The Late Neogene represents warm Earth conditions immediately prior to the development of extensive northern hemisphere glaciation, and this period in Earth history may therefore provide the best available analog for the projected outcome of continued global warming. There are few interior continental sites of Late Neogene age from the eastern half of North America and subsequently very little is known about the conditions characterizing climate. The Early Pliocene (~ 5 Ma) Pipe Creek Sinkhole (PCS) includes the sediment fill of a complex karst environment that developed in north-central Indiana, USA (Lat. 40° 27′ 25.4″, Long. 85° 47′ 37.2″). The site includes more than 3 m of high-chroma, red-colored silty-clay sediment interpreted to be terra rossa. The terra rossa δ13C values average - 20 ± 0.7‰ PDB and are interpreted to represent sediment deposited in a closed cave system under high summer temperatures and with well-drained soils. An in-situ paleosol at the top of the terra rossa represents a transition from a closed cave to an open environment that eventually flooded, thereby becoming a small pond. δ13C values from lacustrine sediments with organic matter derived dominantly from algae average - 20.6‰ and suggest the pond was stagnant and enriched with bicarbonate from the underlying limestones or via aquifers. Pond sediments include abundant vertebrate fossils, which are broadly consistent with those inhabiting an open ecosystem such as a savannah or parkland. However, the PCS pollen includes low taxonomic diversity that is dominated by pine with some hickory and flowering plants, but no grass pollen. We propose two hypotheses to explain the PCS stratigraphic record: (1) The pollen assemblage may represent a local pine dominated ecosystem associated with the pond paleoenvironment, such as a riparian community, and that the greater landscape was drier and open; (2) Alternatively, the climate may have became wetter raising the elevation of the groundwater table and initiating the formation of the pond. Then in response to the wetter conditions an early succession forest ecosystem developed.

Diverted from its former course to the Pacific Ocean by basalt flows in Gem Valley, Idaho, the Bear River presently flows south into the Bonneville Basin. Constraining the timing of the river's diversion is pivotal to understanding the hydrologic budgets, and thus the climatological implications of the Bonneville Basin lakes. This study employs strontium (Sr) isotopes in mollusc fossils as a tracer of the Bear River water that entered Lake Thatcher, a small, closed-basin lake into which the redirected river flowed en route to the Bonneville Basin. The Sr ratios, combined with the temporal control afforded by amino acid geochronology and tephrochronology, were compared to mixing models constructed from the 87Sr/86Sr composition of the modern rivers draining into the basin to stimulate the Sr isotropic composition of Lake Thatcher. Strontium ratios of six fossil molluscs collected from the lower-most exposed section of the Main Canyon Formation (MCF) indicate that during the early Quaternary (>620 ka), Thatcher Basin was occupied by a locally fed, isotopically-enriched (87Sr/86Sr=0.71309) lake and did not receive input form the Bear River. Eleven fossils, collected from the uppermost exposed section of the MCF, indicate at least three course changes of the Bear River in the late Quaternary: diversion into the basin around 140 ka, diversion from the basin sometime between 140 and 100 ka, and finally diversion back into the basin around 50 ka. Hydrologic modeling of Thatcher Basin with and without the input of the Bear River suggests that water from both a Bear River-influenced or a locally fed lake is capable of filling the basin and causing it to spillover into the adjacent Bonneville Basin. Thus, the Bonneville Basin may have been receiving water from either the Bear River, or the Thatcher Basin rivers, significantly earlier than the ~30 ka previously proposed. Additional hydrologic modeling in Thatcher Basin suggests that a two-fold reduction in the effective precipitation as compared to modern conditions would be required to lower a locally fed Lake Thatcher the ~30 m necessary to account for the paleosol exposed in the uppermost MCF.

Magister Philosophiae - MPhil / Microplastics (MPs) are an emerging micro-pollutant that pose a threat to the ecological integrity of freshwater rivers and wetlands. Most previous work on MPs pollution has focused on marine environments. This study aimed to investigate the spatial distribution and abundance of MPs particles in the bed sediment of a freshwater coastal lake in the Zeekoevlei Nature Reserve, Cape Town, which is fed by rivers and stormwater outlets draining a heavily urbanized environment. The first objective was to characterize the spatial distribution of MPs across the lakebed environment, in relation to possible point and non-point sources of contamination.

No description available.

No description available.

Thesis advisor: Noah Snyder / Rivers impounded by dams experience morphological changes that provide an opportunity to calculate reservoir sedimentation rates and relate them to watershed land-use history. In April 2023, 10 sediment cores were collected from 5 locations in Lake Seminole, Georgia. Analysis of loss on ignition (LOI), bulk density, elemental concentrations, and short-lived radionuclide geochronology aided in completing the following research objectives: correlating short and long sediment cores, determining whether the pre-dam sediment surface was reached at each location, measuring the sedimentation rates in the Chattahoochee and Flint arms of the reservoir, and evaluating the characteristics of each core in the context of its location and the history of Lake Seminole. This research explores how differences in river management, land use, and upstream geology in the watersheds have contributed to sedimentation differences in the Chattahoochee and Flint Rivers. / Thesis (BS) — Boston College, 2024. / Submitted to: Boston College. Morrissey School of Arts and Sciences. / Discipline: Earth and Environmental Sciences. / Discipline: Departmental Honors.

The Stuart Oil Shale Deposit is a major oil shale resource located near Gladstone on the central Queensland coast. It contains an estimated 3.0 billion barrels of oil in place in 5.6 billion tonnes of shale. Commissioning of a plant capable of producing 4,500 barrels per day has recently commenced. The shale is preserved in Tertiary age sediments of The Narrows Beds in the southern part of The Narrows Graben. The oil shale sequence consists of repetitive cycles composed of oil shale, claystone and lesser carbonaceous oil shale in the 400 metre thick Rundle Formation. The formation is the main oil-shale bearing unit in the preserved half-graben sequence up to 1,000 metres thick. Previous studies on the lacustrine sedimentology of the Rundle Oil Shale Deposit in the northern part of The Narrows Graben have recognised eight facies that exhibit unique and recognisable cycles. The cycles and sequence for the Kerosene Creek Member of the Rundle Formation is correlatable between the Rundle and Stuart deposits. The nature of these facies and the cycles is reviewed in some detail. In conjunction with the principles of sequence stratigraphy, the ideal oil shale cycle is described as the equivalent of a parasequence within a lacustrine system. The lacustrine parasequence is bounded by lacustrine flooding surfaces. The organic material in the oil shale consists of both Type I (algal dominated) and Type III (higher plant matter dominated) kerogen. Where Type I kerogen dominate, oil yields greater than about 100 litres per tonne are common. In contrast where Type III kerogens are dominant, yields above 100 litres per tonne are rare. The variation in oil yield is described for the Stuart lacustrine system. The variation is consequent on the balance between production, preservation and degradation of the kerogen in the parasequences within systems tracts. A system for the recognition of oil shale deposition in terms of lacustrine systems tracts is established based on oil yield assay parameters and the assay oil specific gravity. The oil yield and oil specific gravity variation within the Rundle Formation is modelled by member and the nature and distribution of oil yield quality parameters in terms of the contribution of organic and inorganic source material are described. The presence of significant oil yield (greater than 50 litres per tonne) is dependent on the dominance of lacustrine transitional systems tracts and to a lesser extent, lacustrine highstand systems tracts within the parasequence sets deposited in a balanced lake system in a generally warm wet climate during the middle to late Tertiary.

West Reflex Lake is a hypersaline lake in the Canadian Great Plains. The lake contains four types of shoreline carbonate structures: isolated pinnacles, bioherms (aggregates of pinnacles), laminated coatings, and beachrock. This study investigates the processes of formation of West Reflex Lake’s shoreline carbonates. A variety of petrographic and geochemical techniques were used to characterize the texture, mineralogy, and chemistry of the carbonates. The shoreline carbonates formed as a result of biotic and abiotic precipitation at the site of saline springs that supply Ca2+ to the lake. Evidence for biologically-influenced precipitation includes strong epifluorescence, presence of micrite cements, and abundance of microbial filaments. Abiotically-precipitated cements formed due to groundwater inflow. The isolated pinnacles and bioherms formed as a result of groundwater percolating through a framework of microbial filaments, whereas the laminated coatings formed as a result of calcification of coherent microbial mats adhering to a substrate. / May 2017

Un futur climat planétaire plus chaud avec une sècheresse plus marquée durant toute l’année est aujourd’hui prévus, en particulier pour les hautes latitudes de l’hémisphère nord. Ces changements environnementaux seraient marqués par des fréquences et des intensités plus importantes des perturbations naturelles, qui pourraient menacer l’intégrité de certains écosystèmes forestiers boréaux. L’une des conséquences prévisibles serait une augmentation significative de l’occurrence des feux de forêt qui est déjà et deviendrait davantage encore l’élément perturbateur majeur de ces écosystèmes. Le devenir des écosystèmes boréaux suscite donc de nombreuses interrogations et des incertitudes, ce qui amène à souligner la nécessité d’une bonne caractérisation des changements climatiques spatio-temporels et de leurs conséquences sur ces écosystèmes.Afin de maintenir ces paysages forestiers dans les limites de leur variabilité naturelle, le Ministère des Forêts, de la Faune et des Parcs du Québec (MFFP) se propose, dans un contexte d’aménagement écosystémique durable, d’établir un Registre des états de référence. Dans cette perspective, l’objectif de recherche de cette thèse était de produire des reconstitutions des paléotempératures holocènes les plus robustes possibles au sein de la pessière à mousses de l’ouest du Québec. La recherche a porté sur une approche multi-indicateurs incluant les Chironomidae et le pollen contenus dans les sédiments des deux lacs retenus. Les résultats mettent en évidence la pertinence des capsules céphaliques de Chironomidae pour reconstituer à haute résolution temporelle, les paléotempératures holocènes du mois d’août provenant du Lac Aurélie à l’aide de deux Fonctions de Transfert (FT). La FT Est canadienne s’est avérée plus en accord avec le signal régional que la FT canadienne. De surcroit, les assemblages de Chironomidae du Lac Lili ont donné une reconstitution surestimée des paléotempératures en raison de la faible profondeur de ce lac. Enfin, la reconstitution quantitative combinée (Chironomidae et pollen) des paléotempératures du mois d’août a souligné trois périodes principales: (i) 8500-4500 ans AA, identifiée comme le Maximum Thermique de l’Holocène (HTM) durant laquelle les températures d’août sont plus chaudes que les températures actuelles; (ii) 4500-1000 ans AA, marquée par le début de la période Néoglaciaire froide, où les températures oscillent autour des valeurs actuelles et (iii) les derniers 1000 ans AA, caractérisés par une diminution générale des températures. Plusieurs événements climatiques courts ont également été identifiés pour chaque période : (i) l’évènement froid de 8200 ans AA; (ii) l’évènement chaud de 4200 ans AA; (iii) la période chaude dite Romaine (RWP, 1900-1700 ans AA) ; (iv) la période froide de l’Âge Sombre (DACP, 1700-1500 ans AA) ; (v) l’Anomalie Climatique Médiévale (MCA, 1100 ans AA) et (vi) le Petit Âge Glaciaire (LIA, 500-250 ans AA). Une série d’événements froids est également observée vers 5900, 4300, 2800 et 400 ans AA, se référant probablement aux évènements « Bond ». La durée et l’amplitude observées des événements climatiques rejoignent les enregistrements régionaux, nord-américains et plus largement ceux de l’Hémisphère Nord. Par ailleurs, la synthèse soulignant les relations entre climat-végétation-feu confirme l’influence d’une instabilité climatique sur les changements des régimes des feux, principalement causée par les variations saisonnières des précipitations et de l'irrégularité des épisodes de sécheresse. Toutefois, notre reconstitution combinée des paléotempératures indique que les grands feux coïncident avec l’évènement ponctuel de 4200 ans AA et ceux survenus à partir de 2000 ans (RWP, DACP, MCA et LIA). La température estivale conjuguée à d’autres variables climatiques (sécheresse estivale, ensoleillement estival, et précipitations annuelles) joue donc un rôle important dans la variation du régime des feux à l’ouest du Québec. / A future warmer global climate with more severe annual drought has been predicted, especially for the high latitudes of the Northern Hemisphere. Such an environmental change would be marked by higher frequencies and intensities of natural disturbances, which could threaten the integrity of some boreal forest ecosystems. One of the foreseeable consequences would be a significant increase in the occurrence of wildfires, which is already the major disruptive element of these ecosystems. The future of boreal ecosystems thus raises many questions and uncertainties, highlighting the need for a good characterization of spatio-temporal climate changes and its consequences on these ecosystems.In order to maintain these forest landscapes within the limits of their natural variability, the Ministère des Forêts, de la Faune et des Parcs du Québec (MFFP) proposes, in a context of sustainable ecosystem management, to establish a registry of reference states. In this perspective, the research objective of this thesis was to produce the most possible robust reconstructions of Holocene temperatures within the spruce-moss forest of western Québec. The research focused on a multi-indicator approach including Chironomidae and pollen deposited in the sediments of two selected lakes.The results highlight the relevance of Chironomidae head capsules to reconstruct at high temporal resolution the August Holocene temperatures from Lac Aurélie using two Transfer Functions (TF). The East Canadian TF was more in agreement with the regional signal than the Canadian TF. In addition, chironomid assemblages from Lac Lili gave an overestimated paleotemperature reconstruction due to the specific shallowness of this lake. Finally, the combined quantitative reconstruction (Chironomidae and pollen) of the August palaeotemperatures suggested three distinct periods: (i) 8500-4500 years BP, identified as the Holocene Thermal Maximum (HTM) during which the August temperatures are warmer than modern temperatures; (ii) 4500-1000 cal BP, marked by the beginning of the cold Neoglacial period, where the temperatures oscillate around the current values and (iii) the last 1000 cal BP, characterized by a general decrease of the temperatures. Several short climatic events were also identified for each period: (i) the 8200 cal BP cold event; (ii) the 4200 cal BP warm event; (iii) the Roman Warm Period (RWP, 1900-1700 cal BP); (iv) the Dark Age Cold Period (DACP, 1700-1500 cal BP); (v) Medieval Climate Anomaly (MCA, 1100 cal BP) and (vi) the Little Ice Age (LIA, 500-250 cal BP). A series of cold events is also observed around 5900, 4300, 2800 and 400 cal BP, probably corresponding to the "Bond" events. The observed duration and amplitude of climate events are consistent with regional, North American records, and more widely those of the Northern Hemisphere. In addition, the synthesis highlighting climate-vegetation-fire relationships confirms the influence of climatic instability on changes in fire regimes mainly driven by seasonal variations in rainfall and frequency of drought events. However, our paleotemperatures combined reconstitution indicated that large fires coincide with the occasional event of 4200 cal BP and those occurring from 2000 cal BP onwards (RWP, DACP, MCA and LIA). Summer temperatures combined with other climatic variables (summer drought, summer insolation, and annual precipitation) play an important role in the variation of the fire regime in western Québec.

Na costa do leste do Brasil, destacam-se importantes acumulações de carbonatos lacustres do Cretáceo (Aptiano) relacionadas à fase de rift que precede a abertura do Oceano Atlântico, estes carbonatos consistem principalmente em espessos pacotes de bivalves associados a sedimentos siliciclásticos finos. Na bacia de Campos este intervalo equivale a Formação Coqueiros e é portador de hidrocarbonetos sendo reservatório nos campos de Badejo, Linguado, Pampo e Trilha. Estes reservatórios são o foco deste estudo, que teve como objetivo aprofundar o conhecimento desses depósitos através da análise das fácies e associações de fácies para definição de sequências seguindo a compreensão atual dos conceitos de estratigrafia de sequência. Foram descritos testemunhos de poços associados a análise de dados de perfil e sísmica através das quais foram definidas dezesseis fácies. A classificação das fácies utilizou critérios sedimentológicos associados a conceitos tafonômicos o que permitiu a intepretação dos processos sedimentares envolvidos em sua deposição Estas fácies foram agrupadas em associações de acordo com gradiente hidrodinâmico de uma plataforma dominada por ondas o que permitiu a interpretação dos padrões de empilhamento e definição de tratos de sistema transgressivos e regressivos. Foi proposto um ciclo ideal de alta frequência com a sucessão esperada de fácies para cada trato que serviu de base para interpretação de sequências de alta e média frequência. Esta análise permitiu a definição de três sequências internas no intervalo conhecido como Coquina Inferior, correlacionadas entre os poços que possuíam a melhor amostragem do intervalo permitindo assim analisar a variação vertical e lateral de fácies. A metodologia proposta permite a intepretação da estratigrafia em uma escala de maior detalhe auxiliando a interpretação da ocorrência de fácies e sua distribuição espacial na escala de dezenas a centenas de metros. Este tipo de análise é importante para desenvolvimento da produção de campos de hidrocarbonetos sendo útil na construção de modelos geológicos. Pode ser aplicável a ambientes análogos com similaridades quanto à composição das rochas e os processos envolvidos em sua deposição, como a Formação Itapema análoga na Bacia de Santos. / On the eastern Brazilian coast there is an important accumulation of Cretaceous lacustrine carbonates linked to the rift phase, which precedes the opening of the Atlantic Ocean. These carbonates consist mainly of bivalve packages associated with fine siliciclastic sediments. In the Campos Basin this interval is denominated Coqueiros Formation and constitutes a hydrocarbon reservoir in the fields of Badejo, Linguado, Pampo and Trilha. These reservoirs are the focus of this study, which aimed to detail the knowledge of these deposits through the analysis of facies and their associations in order to define sequences according to the present understanding of sequence stratigraphy concepts. Core samples description, well logs and seismic data analyses have been carried out, allowing the definition of sixteen facies. The facies classification was based on sedimentary characteristics associated with taphonomic concepts that allowed the interpretation of sedimentary processes involved in the deposition. These facies were grouped in associations according to a hydrodynamic gradient of a wave-dominated platform, which allowed the interpretation of stacking patterns and the definition of both transgressive and regressive system tracts It was proposed an ideal high frequency cycle with the facies succession from each tract which was used for the interpretation of high and medium frequency sequences. This analysis allowed the definition of three internal sequences in the so-called Lower Coquina Interval correlated among the best sampled wells, and the analysis of vertical and lateral variation of facies. The proposed methodology allows the interpretation of the stratigraphy in a small scale contributing to the interpretation of the occurrence of facies and their spatial distribution in a scale of tens to hundreds of meters. This type of analysis is important for the development of production in a hydrocarbon field and is useful for the construction of geological models and is applicable to similar environments with same composition of the rocks and similarities in the processes involved in their deposition, such as the Itapema Formation in the Santos Basin.