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2D materials like graphene and MoS_2 are atomically thin, extremely strong and flexible, making them attractive for integration into strain engineered devices. Strain on these materials can change physical properties, as well as induce exotic physics, not typically seen in solid-state systems. Here, we probe the novel physics arising from distorted lattices of 2D materials, strained by nanopillars indentation and microelectromechanical systems (MEMS), using Raman and photoluminescence (PL) spectroscopy. From nanopillars strained multilayer MoS_2, we observe exciton and charge carrier funneling due to strain, inducing dissociation of excitons in to free electron-hole pairs in the indirect material. Using MEMS devices, we were able to dynamically strain monolayer and multilayer graphene. Multilayer graphene under MEMS strain showed signatures of loss in Bernal stacking due to shear of the individual layers, indicating that MEMS can be used to tune the layer commensuration with tensile strain. We further explore simulation of pseudo-magnetic fields (PMFs) generated in monolayer graphene strained by MEMS, using machine learning, to accelerate and optimize the strength and uniformity of the PMF in new graphene geometries. Nanopillars provide non-uniform, centrally biaxial strain to multilayer MoS_2 transferred on top. Raman E^1_2g and PL redshift across the pillar confirms 1-2% strain in the material. We also observe a softening in the A_1g Raman mode and an enhancement in the overall PL with an increase in radiative trions, under strain. The changes in these charge-dependent features indicates funneling of charge carriers and neutral excitons to the apex of the pillar, as strain locally deforms the band structure of the conduction and valence bands. DFT calculations of the band structure in bilayer MoS_2 under biaxial strain shows the conduction band is lowered, further increasing the indirectness of multilayer MoS_2. This should cause the PL intensity to decrease, whereas we observe an increase in MoS_2 PL intensity under strain. We theorize that this is due to a dissociation of excitons into free electron-hole pairs. The increase in charge carrier densities due to strain leads to a renormalization of the local band structure and increased dielectric screening, supporting free electron-hole recombination at the K-point without momentum restrictions. In turn, electron-hole recombination occurs around the K-point inducing a high intensity PL, which opens attractive opportunities for utilization in optoelectronic devices. MEMS chevron actuators can dynamically strain 2D materials, which we demonstrate through uniaxial strain in CVD and exfoliated graphene. We use a novel microstructure assisted transfer technique which can deterministically place materials on non-planar surfaces like MEMS devices. Building on previously reported 1.3% in monolayer MoS2 from our group, we report tunable 0.3% strain in CVD monolayer graphene and 1.2% strain in multilayer exfoliated graphene using MEMS chevron actuators, detected by Raman spectroscopy. The asymmetric-to-symmetric strain evolution of the 2D phonon line shape in multilayer graphene is evidence of changes in interlayer interactions, caused by shearing between layers. This demonstrates that MEMS can be used to tune the commensuration in few layer 2D materials, which is a promising avenue towards Moiré engineering. Using machine learning, we also simulate optimal monolayer graphene geometries for generating strong, uniform pseudo-magnetic fields by MEMS strain. The coupled use of finite-element methods, variational auto-encoder, and auxiliary neural network accelerates the search for PMFs in strained graphene, while optimizing the graphene shape for fabrication through electron-beam lithography. Our experimental and simulated work creates a road-map for rapid advancement in zero-field quantum Hall effect devices using graphene-integrated MEMS actuators.

In this work a review of the technology surrounding high deflection strain sensing with an emphasis on that of a recently developed nickel nano-composite strain sensor is presented. A new base silicone material was identified for the nickel nano-composite strain sensor that improves its mechanical stiffness and conductive properties. A previously identified cyclic creep concern was mitigated through preconditioning and the use of adhered backing materials. Through a block design experiment the strain/resistance curves for the strain sensors were characterized over a wide range of nano-filler material compositions. An analytical model was developed based on observation that the resistance of the sensors follows a log-normal response with respect to applied strain. The model demonstrated high fidelity in representing the resistance-strain relationship of the sensors yielding an average R2 value of .93. A standard least squares statistical analysis confirmed strong relationships between curve fit parameters of the modified log-normal model and additive volume fractions with significance at the .05 level for each case. A suitable strain gauge composition was selected for a specific application: a fetal monitoring device. A prototype belt was developed that is worn over the abdomen to detect deflections cause by labor contractions and other fetal movements. Simulation testing on the device was performed and the device was found to be a feasible option for fetal monitoring.

Biological tissues routinely experience large strains and undergo large deformations during normal physiologic activity. Biological tissue deformation is well beyond the range of standard strain gauges, and hence must often be captured using expensive and non-portable options such as optical marker tracking methods that may rely upon significant post-processing. This study develops portable gauges that operate in real time and are compatible with the large strains seen by biological materials. The new gauges are based on a relatively new technique for quantifying large strain in real-time (up to 40 %) by use of a piezoresistive nano-composite strain gauge. The nano-composite strain gauges (NCSGs) are manufactured by suspending nickel nanostrands within a biocompatible silicone matrix. The conductive nickel filaments come into progressively stronger electrical contact with each other as the NCSG is strained, thus reducing the electrical resistance that is then measured using a four-probe method. This thesis summarizes progress in the understanding, design and application of NCSGs for biomechanical applications. The advanced understanding arises from a nano-junction-level finite element analysis of gap evolution that models how the geometry varies with strain in the critical regions between nickel particles. Future work will incorporate this new analysis into global models of the overall piezoresistive phenomenon. The improvements in design focused on the manufacturing route to obtain a reliable thin and flexible gauge, along with a modified connection and data extraction system to reduce drift issues that were present in all previous tests. Furthermore, a pottable data logging system was developed for mobile applications. Finally, a method of analyzing the resultant data was formulated, based upon cross-correlation techniques, in order to distinguish between characteristic wave-forms for distinct physical activities. All of these improvements were successfully demonstrated via a gait-tracking system applied to the insole of standard running shoes.

Thesis advisor: Seth C. Kruckenberg / In the earth’s lithosphere there exists both homogeneous and heterogeneous deformation on a variety of scales. The lower crust specifically plays a critical role in lithospheric deformation; however, the lower crust does not deform homogenously but rather heterogeneously in space and time. One of the best avenues for addressing heterogeneous lower crustal deformation is through an integrated study of shear zones. While many studies have identified factors such as strain rate and temperature as key actors in lower crustal strain localization, more studies are needed to characterize the dominant grain-scale mechanisms that accommodate the development of lower crustal shear zones. The primary aim of this research is to investigate the dominant mechanisms that lead to strain localization in the lower crust. The Capricorn Ridge Shear Zone (CRSZ), Central Australia, is an ideal location for study because it is a lower crustal shear zone that contains discrete zones of strain localization, primarily adjacent to major lithological boundaries. Previous studies conclude that competency contrast caused strain to localize at the lithologic boundaries of the CRSZ, a hypothesis that is tested in this study. Using microstructural, textural, and rheologic analysis, as well as field-based mapping and grain size piezometry, this study finds that differential stresses in Capricorn Ridge range from 17-27 MPa for quartz, 31-42 MPa for plagioclase, and 2.8-7.6 MPa for enstatite. Monophase aggregate strain rates range from 1.6 x 10-15 to 1.7 x 10-14 s-1 for quartz, 4.5 x 10-15 to 3.3 x 10-14 s-1 for plagioclase, and 6.0 x 10-20 to 1.2 x 10-18 s-1 for enstatite; corresponding effective viscosities 0.3-1.7 x 1021 Pa.s, 0.3-1.5 x 1021 Pa.s, and 0.2-1.8 x 1025 Pa.s for quartz, plagioclase, and enstatite, respectively. Data across the CRSZ show that while strain rate (viscosity) in monophase aggregates of quartz and plagioclase are generally similar across the shear zone, they do decrease at lithologic boundaries. In contrast to a previous study’s finding that competency contrast caused strain to localize at these boundaries, both quartz and plagioclase appear to record strain accumulation through grain size reduction. However, the observations made in previous studies are not negated by this study, as it is possible that grain size reduction in the mylonite zones near the boundaries caused strain to accumulate over time and therefore produce the observed pattern of increasing fabric intensity with proximity to the lithologic boundaries. / Thesis (MS) — Boston College, 2021. / Submitted to: Boston College. Graduate School of Arts and Sciences. / Discipline: Earth and Environmental Sciences.

Robert Mertons anomiteori har historiskt fått skarp kritik på grund av sitt svaga empiriska stöd och sina teoretiska antaganden. Vissa har dock menat att det svaga empiriska stödet beror på felaktiga operationaliseringar av Mertons teori. Den här studien syftar således till att studera operationaliseringar i tidigare forskning av Robert Mertons ursprungliga anomiteori som den presenterades år 1938 i Social Structure and Anomie. Först genomförs en noggrann genomgång och analys av artikeln Social Structure and Anomie och den teori som där presenteras. Genom en systematisk litteraturöversikt har sedan 13 artiklar som operationaliserat Mertons teori valts ut och sedan analyserats utifrån de centrala delarna av Robert Mertons paradigm. Resultaten visar att kulturellt definierade intressen nästan enbart har operationaliserats som akademiska och/eller ekonomiska mål och att de accepterade medlen operationaliserats i enlighet med de kulturellt definierade intressena. Vidare konstateras att varken anpassningsformer eller kulturperspektivet har någon framträdande plats i operationaliseringarna. / Historically, Robert Merton’s theory of anomie has suffered from harsh criticism on the basis of its weak empirical support and theoretical assumptions. Although, some have made the claim that the failing support is because of inadequate operationalization of Merton’s theory. The purpose of this study is therefore to analyze the operationalization in previous research of Robert Merton’s original theory of anomie, as it was presented in 1938 in Social Structure and Anomie. Firstly, a thorough examination and analysis is conducted on the article Social Structure and Anomie and the theory therein. Secondly, through a systematic review 13 articles that operationalize Merton’s theory were selected and then analyzed based on the core parts of Robert Merton’s paradigm. Results indicate that the culturally defined goals almost exclusively are operationalized as academic and/or economic goals and that the institutionalized means are operationalized in accord with the culturally defined goals. Furthermore, it is found that neither adaptations nor the cultural perspective have any significant place within operationalization.

This study investigates the misuse of prescription stimulants among undergraduates for a variety of different purposes, including: academic, other instrumental, and recreational. This research is important as existing literature as well as national level surveillance data indicates a substantial increase in this type of prescription drug misuse, especially among young adults aged 18-25. Drawing from several theoretical frameworks, this research focuses on how academic strain, social norms, and gender influence prescription stimulant misuse among undergraduates. Roughly 900 quantitative surveys were collected that specifically address undergraduate prescription stimulant misuse. The results indicate that college students are at an increased likelihood of misusing prescription stimulants if they experienced academic impediments and/or grade strain during the past academic year. Additionally, the findings show that undergraduates who have accepting attitudes of prescription stimulant misuse and who have peers that misuse prescription stimulants are also at an increased likelihood of misusing prescription stimulants. Furthermore, males were at an increased likelihood of prescription stimulant misuse for academic purposes if they had experienced grade strain during the past academic year in comparison to their female counterparts. Female undergraduates, on the other hand, were four times more likely than male undergraduates to obtain prescription stimulants from their close friends for free.