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The Effect of Iron Oxide Nanoparticles on the Fate and Transformation of Arsenic in Aquatic EnvironmentsDickson, Dionne 20 March 2013 (has links)
Iron oxides and arsenic are prevalent in the environment. With the increase interest in the use of iron oxide nanoparticles (IONPs) for contaminant remediation and the high toxicity of arsenic, it is crucial that we evaluate the interactions between IONPs and arsenic. The goal was to understand the environmental behavior of IONPs in regards to their particle size, aggregation and stability, and to determine how this behavior influences IONPs-arsenic interactions.
A variety of dispersion techniques were investigated to disperse bare commercial IONPs. Vortex was able to disperse commercial hematite nanoparticles into unstable dispersions with particles in the micrometer size range while probe ultrasonication dispersed the particles into stable dispersions of nanometer size ranges for a prolonged period of time. Using probe ultrasonication and vortex to prepare IONPs suspensions of different particle sizes, the adsorption of arsenite and arsenate to bare hematite nanoparticles and hematite aggregates were investigated. To understand the difference in the adsorptive behavior, adsorption kinetics and isotherm parameters were determined. Both arsenite and arsenate were capable of adsorbing to hematite nanoparticles and hematite aggregates but the rate and capacity of adsorption is dependent upon the hematite particle size, the stability of the dispersion and the type of sorbed arsenic species. Once arsenic was adsorbed onto the hematite surface, both iron and arsenic can undergo redox transformation both microbially and photochemically and these processes can be intertwined. Arsenic speciation studies in the presence of hematite particles were performed and the effect of light on the redox process was preliminary quantified. The redox behavior of arsenite and arsenate were different depending on the hematite particle size, the stability of the suspension and the presence of environmental factors such as microbes and light. The results from this study are important and have significant environmental implications as arsenic mobility and bioavailability can be affected by its adsorption to hematite particles and by its surface mediated redox transformation. Moreover, this study furthers our understanding on how the particle size influences the interactions between IONPs and arsenic thereby clarifying the role of IONPs in the biogeochemical cycling of arsenic.
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Radionuclide speciation during mineral reactions in the chemically disturbed zone around a geological disposal facilityMarshall, Timothy January 2014 (has links)
Geological disposal of radioactive wastes currently stored at Earth's surface is now the favoured management pathway for these materials. Typically, intermediate level wastes (ILW) are grouted and emplaced in a geological disposal facility (GDF) which will be backfilled, possibly with cementitious materials. Post-closure leaching of the cementitious materials in a GDF is expected to create hyperalkaline conditions in and around the repository, resulting in mineral alteration and crystallisation, both within the engineered barrier and host rock; creating a persistent chemically disturbed zone (CDZ). Iron derived from within the host rock as a result of alkaline breakdown of Fe-bearing silicate minerals (e.g. biotite, chlorite); corrosion products formed within the repository; or iron contained within the waste; will form secondary iron (oxyhydr)oxide minerals. The formation and re-crystallisation of these reactive mineral phases may sequester radionuclides through a host of processes: surface-mediated reduction to less soluble forms; adsorption onto, and/or incorporation into stable secondary or tertiary iron oxide phases. Therefore iron (oxyhydr)oxides will be key to the fate of radionuclides potentially released from within radioactive wastes disposed of in a GDF.In this study, the fate of U(VI) and Tc(VII) was considered during crystallisation of ferrihydrite to more stable iron oxide phases (e.g. hematite and magnetite) and, in three synthetic cement leachates (pH 13.1, 12.5, 10.5) designed to reflect the early-, middle- and late-stage evolution of the CDZ. XRD and SEM/TEM have been used to characterise the mineralogy during crystallisation. Partitioning of U(VI) and Tc(VII) between the solid and solution has been followed throughout, with chemical extractions used to determine the distribution of the radionuclides adsorbed to, and incorporated within the solid. Synchrotron-based XAS techniques have been utilised to probe the oxidation state and molecular scale bonding environment of the radionuclides associated with the solids. The data suggest that: U(VI) is incorporated into the hematite structure in place of Fe(III), in a distorted octahedral environment with elongation of the uranyl bond; Tc(VII) is reduced to Tc(IV) and incorporated into the octahedral site within the magnetite structure in place of Fe(III), and is retained in the same environment even after extensive oxidation of the magnetite to maghemite; and that U(VI) may also be incorporated as U(V) or U(VI) into the magnetite structure, with similar recalcitrant behaviour during oxidation. These results highlight the importance of mineral reactions within the CDZ as potentially significant pathways for immobilising radionuclides released from a GDF.
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Produção do coagulante cloreto férrico a partir de carepa da indústria siderúrgicaSilva, Rogerio Giordani da January 2013 (has links)
A carepa é um resíduo da produção de aço gerado principalmente nas etapas de lingotamento e laminação. O objetivo do presente trabalho foi a produção do coagulante cloreto férrico a partir da carepa oriunda da indústria siderúrgica. Em termos experimentais, foram realizados ensaios de solubilização da carepa avaliando-se o efeito da concentração de ácido clorídrico, tempo de reação e temperatura. Ainda, avaliou-se a oxidação do Fe2+, presente no liquor, para Fe3+ por dois métodos distintos, sendo adição de peróxido de hidrogênio e injeção de ozônio. A solução de cloreto férrico produzido a partir da carepa foi caracterizada e aplicada no tratamento de esgoto doméstico sanitário de uma instituição universitária. Como resultado, a melhor condição para a dissolução da carepa foi com o uso de uma solução de HCl 90%, tempo de reação de 2 horas a uma temperatura de 80oC. Nesta condição, a eficiência de dissolução da carepa foi de 90%. A completa oxidação do Fe2+ dissolvido no liquor para Fe3+ foi possível tanto com a adição de H2O2 como com O3. Contudo, o processo de ozonização apresenta vantagens, pois estequiometricamente é mais eficiente e não dilui a solução rica em cloreto férrico. A análise físico-química do coagulante produzido com a digestão da carepa com HCl 90% e oxidada com ozônio, após evaporação, atendeu ao critério de concentração de Fe de no mínimo 12% em volume. A aplicação do reagente no tratamento de um esgoto doméstico sanitário mostrou que é eficiente na remoção de sólidos suspensos e fósforo. Por fim o estudo mostrou que é possível produzir um coagulante a partir da carepa gerada na indústria siderúrgica. A prática sugerida neste trabalho pode reduzir a quantidade de resíduos deslocados para aterros industriais pela indústria siderúrgica. / Mill scale is a residue of steel production generated mainly in casting and lamination phases. The objective of this work was the production of the ferric chloride coagulant from the mill scale which comes from the steel industry. In experimental terms, trials of mill scale solubility were carried out in order to evaluate the effect of hydrochloric acid concentration, reaction time and temperature. After that, the oxidation of Fe2 +, present in the liquor, to Fe3 + was evaluated by two distinct methods, addition of hydrogen peroxide and ozone injection. The ferric chloride solution produced from mill scale was characterized and applied in the sewage treatment of a university campus. As a result, a good condition for the dissolution of mill scale was with the use of 90% HCl solution, reaction time of 2 hours, at a temperature of 80ºC. In this condition, the efficiency of mill scale dissolution was of 90%. The complete oxidation of Fe2+ dissolved in the liquor for Fe3+ was possible both with the addition of H2O2 as well as with O3. However, the ozonation process has advantages because it is stoichiometrically more efficient and does not dilute the solution rich in ferric chloride. Physico-chemical analysis of the coagulant produced with the dissolution of mill scale with 90% HCl and oxidized with ozone, after evaporation, answered to the criterion of Fe concentration of, at least, 12% in volume. The use of the reagent in the treatment of a sewer showed that it is effective in removing suspended solids and phosphorus. Finally, it is possible to produce a coagulant from mill scale produced in the steel industry. The practice suggested in this work can reduce the amount of waste sent to industrial landfills by the steel industry.
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Environmental and biomedical applications of iron oxide/ mesoporous silica core-shell nanocompositesEgodawatte, Shani Nirasha 01 May 2016 (has links)
Mesoporous silica has shown great potential as an adsorbent for environmental contaminants and as a host for imaging and therapeutic agents. Mesoporous silica materials have a high surface area, tunable pore sizes and well defined surface properties which are governed by the surface hydroxyl groups. Surface modification of the mesoporous silica can tailor the adsorption properties for a specific metal ion or a small drug molecule by providing better sites for chelation or electrostatic interactions.
Iron oxide / mesoporous silica core shell materials couple the favorable properties of both the iron oxide and mesoporous silica materials. The core-shell materials have higher adsorption properties compared to the parent material. With magnetic iron oxide nanoparticle cores, an additional magnetic property is introduced that can be used as magnetic recovery or separation. Heavy metals such as Chromium (Cr) and Arsenic (As) discharged from residential and environmental sources pose a serious threat to human health as well as groundwater pollution.
In this thesis, iron oxide nanoparticles and nanofibers were coated with mesoporous silica and functionalized with (3-aminopropyl)triethoxysilane (APTES) using the post synthesis grafting method. The parent and the functionalized magnetic silica samples were characterized using powder X-ray diffraction (pXRD), thermal gravimetric analysis (TGA), Fourier Transform Infrared (FTIR) spectroscopy and nitrogen adsorption desorption isotherms for surface area and pore volumes. These materials were evaluated for Cr(III) and As(III)/As(V) adsorption from aqueous solutions in the optimum pH range for the specific metal. The aminopropyl functionalized magnetic mesoporous silica displayed the highest adsorption capacity for Cr(III) and Cu(II) of all the materials evaluated in this study. The high heavy metal adsorption capacity was attributed to a synergistic effect of iron oxide nanoparticles and amine functionalization on mesoporous silica as well as a judicious choice of pH. Modified magnetic mesoporous silica material was also found to have high adsorption capacity for high and low pH aqueous solutions of Uranium (VI).
Tuning the loading and release of a small drug molecule (5-FU) onto these iron oxide/ mesoporous silica core-shell materials was also investigated. The polarity of the solvent used to load 5-FU onto the host had an impact not only on the loading but also on the release percentage of 5-FU. The synthesis of a novel core-shell material with a hematite nanofiber core and a SBA type mesoporous silica shell was also explored.
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Preparation et performance d'une cellule photocatalytique à base d'hématite pour la génération d'hydrogèneBouhjar, Feriel 27 July 2018 (has links)
El hidrógeno es un portador de energía que ya ha demostrado su capacidad para reemplazar el
petróleo como combustible. Sin embargo, los medios de producción actualmente en uso
siguen siendo altamente emisores de gases de efecto invernadero. La foto-electrólisis del agua
es un proceso que, a partir de la energía solar, separa los compuestos elementales del agua
como el hidrógeno y el oxígeno utilizando un semiconductor con propiedades físicas
adecuadas. La hematita (¿-Fe2O3) es un material prometedor para esta aplicación debido a su
estabilidad química y su capacidad para absorber una porción significativa de la luz (con una
banda prohibida entre 2.0 - 2.2 eV). A pesar de estas propiedades ventajosas, existen
limitaciones intrínsecas al uso de óxido de hierro para la descomposición fotoelectroquímica
del agua. La primera restricción es la posición de su banda de conducción que es menor que el
potencial de reducción de agua. Esta limitación se puede superar mediante la adición en serie
de un segundo material, en tándem, que absorberá una parte complementaria del espectro
solar y llevar a los electrones a un nivel de energía más alto que el potencial para la liberación
de hidrógeno. El segundo obstáculo proviene del desacuerdo entre la corta longitud de
difusión de los portadores de carga y la profundidad de penetración larga de la luz. Por lo
tanto, es necesario controlar la morfología de los electrodos de hematita en una escala de
tamaño similar a la longitud de transporte del orificio.
En esta tesis, se introduce un nuevo concepto para mejorar el rendimiento fotoelectroquímico
de la hematita. Usando el método hidrotermal depositamos capas delgadas de hematita dopada
con Cr en sustratos de vidrio conductivo. También se ha preparado por medios
electroquímicos una heterounión del tipo p-CuSCN/n-Fe2O3 depositando secuencialmente una
capa de ¿-Fe2O3 y una película de CuSCNsobre sustratos de FTO (SnO2: F).Finalmente, se ha
preparado células solares de perovskitas y óxido de hierro. Para ello se depositó una capa
delgada, densa y uniformede óxido de hierro (¿-Fe2O3) como capa de transporte de electrones
(ETL) en lugar de dióxido de titanio (TiO2) que se utiliza convencionalmente en las células
fotovoltaicas perovskitastipoCH3NH3PbI3 (SGP). Este último dispositivo mostró un aumento
en la fotocorriente del 20% y un IPCE30 veces mayor que la hematita simple, lo que sugiere
una mejor conversión de las longitudes de onda por encima de 500 nm.
Palabras clave:
Fotoelectroquímica, división de agua, producción de hidrógeno, evolución de oxígeno,
semiconductores de óxido de metal, hematita, óxido de hierro, nanoestructuras / Hydrogen is an energy carrier that has already demonstrated its ability to replace oil as a fuel.
However, the means of production currently used remain highly emitting greenhouse gases.
Photo-electrolysis of water is a process that uses solar energy to separate the elemental
compounds of water such as hydrogen and oxygen using a semiconductor with adequate
physical properties. Hematite (¿-Fe2O3) is a promising material for this application because of
its chemical stability and ability to absorb a significant portion of light (with a band-gap
between 2.0 - 2.2 eV). Despite these advantageous properties, there are intrinsic limitations to
the use of iron oxide for the photoelectrochemical cracking of water. The first constraint is the
position of its conduction band, which is lower than the water reduction potential. This
constraint can be overcome by the addition in series of a second material, in tandem, which
will absorb a complementary part of the solar spectrum and bring the electrons to a higher
energy level than the potential of hydrogen release. The second obstacle comes from the
disagreement between the short diffusion length of the charge carriers and the long light
penetration depth. It is therefore necessary to control the morphology of the hematite
electrodes on a scale of similar size to the transport length of the hole.
In this thesis a new concept is introduced to improve the photoelectrochemical performances.
Using the hydrothermal method we deposited thin layers of Cr-doped hematite on conductive
glass substrates. We also electrochemically prepared a p-CuSCN / n-Fe2O3 heterojunction by
sequentially depositing ¿-Fe2O3 and CuSCN films on FTO (SnO2: F) substrates. Finally, we
have used uniform and dense thin layers of iron oxide (¿-Fe2O3) as an electron transport layer
(ETL) in place of titanium dioxide (TiO2) conventionally used in photovoltaic cells based on
perovskites CH3NH3PbI3 (PSC). This latter concept showed a 20% increase of the
photocurrent and an IPCE 30 times greater than the simple hematite, suggesting better
conversion of high wavelengths (> 500 nm).
Keywords:
Photoelectrochemistry, Water Splitting, Hydrogen Production, Oxygen Evolution, MetalOxide
Semiconductors, Hematite, Iron Oxide, Nanostructures, Surface. / L'hidrogen és un proveïdor d'energia que ja ha demostrat la seva capacitat per reemplaçar el
petroli com a combustible, però els mitjans de producció actuals continuen essent fortament
emissors dels gasos responsables d'efecte hivernacle. La fotoelectròlisi de l'aigua és un procés
que, a partir de l'energia solar, separa els compostos elementals d'aigua com l'hidrogen i
l'oxigen utilitzant un semiconductor amb propietats físiques adequades. La hematita (¿-Fe2O3)
és un material prometedor per a aquesta aplicació a causa de la seva estabilitat química i
capacitat d'absorbir una porció significativa de la llum (amb un gap entre 2,0 i 2,2 eV).
Malgrat aquestes propietats avantatjoses, hi ha limitacions intrínseques per a l'ús d'òxid de
ferro per a la descomposició fotoelectroquímica de l'aigua. La primera restricció és la posició
de la seva banda de conducció que és inferior al potencial de reducció d'aigua. Aquesta
limitació es pot superar mitjançant l'addició en sèrie d'un segon material, en tàndem, que
absorbirà una part complementària de l'espectre solar i portar els electrons a un nivell
d'energia més alt que el potencial per a l'alliberament d'hidrogen. El segon obstacle prové del
desacord entre la curta durada de la difusió dels portadors de càrrega i la llarga profunditat de
penetració de la llum. Per tant, és necessari controlar la morfologia dels elèctrodes d'hematita
en una escala de mida similar a la longitud del forat del transport.
En aquesta tesi, es presenta un nou concepte per millorar el rendiment fotoelectroquímic.
Mitjançant el mètode hidrotermal es van dipositar capes primes de hematita Cr-doped sobre
substrats de vidre conductor. També s'han preparat electroquímicamentheterounions de tipus
p-CuSCN/n-Fe2O3 dipositant seqüencialment una capa de ¿-Fe2O3 i altra de CuSCN sobre
substrats FTO (SnO2: F).Finalment, s'han produït cél·lules solars de perovskitesi óxid de
ferro. Per això es va depositaruna capa prima,densai uniforme d'òxid de ferro (¿-Fe2O3) com
a capa de transport d'electrons (ETL) en lloc de diòxid de titani (TiO2) que s'utilitza
convencionalment en les cèl·lules fotovoltaiques de perovskita híbrida del tipus CH3NH3PbI3
(SGP). Aquest últim dispositiu va mostrar un augment del fotocorrent del 20% i una IPCE30
vegades superior a la hematita simple, la qual cosa suggereix una millor conversió a longitud
d'ones per sobre de 500 nm.
Paraules clau:Fotoelectroquímica, divisió d'aigua, producció d'hidrogen, evolució d'oxigen,
semiconductors d'òxids metàl·lics, hematita, òxid de ferro, nanoestructures. / Bouhjar, F. (2018). Preparation et performance d'une cellule photocatalytique à base d'hématite pour la génération d'hydrogène [Tesis doctoral no publicada]. Universitat Politècnica de València. https://doi.org/10.4995/Thesis/10251/106345 / TESIS
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Design and Synthesis of Porous Smart Materials for Biomedical ApplicationsOmar, Haneen 11 1900 (has links)
Porous materials have garnered significant interest within scientific community
mainly because of the possibility of engineering their pores for selective applications.
Currently, much research has focused on improving the therapeutic indices of the active
pharmaceutical ingredients engineered with nanoparticles.
The main goal of this dissertation is to prepare targetable and biodegradable
silica/organosilica nanoparticles for biomedical applications with a special focus on
engineering particle pores.
Herein, the design of biodegradable silica-iron oxide hybrid nanovectors with large
mesopores for large protein delivery in cancer cells is described. The mesopores of the
nanomaterials span 20 to 60 nm in diameter, and post-functionalization allowed the
electrostatic immobilization of large proteins (e.g., mTFP-Ferritin, ~534 kDa). The
presence of iron oxide nanophases allowed for the rapid biodegradation of the carrier in
fetal bovine serum as well as magnetic responsiveness. The nanovectors released large
protein cargos in aqueous solution under acidic pH or magnetic stimuli. The delivery of
large proteins was then autonomously achieved in cancer cells via the silica-iron oxide
nanovectors, which is thus promising for biomedical applications.
Next, the influence of competing noncovalent interactions in the pore walls on the
biodegradation of organosilica frameworks for drug delivery applications is studied.
Enzymatically-degradable azo-bridged organosilica nanoparticles were prepared and
then loaded with the anticancer drug doxorubicin (DOX). Controllable drug release was
observed only upon the stimuli-mediated degradation of azo-bridged organosilica
nanoparticles in the presence of azoreductase enzyme triggers or under hypoxia
conditions. These results demonstrated that azo-bridged organosilica nanoparticles are
biocompatible, biodegradable drug carriers and that cell specificity can be achieved both
in vitro and in vivo. Overall, the results support the importance of studying self-assembly
patterns in hybrid frameworks to better engineer the next generation of dynamic or “soft”
porous materials.
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Simultaneous removal of H₂S and siloxane from biogas using a biotrickling filter / 生物付着担体充填塔を用いたバイオガスからの硫化水素とシロキサンの同時除去に関する研究Zhang, Yuyao 23 March 2021 (has links)
京都大学 / 新制・課程博士 / 博士(工学) / 甲第23181号 / 工博第4825号 / 新制||工||1754(附属図書館) / 京都大学大学院工学研究科都市環境工学専攻 / (主査)教授 高岡 昌輝, 教授 橋本 訓, 准教授 大下 和徹 / 学位規則第4条第1項該当 / Doctor of Philosophy (Engineering) / Kyoto University / DFAM
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Decomposition of ammonium perchlorate encapsulated nanoscale and micron-scale catalyst particlesSpencer A Fehlberg (8774588) 29 April 2020 (has links)
<p>Iron oxide is the most common catalyst in
solid rocket propellant. We have previously demonstrated increased performance
of propellant by encapsulating iron oxide particles within ammonium perchlorate
(AP), but only nanoscale particles were used, and encapsulation was only
accomplished in fine AP (~20 microns in diameter). In this study, we extended the
size of particle inclusions to micron-scale within the AP particles as well the
particle sizes of the AP-encapsulated catalyst particles (100s of microns) using
fractional crystallization techniques with the AP-encapsulated particles as
nucleation sites for precipitation. Here we report catalyst particle inclusions
of micron-scale, as well as nanoscale, within AP and present characterization
of this encapsulation. Encapsulating micron-sized particles and growing these
composite particles could pave the way for numerous possible applications. A
study of the thermal degradation of these AP-encapsulated particles compared
against a standard mixture of iron oxide and AP showed that AP-encapsulated
micron-scale catalyst particles exhibited similar behavior to AP-encapsulated
nanoscale particles. Using computed tomography, we
found that catalyst particles were dispersed throughout the interior of coarse
AP-encapsulated micron-scale catalyst particles and decomposition was induced
within these particles around catalyst-rich regions.</p>
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Metal-Support Interaction and Electrochemical Promotion of Nano-Structured Catalysts for the Reverse Water Gas Shift ReactionPanaritis, Christopher 01 April 2021 (has links)
The continued release of fossil-fuel derived carbon dioxide (CO₂) emissions into our atmosphere led humanity into a climate and ecological crisis. Converting CO₂ into valuable chemicals and fuels will replace and diminish the need for fossil fuel-derived products. Through the use of a catalyst, CO₂ can be transformed into a commodity chemical by the reverse water gas shift (RWGS) reaction, where CO₂ reacts with renewable hydrogen (H₂) to form carbon monoxide (CO). CO then acts as the source molecule in the Fischer-Tropsch (FT) synthesis to form a range of hydrocarbons to manufacture chemicals and fuels. While the FT synthesis is a mature process, the conversion of CO₂ into CO has yet to be made commercially available due to the constraints associated with high reaction temperature and catalytic stability.
Noble metal ruthenium (Ru) has been widely used for the RWGS reaction due to its high catalytic activity, however, several constraints hinder its practical use, associated with its high cost and its susceptibility to deactivation. The doping or bimetallic use of non-noble metals iron (Fe) and cobalt (Co) is an attractive option to lower material cost and tailor the selectivity of the CO₂ conversion towards the RWGS reaction without compromising catalytic activity. Furthermore, employing nanostructured catalysts as nanoparticles is a viable solution to further lower the amount of metal used and utilize the highly active surface area of the catalyst. Dispersing nanoparticles on ionically conductive supports/solid electrolytes which contain species like O²⁻, H⁺, Na⁺, and K⁺, provide an approach to further enhance the reaction. This phenomenon is referred to as metal-support interaction (MSI), allowing for the ions to back spillover from the support and onto the catalyst surface. An in-situ approach referred to as Non-Faradaic Modification of catalytic activity (NEMCA), also known as electrochemical promotion of catalysis (EPOC) is used to in-situ control the movement of ionic species from the solid electrolyte to and away from the catalyst. Both the MSI and EPOC phenomena have been shown to be functionally equivalent, meaning the ionic species act to alter the work function of the catalyst by forming an effective neutral double layer on the surface, which in turn alters the binding energy of the reactant and intermediate species to promote the reaction.
The main objective of this work is to develop a catalyst that is highly active and selective to the RWGS reaction at low temperatures (< 400 °C) by employing the MSI and EPOC phenomena to enhance the catalytic conversion. The electrochemical enhancement effect will lower energy requirements and allow the RWGS reaction to take place at moderate temperatures. Catalysts composed of Ru, Fe and Co were synthesized through the polyol synthesis technique and deposited on mixed-ionically conductive and ionically conductive supports to evaluate their performance towards the RWGS reaction and the MSI effect. The nano-structured catalysts are deposited as free-standing nanoparticles on solid electrolytes to in-situ promote the catalytic rate through the EPOC phenomenon. Furthermore, Density Functional Theory (DFT) calculations were performed to correlate theory with experiment and elucidate the role polarization has on the binding energy of reactant and intermediate species.
The high dispersion of RuFe nanoparticles on ion-containing supports like samarium-doped ceria (SDC) and yttria-stabilized zirconia (YSZ) led to an increase in the RWGS activity due to the MSI effect. A direct correlation between experimental and DFT modeling was established signifying that polarization affected the binding energy of the CO molecule on the surface of Ru regardless of the type of ionic species in the solid electrolyte. The electrochemical enhancement towards the RWGS reaction has been achieved with iron-oxide (FeOₓ) nanowires on YSZ. The in-situ application of O²⁻ ions from YSZ maintained the most active state of Fe₃O₄ and FeO towards the RWGS reaction and allowed for persistent-promoted state that lasted long after potential application. Finally, the deposition of FeOₓ nanowires on Co₃O₄ resulted in the highest CO₂ conversion towards the RWGS reaction due to the metal-oxide interaction between both metals, signifying a self-sustained electro-promoted state.
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Adsorbate-enhanced Corrosion Processes at Iron and Iron Oxide SurfacesMurray, Eric 12 1900 (has links)
This study was intended to provide a fuller understanding of the surface chemical processes which result in the corrosion of ferrous materials.
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