Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2017. / Cataloged from PDF version of thesis. / Includes bibliographical references (pages 137-149). / Significant changes occurred during the last deglaciation (roughly 10-20 thousand years (ka) before present) throughout the climate system. The ocean is a large reservoir of carbon and heat, however, its role during the deglaciation is still not well understood. In this thesis, I rely on radiocarbon measurements on fossil biogenic carbonates sampled from the seafloor to constrain deglacial ocean ventilation rates, using new data, an extensive data compilation, and inverse modeling. First, based on a sediment core that is absolutely dated from wooden remains, I argue that the deglacial ¹⁴C reservoir age of the upper East Equatorial Pacific was not very different from today. Combined with stable carbon isotope data, the results suggest that the deglacial atmospheric CO₂ rise was probably due to CO₂ released directly from the ocean (e.g., in the Southern Ocean) to the atmosphere rather than first mixed through the upper ocean. Then using a high-deposition-rate sediment core located close to deep water formation regions in the western North Atlantic, I show that compared to today, the mid-depth water production in the North Atlantic was probably stronger during the Younger Dryas cold episode, and weaker during other intervals of the late deglaciation. However, the change was not as large as suggested by previous studies. Finally, I compile published and unpublished deep ocean ¹⁴C data, and find that the ¹⁴C activity of the deep ocean mirrors that of the atmosphere during the past 25 ka. A box model of modern ocean circulation is fit to the compiled data using an inverse method. I find that the residuals of the fit can generally be explained by the data uncertainties, implying that the compiled data jointly do not provide strong evidence for basin-scale ventilation changes. Overall, this thesis suggests that, although deep ocean ventilation may have varied at some locations during the last deglaciation, the occurrence of basin-scale ventilation changes are much more difficult to be put on a firm footing. An imbalance between cosmogenic production and radioactive decay appears as the most natural explanation for the deglacial ¹⁴C activity decline observed in both the atmosphere and the deep ocean. / by Ning Zhao. / Ph. D.

Thesis (Ph.D.)--Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Dept. of Biology, and the Woods Hole Oceanographic Institution), 2002. / Includes bibliographical references (p. 130-138). / Mark-recapture analysis of populations is becoming an important tool in population biology. Mark-recapture methods can be used to estimate transition probabilities among life-stages from capture histories of marked individuals for which stages can be determined at each sampling occasion. This method is called a multi-stage mark-recapture (MSMR) method. In this thesis, I describe advances I made in the MSMR method and present analyses that apply this method to actual data. The advances I made in the MSMR method are motivated by a need to provide a link between mark-recapture data and demographic models such as matrix population models and integrodifference models. I resolve some issues that are commonly encountered during sampling, such as the fact that the sex or life-stage of some individuals is unknown during some sampling occasions and that individuals become unobservable during some life-stages. I introduce a stage-structure that permits simple conversion of estimated transition probabilities into a matrix population model. I describe an algorithm to simplify programming for parameter estimation. I also introduce a method to estimate the distribution of dispersal displacements (a dispersal kernel) from mark-recapture data. I apply some of the methods described above to data of the North Atlantic right whale (Eubalaena glacialis). The right whales are considered one of the most endangered mammals. The current population size is about 300 in the northwestern Atlantic, and the number is declining. I applied the multi-stage mark-recapture statistics to the 17-year in- dividual sighting history data. / (cont.) Using the estimated transition probabilities, I constructed a population projection matrix, which was used for further demographic analyses. I found that the population was slowly increasing in 1980, but it started to decline slowly around 1992. I show that (1) this change was caused by increased mortality of females that have just given birth, (2) protecting two females a year from the deaths is enough to prevent the declining trend, and (3) demographic stochasticity is a more important factor influencing their long-term viability than environmental stochasticity. / by Masami Fujiwara. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, and the Woods Hole Oceanographic Institution), 2003. / Includes bibliographical references (p. 343-369). / This thesis examines the evolution of a mud-dominated coastal sedimentary system on multiple time scales. Fine-grained systems exhibit different properties and behavior from sandy coasts, and have received relatively little research attention to date. Evidence is presented for shoreline accretion under energetic conditions associated with storms and winter cold fronts. The identification of energetic events as agents of coastal accretion stands in contrast to the traditional assumption that low-energy conditions are required for deposition of fine-grained sediment. Mudflat accretion is proposed to depend upon the presence of an unconsolidated mud sea floor immediately offshore, proximity to a fluvial sediment source, onshore winds, which generate waves that resuspend sediment and advect it shoreward, and a low tidal range. This study constrains the present influence of the Atchafalaya River on stratigraphic evolution of the inner continental shelf in western Louisiana. Sedimentary and acoustic data are used to identify the western limit of the distal Atchafalaya prodelta and to estimate the proportion of Atchafalaya River sediment that accumulates on the inner shelf seaward of Louisiana's chenier plain coast. The results demonstrate a link between sedimentary facies distribution on the inner shelf and patterns of accretion and shoreline retreat on the chenier plain coast. / by Amy Elizabeth Draut. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2009. / Includes bibliographical references. / The radionuclides ²³¹Pa and ²³⁰Th, produced in the water column and removed from the ocean by particle scavenging and burial in sediments, offer a means for paleoceanographers to examine past dynamics of both water column and sedimentary processes. I show for the first time that a state of balance exists between ²³⁰Th production and burial in the Central Arctic basins, based on measured sedimentary ²³⁰Th, inventories in box cores, establishing this nuclide's utility as a paleoceanographic indicator of sedimentary processes and as a normalization tool. I present the first ²³⁰Th-normalized particle fluxes calculated for the central Arctic: vertical particle fluxes were extremely low during the late glacial, rose during the deglaciation due to particle inputs from shelf inundation, increased productivity and ice-rafted debris, and fell again following the establishment of interglacial conditions. A major event of lateral sediment redistribution, inferred from surplus ²³⁰Th, inventories, occurred in the Makarov Basin during the deglaciation and may have been due to destabilization of slope and shelf sediments as sea level rose. I present the first high-resolution, radiocarbon-dated downcore records of sedimentary ²³¹Pa/²³⁰Th from the Arctic Ocean. Low ratios indicate that ²³¹Pa was exported from all sites during the late glacial period, with export decreasing during the deglaciation and Holocene. 231Pa/²³⁰Th measurements in cores from three continental slope sites show no evidence for a ²³¹Pa sink related to boundary scavenging on the continental slopes. Holocene ²³¹Pa/²³⁰Th ratios show a very significant variation by depth, with strong export of ²³¹Pa at deep sites but little or no export at shallow sites, a result which echoes findings for the South Atlantic and the Pacific. / (cont.) The Arctic thus appears fundamentally similar to other ocean basins in its ²³¹Pa and ²³⁰Th dynamics, despite its peculiar qualities of sea ice cover, low particle flux, and relatively isolated deep waters. / by Sharon Susanna Hoffmann. / Ph.D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2012. / Cataloged from PDF version of thesis. / Includes bibliographical references. / Trace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological and abiotic sources and sinks. Their open ocean concentrations range from picomolar to nanomolar, and their bioavailabilities can impact primary production. Understanding the biogeochemical cycling of these hybrid-type metals with an emphasis on cobalt was the focus of this thesis. This was accomplished by determining the dissolved distributions of these metals in oceanic regions that were characterized by different dominant biogeochemistries. A large subsurface plume of dissolved cobalt, iron, and manganese was found in the Eastern South Atlantic. The cause of this plume is a combination of reductive dissolution in coastal sediments, wind-driven upwelling, advection, biological uptake, and remineralization. Additional processes that are discussed as sources of metals to the regions studied during this thesis include isopycnal uplift within cold-core eddies (Hawaii), ice melt (McMurdo Sound, Antarctica), riverine input (Arctic Ocean), and winter mixing (McMurdo Sound). The biological influence on surface ocean distributions of cobalt was apparent by the observation of linear relationships between cobalt and phosphate in mid to low latitudes. The cobalt:phosphate ratios derived from these correlations changed over orders of magnitude, revealing dynamic variability in the utilization, demand, and sources of this micronutrient. Speciation studies suggest that there may be two classes of cobalt binding ligands, and that organic complexation plays an important role in preventing scavenging of cobalt in the ocean. These datasets provided a basis for comparing the biogeochemical cycles of cobalt, iron, and manganese in three oceanic regimes (Hawaii, South Atlantic, McMurdo Sound). The relative rates of scavenging for these metals show environmental variability: in the South Atlantic, cobalt, iron, and manganese were scavenged at very different rates, but in the Ross Sea, mixing and circulation over the shallow sea was fast, scavenging played a minor role, and the cycles of all three metals were coupled. Studying the distributions of these metals in biogeochemically distinct regions is a step toward a better understanding of their oceanic cycles. / by Abigail Emery Noble. / Ph.D.

Thesis: S.M., Joint Program in Oceanography (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2014. / Cataloged from PDF version of thesis. / Includes bibliographical references (pages 139-148). / Observations suggest that during the last deglaciation (roughly 20,000-10,000 years ago) the Earth warmed substantially, global sea level rose approximately 100 meters in response to melting ice sheets and glaciers, and atmospheric concentrations of carbon dioxide increased. This interval may provide an analog for the evolution of future climate. The ocean plays a key role in the modern climate system by storing and transporting heat, salt, and nutrients, but its role during the last deglaciation remains uncertain. Prominent signals of the last deglaciation in the ocean are a gradual warming and a decrease of the seawater oxygen isotope ratio 5180 (a signature of melting land ice sheets). These changes do not occur uniformly in the ocean, but propagate like plumes of dye over hundreds and thousands of years, the aggregate results of turbulent advective and diffusive processes. Information about changing temperatures and oxygen isotopes is stored in the shells of benthic organisms recovered in ocean sediment cores. This thesis develops and applies an inverse framework for understanding deglacial oxygen isotope records derived from sediment cores in terms of the Green functions of ocean tracer transport and ocean mixed layer boundary conditions. Singular value decomposition is used to find a solution for global mixed layer tracer concentration histories that is constrained by eight last-deglacial sediment core records and a model of the modern ocean tracer transport. The solution reflects the resolving power of the data, which is highest at model surface locations associated with large rates of volume flux into the deep ocean. The limited data resolution is quantified and rationalized through analyses of simple models. The destruction of information contained in tracers is a generic feature of advective-diffusive systems. Quantifying limitations of tracer records is important for making and understanding inferences about the long-term evolution of the ocean. / by Daniel Edward Amrhein. / S.M.

Thesis: Ph. D., Joint Program in Oceanography/Applied Ocean Science and Engineering (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2014. / Cataloged from PDF version of thesis. / Includes bibliographical references. / At the land-ocean interface, terrestrial groundwater interacts with seawater to form a subterranean estuary, which can play host to dynamic biogeochemical cycling of nutrients, trace metals and radionuclides. This chemically altered groundwater enters the ocean through submarine groundwater discharge (SGD), a process that is driven by a number of physical processes acting on aquifers and the coastal ocean. In this thesis, seasonal variability in chemical cycling and associated loading to the coastal ocean was observed in a monthly time series within the Waquoit Bay (MA, USA) subterranean estuary. The position of the aquifer mixing zone moved seaward with an increase in hydraulic gradient, resulting in low salinity conditions and reduced mixing, while a decrease in gradient led to landward movement, high salinity groundwater and enhanced mixing. At this location, seasonal variability in sea level, not groundwater level, was the dominant variable driving the hydraulic gradient and therefore SGD. Fluxes of sediment bound cations to the ocean increased coincidently with sea level rise due to desorption. There was enhanced nitrogen attenuation during winter, potentially due to longer groundwater residence times, with greater nutrient delivery to coastal waters during the spring and summer bloom. Interannual climate fluctuations that control sea level and precipitation may ultimately control the timing and magnitude of chemical and water flux via SGD. In addition to temporal variability, aquifer lithology influences chemical export. This thesis also demonstrates that SGD from karst subterranean estuaries may play a role in local and global element budgets. The potential for the chemical signature of SGD to be recorded in the coral record was tested through a combination of coral culture experiments and field and modeling studies in the Yucatan Peninsula. Coral barium was well correlated with precipitation for a twelve-year record, with coral geochemistry reflecting the passage of a hurricane in 2002. While additional complexities in deciphering coral records remain, this proxy offers the potential to extend SGD records into the past. / by Meagan Joan Eagle Gonneea. / Ph. D.

Thesis (Ph. D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and, the Woods Hole Oceanographic Institution), 2004. / Includes bibliographical references. / The most ubiquitous source of polycyclic aromatic hydrocarbons (PAHs) to the environment is incomplete combustion. This study generated a high-resolution historical record of pyrogenic PAH emissions since pre-industrial times from anoxic aquatic sediments, allowing for detailed comparison with energy consumption data. We show that an increase in PAH concentrations over the last decade may be due to a rise in emissions from diesel-powered vehicles. Compound-specific radiocarbon measurements demonstrated unequivocally that the proportion of PAHs derived from fossil fuel combustion has increased substantially during the 20th century. [delta]¹³C and [delta]¹⁴C measurements were also used to constrain the relative importance of combustion versus in situ production as sources of perylene. In addition, a comparison of the down-core concentration and isotopic profiles of black carbon (BC) generated by a combination of chemical and/or thermal oxidation methods highlighted the limitations of these methods when applied to sedimentary matrices. Finally, parallel lead and cesium isotopic records revealed two new potential stratigraphic markers in North American sedimentary records. ²⁰⁶Pb/²⁰⁷Pb profiles show a distinct peak in the mid-19th century, while a ¹³⁷Cs peak was found to coincide with the 1986 Chernobyl accident. / by Anna Lúcia Cessel de Lima. / Ph.D.

Thesis: Ph. D., Joint Program in Oceanography (Massachusetts Institute of Technology, Department of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2017. / Cataloged from PDF version of thesis. / Includes bibliographical references (pages 105-114). / The circulation of air in the stratosphere is important for the distribution of radiatively-important trace gases, such as ozone and water vapor, and other chemical species, including ozone-depleting chlorofluorocarbons. Age of air in the stratosphere is an idealized tracer with unique mathematical properties, which we exploit to derive a theory for the relationship of tracer observations to the stratospheric circulation. We show that the meridional age gradient is a measure of the global diabatic circulation, the total overturning strength through an isentropic surface, and test this time-dependent theory in a simple atmospheric general circulation model. We apply the theory to satellite data of sulfur hexafluoride (SF6 and nitrous oxide to derive the first observationally-based estimates of the global meridional overturning circulation strength at all levels in the stratosphere. These two independent global satellite data products agree to within 5% on the strength of the diabatic circulation in the lower stratosphere. We compare to re-analyses and find broad agreement in the lower stratosphere and disagreement (~ 100%) in the upper stratosphere. To understand the relationship between the diabatic circulation and other metrics of the circulation, we calculate it in a state-of-the-science atmospheric model and in three different reanalysis data products. The variability of the global diabatic circulation is very similar to one typical circulation metric, and it is correlated with total column ozone in the tropics and in Southern hemisphere mid latitudes in both a model and in reanalysis-data comparisons. Furthermore, we develop a metric for the mean adiabatic mixing, showing that it is related to the meridional age difference and the vertical gradient of age. We calculate this metric for a range of simple model runs to determine its utility as a measure of mixing. We find very little mixing of air into the tropics in the mid-stratosphere, and the vertical structure of mixing in the lower stratosphere and upper stratosphere varies among model runs and between hemispheres. A picture of global average stratospheric circulation could thus be obtained using age of air data, given reliable long-term records. / by Marianna Katherine Linz. / Ph. D.

Thesis (Ph.D.)--Joint Program in Oceanography (Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences; and the Woods Hole Oceanographic Institution), 2010. / This electronic version was submitted by the student author. The certified thesis is available in the Institute Archives and Special Collections. / Cataloged from student submitted PDF version of thesis. / Includes bibliographical references. / Anthropogenic activity is rapidly changing the global climate through the emission of carbon dioxide. Ocean carbon and sulfur cycles have the potential to impact global climate directly and through feedback loops. Numerical modeling, field and laboratory studies are used to improve our mechanistic understanding of the impact of natural variability on carbon and sulfur cycling. Variability in ocean physics, specifically changes in vertical mixing, is shown to significantly impact both cycles. The impact of interannual variability on the detection and attribution of anthropogenic carbon (Canthro) and the storage of Canthro in the Atlantic Ocean is analyzed using a three-dimensional global ocean model. Several regions are identified where empirical methods used to estimating Canthro are not able to correct for natural variability in the ocean carbon system. This variability is also shown to bias estimates of long term trends made from hydrographic observations. In addition, the storage of Canthro in North Atlantic mode waters is shown to be strongly influenced by water mass transformation during wintertime mixing events. The primary mechanisms responsible for seasonal variability in dimethylsulfoniopropionate (DMSP) degradation and dimethylsulfide (DMS) production in the oligotrophic North Atlantic are investigated using potential enzyme activity and gene expression and abundance data. Vertical mixing and UV radiative stress appear to be the dominant mechanisms behind seasonal variability in DMS production in the Sargasso Sea. This thesis demonstrates the importance of and dynamics of bacterial communities responsible for DMSP degradation and DMS production in oligotrophic surface waters. These findings suggest that modifications to current numerical models of the upper ocean sulfur cycle may be needed. Specifically, current static parameterizations of bacterial DMSP cycling should be replaced with a dynamic bacterial component including DMSP degradation and DMS production. / by Naomi Marcil Levine. / Ph.D.