<p>In this project we have used Fourier transform infrared spectroscopy to study the photoresponse of two different types of quantum dot-in-a-well infrared photodetectors (DWELL QDIPs). The basic task was to compare the photoresponse of these two detectors, and to study the influence of external resonant laser pumping on the photoresponse. Series of measurements were done at 77K. In the first measurements we investigated the photoresponse for different applied voltages at 77K. </p><p>In a second run of experiments, we used a 1064 nm infrared semiconductor laser to resonantly </p><p>pump the fundamental transition of the quantum dots. The results show that by using this </p><p>additional illumination the photoresponse was dramatically increased by creating additional </p><p>charge carriers in the quantum dots. This could be used to increase the sensitivity of infrared </p><p>detectors based on QDs.</p>

In this project we have used Fourier transform infrared spectroscopy to study the photoresponse of two different types of quantum dot-in-a-well infrared photodetectors (DWELL QDIPs). The basic task was to compare the photoresponse of these two detectors, and to study the influence of external resonant laser pumping on the photoresponse. Series of measurements were done at 77K. In the first measurements we investigated the photoresponse for different applied voltages at 77K. In a second run of experiments, we used a 1064 nm infrared semiconductor laser to resonantly pump the fundamental transition of the quantum dots. The results show that by using this additional illumination the photoresponse was dramatically increased by creating additional charge carriers in the quantum dots. This could be used to increase the sensitivity of infrared detectors based on QDs.

Photodetectors are semiconductor devices capable of converting optical signals into electrical signals. There is a wide range of applications for photodetectors such as fiber optics communication, infrared heat camera sensors, as well as in medical and military equipment.Nanowires are thin needle-shaped structures consisting of semiconductor materials such as gallium arsenide (GaAs), indium phosphide (InP) or silicon (Si). They are ideally suited for sensitive photodetectors with low noise due to their small size, well-controlled crystal structure, and composition tunability, as well as the possibility to fabricate them monolithically on silicon.In this thesis, Fourier Transform Infrared (FTIR) Spectroscopy was used to investigate the optical characteristics of InP nanowire-based n+-i-n+ photodetectors with 20 embedded InAsP quantum discs in each InP nanowire. The spectrally resolved photocurrent was measured and analyzed at different angles of incidence. Also, detailed current-voltage characteristics in dark and under illumination were recorded and analyzed.Summarized, the samples showed very good I-V performance with low dark leakage currents. The photocurrent scales with the numbers of nanowires, from which we conclude that most of the photocurrent is generated in the nanowires. Spectrally resolved photocurrent data, recorded at room-temperature, shows strong absorption in the near-infrared region with interesting peaks that reveal, the underlying optical processes in the substrate and nanowires.

Quantum well infrared photodetectors (QWIP) utilize quantum wells of large bandgap materials to detect infrared radiation. When compared to conventional low bandgap LWIR photodetectors, the QWIP technology offers largest format thermal imagers with much better uniformity. The theoretical part of this study includes the development of a QWIP ensemble Monte-Carlo simulator. Capture paths of electrons to quantum wells are simulated in detail. For standard AlGaAs/GaAs QWIPs, at medium and high E-fields L valley quantum well (QW) is a trap for electrons which causes higher capture probability when compared with InP/InGaAs and GaAs/InGaAs QWIPs. The results suggest that high photoconductive gain observed in InP/InGaAs and GaAs/InGaAs QWIPs is not due to good transport properties of binary barrier material but due to higher &amp / #61511 / -L valley energy separation. The experimental part of the study includes the fabrication and characterization of InP/InGaAs and InP/InGaAsP QWIPs and 640x512 FPAs with the main objective of investigating the feasibility of these material systems for QWIPs. The InP/InGaAs and InP/InGaAsP QWIP detectors showed specific detectivity values above 1010 cm.Hz1/2/W (70K, f/2, background limited). The devices offer higher allowable system noise floor when compared with the standard AlGaAs/GaAs QWIP technology. It is also experimentally shown that for strategic applications LWIR InP based QWIPs have advantages over the standard QWIP technology. The InP/InGaAs 640x512 QWIP FPA reached 36 mK average NETD value at 70 K with f/1.5 optics and 10 ms integration time. The InP/InGaAsP QWIP on the other hand yielded 38 mK NETD histogram peak at 70 K with f/1.5 optics and 5 ms integration time on 320x256 window of the 640x512 FPA.

<p>This master’s thesis deals with studies of lateral and vertical carrier transport Dot-in- </p><p>a-Well (DWELL) Quantum Dot Infrared Photodetectors (QDIPs). During the pro ject, </p><p>devices have been developed and tested using a Fourier Transform Infrared (FTIR) spec- </p><p>trometer with the purpose to find the processes governing the flow of photocurrent in </p><p>the different kinds of detectors, the dark current magnitude in the vertical Quantum Dot </p><p>Infrared Photodetector (QDIP) and the Quantum Well Infrared Photodetector (QWIP) </p><p>and the light polarization dependences for the vertical QDIP and the QWIP. </p><p>The lateral carrier transport DWELL QDIP was found to have poor conduction </p><p>in the well mainly due to re-trapping of electrons in this region. The main process gov- </p><p>erning the flow of photocurrent for this type of device at 77K is photo-excitation from </p><p>the Quantum Dot (QD)s to the excited state in the Quantum Well (QW) and further </p><p>thermal excitation. If the electrons are mainly transported in the matrix or the well at </p><p>77K is presently not clear. </p><p>For the vertical carrier transport DWELL QDIP at 77K, the wavelength response </p><p>could be tuned by altering the applied voltage. At higher voltages, the dominant process </p><p>was found to be photo-excitation from the QDs to the excited state in the QW followed </p><p>by thermal assisted tunneling into the GaAs-matrix. At lower voltages, photo-excitation </p><p>from the QDs directly into the the GaAs-matrix was the predominant process. The dark </p><p>current level in the vertical QDIPs was found to be 1.5 to 5 orders of magnitude smaller </p><p>than for the QWIP measured at 77K. Furthermore, the QDIP was found to be close to </p><p>polarization independent. As expected the QWIP had a reduced sensitivity to normal </p><p>incident light. The existence of this signal was attributed to interface scattering of light </p><p>inside the device.</p>

This master’s thesis deals with studies of lateral and vertical carrier transport Dot-in- a-Well (DWELL) Quantum Dot Infrared Photodetectors (QDIPs). During the pro ject, devices have been developed and tested using a Fourier Transform Infrared (FTIR) spec- trometer with the purpose to find the processes governing the flow of photocurrent in the different kinds of detectors, the dark current magnitude in the vertical Quantum Dot Infrared Photodetector (QDIP) and the Quantum Well Infrared Photodetector (QWIP) and the light polarization dependences for the vertical QDIP and the QWIP. The lateral carrier transport DWELL QDIP was found to have poor conduction in the well mainly due to re-trapping of electrons in this region. The main process gov- erning the flow of photocurrent for this type of device at 77K is photo-excitation from the Quantum Dot (QD)s to the excited state in the Quantum Well (QW) and further thermal excitation. If the electrons are mainly transported in the matrix or the well at 77K is presently not clear. For the vertical carrier transport DWELL QDIP at 77K, the wavelength response could be tuned by altering the applied voltage. At higher voltages, the dominant process was found to be photo-excitation from the QDs to the excited state in the QW followed by thermal assisted tunneling into the GaAs-matrix. At lower voltages, photo-excitation from the QDs directly into the the GaAs-matrix was the predominant process. The dark current level in the vertical QDIPs was found to be 1.5 to 5 orders of magnitude smaller than for the QWIP measured at 77K. Furthermore, the QDIP was found to be close to polarization independent. As expected the QWIP had a reduced sensitivity to normal incident light. The existence of this signal was attributed to interface scattering of light inside the device.

Quantum well infrared photodetectors (QWIP) utilize quantum wells of large bandgap materials to detect infrared radiation. When compared to conventional low bandgap LWIR photodetectors, the QWIP technology offers largest format thermal imagers with much better uniformity. The theoretical part of this study includes the development of a QWIP ensemble Monte Carlo simulator. Capture paths of electrons to quantum wells are simulated in detail. For standard AlGaAs/GaAs QWIPs, at medium and high E-fields L valley quantum well (QW) is a trap for electrons which causes higher capture probability when compared with InP/InGaAs and GaAs/InGaAs QWIPs. The results suggest that high photoconductive gain observed in InP/InGaAs and GaAs/InGaAs QWIPs is not due to good transport properties of binary barrier material but due to higher &amp / #61511 / -L valley energy separation. The experimental part of the study includes the fabrication and characterization of InP/InGaAs and InP/InGaAsP QWIPs and 640x512 FPAs with the main objective of investigating the feasibility of these material systems for QWIPs. The InP/InGaAs and InP/InGaAsP QWIP detectors showed specific detectivity values above 1x1010 cm.Hz1/2/W (70K, f/2, background limited). The devices offer higher allowable system noise floor when compared with the standard AlGaAs/GaAs QWIP technology. It is also experimentally shown that for strategic applications LWIR InP based QWIPs have advantages over the standard QWIP technology. The InP/InGaAs 640x512 QWIP FPA reached 36 mK average NETD value at 70 K with f/1.5 optics and 10 ms integration time. The InP/InGaAsP QWIP on the other hand yielded 38 mK NETD histogram peak at 70 K with f/1.5 optics and 5 ms integration time on 320x256 window of the 640x512 FPA.

Quantum Well Infrared Photodetectors (QWIPs) are strong competitors to other detector technologies for future third generation thermal imagers. QWIPs have inherent advantages of mature III-V material system and well settled fabrication technology, as well as narrow band photo-response which is an important property facilitating the development of dual-band imagers with low crosstalk. This thesis focuses on the development of long/mid wavelength dual band QWIP focal plane arrays (FPAs) based on the AlGaAs/GaAs material system. Apart from traditional single band QWIPs, the dual-band operation is achieved by proper design of a bias tunable quantum well structure which has two responsivity peaks at 4.8 and 8.4 um for midwave infrared (MWIR) and longwave infrared (LWIR) atmospheric windows, respectively. The fabricated large format (640x512) FPA has MWIR and LWIR cut-off wavelengths of 5.1 and 8.9 um, and it provides noise equivalent temperature differences (NETDs) of ~ 20 and 32 mK (f/1.5 at 65 K) in these bands, respectively. The employed bias tuning approach for the dual-band operation requires the same fabrication steps established for single band QWIP FPAs, which is an important advantage of the selected method resulting in high-yield, high-uniformity and low-cost. Results are encouraging for fabrication of low cost, large format, and high performance dual band FPAs, making QWIP a stronger candidate in the competition for third generation thermal imagers

The physics and technology of the heterojunction infrared photodetectors having different material systems have been studied extensively. Devices used in this study have been characterized by using mainly optical methods, and electrical measurements have been used as an auxiliary method. The theory of internal photoemission in semiconductor heterojunctions has been investigated and the existing model has been extended by incorporating the effects of the difference in the effective masses in the active region and the substrate, nonspherical-nonparabolic bands, and the energy loss per collisions. The barrier heights (correspondingly the cut-off wavelengths) of SiGe/Si samples have been found from their internal photoemission spectrums by using the complete model which has the wavelength and doping concentration dependent free carrier absorption parameters. A qualitative model describing the mechanisms of photocurrent generation in SiGe/Si HIP devices has been presented. It has been shown that the performance of our devices depends significantly on the applied bias and the operating temperature. Properties of internal photoemission in a PtSi/Si Schottky type infrared detector have also been studied. InGaAs/InP quantum well photodetectors that covers both near and mid-infrared spectral regions by means of interband and intersubband transitions have been studied. To understand the high responsivity values observed at high biases, the gain and avalanche multiplication processes have been investigated. Finally, the results of a detailed characterization study on a systematic set of InAs/GaAs self-assembled quantum dot infrared photodetectors have been presented. A simple physical picture has also been discussed to account for the main observed features.

Quantum dot infrared photodetectors (QDIPs) have emerged as a promising technology in the mid- and far-infrared (3-25 μm) for medical and environmental sensing that have a lot of advantages over current technologies based on Mercury Cadmium Telluride (MCT) and quantum well (QW) infrared photodetectors (QWIPs). In addition to the uniform and stable surface growth of III/V semiconductors suitable for large area focal plane applications and thermal imaging, the three dimension confinement in QDs allow sensitivity to normal incidence, high responsivity, low darkcurrent and high operating temperature. The growth, processing and characterizations of these detectors are costly and take a lot of time. So, developing theoretical models based on the physical operating principals will be so useful in characterizing and optimizing the device performance. Theoretical models based on non-equilibrium Green's functions have been developed to electrically and optically characterize different structures of QDIPs. The advantage of the model over the previous developed classical and semiclassical models is that it fairly describes quantum transport phenomenon playing a significant role in the performance of such nano-devices and considers the microscopic device structure including the shape and size of QDs, heterostructure device structure and doping density. The model calculates the density of states from which all possible energy transitions can be obtained and hence obtains the operating wavelengths for intersubband transitions. The responsivity due to intersubband transitions is calculated and the effect of having different sizes and different height-to-diameter ratio QDs can be obtained for optimization. The dark and photocurrent are calculated from the quantum transport equation provided by the model and their characteristics at different design parameter are studied. All the model results show good agreement with the available experimental results. The detectivity has been calculated from the dark and photocurrent characteristics at different design parameters. The results shows a trade off between the responsivity and detectivity and what determines the best performance is how much the rate of increase of the photocurrent and dark current is affected by changing the design parameters. Theoretical modeling developed in the thesis give good description to the QDIP different characteristics that will help in getting good estimation to their physical performance and hence allow for successful device design with optimized performance and creating new devices, thus saving both time and money. / Thesis / Doctor of Philosophy (PhD)